Abstract: Alkali-soluble resins, their preparation and use are disclosed herein. The resins are carboxylated polyamide/acrylic resins and are synthesized in a two-step fusion process in which a polyamide is first condensed with a carboxylated rosin and this intermediate product is then further condensed with an acrylic or styrene/acrylic copolymer.
Type:
Grant
Filed:
September 21, 1988
Date of Patent:
February 2, 1993
Assignee:
BASF Corporation
Inventors:
Sobhy El-Hefnawi, Shailesh C. Shah, Basil Wasyliw
Abstract: Acicular, cobalt-modified iron oxides consisting of a core of an iron oxide of the formula FeO.sub.x where x is from 1.33 to 1.5 and a ferrite shell which contains a total amount of from 0.4 to 12% by weight of cobalt ions and not more than 5% by weight of iron(II) ions, the percentages being based on the total amount of the material, which iron oxides have improved aging resistance, particularly with regard to the coercive forces, and a process for their preparation.
Type:
Grant
Filed:
May 21, 1990
Date of Patent:
February 2, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Ekkehard Schwab, Ronald J. Veitch, Helmut Auweter
Abstract: Mixtures of medium viscosity polymeric MDI and HCFC-22 have unexpectedly low vapor pressure, rendering such mixtures suitable for the preparation of polyurethane and polyisocyanate foams.
Abstract: A water-dilutable coating comprising a binder obtained from an epoxide resin-modified polyester possessing free carboxyl groups prepared from the reaction of:A) a polyester polymerized from:a.sub.1) a polycarboxylic acid containing at least three carboxyl groups and/ora.sub.2) a polyol containing at least one carboxyl group anda.sub.3) a polycarboxylic acid containing two carboxyl groups anda.sub.4) a polyol; wherein the polyester contains (cyclo)aliphatic elements having at least six carbon atoms; andB) from 0.3-1.5 equivalents per polyester molecule of a bisphenol epoxide resin or a reaction product thereof containing at least one epoxide group per molecule with a carboxylic acid.
Type:
Grant
Filed:
November 21, 1990
Date of Patent:
February 2, 1993
Assignee:
BASF Lacke & Farben AG
Inventors:
Lutz-Werner Gross, Ulrich Poth, Dieter Hille, Klaus Weidemeier
Abstract: The reactive dyes have the formula ##STR1## where n is 0 or 1,R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl,R.sup.4 is fluorine, chlorine, bromine, C.sub.1 -C.sub.4 -alkylsulfonyl, phenylsulfonyl or a radical of the formula ##STR2## L is a bridgemember, A is substituted or unsubstituted C.sub.2 -C.sub.8 -alkylene,Y is vinyl or a radical of the formula --CH.sub.2 --CH.sub.2 --Q, where Q is a group which is detachable under alkaline reaction conditions, andD is phenyl or naphthyl, which may each be substituted.The present dyes are useful in dyeing or printing hydroxyl- or nitrogen-containing fibres.
Abstract: A yarn coating applicator includes a pair of yarn guide blocks and an intermediate delivery plate. The guide blocks include an opening which may be in the form of a slot at the edge of the guide block. The plate includes a supply means, such as an inlet, for providing the coating fluid to the plate and channels by which the treatment fluid is conveyed to fluid reservoirs in the applicator. The openings in the guide blocks communicate with the reservoir hole in the plate to provide a yarn passageway through the applicator.
Abstract: The invention relates to a reference electrode for chemical sensors based on ion-selective field-effect transistors (CHEMFETs) in an electrolyte/insulator/semiconductor system. The reference electrode is essentially composed of a polyglutamate-coated insulator/semiconductor substrate or of a polyglutamate-coated phthalocyaninato-polysiloxane polymer film applied to an insulator/semiconductor substrate.
Type:
Grant
Filed:
May 24, 1991
Date of Patent:
January 26, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Stefan Schwiegk, Klemens Mathauer, Gerhard Wegner, Bernd F. W. Hoffmann, Albrecht Vogel
Abstract: Foam sheets of high compressive strength are produced by extruding a mixture of a styrene polymer and from 5 to 16% by weight of a blowing agent mixture containinga) from 3 to 70% by weight of an alcohol or ketone having a boiling point of from 56.degree. to 100.degree. C.,b) from 5 to 50% by weight of carbon dioxide andc) from 0 to 90% by weight of a saturated C.sub.3 - to C.sub.5 -hydrocarbon and/or of a hydrogen-containing chlorofluorocarbon or fluorinated hydrocarbon boiling at from -30.degree. to +30.degree. C.
Type:
Grant
Filed:
July 1, 1991
Date of Patent:
January 26, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Heinz Voelker, Gerhard Alicke, Horst Schuch, Manfred Weilbacher, Reinhold Weber
Abstract: A finish applicator includes one or more applicator plates stacked adjacent a guide plate and preferably between a pair of guide plates, at least one of the guide plates having an opening formed therein forming a yarn passageway and positioning the yarn in close proximity to, or in contact with an edge of the applicator plate. Alternatively, the guide plate and applicator plate may each have one or more openings formed therein which in registry form a yarn passageway when the plates are stacked. The opening in the guide plates may define retaining arms which maintain the yarn to be treated in close proximity to, or in contact with a treatment edge of each applicator plate.
Abstract: Azo dyes of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 independently denote hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.4 denotes C.sub.1 -C.sub.6 -alkyl andR.sup.5 denotes C.sub.2 -C.sub.8 -alkyl which is substituted by hydroxy and may be interrupted by 1, 2 or 3 oxygen atoms,provided that the total number of carbon atoms in the radicals R.sup.4 and R.sup.5 is at least 5,mineral oils containing one or more of said novel dyes and the use of said dyes for marking mineral oils.
Type:
Grant
Filed:
September 26, 1990
Date of Patent:
January 26, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernd Derber, Guenter Hansen, Helmut Reichelt, Christos Vamvakaris, Georg Zeidler
Abstract: The invention relates to transparent, substantially compact polyurethane casting compositions, sterilizable with superheated steam, which are prepared by the reaction of:A) modified diphenylmethane diisocyanates (A) that are liquid at 23.degree. C. and are in turn are obtained by the reaction of1) a diphenylmethane diisocyanate isomer mixture, which in terms of 100 parts by weight comprises 60 to 90 parts by weight of 4,4'-diphenylmethane diisocyanate, 40 to 8 parts by weight of 2,4'-diphenylmethane diisocyanate, and 0 to 5 parts by weight of 2,2'-diphenylmethane diisocyanate with2) at least one polyoxypropylene polyol initiated with glycerine and/or trimethylol propane, having a molecular weight of 350 to 800 with a ratio of NCO:OH groups of 2.5:1 to 15:1, withB) at least one compound having at least two reactive hydrogen atoms in the presence or absence ofC) catalysts,as well as to a process for preparing the polyurethane casting compounds and their use for medical-technical articles.
Type:
Grant
Filed:
May 7, 1990
Date of Patent:
January 26, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Horn, Walter Heckmann, Falko Ramsteiner, Friedrich Gerold
Abstract: Mixtures of medium viscosity polymeric MDI and HCFC-22 have unexpectedly low vapor pressure, rendering such mixtures suitable for the preparation of polyurethane and polyisocyanate foams.
Abstract: The useful dye intermediate 1-amino-2-chloro-4-hydroxyanthraquinone is prepared by chlorinating 1-amino-4-hydroxy-2,3-dihydroanthraquinone with chlorine in concentrated sulfuric acid.
Abstract: Derivatives of a tumor necrosis factor (TNF), which originate from a modification at the amino terminus of the TNF molecule are suitable for controlling diseases.
Type:
Grant
Filed:
May 13, 1988
Date of Patent:
January 19, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Doerper, Achim Moeller, Heinz Hillen, Gerhard Keilhauer, Franz Emling, Lothar Daum
Abstract: A shock-absorbing propylene polymer composite molding containsa. a layer with a thickness of from 0.5 to 10 mm which contains a propylene polymer having a melting point of from 130.degree. to 165.degree. C.,b. an intermediate layer with a thickness of from 0.05 to 0.5 mm comprising a hot-melt adhesive based on an olefin copolymer having a melting point of from 90.degree. to 140.degree. C.,c. a foam layer with a thickness of from 3 to 200 mm and a density of from 0.015 to 0.1 g/cm.sup.3 based on a propylene copolymer having a melting point of from 125.degree. to 155.degree. C.,d. an intermediate layer with a thickness of from 0.05 to 0.5 mm comprising a hot-melt adhesive based on an olefin copolymer having a melting point of from 90.degree. to 140.degree. C.,e. a layer with a thickness of from 0.5 to 10 mm which contains a propylene polymer having a melting point of from 130.degree. to 165.degree. C.
Type:
Grant
Filed:
January 17, 1992
Date of Patent:
January 19, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Udo Haardt, Erhard Seiler, Hermann Tatzel, Harald Schwager, Friedrich Domas
Abstract: The water absorption capacity of crosslinked, water-swellable polymers is improved by a process in which a water-containing, finely divided polymer gel having a solids content of from 20 to 65% by weight is treated with steam at not less than 50.degree. C., the solids content of the water-containing polymer gel increasing by not more than 30% by weight, and the polymer gel is then dried in a conventional manner.
Type:
Grant
Filed:
August 8, 1990
Date of Patent:
January 19, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Manfred Niessner, Juergen Beck, Heinrich Hartmann, Andreas H. Kemna, Stefan Wickel
Abstract: A preferred process for producing 3-hydroxy-2,2,4-trimethylpentyl isobutyrate is described. The spent aqueous phase from an alkali metal hydroxide-catalyzed isobutyraldehyde condensation is concentrated in alkali metal isobutyrate salt, and the concentrated medium is introduced into a subsequent condensation to advantageously modify the isobutyraldehyde reaction. Increased conversions and productivities can thus be achieved. Preferred continuous processes, as well as preferred processes of controlled reaction duration and reactant/catalyst/salt ratios are also described. Further described is a preferred process for producing the diisobutyrate ester of 2,2,4-trimethyl-1,3-pentanediol, which in a preferred mode also achieves a desirable coproduction of the diol and its monoisobutyrate ester.
Abstract: Thermoplastic molding materials containA) not less than 5% by weight of a polymer component consisting of from 50 to 100% by weight of polyphenylene ethers and from 0 to 50% by weight of a styrene polymer differing from component C),B) not less than 5% by weight of a polyester,C) not less than 0.1% by weight of a copolymer consisting ofC.sub.1) not less than 20% by weight of .alpha.-olefins of 2 to 8 carbon atoms, styrene or substituted styrenes of the general formula I ##STR1## where R and R.sup.1 is alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1 or 2, or a mixture of these monomers,C.sub.2) not less than 0.5% by weight of a polymerizable monomer containing epoxide groups, and/orC.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer having the structural unit (II) ##STR2## where X is halogen and R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3, and/orC.sub.4) not less than 0.
Type:
Grant
Filed:
August 29, 1990
Date of Patent:
January 19, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Christof Taubitz, Erhard Seiler, Klaus Boehlke, Dietrich Lausberg
Abstract: Novel water-soluble compositions are described. In particular, water soluble polyamide-acrylic, polyamide-styrene acrylic and polyamide-styrene maleic resins are disclosed as well as novel methods for their production.
Abstract: Phenoxyalkyl-substituted heteroaromatics of the general formulae Ia and Ib ##STR1## where A is an unsubstituted or substituted heteroaromatic radical having 6 ring members and 1, 2 or 3 nitrogen atoms in the ring, R.sup.1 is hydrogen, halogen or C.sub.1 -C.sub.3 -alkyl, R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, Q.sub.a is an unsubstituted or substituted azole radical and Q.sub.b is a substituted or unsubstituted heteroaromatic radical which has a five-menbered ring, and their use for combating pests.
Type:
Grant
Filed:
February 13, 1992
Date of Patent:
January 19, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Joachim Leyendecker, Hans-Juergen Neubauer, Uwe Kardorff, Christoph Kuenast, Peter Hofmeister, Wolfgang Krieg