Patents Assigned to BASF Aktiengesellschaft
  • Patent number: 4876347
    Abstract: Methine dyes (I) which conform in one of their tautomeric forms to the general formula ##STR1## where Y.sup.1 is in both or either case an electron-attracting group and the other Y.sup.1 is hydrogen,Y.sup.2 is in each case, independently of the others, hydrogen, --CN, halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl, pyridyl or together with a further Y.sup.2 a five- or six-membered ring which may have a fused-on benzene ring,R is hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.7 -C.sub.10 -aralkyl or .beta.
    Type: Grant
    Filed: March 24, 1988
    Date of Patent: October 24, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Ewald Daltrozzo, Werner Sulger
  • Patent number: 4874865
    Abstract: Preparation of substituted lactams Ia to Ic ##STR1## where n is 0 or 1, X is --O--CO--R.sup.1, --O--SO.sub.2 --R.sup.1, --CO--R.sup.2, --CO--O--R.sup.3 or --CO--NR.sup.4 R.sup.5, R.sup.1 is a C.sub.1 -C.sub.8 -radical of a carboxylic or sulfonic acid, R.sup.2 is C.sub.1 -C.sub.8 -alkyl, R.sup.3 is H or alkyl, aryl or aralkyl of not more than 8 carbon atoms, R.sup.4 and R.sup.5 are each H or C.sub.1 -C.sub.4 -alkyl or together form a 5-membered or 6-membered ring, by reacting a lactam II ##STR2## with a vinyl compound IIICH.sub.2 .dbd.CH-Xand a compound IV which forms free radicals to give Ia, and preparation of Ib by hydrolysis of a compound Ia in which X is (--O--CO--R.sup.1) or (--O--SO.sub.2 --R.sup.1), and preparation of Ic by thermolysis of Ib or of a compound Ia in which X is (--O--CO--R.sup.1) or (--O--SO.sub.2 --R.sup.1), and the novel substituted lactams Ia and Ib where X is (--O--CO--R.sup.1) and (--O--SO.sub.2 --R.sup.1).
    Type: Grant
    Filed: June 2, 1988
    Date of Patent: October 17, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Ludwig Wambach, Martin Fischer
  • Patent number: 4874899
    Abstract: Unsaturated ketones of the formula ##STR1## and saturated ketones of the formula ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, alkyl of 1 to 12 carbon atoms or a cycloalkyl, aryl, aralkyl or alkylaryl radical which inturn may be substituted, or R.sup.1 and R.sup.3 or R.sup.2 and R.sup.3, together with the carbon atoms to which they are bonded, may form a cycloalkane, are prepared by a process in which a 5-methylene-1,3-dioxolanone which is substituted in the 4-position and is of the forumla ##STR3## where R.sup.1, R.sup.2 and R.sup.3 have the above meanings, (a) for the preparation of an unsaturated ketone, is converted in the presence of a zeolite, of a phosphate having a zeolite structure and/or of B, Ce, Fe, Zr or Sr phosphate as catalysts and (b) for the preparation of a saturated ketone, is converted in the presence of the same catalysts which additionally carry one or more hydrogenation components.
    Type: Grant
    Filed: June 15, 1988
    Date of Patent: October 17, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Hoelderich, Leopold Hupfer, Kurt Schneider
  • Patent number: 4874889
    Abstract: 3-Pentenoates are prepared by isomerization of 2-pentenoates to 3-pentenoates by a process in which the 2-pentenoate is treaated with from 0.01 to 0.5 mole of cyclic tertiary amine having a pK.sub.a of >6 per mole of 2-pentenoate at from 50.degree. to 250.degree. C. and the 3-pentenoate is distilled off continuously.
    Type: Grant
    Filed: November 18, 1987
    Date of Patent: October 17, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Rolf Fischer, Franz Merger, Hans-Juergen Gosch
  • Patent number: 4874701
    Abstract: Novel microorganisms can be used to convert n-eugenol to coniferylaldehyde.
    Type: Grant
    Filed: February 9, 1987
    Date of Patent: October 17, 1989
    Assignee: BASF Aktiengesellschaft
    Inventor: Bryan Cooper
  • Patent number: 4873299
    Abstract: Crosslinked, finely divided, water-absorbing polymers are prepared in a batchwise process by copolymerization of 100 parts by weight of a monomer mixture of acrylic acid or methacrylic acid, each of which is neutralized with from 0 to 100 mol% of an alkali metal or ammonium base,or acrylamide, methacrylamide or N-vinylpyrrolidone with, as a crosslinking agent, from 0.01 to 5 parts by weight of a monomer containing two or more ethylenically unsaturated double bonds in 20-80% by weight aqueous solution in the presence of an initiator in a multistage procedure in a batchwise mixing apparatus wih constant thorough mixing in all stages, in the first stage the aqueous monomer solution being copolymerized at from 45.degree. to 95.degree. C. and under from 0.1 to 0.8 bar with removal of some of the water by distillation, in the second stage the copolymerization being completed at from 100.degree. to 170.degree. C.
    Type: Grant
    Filed: March 20, 1987
    Date of Patent: October 10, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernhard H. Nowakowsky, Juergen Beck, Heinrich Hartmann, Christos Vamvakaris
  • Patent number: 4873372
    Abstract: A process for the isolation of 4,4'-dichlorodiphenyl sulfone from a mixture of dichlorodiphenyl sulfones in which the ratios of the masses of 2,4'-dichlorodiphenyl sulfone and 3,4'-dichlorodiphenyl sulfone to the mass of 4,4'-dichlorodiphenyl sulfone are respectively from 0.5% to 20% and from 0.5% to 30% by treating the mixture with an alkanol at temperatures of from 20.degree. C. to 250.degree. C., cooling, and separating the pure 4,4'-dichlorodiphenyl sulfone that precipitates.
    Type: Grant
    Filed: January 25, 1988
    Date of Patent: October 10, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerhard Schaefer, Heinz Eilingsfeld, Peter Neumann, Michael Stumpp
  • Patent number: 4873246
    Abstract: Novel 6-(acylaminaryl)-3(2H)-pyridazinones of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, A and B have the meanings given in the description, and their preparation are described.The compounds have thrombocyte aggregation-inhibiting activity.
    Type: Grant
    Filed: October 8, 1986
    Date of Patent: October 10, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Philip A. Rossy, Marco Thyes, Albrecht Franke, Horst Koenig, Hans D. Lehmann, Josef Gries, Ludwig Friedrich, Dieter Lenke
  • Patent number: 4873362
    Abstract: 2-Substituted 4-acyloxy-2-butenals of the general formula I ##STR1## where R.sup.1 is alkyl of 1 to 12 carbon atoms which may be substituted by cycloalphatic, aromatic or heterocyclic radicals, by alkenyl or alkynyl or by hydroxyl, ether, thioether, acetoxy acyl, alkylamino, carboxyl or carbalkoxy, and R.sup.2 is acyloxy, are prepared by reacting a monosubstituted acetaldehyde of the general formula II ##STR2## where R.sup.2 has the abovementioned meaning, with an aldehyde of the general formula III ##STR3## where R.sup.1 has the abovementioned meaning, in the presence of a linear or cyclic secondary amine and of an organic acid at from 20.degree. to 100.degree. C.
    Type: Grant
    Filed: November 2, 1987
    Date of Patent: October 10, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Franz Merger, Rolf Fischer, Hans Horler
  • Patent number: 4873023
    Abstract: Compounds of the general formulae ##STR1## where R is versatyl and R' is unsubstituted or alkyl-substituted straight-chain alkylene of 4 or 5 carbon atoms can be prepared by reacting the versatic ester of 1,3-dihydroxy-propyl-2 acrylate and/or of 2,3-dihydroxy-propyl-1 acrylate with equimolar amounts of saturated or monoolefinically unsaturated cyclic dicarboxylic anhydrides having 4 or 5 carbon atoms and an oxygen atom in the ring at from 50.degree. to 150.degree. C. in the presence of customary esterification catalysts and can be used as reactive diluents in radiation-curable contact adhesives.
    Type: Grant
    Filed: November 21, 1988
    Date of Patent: October 10, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Guenther Schulz, Wolfgang Druschke, Helmut Jaeger
  • Patent number: 4873369
    Abstract: Cyclohexanone oxime containing ammonium sulfate is purified by a process in which cyclohexanone oxime in the molten state is passed over an acidic ion exchanger and a basic ion exchanger.
    Type: Grant
    Filed: March 5, 1987
    Date of Patent: October 10, 1989
    Assignee: BASF Aktiengesellschaft
    Inventor: Hugo Fuchs
  • Patent number: 4873284
    Abstract: Bismaleimide resion systems containing a bismaleimide and a multinuclear alkenyl and/or alkynyl arene as comonomers have improved toughness while maintaining high glass transition temperatures.
    Type: Grant
    Filed: January 20, 1988
    Date of Patent: October 10, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Ittemann, Philipp Eisenbarth
  • Patent number: 4871373
    Abstract: Solutions of low viscosity solvents and high viscosity, pasty products, for example water and sodium dithionite formulations, are prepared in a continuous manner in a matter of seconds in static and dynamic mixers connected in series while at the same time the ingress of air is avoided.
    Type: Grant
    Filed: December 17, 1987
    Date of Patent: October 3, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Kiener, Guenther Nonn, Bernhard Seid, Harald Schewski, Karl Buellmeyer
  • Patent number: 4871481
    Abstract: 1,4-Diaminoanthraquinone-2-sulfonic acid or salts thereof are reacted with cyanide ions at pH 8-11 in the presence of oxidizing agents in a mixture of water and 1-methoxy-2-propanol, 2-methoxy-1-propanol, N,N-dimethylformamide, N,N-dimethylacetamide, N,N-dimethylpropionamide, dimethyl sulfoxide, dioxane, N-methylpyrrolidone or mixtures thereof, the ratio water: organic liquid being .gtoreq.3:1, the reaction proceeding at higher concentrations than in a purely aqueous medium and producing appreciably purer products in a high space-time yield.
    Type: Grant
    Filed: December 24, 1987
    Date of Patent: October 3, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Miederer, Eberhard Michaelis
  • Patent number: 4871631
    Abstract: A flexographic printing relief-plate, which has a relief layer (P), an interlayer (Z) and a base layer (U), is provided with a double-sided adhesive sheet (W). The double-sided adhesive sheet (W) transmits actinic light and is firmly bonded to the base layer (U) on one side. On the opposing side, the adhesive sheet (W) has an adhesive force of from 1 to 6 N/25 mm. This force is less than the adhesive force on the side bonded to the base layer (U). The adhesive sheet (W) permits the flexographic relief printing plate to be repeatedly adhered to and removed from the printing cylinder without damaging the plate.
    Type: Grant
    Filed: October 21, 1987
    Date of Patent: October 3, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Hartwig Pieper, Reiner Michels, Heinz-Ulrich Werther
  • Patent number: 4871650
    Abstract: For coating printing cylinders or sleeves with a seamless, smooth photosensitive layer, two or more strata of a thin, prefabricated, essentially solvent-free, unsupported, thermoplastically processible, solid, photosensitive layer are applied to the printing cylinder or the sleeve, without bubbles and with displacement of the air between the individual strata, and the total photosensitive layer material is then heated under pressure and with joining or fusion of the individual strata to form a single, continuous photosensitive layer, and the surface of the resulting photosensitive layer is aftertreated to shape it exactly to size and is smoothed, with formation of an exactly cylindrical shape.
    Type: Grant
    Filed: February 9, 1988
    Date of Patent: October 3, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Guenter Wallbillich, Jan H. Van Heuvelen
  • Patent number: 4871701
    Abstract: Pentasil coated catalysts and fully crystalline catalysts in which the individual pentasil crystals are larger than 5 .mu.m are prepared by hydrothermal treatment of SiO.sub.2 by a process in which the SiO.sub.2 moldings are subjected to a hydrothermal treatment at from 140.degree. to 220.degree. C. in an alkali-free mixture of water, an amine and/or a tetraalkylammonium compound, with or without ammonia. The aluminum component for the preparation of an aluminosilicate zeolite can be kneaded into the SiO.sub.2 moldings or fed in via the liquid phase during the hydrothermal treatment. The tetraalkylammonium compound used can be a tetra-n-propyl-ammonium salt or hydroxide.
    Type: Grant
    Filed: August 24, 1988
    Date of Patent: October 3, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Alfred Danner, Ulaich Mueller, Klaus Unger, Wolfgang Hoelderich
  • Patent number: 4870100
    Abstract: 2-benzylfuryl compounds of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different substituents and are each hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, haloalkylthio, alkenyl or haloalkenyl, each of not more than 6 carbon atoms, n being 1, 2 or 3 where R.sup.3 is not hydrogen, and R.sup.4 and R.sup.5 are each hydrogen or alkyl of not more than 6 carbon atoms, R is --CHO or CHR.sup.6 OA, R.sup.6 is hydrogen, cyano, alkyl, alkenyl, haloalkenyl or alkynyl, each of not more than 6 carbon atoms, or carboxamide, and A is either hydrogen or a radical of an acid typical for pyrethroids, with the proviso that R.sup.2 is not hydrogen, chlorine, bromine, methyl or methoxy when R.sup.1 is hydrogen or methyl and R.sup.3 and A are each hydrogen, and furthermore with the proviso that R.sup.1 and R.sup.2 are not methyl when A is a radical of tetramethylcyclopropanecarboxylic acid, and finally with the proviso that R.sup.2 is not methyl, chlorine, bromine or methoxy and R.
    Type: Grant
    Filed: December 11, 1986
    Date of Patent: September 26, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Wolf, Hans Theobald, Rainer Becker, Norbert Goetz, Walter Himmele, Rudolf Kropp
  • Patent number: 4869997
    Abstract: A printing cylinder or a sleeve is coated with a continuous photosensitive recording layer by applying a first jointless stratum of a photosensitive recording layer to the printing cylinder or the sleeve, and uniformly preexposing this first stratum to actinic light and thereafter applying one or more further jointless strata of the photosensitive recording layer to this preexposed first stratum.
    Type: Grant
    Filed: February 9, 1988
    Date of Patent: September 26, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Horst Koch, Helmut Bach, Klaus-Peter Jaeckel
  • Patent number: RE33073
    Abstract: Caprolactam is obtained by cleaving oligomers of caprolactam by a process in which the oligomers, in a liquid or solid state, are introduced into a fluidized alumina bed and cleaved at from 290.degree. to 400.degree. C. in the presence of steam, and, in addition to the amount of inert gas required to fluidize the alumina bed, from 0.1 to 3 times this amount of inert gas is introduced above the fluidized bed.
    Type: Grant
    Filed: March 21, 1988
    Date of Patent: September 26, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Hugo Fuchs, Uwe Brand, Helmut Buchaeckert