Abstract: The invention relates to a process for the production of multi-layer finishes in which the base coating contains crosslinked polymer microparticles which are obtainable by(A) reacting a polyester-polyol or a mixture of polyester-polyols with a polyisocyanate or with a mixture of polyisocyanates and(B) when at least 25% of the NCO groups have reacted, dispersing the resulting reaction mixture in water.
Type:
Grant
Filed:
December 27, 1993
Date of Patent:
June 2, 1998
Assignees:
BASF Lacke, Farben, AG
Inventors:
Wolfgang Baltus, Jan Berg, Arnold Dobbelstein, deceased
Abstract: Rigid polyurethane foams, preferably semirigid polyurethane foams, are produced by reacting an organic and/or modified organic polyisocyanates with relatively high molecular weight polyhydroxyl compounds and, optionally, low molecular weight chain extenders and/or crosslinkers in the presence of water or mixtures of water and physically acting blowing agents, optionally, catalysts, at least one additive selected from the group consisting of sulfonate salts of an acid group-containing alkylene oxide polymer, a phosphonate salt of an acid group-containing alkylene oxide polymer, and mixtures thereof, additional other additives and optionally, auxiliaries. The polyurethane foams produced by this process can be used to produce composite comprising at least one covering layer and at least one layer comprising a rigid or semirigid polyurethane foam produced by the process of the present invention.
Type:
Grant
Filed:
September 6, 1996
Date of Patent:
June 2, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Horn, Gerhard Lehr, Sarbananda Chakrabarti, Dieter Hertel, Ludwig Jung
Abstract: The present invention relates to a process for the production of textured coatings on plastics surfaces using coating compositions based on hydroxyl group-containing binders and polyisocyanates, and using pulverulent texturing agents.
Abstract: Novel polypeptides having fibrinogenolytic properties and having amino acid sequences as SEQ ID NO: 3, SEQ ID NO: 4, SEQ ID NO: 5 and SEQ ID NO: 6 indicated in the Sequence Listing, the preparation and use thereof for controlling diseases.
Type:
Grant
Filed:
July 25, 1996
Date of Patent:
June 2, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Alfred Bach, Heinz Hillen, Siegfried Bialojan
Abstract: Reagent grade hydrochloric acid having an iron content of less than 200 p.p.b. is made from an industrial organic isocyanate manufacturing process by removing hydrogen chloride from organic isocyanates produced in the reaction between phosgene and an organic amine, converting the hydrogen chloride to concentrated aqueous hydrochloric acid, and contacting the acid with a strongly basic anion exchange resin.
Abstract: A process for the preparation of an aqueous polymer emulsion, in which an aqueous emulsion of a polymer which contains at least one chemically bonded monomer having at least one ethylenically unsaturated group is produced in a manner known per se so that the total content of free monomers having at least one ethylenically unsaturated double bond, ie. monomers of this type which are not chemically bonded, in the aqueous polymer emulsion is from >0 to .ltoreq.1% by weight, based on the polymer content of the aqueous polymer emulsion, and this residual monomer content is then reduced by the action of a free radical redox initiator system comprising at least one oxidizing agent and at least one reducing agent, wherein the redox initiator system comprises, as the reducing agent, one which is present, in aqueous solution, in at least two tautomeric forms in equilibrium with one another (for example aminoiminomethanesulfinic acid and/or the salts thereof).
Abstract: Aliphatic alpha,omega-aminonitriles are prepared by partial hydrogenation of aliphatic alpha,omega-dinitriles at elevated temperatures and superatmospheric pressure in the presence of a solvent and of a catalyst by a process in which the catalyst(a) contains a compound based on a metal selected from the group consisting of nickel, cobalt, iron, ruthenium and rhodium and(b) contains from 0.
Type:
Grant
Filed:
May 16, 1996
Date of Patent:
May 26, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Klemens Flick, Johann-Peter Melder, Werner Schnurr, Klaus Ebel, Tom Witzel, Wolfgang Harder, Alwin Rehfinger, Rolf Fischer
Abstract: A curable coating composition is described comprising(A) a compound comprising a plurality of functional crosslinking groups, at least one of which is a carbamate or urea functional group, which compound also includes at least one carbonate group having the structure: ##STR1## and (B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).
Type:
Grant
Filed:
August 15, 1996
Date of Patent:
May 26, 1998
Assignee:
BASF Corporation
Inventors:
Walter H. Ohrbom, John W. Rehfuss, John D. McGee, Gregory G. Menovcik, Paul J. Harris
Abstract: A process for preparing alkyl cyanoacetates of the general formula I ##STR1## where R is an n-valent aliphatic radical which has 6 to 20 carbon atoms and whose carbon framework can be interrupted by one to three oxygen atoms in ether functionality, and n is a number from 1 to 6, by reacting cyanoacetic acid in aqueous medium with an alcohol R(OH).sub.n, where the esterification is carried out in the presence of an inert entrainer and, during the reaction, water and entrainer are distilled out.
Type:
Grant
Filed:
October 21, 1996
Date of Patent:
May 26, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Clemens Grund, Martin Holderbaum, Helmut Reichelt, Stefan Beckmann
Abstract: Aqueous preparations comprising an alkyl polyglycoside and a polyethylene glycol ether derivative of the formula I ##STR1## where R.sup.1 is alkyl having 8-22 carbon atoms,A is a divalent radical derived from a diisocyanate andn is 20-400are described.
Abstract: A process for the regeneration of plastic diaphragms is described, in which a mineral acid solution is mixed with a suitable corrosion inhibitor, this mixture is temperature controlled at from approximately 0.degree. to 100.degree. C., preferably 40.degree. to 80.degree. C., in particular 50.degree. to 70.degree. C., and passed through the diaphragm for from approximately 0.1 to 84 hours, preferably 1 to 72 hours, in particular 2 to 24 hours.
Type:
Grant
Filed:
June 16, 1997
Date of Patent:
May 26, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Rudi Kroner, Bernd Leutner, Hans-Michael Schneider, Holger Friedrich, Kurt Hecky, Dieter Schlafer, Wolfgang Steiner
Abstract: Method of making compositions comprising gluten and polysaccharides that contain uronic acid residues encapsulating fats, oils and solids comprising double emulsion techniques.
Type:
Grant
Filed:
September 3, 1996
Date of Patent:
May 26, 1998
Assignee:
BASF Corporation
Inventors:
Frederick K. Chaundy, Scott P. Melidosian, Rudolph E. Lisa, Jeffrey L. Finnan
Abstract: The invention relates to novel subunits for glutamate receptors and to the DNA sequences coding therefor, and to processes for preparing DNA sequences and receptors. The invention furthermore relates to methods for identifying functional ligands for these receptors.
Type:
Grant
Filed:
August 5, 1996
Date of Patent:
May 26, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Hoger, Andreas Ultsch, Alfred Bach, Sylvia Sterrer, Hans-Georg Lemaire
Abstract: Packaging films are coated with a polyurethane which bears hydrophilic groups which make the polyurethane water-dispersible and which has a melting point of from 20.degree. to 70.degree. C., with the enthalpy of fusion in this temperature range being at least 20 J/g.
Type:
Grant
Filed:
April 15, 1996
Date of Patent:
May 26, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Ulrike Licht, Hermann Seyffer, Jens Rieger, Helmut Kaehs, Rainer Hummerich
Abstract: The present invention relates to high molecular weight homopolymers and copolymers of ethene, which homopolymer or copolymer is obtained by polymerizing the monomer(s) at a temperature of from 70.degree. to 150.degree. C. and under a pressure of from 2 to 150 bar in contact witha chromium trioxide catalyst,(1) loading a support based on silicon dioxide with(2) either chromium trioxide or a chromium compound capable of being converted to chromium trioxide under the conditions of stage (3) below and then(3) heating the resulting intermediate in a gas stream containing oxygen,the support (1) being a special silica xerogel obtained by extracting not more than 30% of the water from a silica hydrogel by means of an alkanol, an alkanone or a mixture thereof followed by drying, comminution and fractional screening.
Type:
Grant
Filed:
September 30, 1992
Date of Patent:
May 26, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans Gropper, Guido Funk, Erich Kolk, Dieter Oeder
Abstract: Naphthalene derivatives of the formula ##STR1## where the rings A and B may be benzofused,X is nitrogen or a radical of the formula CH or CH.dbd.CH--CH,Z is a heterocyclic radical or additionally, when x is CH.dbd.CH--CH, a 5- or 6-membered aromatic carbocyclic radical, andR.sup.1, R.sup.2 and R.sup.3 are hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.5 -C.sub.7 -cycloalkyl, are useful in nonlinear optics.
Type:
Grant
Filed:
December 24, 1996
Date of Patent:
May 26, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Stefan Beckmann, Karl-Heinz Etzbach, Rudiger Sens
Abstract: A process is disclosed for preparing D,L-aspartic acid by beating aqueous solutions of ammonium salts of the maleic acid. The molar ratio of maleic acid to ammonia ranges from 1:1 to 1:50. The process is carried out at temperatures from 60.degree. to 250.degree. C. and pressures of at least 1 bar. The pressure applied during the reaction is adjusted to ensure that the reaction mixture is almost completely present in liquid phase. Excess ammonia is removed and the reaction solution is acidified so as to release D,L-aspartic acid, which is then isolated.
Type:
Grant
Filed:
March 24, 1997
Date of Patent:
May 26, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Detlef Kratz, Tom Witzel, Rudolf Bazner, Matthias Kroner, Uwe Pressler
Abstract: Polymers which contain polyacetal blocks are obtainable by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the polymers with at least bifunctional crosslinking agents in the presence of acids or Lewis acids and, if required hydrolyzing the ester groups present as polymerized units, process for the preparation of the polymers containing polyacetal blocks by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the resulting polyacetals containing terminal hydroxyl groups with at least bifunctional crosslinking agents in the presence of acids or Lewis acids, and the use of the resulting polymers as additives in phosphate-free and reduced phosphate detergents and cleaning agents, as scale inhibitors and as dispersants for pigments.
Type:
Grant
Filed:
September 19, 1997
Date of Patent:
May 26, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Angelika Funhoff, Dieter Boeckh, Matthias Kroner, Richard Baur, Alexander Kud, Gunnar Schornick, Volker Schwendemann
Abstract: Polymers and oligomers of olefinically unsaturated C.sub.2 -C.sub.20 -hydrocarbons having one or two 2-oxazolinyl end groups have the structure (I) ##STR1## where A is a polymer or oligomer radical derived from the olefinically unsaturated C.sub.2 -C.sub.20 -hydrocarbons and the radicals R can be identical or different and have the following meanings:hydrogen,C.sub.1 -C.sub.10 -alkyl,C.sub.6 -C.sub.10 -aryl,C.sub.3 -C.sub.6 -cycloalkyl.
Type:
Grant
Filed:
July 26, 1996
Date of Patent:
May 26, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Joachim Rosch, Hans-Joachim Muller, Arthur Hohn, Rolf Muelhaupt, Christof Woerner
Abstract: A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine from 3-cyano-3,5,5-trimethylcyclohexanone which requires three spatially separated reaction spaces, in order to carry out the following three steps in sequence:a) reacting the 3-cyano-3,5,5-trimethylcyclohexanone with excess ammonia on acidic metal-oxide catalysts in a first reaction space at from 20.degree. to 150.degree. C. and from 50 to 300 bar,b) hydrogenating the resultant reaction products using hydrogen in a second reaction space in the presence of excess ammonia and preferably liquid ammonia on hydrogenation catalysts, optionally using basic components or on neutral or basic supports at from 50.degree. to 100.degree. C. and at from 50 to 300 bar, andc) hydrogenating the resultant reaction products in the presence of hydrogen and also ammonia in a third reaction space on hydrogenation catalysts, optionally using basic components or on neutral or basic supports at from 110.degree. to 160.degree. C. and at from 150 to 300 bar.
Type:
Grant
Filed:
February 28, 1996
Date of Patent:
May 26, 1998
Assignee:
BASF Aktiengesellschaft
Inventors:
Guido Voit, Tom Witzel, Boris Breitscheidel, Wolfgang Harder, Hermann Luyken, Axel Paul, Karl-Heinz Ross, Peter Wahl