Abstract: A thermoprocessable copolymer of TFE essentially formed by:
(a) from 4.5 to 8.5% by weight of perfluoromethylvinylether (PMVE);
(b) from 0.3 to 1.6% by weight of a perfluorodioxole of formula:
wherein:
Y═F, ORf, Rf wherein Rf is a perfluoroalkyl having from 1 to 5 carbon atoms;
X1 and X2, equal to or diferent from each other, are —F or —CF3;
(c) TFE, forming the remaining part to 100%.
Abstract: Use as preservative in formulations for topical use containing water of a component A): a (per)fluoropolyether phosphate of general formula:
Rf—[CF2CH2—Q—L—P(O) (OZ1) (OZ2)]l (I)
wherein l=1 or 2; L is a bivalent linking group; Z1 equal to or different from Z2 selected from H, alkaline or ammonium cation, di- or tri-alkanolammonium cation, di- or tri- or tetra-alkylammonium cation; Rf is a (per)fluoropolyether chain having number average molecular weight in the range from about 400 to about 1,800.
Abstract: Metal substrates having a coating based on ethylene/chlorotrifluoroethylene (E/CTFE) having a TmII of 230° C.-264° C. and a MFI lower than 5 g/10′.
Type:
Application
Filed:
August 1, 2002
Publication date:
February 13, 2003
Applicant:
AUSIMONT S.p.A.
Inventors:
Julio A. Abusleme, Giambattista Besana, Claudia Manzoni
Abstract: Mixtures of fluoropolymer dispersion, wherein:
a) a dispersion is formed by TFE (co)polymers with average particle sizes in the range 180-400 nm;
b) another dispersion selected from:
1) (co)polymer dispersion of TFE;
2) thermoplastic copolymers of TFE;
the average particle sizes of dispersion b) range from 20 to 60 nm;
the ratio between the particle sizes of dispersion b) compared with those of dispersion a) is lower than 0.3.
Type:
Grant
Filed:
June 30, 1999
Date of Patent:
February 11, 2003
Assignee:
Ausimont S.p.A.
Inventors:
Mario Visca, Daria Lenti, Marco Malvasi, Enrico Marchese
Abstract: Use of fluorinated compounds to confer release properties to cellulosic substrata, selected from the following structures:
(A) [Rf—CFY—L—O]mP(O) (O−Z+)3−m
(B) (O−Z+)2P(O)[O—L—YFC—O—Rf—CFY—L—O—P(O) (O−Z+)]m′——[O—L—YFC—O—Rf—CFY—L—O]P(O) (O−Z+)2
(C) Fluorinated (meth)acrylic copolymers
(D) [Rt—CF2—SO2N(U1) (U2) —O]g—P(O) (OZ)3−g
wherein: m′ is an integer from 0 to 20; L is an organic group selected from —CH2—(OCH2CH2)n—, —CO—NR′—(CH2)q—, with R′═H or C1-C4 alkyl group; n=0-8, q=1-8; Z═H, alkane metal or a NR4 group with R═H or C1-C4 alkyl group; Y═F, CF3; m=1,2,3;
Rf is a perfluoropolyether radical;
Rt is a linear or branched perfluorocarbon radical having from
Type:
Grant
Filed:
February 28, 2001
Date of Patent:
February 4, 2003
Assignee:
Ausimont S.p.A.
Inventors:
Gabriella Carignano, Mattia De Dominicis
Abstract: A gaseous process for reducing the amount of chloropentafluoroethane (CFC 115) impurity present in pentafluoroethane (HFC 125) characterized in that pentafluroethane is allowed to flow on a catalyst formed by a trivalent chromium salt, optionally supported, at temperatures in the range 200° C.-400° C., obtaining the reaction of chloropentafluoroethane with pentafluoroethane with formation of hexafluoroethane (FC 116) and tetrafluorochloroethane (HCFC 124).
Abstract: Crosslinked polymer compositions obtained by subjecting to ionizing radiations compositions comprising:
I) thermoprocessable copolymers of ethylene with tetrafluoroethylene (TFE) and/or chlorotrifluoroethylene (CTFE) modified with acrylic monomers of formula:
CH2═CH—CO—O—R2 (a)
R2 is a hydrogenated radical from 1 to 20 carbon atoms, C1-C20, alkyl, linear and/or branched radical, or cycloalkyl, or R2 is H. The radical R2 can optionally contain: heteroatoms preferably Cl, O, N; one or more functional groups preferably selected from OH, COOH, epoxide, ester and ether; and double bonds;
II) one or more cross-linking agents;
III) one or more optional ingredients.
Abstract: A process for preparing perfluoropolyoxyalkylenes with hydroxyl end groups having structure:
T1—CFW1—O—Rf—CFW2—T2 (I)
wherein: T1, T2, are selected from —CH2OH, —F, —CF3, —CF2CF3 with the proviso that at least one of T1 and T2 is —CH2OH;
W1 and W2 are selected from F, CF3;
Rf is a perfluoropolyoxyalkylene chain having a number average molecular weight 500-10,000 comprising one or more units of the type —CF2CF2O—, —CF2O—, —C3F6O—, —CF2(CF2)zCF2O— (z=1,2); —CR4R5CF2CF2O— with R4 and R5 selected from H, Cl, perfluoroalkyl group; said process comprising the following steps:
a) adding an ester precursor having structure (I) and T1, T2 end groups selected from —F, —CF3, —CF2CF3, —COOR (R=linear or branched alkyl group having a number of C atoms from 1 to 5), with the proviso that at least one of T1 and T2 is —COOR, in a reaction mixture f
Type:
Grant
Filed:
December 29, 2000
Date of Patent:
January 21, 2003
Assignee:
Ausimont S.p.A.
Inventors:
Claudio Tonelli, Antonio Russo, Ezio Strepparola
Abstract: Compositions formed of aqueous dispersions comprising a mixture of the following fluorinated polymers:
A) (meth)acrylic (co)polymers containing fluorine, and
B) cationic ionomers of fluorinated polyurethanes based on (per) fluoropolyethers, the weight ratio A):B), calculated on the dry product, being in the range 70:30 and 30:70.
Abstract: Curable fluoroelastomers comprising monomeric units formed by triazine iodinated derivative having general formula:
wherein Y′ is independently H, Cl, F, CH3, or CF3, m′ and t′ are 0 or 1, and m′+t′=0 or 1, preferably m′+t′=0; p′ is an integer and is equal to 1 when t′=1, or p′=0; X′ is independently H, Cl, F, alkyl or perfluoroalkyl C1-C3, preferably F; n′ is an integer between 2 and 20, preferably between 4 and 12, more preferably between 4 and 8.
Type:
Grant
Filed:
August 9, 1999
Date of Patent:
December 31, 2002
Assignee:
Ausimont S.p.A.
Inventors:
Ivan Wlassics, Marco Apostolo, Margherita Albano
Abstract: Compositions containing core-shell particles having a core polytetrafluoroethylene-based polymers (PTFE) and shell styrene-based polymers (PS), wherein the particles contain an amount by weight of PTFE from 3 to 50%, preferably from 5 to 30% by weight, wherein the core PTFE particles have an average diameter from 5 to 100 nm, preferably from 10 to 70 nm, the core-shell particles having an average diameter from 10 to 170 nm, preferably from 20 to 100 nm.
Abstract: Amorphous (per) fluorinated polymers containing an amount lower than 0.05 mmoles/kg polymer of each of the following ionic end groups: COF, COOH, their amidic derivatives, esters or salts, when the used determination method for said end groups is the IR spectroscopy by Nicolet® Nexus FT-IR equipment (256 scannings, resolution 2 cm−1).