Abstract: Aqueous dispersions of fluoropolymers containing as stabilizer from 1 to 30% by weight with respect to the fluoropolymer, of a non ionic surfactant having the following structure:
Abstract: Use in curable fluoroelastomer compositions of additives having polyacetal structure of general formula:
HOCH2—[Rf—CH2O(CH2O)cCH2]t—Rf—CH2OH (I)
wherein:
c=1-10, preferably 1-3; t=0.5-20.
Rf=poly-fluorooxyalkylenic chain, having number average molecular weight ({overscore (M)}n) in the range 500-2,500, preferably 1,000-2,000;
the number average molecular weight of the formula (I) additive is in the range 3,000-15,000, preferably 3,000-10,000.
Abstract: Process for preparing aluminum fluoride which comprises fluorination of alumina with gaseous HF, characterized in that the alumina is fluorinated with HF at an initial temperature lower than 300° C., the temperature is raised with a temperature gradient ≦100° C./hour up to the final temperature >320° C. and <450° C., fluorination is continued at the final temperature until feeding a HF molar amount at least equal to the stoichiometric with respect to the alumina, fluorination being carried out until a fluorinated alumina with a fluorine content not lower than 95% of the stoichiometric is obtained.
Abstract: A gaseous process for obtaining pentafluoroethane by dismutation of chlorotetrafluoroethane in the presence of a supported catalyst, said catalyst being formed of a mixture of trivalent chromium oxide with at least an alkaline-earth metal oxide selected from Mg, Ca, Sr and Ba.
Abstract: A composition comprising a polymer mixture A of polymers formed by:
(a) from 10 to 70% by moles of ethylene (E),
(b) from 30 to 90%, by moles of a fluorinated monomer selected from tetrafluoroethylene (TFE), chlorotrifluoroethylene (CTFE), or mixtures thereof,
(c) from 0.1 to 30% by moles, with respect to the total amount of monomers (a) and (b), of one or more acrylic monomers;
characterized in that the polymer mixture A comprises polymer fractions having a different content of the acrylic comonomer such that the elastic modulus at 23° C. (ASTM D1708) of said polymer mixture A is lower than at least 10% of the elastic modulus of a polymer formed by monomers a), b) and c) wherein the polymer fractions have substantially an equal content of the acrylic comonomer.
Abstract: Use of surfactants in the suspension polymerization of fluorinated monomers for preparing fluoropolymers containing hydrogen, said surfacants having the general formula:
Rf—[L—(OCHR1—CHR2)m—OZ)]i
wherein:
i is equal to 1 or 2;
m is an integer comprised between 4 and 60;
L can be chosen between: —(CFY—CO—O)pR′— and —(CFY—CO—NH)pR′—
wherein is an integer equal to 0 or to 1;
Y═F, CF3; R′=alkylic radical C1-C5, linear or branched when possible;
R1, R2 can be both H or the former H and the latter CH3;
Z can be H, alkyl radical C1-C3, linear or branched when possible; or (CH2)nOH with n an integer from 1 to 6;
Rf is a perfluoroalkylic radical or a perfluoropolyether radical, having a number average molecular weight comprised between 250 and 1500.
Abstract: Perfluoropolyether lubricants containing sulphonylfluoride groups pending along the perfluoropolyether chain and having the following formula:
wherein:
T are end groups selected from —CF2X (X═F,CF3Cl), —C3F7, —COF, —CF(CF3)COF, —CF2COF, —CF2COCF3;
d,e,f,h are integers; a,b,c can be zero or integers; said units are statistically distributed along the chain, being a+b+c+d+e+f+h such that the number average molecular weight ranges from 500 to 5×105, preferably from 1,000 to 50,000.
Abstract: Method for removing water from surfaces of various materials, comprising the steps of covering said surface with a composition having specific weight higher than that of water and subsequently removing water from the composition by skimming, wherein a composition essentially consisting of the following components is used:
Abstract: Fluoropolymers comprising a fluoroelastomer matrix incorporating therein particles of a semicrystalline fluoropolymer formed of tetrafluoroethylene (TFE) homopolymers or copolymers, wherein the average particle sizes of the semicrystalline fluoropolymer latex range from 10 to 100 nm.
Type:
Grant
Filed:
February 23, 2000
Date of Patent:
May 28, 2002
Assignee:
Ausimont S.p.A.
Inventors:
Margherita Albano, Marco Apostolo, Vincenzo Arcella, Enrico Marchese
Abstract: Chlorotrifluoroethylene (CTFE) thermoplastic perhalogenated polymers, formed by the following polymer components:
(I) 10-90% by weight of a CTFE homopolymer and
(II) 90-10% by weight of a CTFE copolymer modified with comonomer (a) selected from one or more perfluoroalkyl vinylethers having the formula:
Rf—O—CF═CF2
wherein:
Rf is a C2-C5 perfluoroalkyl group, resulting in the final polymer (I)+(II), the amount of (a) being from 0,2 to 5% by moles and the CTFE the remaining part to 100% by moles.
Abstract: Use of a composition for preparing by radical route polymeric films having refractive index lower than 1.400, said composition comprising:
a) a perfluoropolyether of formula:
T′—Rf.T (Ia)
b) from 0.1 to 10% by weight of a perfluoropolyether of formula:
T—Rf—CH2OH (Ib)
c) from 0 to 30% by weight of compounds selected from c1):
compounds not containing fluorine: non fluorinated (meth)acrylic esters or vinyl monomers;
or c2) compounds containing fluorine: mono(meth)acrylate perfluoropolyethers or perfluoroalkyl mono(meth)acrylates,
d) from 0.01 to 10% by weight of a photoinitiator and/or radical initiators,
the amount of component a) being the complement to 100 of the composition, with the proviso that defining by B0 the mole number of —CF2CH2OH and by B1 the sum of the moles of the (meth)acrylic end groups, the (B0+B1)/B1 ratio is in the range 1.50-1.01.
Abstract: Thermoplastic fluoropolymer compositions, flexible, without whitening, comprising: I) ETFE or ECTFE fluoropolymers modified with hydrogenated monomers; II) one or more hydrogenated plasticizers; III) one or more inorganic fire retardants; IV) optionally other ingredients such as fillers, smoke retarders, intumescent agents, pigments, lubricants, organic fire retardants and thermal stabilizers.
Type:
Grant
Filed:
October 1, 1998
Date of Patent:
April 9, 2002
Assignee:
Ausimont S.p.A.
Inventors:
Mikhail Zolotnitsky, Gary Stanitis, Julio A. Abusleme