Patents Assigned to Ashland Oil, Inc.
  • Patent number: 4783518
    Abstract: A rapid curing composition comprising a mixture of (A) a polyepoxide and an amine curing agent and (B) a novel thiocyanate salt of the reaction product of an alkylene polyamine, such as ethylene diamine, and a bicyclic amide acetal and a method for curing said composition are described.
    Type: Grant
    Filed: September 28, 1987
    Date of Patent: November 8, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4780195
    Abstract: The invention is particularly concerned with controlling the two stage regeneration temperatures of the RCC residual oil cracking unit below 760.degree. C. (1400.degree. F.) by effecting a first stage regeneration with direct injection of water in an oxygen lean atmosphere to product CO rich flue gases under temperature conditions restricted not to substantially exceed 732.degree. C. (1350.degree. F.) preferably less than 732.degree. C. (1350.degree. F.) thereby partially regenerating the catalyst. The partially regenerated catalyst is withdrawn and directly cooled with boiler feed water to produce steam in an external catalyst cooler before passing the catalyst to a second stage catalyst regeneration for contact with an oxygen rich atmosphere restricted not to exceed 760.degree. C. (1400.degree. F.) and preferably maintain less than 760.degree. C. (1400.degree. F.). The catalyst regenerated by this technique comprising residual coke less than 0.
    Type: Grant
    Filed: July 25, 1983
    Date of Patent: October 25, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Charles B. Miller
  • Patent number: 4780568
    Abstract: A process for separation of methacrylic acid from methacrylic acid-isobutyric acid mixtures involving the selective crystallization and removal of the methacrylic acid from said mixtures is decribed.
    Type: Grant
    Filed: October 19, 1987
    Date of Patent: October 25, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Ralph F. Pascoe
  • Patent number: 4780489
    Abstract: The subject invention relates to modifiers for aqueous basic solutions of phenolic resins. The modifiers are open-chain ether alcohols or ketone alcohols. They assist in stabilizing the aqueous basic solutions of phenolic resole resins and improve the tensile strength of foundry shapes prepared from foundry mixes made with the aqueous basic solutions.
    Type: Grant
    Filed: May 15, 1987
    Date of Patent: October 25, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: William R. Dunnavant, Robert B. Fechter, Gary R. Hysell, Young D. Kim, Heimo J. Langer
  • Patent number: 4780526
    Abstract: Polymeric cyclopentadiene derivatives, method for preparing polymeric cyclopentadiene derivatives, and use of polymeric cyclopentadiene derivatives in curable binder compositions.
    Type: Grant
    Filed: October 14, 1986
    Date of Patent: October 25, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Bruce A. Gruber, Heimo J. Langer, William R. Dunnayant
  • Patent number: 4780109
    Abstract: Disclosed is a composition and method from making coal water slurries containing carbon black. A composition disclosed comprises: 65 to 85% by weight coal particulates; 0.2 to 2% by weight, based on the total weight of dry coal, of carbon black, and optionally 0.2 to 2% by weight, based on the total weight of the dry coal, of a dispersant.
    Type: Grant
    Filed: December 24, 1986
    Date of Patent: October 25, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Donald P. Malone, David G. Thompson
  • Patent number: 4775734
    Abstract: A curable composition comprising a polyepoxide, an amine curing agent and a catalytic amount of a non-nucleophilic acid salt of an amine having the formula R(R')(R")NH.sup.+ X.sup.- wherein R, R' and R" independently represent an alkyl group having from 1 to 20 carbon atoms, an alkaryl group having from 7 to 20 carbon atoms or an oxyalkylene group having from 2 to 50 carbon atoms and wherein R' and R" independently also may represent hydrogen and R may also represent the formula [--Y--(R')(R")NH.sup.+ X.sup.- ].sub.n wherein R' and R" have the foregoing designations, Y represents an alkylene or alkylene ether group having from 2 to 50 carbon atoms and n represents an integer of from 1 to 5 is described.
    Type: Grant
    Filed: August 12, 1987
    Date of Patent: October 4, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4775735
    Abstract: A moisture curable composition comprising a mixture of(A) a polyepxoide(B) a polyimine curing agent and(C) an amine thiocyanate salt cure accelerator,and a process for curing said composition in an atmosphere having a relative humidity of from about 20% to about 90% at a temperature in the range of from about 15.degree. C. to about 150.degree. C. are described.
    Type: Grant
    Filed: October 7, 1987
    Date of Patent: October 4, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4775737
    Abstract: A process for the preparation of a thermoset polymer having good adhesive properties comprising reacting a compound containing a plurality of oxazoline groups with an alkenyl phosphonic acid at a temperature of from about room temperature to about 300.degree. C. is described.
    Type: Grant
    Filed: March 6, 1987
    Date of Patent: October 4, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4775728
    Abstract: An adhesive composition which results from the mixture of two components, the first component comprising a polyepoxide and the second component comprising a finely dispersed solid salt of a polyamine and a polyphenol in a liquid adduct of a poly(alkylene oxide) polyamine and a polyphenol and the use of this non sagging, high performance adhesive in structural applications is described.
    Type: Grant
    Filed: February 24, 1987
    Date of Patent: October 4, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4772490
    Abstract: The invention relates to a method for producing a water-permeable covering on granular, water-soluble substances by coating them with a synthetic resin. The method of the invention uses a coating composition which comprises a polyisocyanate and a polyol component of a condensation product from phenols and aldehydes, a softener containing hydroxyl groups and optionally a diluent containing hydroxyl groups. The coating composition is cured at room temperature with an amine as a catalyst.
    Type: Grant
    Filed: December 16, 1986
    Date of Patent: September 20, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Hubert Kogler, Reinhard Winter, Peter Kuhlmann
  • Patent number: 4771946
    Abstract: Disclosed are modified spray guns, particularly electrostatic spray guns, for implementation of the vaporous amine catalyst spray method disclosed in U.S. Pat. No. 4,517,222. In particular, the present invention broadly is directed to a spray gun for spraying atomized liquid, e.g. vapor permeation curable paint, with the assistance of a vaporous amine flow via an amine flow path established in the spray gun wherein the improvement comprises a control apparatus actuable in the absence of the vaporous amine flow to cause a heated non-amine gas, preferably heated air, to flow through and purge the amine flow path within the gun for maintaining a desired flow path temperature adequate for suppressing amine condensation in the flow path. The spray gun can be a hand spray gun or an automated spray gun utilizing air atomization or mechanical atomization, operating under electrostatic spray conditions if desired.
    Type: Grant
    Filed: November 13, 1986
    Date of Patent: September 20, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Timothy Y. Moy, Jeffery W. Radcliff
  • Patent number: 4771102
    Abstract: Thermoset polymers are prepared by reacting an ethylenically unsaturated resin monomer and a bicyclic amide acetal with a polyisocyanate in the absence or presence of a vinyl monomer. Reaction rates are suitable for effecting RIM processing. The resultant polymers exhibit improved impact resistance. Further variation in physical properties can be achieved through the use of a diol chain extender for the polyisocyanate.
    Type: Grant
    Filed: August 5, 1987
    Date of Patent: September 13, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Anil B. Goel, Timothy A. Tufts, Joseph G. Holehouse
  • Patent number: 4766949
    Abstract: The subject invention relates to a hot box process for forming foundry shapes. The foundry shapes are formed with a mixture of an aggregate and certain aqueous basic solutions of phenolic resole resins which act as binders. The use of these binders results in foundry shapes which are cured by heating at elevated temperatures without requiring an acid-generating curing catalyst.
    Type: Grant
    Filed: May 8, 1987
    Date of Patent: August 30, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Satish S. Jhaveri, William R. Dunnavant, James T. Schneider
  • Patent number: 4766201
    Abstract: The process for preparing hydroxy alkyl amide thio ethers by the reaction of a bicyclic amide acetal with a thiol is described.
    Type: Grant
    Filed: January 20, 1987
    Date of Patent: August 23, 1988
    Assignee: Ashland Oil Inc.
    Inventor: Anil B. Goel
  • Patent number: 4766196
    Abstract: A rapid curing epoxy resin composition comprising a mixture of(A) A first component comprising a polyepoxide and(B) A second component comprising a mixture of the novel reaction product of(1) an ammonium salt of a non-nucleophilic acid with(2) the reaction product of(a) a bicyclic amide acetal with(b) an amine, and(3) an amine curing agent, is described.
    Type: Grant
    Filed: August 14, 1987
    Date of Patent: August 23, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Anil B. Goel, Teresa A. DeLong
  • Patent number: 4762883
    Abstract: A solution of a non-reactive polymer in a liquid oxazoline which may include a reactive additive such as a polyisocyanate to provide solid polymers by interpolymerization of the oxazoline and reactive additive are described.
    Type: Grant
    Filed: May 6, 1985
    Date of Patent: August 9, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil Goel
  • Patent number: 4762864
    Abstract: An adhesive composition which is curable by electromagnetic induction heating when it is applied to various substrates, said adhesive comprising a mixture of(I) An epoxy resin component and(II) A hardener component and(III) From 2 to 60% by weight of (I) and (II) of an electromagnetic energy absorbing material is described.
    Type: Grant
    Filed: June 19, 1986
    Date of Patent: August 9, 1988
    Assignee: Ashland Oil Inc.
    Inventors: Anil B. Goel, Joseph G. Holehouse, Jeffrey P. Jones, Teresa DeLong
  • Patent number: 4761466
    Abstract: An adhesive composition comprising a mixture of a polyepoxide, an amine curing agent and a thiocyanate salt of a compound having the formula ##STR1## wherein R represents an alkyl group having from 1 to 20 carbon atoms, an aryl group having from 6 to 20 carbon atoms or an alkaryl group having from 7 to 20 carbon atoms, R', R" and R'" independently represent hydrogen, an alkyl group having from 1 to 10 carbon atoms or an alkyl ether group having from 1 to carbon atoms and n represents 2 or 3 is described.
    Type: Grant
    Filed: August 12, 1987
    Date of Patent: August 2, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4760178
    Abstract: A process for producing compounds containing hydroxy alkyl amide groups by the reaction of a bicyclic amide acetal with a member selected from the group consisting of urea, biuret, thiourea, thiobiuret, alkyl substituted ureas, aryl substituted ureas, alkyl substituted thioureas, aryl substituted thioureas, alkylene ether ureas, arylene ether ureas, alkylene ether tioureas and arylene ether thioureas is disclosed.
    Type: Grant
    Filed: April 11, 1986
    Date of Patent: July 26, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel