Abstract: Fluoropolymer aqueous dispersions comprising an hydrogenated nonionic surfactant and a fluorinated nonionic surfactant selected from the following classes:
Rf—L—(OCH(R1)—CH(R2))n—O—A (I)
wherein:
n is an integer comprised between 4 and 60;
L is selected from:
—(CF(Y)—CO—O)pR′—; —(CF(Y)—CO—NH)pR′—;
—(CF(Y)—SO2—NH)pR′—;
wherein: p is 0 or 1; Y can be F or CF3; R′ is an alkylic radical C1-C5;
R1, R2 can preferably be both H or the former H and the latter CH3,
Rf can be a radical of (per)fluoroalkane type from 4 to 20 C atoms or of (per)fluoropolyether type;
A is selected from the following ones:
—H; —CH, —CH2OH; —CH2OCH2CH2OH; —CH2(OCH2CH2)n′″OR′ wherein n′″ is an integer between 2 and 15 and R′ is H, CH3, COCH3; —CONHCH2CH2OH.
Abstract: Use of fluorine containing polymers for the preparation of high dry formulations wherein the fluorine containing polymers are based on fluoropolyethers comprising a fluorine containing part RF and optionally an hydrogenated part RH, the bonds joining the fluorine containing part to the hydrogenated one being an ether —C—O—C—, bond the terminals T being such as to render the structure bi or polyfunctional, making thus possible the cross-linking reaction, the hydrogenated part RH not containing groups capable of linking by means of hydrogen bonds to basic acceptors.
Abstract: A reductive dimerization process of 1,1,1-trifluoro, 2,2,2-trichloroethane (CFC-113a) with hydrogen, with formation of 1,1,1,4,4,4-hexafluoro-2,2,3,3-tetrachlorobutane and 1,1,1,4,4,4-hexafluoro-2,2-dichlorobutene, and mixtures thereof, wherein the catalyst is constituted by metal ruthenium supported on graphitized carbon obtainable by treatment of the carbon at temperatures higher than 2000° C., in inert gas, or aluminum fluoride having an high surface area.
Type:
Grant
Filed:
February 2, 2000
Date of Patent:
February 19, 2002
Assignee:
Ausimont S.p.A.
Inventors:
Paolo Cuzzato, Ornella Majaron, Francesco Pinna
Abstract: Use of fluorinated polyurethanes thermally crosslinkable for obtaining coatings having an improved friction coefficient for the dry lubrication of rubbers, plastics, metals, glass, said polyurethanes obtainable from aqueous dispersions of cationic oligourethanes having a molecular weight ≦9,000, formed by: a) polyisocyanates, having NCO functionality higher than 2, b) bifunctional hydrogenated monomers, c) bifunctional hydroxylated (per)fluoropolyethers, e) monofunctional hydroxyl or carboxylic (per)fluoropoly-ethers or monofunctional hydroxyl (per)fluoroalkanes optionally: d) hydrogenated monomers by which it is possible to insert a crosslinkable chemical function in the oligourethane; dI) hydrogen-active compounds, able to form with the NCO functions thermolabile bonds.
Abstract: Tetrafluoroethylene (TFE) thermoprocessable copolymer microspheres having a substantially spherical shape for at least 95% by weight, the average size of the microspheres being in the range 25 &mgr;m and 2 mm, the bulk density being in the range 0.5 and 1.1 g/cm3.
Abstract: Thermoprocessable copolymer, having a Melt Flow Index (MFI) between 0.01 and 1000, of the CTFE with an acrylic monomer having the general formula:
CH2═CH—CO—O—R1 (I)
wherein R1 is a hydrogenated radical from 1 to 20 C atoms, C1-C20, alkyl, linear and/or branched, or cycloalkyl radical, or R1 is H. The radical R1 can optionally contain: heteroatoms preferably Cl, O, N; one or more functional groups preferably selected from —OH, —COOH, epoxide, ester and ether; and double bonds; the amount of the comonomer of formula (I) ranges from 0.01 to 5% by moles.
Type:
Grant
Filed:
June 2, 1999
Date of Patent:
January 29, 2002
Assignee:
Ausimont S.p.A.
Inventors:
Claudia Manzoni, Julio A. Abusleme, Massimo Malavasi
Abstract: Azeotropic or near-azeotropic composition essentially consisting of:
35-99.1% by weight of CH2F2 (R 32), difluoromethane,
0.1-65% by weight of CHF2—O—CF3, 1,1,1,2,2,-pentafluorodimethylether.
Abstract: Copolymers of perfluoro-4-alkyl-1,3-dioxoles having the general formula
wherein Rf is a perfluoroalkylic radical having from 1 to 5 carbon atoms, allow to prepare copolymers with Tg higher than those of the copolymers containing the same molar percentage of fluorinated dioxoles of the art.
Abstract: Water-based dispersions of the &egr;-phthalimido peroxyhexanoic acid comprising as stabilizers copolymers of methyl-vinyl-ether with the acid and/or maleic anhydride, in 1:1 ratio with alternated structure, usable in detergent, hygienizing, cosmetic applications.
Abstract: Fluorovinyl ethers having the formula CFX═CXOCF2OR, wherein R is a C2-C6 linear, branched or C5-C6 cyclic (per)fluoroalkyl group, or a C2-C6, linear, branched (per)fluoro oxyalkyl group containing from one to three oxygen atoms; when R is fluoroalkyl or fluorooxyalkyl group as above defined, it can contain from 1 to 2 atoms, equal or different, selected from the following: H, Cl, Br, I; X═F, H; and homopolymers or polymers obtainable polymerizing said Fluorovinyl ethers with at least another polymerizable monomer.
Abstract: Use for improving the hydro- and oil-repellence properties of substrata having a low surface energy of (per)fluoropolyether mono- and bifunctional derivatives having the structures:
Abstract: Ethylene fluoro-containing copolymers of the ECTFE and ETFE type, optionally in the presence of a third comonomer in amount comprised between 0.1 and 10% by moles, having a viscosity between 102 and 105 Pa.sec with shear rates of 1 sec−1 measured at the temperature of about 30° C. higher than the second melting temperature, and having a rheologic curve in the diagram shear viscosity/shear-rate with a slope higher than 200, calculated as ratio between the viscosity in Pa.sec and the shear-rate in sec−1 in the shear-rate range comprised between 1 and 10 sec−1, and having a processability zone with shear-rate values higher than 10 s−1.
Type:
Grant
Filed:
July 16, 1999
Date of Patent:
December 11, 2001
Assignee:
Ausimont S.p.A.
Inventors:
Julio A. Abusleme, Vincenzo Arcella, Giambattista Besana
Abstract: A process for obtaining pentafluoroethane HFC 125 by dismutation of gaseous tetrafluorochloroethane HCFC 124, at temperatures in the range 200°-300° C., on a trivalent chromium oxide (Cr2O3) catalyst, supported on aluminum fluoride, by feeding HF in such amount that the HCFC 124/HF molar ratio is in the range 10/1-1/1.
Type:
Grant
Filed:
May 11, 2000
Date of Patent:
November 27, 2001
Assignee:
Ausimont S.p.A.
Inventors:
Paolo Cuzzato, Letanzio Bragante, Francesco Rinaldi
Abstract: Curable fluoroelastomers formed from the following fluoroelastomer mixtures:
a) from 20 to 70% by weight of a fluorolastomer having the Mooney viscosity value, ML (1+10) at 121° C., of greater than 60 points and containing from 0.01 to 3% by weight of iodine;
b) from 0 to 70% by weight of a fluoroelastomer having the Mooney viscosity value, ML (1+10) at 121° C., in the range of 20-60 points and containing from 0.2 to 5% by weight of iodine;
c) from 5 to 60% by weight of a fluoroelastomer having the Mooney viscosity value, ML (1+10) at 121° C., in the range of 1-20 points and containing an iodine percentage by weight greater than 0.3; said Mooney viscosity ML (1+10) at 121° C. determined according to the ASTM D 1646 method;
where said fluoroelastomers comprise monomeric units derived from a bis-olefin.
Abstract: Fluorinated triazinic compounds having the formula:
wherein Z=T—Y, with T=—(CH2)q, —SO2, —CO, q= is an integer from 1 to 20; Y=O—, O(C2H4O)p—, O(CH2)n—NR—, O (CH2)n—O—, O(C3H6O)p—, NR—, S—, S(C2H4O)p—, S(C3H6O)p—; wherein R=H, alkyl from 1 to 10 C atoms; n is an integer from 1 to 20; p is an integer from 1 to 5; Rf represents a linear or branched fluoroalkyl chain or a (per)fluoropolyether chain. X is selected from: Cl; Rf—CF2—Z; CF3—Z. Use of these triazinic compounds or of their formulations for the treatment of natural or synthetic fiber textiles.
Type:
Grant
Filed:
March 2, 2000
Date of Patent:
November 6, 2001
Assignee:
Ausimont S.p.A.
Inventors:
Gabriella Carignano, Antonio Russo, Piero Savarino, Paolo Baratta, Mario Visca