Abstract: Propylene polymers which comprise from 25 to 97% by weight of a propylene polymer (I) containing from 0 to 15% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes and also comprise from 3 to 75% by weight of a further propylene polymer (II) containing from 15 to 80% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes, are obtainable by two-stage polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system which comprises a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also as cocatalysts an aluminum compound b) and a further electron donor compound c), where, in a first polymerization stage, propylene is polymerized in the presence or absence of further C.sub.2 -C.sub.10 -alk-1-enes at from 50.degree. to 100.degree. C., pressures in the range from 15 to 40 bar and a mean residence time of from 0.
Type:
Grant
Filed:
December 6, 1996
Date of Patent:
June 30, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Stephan Huffer, Meinolf Kersting, Franz Langhauser, Rainer Alexander Werner, Stefan Seelert, Patrik Muller, Jurgen Kerth
Abstract: In a process for producing polyolefin foam particles, partially foamed particles are produced in a first stage by extrusion of a polyolefin containing solid blowing agents, and these are then further foamed in the second stage using steam.
Type:
Grant
Filed:
December 4, 1996
Date of Patent:
June 30, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Joachim Fischer, Jens Rieger, Klaus Hahn, Isidoor De Grave, Wolfram Kogel
Abstract: A process for preparing amines of the formula I ##STR1## where R.sup.1,R.sup.2,R.sup.3,R.sup.4,R.sup.5 and R.sup.6 are each hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl,R.sup.1 and R.sup.2 are together a saturated or unsaturated C.sub.3 -C.sub.9 -alkylene dichain, andR.sup.3 or R.sup.5 is C.sub.21 -C.sub.200 -alkyl or C.sub.21 -C.sub.200 -alkenyl or together they are a C.sub.2 -C.sub.12 -alkylene dichain,by reacting olefins of the formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each as defined above, with ammonia or primary or secondary amines of the formula III ##STR3## where R.sup.1 and R.sup.2 are each as defined above, at temperatures from 200.degree. to 350.degree. C.
Type:
Grant
Filed:
January 21, 1997
Date of Patent:
June 30, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Karsten Eller, Rudolf Kummer, Eugen Gehrer
Abstract: Catalyst systems of the Ziegler-Natta type comprising as active constituentsa) a titanium-containing solid component prepared using a titanium compound, a compound of magnesium, a halogenating agent and an electron donor component,b) an aluminum compound andc) as further electron donor component, an organosilicon compound of the formula (I)R.sup.1 R.sup.2 si(OR.sup.3).sub.2 (I)in whichR.sup.1 is a C.sub.1 -C.sub.10 -alkyl radical or a C.sub.3 -C.sub.8 -cycloalkyl radical, R.sup.2 is a 2,4,4,6,6-pentamethylheptyl radical andR.sup.3 is a C.sub.1 -C.sub.8 -alkyl radical,are particularly suitable for the preparation of polymers of C.sub.2 -C.sub.10 -alk-1-enes.
Type:
Grant
Filed:
March 10, 1997
Date of Patent:
June 30, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Holger Friedrich, Stephan Huffer, Roland Hingmann
Abstract: Polymers of alkyl-1-vinylimidazoles, a process for preparing polymers of alkyl-1-vinylimidazoles by free-radical polymerization of a monomer mixture comprising(a) 10-100% by weight of at least one alkyl-1-vinylimidazole and(b) 0-90% by weight of 1-vinylpyrrolidone, 1-vinylcaprolactam, 1-vinyltriazole, 1-vinylimidazole, 1-vinyloxazolidinone or mixtures thereof,(c) 0-30% by weight of other monoethylenically unsaturated monomers and(d) 0-10% by weight of a monomer containing at least 2 monoethylenic double bondsin water, at least one C.sub.1 -C.sub.4 -alcohol or mixtures thereof, and the use of polymers which comprise at least 10% by weight of an alkyl-1-vinylimidazole as copolymerized unit as additive to detergents to inhibit transfer of dyes during the washing process.
Type:
Grant
Filed:
May 20, 1996
Date of Patent:
June 30, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Christian Schade, Hans-Ulrich Jager, Jurgen Detering
Abstract: Novel amido-quinoxalinediones of the formula ##STR1## where R.sup.1 -R.sup.5, n and m have the meanings stated in the description, and the preparation thereof are described. The compounds are suitable for controlling diseases.
Type:
Grant
Filed:
December 20, 1996
Date of Patent:
June 30, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Wilfried Lubisch, Berthold Behl, Hans Peter Hofmann
Abstract: Volatile components are eliminated from polyacrylate melts by distilling off the volatile components by a process in which the volatile components are distilled off under reduced pressure, entraining agents are added to the melts at above 100.degree. C. and the melts are simultaneously circulated.
Type:
Grant
Filed:
June 17, 1996
Date of Patent:
June 30, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Jurgen Barwich, Oral Aydin, Ulrich Erhardt, Walter Holtrup
Abstract: Aromatic compounds in which at least one amino group is bonded to an aromatic nucleus are catalytically hydrogenated in the liquid phase by a process in which the catalyst consists essentially of ruthenium and, optionally at least one metal of subgroup I, VII or VIII in an amount of from 0.01 to 30% by weight, based on the total weight of the catalyst, applied to a carrier which has a mean pore diameter of at least 0.1 .mu.m and a surface area of not more than 15 m.sup.2 /g.
Type:
Grant
Filed:
August 23, 1996
Date of Patent:
June 30, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Heinz Rutter, Thomas Ruhl, Boris Breitscheidel, Jochem Henkelmann, Andreas Henne, Thomas Wettling
Abstract: Methine dyes of the formula ##STR1## where K is a 5- or 6-membered carbocyclic or heterocyclic radical,X is nitrogen or a radical of formula C--Q.sup.1, andQ.sup.1, Q.sup.2 and Q.sup.3 are each independently of the others hydrogen, C.sub.1 -C.sub.6 -alkyl with or without interruption by 1 or 2 oxygen atoms in ether function, benzyl, C.sub.3 -C.sub.8 -cycloalkyl, substituted or unsubstituted phenyl, C.sub.1 -C.sub.4 -fluoroalkyl, C.sub.1 -C.sub.6 -alkoxy, benzyloxy, substituted or unsubstituted phenoxy, C.sub.1 -C.sub.6 -alkylthio, halogen, cyano, formylamino or a radical of the formula R.sup.3, --COR.sup.1, --CO--NHR.sup.1, --CO--NH--CO--R.sup.1, --CO--NH--CO--R.sup.4, --CO--NH--SO.sub.2 R.sup.4, --NH--CO--R.sup.1, --NH--CO--OR.sup.1, --NH--CO--NR.sup.1 R.sup.2, --NH--CSOR.sup.1, --NH--CS--NR.sup.1 R.sup.2, --NH--CO--R.sup.4, --NH--SO.sub.2 --R.sup.1, --NH--SO.sub.2 --R.sup.4 or --NH--SO.sub.2 --NR.sup.1 R.sup.2, where R.sup.1 and R.sup.2 are each independently of the other C.sub.1 -C.sub.
Abstract: A process for the preparation of polytetrahydrofuran or polytetrahydrofuran monoesters of C.sub.1 -C.sub.10 monocarboxylic acids by the polymerization of tetrahydrofuran over a heterogeneous catalyst in the presence of one of the telogens water, 1,4-butanediol or polytetrahydrofuran having a molecular weight of from 200 to 700 dalton or a C.sub.1 -C.sub.10 monocarboxylic acid or mixtures of these telogens, wherein a supported catalyst is used as catalyst, which contains a catalytically active amount of an oxygen-containing tungsten or molybdenum compound or mixtures of these compounds on an oxidic support material and which was calcined at temperatures ranging from 500.degree. to 1000.degree. C. following the application of the precursor compounds of said oxygen-containing molybdenum and/or tungsten compounds to the support material precursor.
Type:
Grant
Filed:
March 7, 1997
Date of Patent:
June 30, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Rainer Becker, Christoph Sigwart, Michael Hesse, Rolf Fischer, Karsten Eller, Gerd Heilen, Klaus-Dieter Plitzko
Abstract: The use of polyaspartic acid prepared by polycondensation of aspartic acid in the presence of phosphoric acid in a molar ratio of from 1:0.05 to 1:10 at temperatures of at least 120.degree. C. to give polysuccinimide, and subsequent hydrolysis of the polysuccinimide with bases to give at least partially neutralized polyaspartic acid, as additive to detergents and cleaners in amounts of from 0.1 to 10% by weight, and detergents and cleaners which contain polyaspartic acids prepared in the presence of phosphoric acid.
Type:
Grant
Filed:
May 20, 1996
Date of Patent:
June 23, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Matthias Kroner, Gunnar Schornick, Richard Baur, Alexander Kud, Volker Schwendemann
Abstract: A curable coating composition is described comprising (A) a compound comprising a plurality of functional crosslinking groups, at least one of which is a carbamate or urea functional group, which compound also includes at least one ester or amide group derived from a reaction of an active hydrogen group with a lactone ring or a hydroxy carboxylic acid, and (B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).
Type:
Grant
Filed:
August 15, 1996
Date of Patent:
June 23, 1998
Assignee:
BASF Corporation
Inventors:
John D. McGee, Brian D. Bammel, Walter H. Ohrbom, Todd A. Seaver, Gregory G. Menovcik, Paul J. Harris, John W. Rehfuss
Abstract: .gamma.-Fe.sub.2 O.sub.3 pigments and Fe.sub.3 O.sub.4 pigments with a particle diameter of 2 to 100 nm, a saturation magnetization above 40 nTm.sup.3 /g, a remanence below 10 nTm.sup.3 /g, a Cr content below 40 mg/kg of pigment, a Cu content below 40 mg/kg of pigment and C content below 100 mg/kg of pigment and aqueous suspension of these pigments. The pigments are used in aqueous suspension in the medical sector, in particular as contrast agents in magnetic resonance imaging.
Type:
Grant
Filed:
February 18, 1997
Date of Patent:
June 23, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Claudius Kormann, Ekkehard Schwab, Reinhold Schlegel
Abstract: A process for producing microorganisms which have increased L-lysine productivity is described. The process makes use of microorganisms of the genera Corynebacterium and Brevibacterium which are resistant to feedback inhibition by 2-azido-.epsilon.-caprolactam.
Type:
Grant
Filed:
March 12, 1996
Date of Patent:
June 23, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Ladner, Uwe Pressler, Wolfgang Siegel
Abstract: A polyol composition is provided which when reacted with an organic isocyanate, has good flow characteristics and makes a rigid polyurethane foam having good dimensional stability at low densities. The polyol composition has a polyol component which must have present a polyoxyalkylene polyether polyol having an equivalent weight of 130 or less and a hydroxyl number of 400 or more, a polyoxyalkylene polyether polyol having an average functionality from 1.5 to 3.1 and a viscosity of less than 800 cP at 25.degree. C., and a polyoxyalkylene polyether polyol having an average functionality of greater than 3.1 and a viscosity of 5,000 cp or less at 25.degree. C. The polyol composition also has formic acid or a mixture of formic acid and water as blowing agents, and further contains a delayed action blow catalyst and a delayed action gel catalyst.
Type:
Grant
Filed:
December 15, 1995
Date of Patent:
June 23, 1998
Assignee:
BASF Corporation
Inventors:
Thomas B. Lee, Thomas L. Fishback, Curtis J. Reichel
Abstract: A process for the preparation of 1,2-butylene oxide by the catalytic hydrogenation of vinyl oxirane, in which use is made of a palladium catalyst on a support of barium sulfate, zirconium oxide or titanium dioxide or a rhenium-containing supported palladium catalyst.
Type:
Grant
Filed:
December 27, 1996
Date of Patent:
June 23, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Lingelbach, Joachim Roser, Christoph Sigwart, Werner Schnurr, Hans-Jurgen Weyer
Abstract: A process for preparing aqueous preparations of azo dyes of the formula ##STR1## where R is hydrogen or C.sub.1 -C.sub.4 -alkyl andKat.sym. is the equivalent of a cation which derives from a tertiary amine of the ethanolamine or propanolamine series,by diazotization of an aniline of the formula ##STR2## with neopentylglycol dinitrite in an aqueous medium and coupling of the resulting reaction mixture with .beta.-naphthol in the presence of a water-miscible diluent and of an amine comprises using an amine comprising a tertiary amine of the ethanolamine or propanolamine series.
Abstract: Polymer blends containa) from 10 to 90% by weight of an imide of a copolymer based on an .alpha.-olefin and on an ethylenically unsaturated dicarboxylic acid and a polyamine andb) from 10 to 90% by weight of a copolymer which differs from a) and contains at least two monomers selected from the group consisting of ethylene, acrylates, vinyl esters, vinyl ethers and ethylenically unsaturated dicarboxylic acids or dicarboxylic acid derivatives,and are used as additives for mineral oil middle distillates.
Abstract: Impurities are separated from aqueous solutions of 1,6-hexanediol or 1,6-hexanediol precursors, such as adipic and 6-hydroxycaproic acid, by a process which comprises adding at least one carboxylic acid to a solution (a) of 1,6-hexanediol and subjecting this solution (a) or a solution (b) containing carboxylic acid(s) as precursor(s) of 1,6-hexanediol to a heat treatment at temperatures above room temperature in the absence of hydrogen.
Type:
Grant
Filed:
July 1, 1997
Date of Patent:
June 16, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Roman Dostalek, Rolf Fischer, Wolfgang Harder, Axel Paul, Rolf Pinkos