Abstract: An organic compound of an alkali metal, of the formula I ##STR1## which is obtained by reaction of an appropriate diarylethylene of the formula II with an alkali metal (M), especially lithium, ##STR2## where Ar.sup.1 and Ar.sup.2 are identical or different aryl or hetaryl radicals which have one or more rings which are either separate or fused, and where R is at least one substituent different from hydrogen and which is chemically inert to the alkali metal or its alkyl, with the proviso that the total of the carbon atoms in all the R is at least 3, and m and n are each an integer up to 4, is used for the preparation of polymers whose monomers are amenable to anionic polymerization.
Abstract: Wood stains contain in addition to a colorant and a solvent at least one stabilizer against the action of light, oxygen and heat on the wood treated with the wood stain, said stabilizer containing at least one structural element of the formula I ##STR1## where X is oxygen or nitrogen.
Abstract: Sulfonamides of the general formula I ##STR1## where R.sup.1 is hydrogen of C.sub.1 -C.sub.4 -alkyl,R.sup.2 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl; C.sub.3 -C.sub.4 -alkenyl; C.sub.3 -C.sub.4 -alkynyl or substituted or unsubstituted saturated or singly unsaturated 5- to 7- membered heteroaryl;R.sup.3 and R.sup.4 are halogen; substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkenyloxy, C.sub.2 -C.sub.6 -alkenylthio, C.sub.2 -C.sub.6 -alkynyl, C.sub.2 -C.sub.6 -alkynyloxy, C.sub.2 -C.sub.6 -alkynylthio, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.3 -C.sub.6 -cycloalkylthio, C.sub.5 -C.sub.6 -cycloalkenyl, C.sub.3 -C.sub.6 -cycloalkoxy, C.sub.5 -C.sub.6 -cycloalkenyloxy, C.sub.5 -C.sub.6 -cycloalkenylthio, phenyl, phenoxy, phenylthio, benzyl, benzyloxy or benzylthio;the group given for R.sup.2, or NR.sup.7 R.sup.8, where R.sup.7 and R.sup.8 are hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.
Type:
Grant
Filed:
May 9, 1990
Date of Patent:
December 15, 1992
Assignee:
BASF Akteingesellschaft
Inventors:
Klaus Fischer, Horst Mayer, Klaus Ditrich, Gerhard Hamprecht, Bruno Wuerzer, Karl-Otto Westphalen
Abstract: The color of a polymer, particularly polytetrahydrofuran, is improved by subjecting the polymer to microwave energy of such magnitude and frequency so as to cause a decrease in the APHA color number.
Abstract: A process for preparing polyphenylene ethers from monohydric phenols which have alkyl substituents in both ortho positions and possibly also in one meta position but not in the para position, by oxidative coupling with oxygen-containing gases in the presence of an oxidation catalyst and of an electrically conducting compound which counteracts the electrostatic charge in the reaction mixture, in organic solution, comprises using as electrically conducting compound a salt of a carboxamide derivative of the formula I ##STR1## or mixtures of such salts, where R.sup.1 is a saturated or singly or multiply unsaturated aliphatic group which can have a terminal phenyl group and which contains a total of 8-30 carbon atoms, it also being possible for these carbon atoms to be interrupted by isolated oxygen atoms,R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl,A is an aliphatic, araliphatic or cycloaliphatic or aromatic bridge of up to 10 carbon atoms,n and m are each 1 to 3,Q.sup..sym.
Type:
Grant
Filed:
May 3, 1991
Date of Patent:
December 15, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Carola Hedtmann-Rein, Bernhard Czauderna, Martina von Deessen, Karl Hennig
Abstract: The invention relates to coating compositions which are particularly suitable for the preparation of the basecoat for two-coat coatings of the basecoat/clearcoat type, and which comprise organic diluents, at least one resin containing urethane and urea groups, and, where appropriate, other resins, pigments and other conventional additives in common use.
Type:
Grant
Filed:
April 4, 1990
Date of Patent:
December 8, 1992
Assignee:
BASF Lacke + Farben AG
Inventors:
Hans-Dieter Hille, Arnold Dobbelstein, Horst Grosch
Abstract: Binary azulenesquaric acid dyes of the formula ##STR1## where X is a bridging member, Y is hydrogen, cyano or formula CO--OR.sup.5, CO--NHR.sup.5, OR.sup.5, O--CO--OR.sup.5, NH--CO--R.sup.5, NH--CO--OR.sup.5 or NH--SO.sub.2 --R.sup.5, where R.sup.5 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.12 -alkenyl, C.sub.5 -C.sub.7 -cycloalkyl or unsubstituted or substituted phenyl, L.sup.1 and L.sup.2 are each, independently of one another, a chemical bond or unsubstituted or substituted C.sub.1 -C.sub.12 -alkylene and R.sup.1, R.sup.2, R.sup.3, R.sup.4, Q.sup.1, Q.sup.2, Q.sup.3 and Q.sup.4 are each, independently of one another, hydrogen or unsubstituted or substituted C.sub.1 -C.sub.12 -alkyl, their intermediates and an optical recording medium containing the novel dyes are described.
Type:
Grant
Filed:
November 15, 1991
Date of Patent:
December 8, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Schmitt, Bernhard Albert, Sibylle Brosius, Klaus D. Schomann, Harald Kuppelmaier
Abstract: Water-dilutable polyurethane/acrylic copolymers which may be either completely nonionically stabilized or partically nonionically and partically anionically stabilized comprise the reaction product of an ethylenically terminated polyurethane macromonomer containing poly(oxyalklyene) segments and one or more ethylencially unsaturated monomers selected from acrylic acid, methacruylic acid, fumaric acid, styrene, vintyltoluene, and alkyl and hydroxyalkyl esters of acrylic, methacrylic, and furamic acids. The copolymers are useful as principal resins and as pigment grind resins in water-borne automotive base coat paint formulations.
Abstract: A process for reducing the size of polyisobutene with a molecular weight of from 5,000,000 to 12,000,000 by grinding under pressures of from 1 to 50 bar and with average residence times of from 0.1 to 30 minutes entails the grinding being carried out at from 0.degree. to 60.degree. C.
Type:
Grant
Filed:
September 10, 1991
Date of Patent:
December 8, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Karl-Heinz Fauth, Franz-Dieter Martischius, Bernhard Raab
Abstract: A process for the preparation of .alpha.,.beta.-unsaturated carbonyl compounds of the formula I ##STR1## where R.sup.1 is hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.10 -alkoxy or aryloxy,R.sup.2 is aryl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, trifluoromethyl and/or halogen andR.sup.3 is tetrahydrofuranyl or aryl which is substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, trifluoromethyl and/or halogen, which comprises reacting 3-amino-2-propen-1-ones of the formula II ##STR2## where R.sup.1 and R.sup.2 have the abovementioned meanings, and R.sup.4 and R.sup.5 are, independently of one another, hydrogen, C.sub.1 -C.sub.10 -alkyl or aryl, with a magnesium halide of the formula IIIR.sup.3 --Mg--Y (III)where Y is halogen, at from -20.degree. to 100.degree. C., and novel .alpha.,.beta.-unsaturated carbonyl compounds and novel 3-amino-2-propen-1-ones are described.
Type:
Grant
Filed:
October 1, 1991
Date of Patent:
December 8, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Heinz Isak, Norbert Goetz, Thomas Kuekenhoehner
Abstract: Magnetic recording media consist of a nonmagnetic substrate and at least one magnetizable layer which is firmly applied thereon and is based on a polyurethane binder, not less than 50% by weight of the binder consisting of a high molecular weight branched polyurethane elastomer having OH-containing urea groups at the chain ends, and the frictional properties of the binder being improved and its coefficient of friction reduced by incorporation of perfluoro groups.
Type:
Grant
Filed:
August 23, 1990
Date of Patent:
December 8, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael Bobrich, August Lehner, Albert Kohl, Rudolf Suettinger, Uwe Keppeler, Werner Lenz, Roller Hermann, Helmut Kopke, Guenther Schulz
Abstract: Riboflavin is removed from fermentation suspensions by them being heated at from 50.degree. to 90.degree. C. for from 1 to 3 hours, than cooled to from 0.degree. to 30.degree. C. over a period of from 1 to 5 hours, and subsequently being centrifuged to give a sediment fraction and liquid fraction in such a way that the sediment fraction contains predominantly riboflavin crystals as solid, and the liquid fraction contains virtually no crystalline riboflavin, and, where appropriate, resuspending the sediment fraction in from 0.5 to 2 parts by volume of water per part by volume of sediment fraction and repeating procedure c.
Type:
Grant
Filed:
January 23, 1991
Date of Patent:
December 8, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Tillmann Faust, Joachim Meyer, Georg Wellinghoff, Walter Gosele, Christoph Martin, Johannes Grimmer
Abstract: Cyclohexenone derivatives of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3 and A have the meanings stated in the description, herbicides which contain these compounds as active ingredients, and a method for controlling undesirable plant growth.
Type:
Grant
Filed:
August 30, 1990
Date of Patent:
December 8, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Dieter Jahn, Rainer Becker, Michael Keil, Ulrich Schirmer, Bruno Wuerzer, Norbert Meyer
Abstract: A process for the continuous recovery of .epsilon.-caprolactam provides a carpet made from nylon 6 fibers and having a backing to a separator to prepare scrap containing nylon 6 and waste. The scrap from the separator is fed to a depolymerizing reactor where the scrap is subjected to a depolymerization catalyst, temperatures of at least the melting point of nylon 6 and superheated steam to produce an .epsilon.-caprolactam containing distillate and more waste. The .epsilon.-caprolactam in the distillate is separated from other volatiles therein; and purified.
Type:
Grant
Filed:
June 21, 1991
Date of Patent:
December 8, 1992
Assignee:
BASF Corporation
Inventors:
Thomas F. Corbin, Edward A. Davis, Jack A. Dellinger
Abstract: The present invention provides a resin which is a mixture of a) the product of a diol and one or more diepoxides and b) an A-B-A block copolymer wherein A represents blocks of an epoxy/diol copolymer which is the reaction product of a diol and a diepoxide, and B represents blocks of an epoxy-capped, carboxyl-terminated polybutadiene or polybutadiene/acrylonitrile copolymer.Amine resins, produced by reaction of this resin with an amine are useful as the principal resin in electrocoating formulations which produce deposited films having excellent corrosion resistance and improved impact and chip resistance.
Abstract: The application relates to a process for removing nobler metal ions than iron, especially copper ions, from acidic process and waste waters by reduction under an inert gas atmosphere with carbonyl iron powders which have previously been subjected to a thermal treatment with hydrogen to remove nitrides and carbides. This process results in residual metal ion content <0.5 ppm and thus complete removal of the metal ions to be reduced.
Type:
Grant
Filed:
January 13, 1992
Date of Patent:
December 8, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgag Habermann, Armin Haag, Wolfgang Kochanek
Abstract: A predominantly polyester fabric has a multi-colored pattern. The fabric includes at least one non-aromatic, partially crystalline polymethylolefin yarn melting above about 180.degree. as less than 50%, by weight, of the fabric, and polyester yarn. The polymethylpentene yarn and the polyester yarn are fabricated in a predetermined pattern and then piece dyed with disperse dye techniques.
Type:
Grant
Filed:
November 25, 1991
Date of Patent:
December 8, 1992
Assignee:
BASF Corporation
Inventors:
Matthew B. Hoyt, Bobby J. Bailey, Dean R. Gadoury
Abstract: There is disclosed a metallic and nonmetallic water borne base coat compositions exhibiting excellent appearance. A method for long term stability and the introduction of aluminum flake pigments into a water borne coating is also disclosed. The method is based on storing the aluminum flake in a solvent environment with introduction of the aluminum flake in to the aqueous environment just before appling the base coat coating. A water reducible acrylic resin with nonionic and acid functionality has been disclosed that allows for direct introduction of aluminum flake in to an aqueous environment. The coating vehicle is based on acrylic latex vehicle which exhibits excellent drying and film properties. The rheology control agent employed allows for a wetter application of the coating to the substrate. The coating compositions disclosed are also in compliance with current and proposed volatile organic compound regulations.
Type:
Grant
Filed:
September 10, 1990
Date of Patent:
December 1, 1992
Assignee:
BASF Corporation
Inventors:
James L. Anderson, Jr., Horst J. Finkenauer, David L. Newton, Jeff P. Jones
Abstract: An acrylic multifilamentary material possessing an internal structure which is particularly suited for thermal conversion to high strength carbon fibers is formed via a specifically defined combination of processing conditions. The acrylic polymer while in substantially homogeneous admixture with appropriate concentrations (as defined) of acetonitrile and water is melt extruded and is drawn at a relatively low draw ratio which is substantially less than the maximum draw ratio achievable. This fibrous material which is capable of readily undergoing drawing is passed through a heat treatment zone wherein the evolution of residual acetonitrile and water takes place. The resulting fibrous material following such heat treatment is subjected to additional drawing to accomplish further orientation and internal structure modification and to produce a fibrous material of the appropriate denier for carbon fiber production.
Type:
Grant
Filed:
March 26, 1990
Date of Patent:
December 1, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Gene P. Daumit, Yoon S. Ko, Christopher R. Slater, Jozef G. Venner, Chi C. Young
Abstract: The invention relates to energy absorbing, water blown, rigid polyurethane foams. The foams of the present invention are low density, predominantly open celled foams which exhibit a relatively constant consistency of compressive strength over deflection. Such foams are suitable as light weight alternatives in traditional energy absorbing applications.
Type:
Grant
Filed:
March 23, 1992
Date of Patent:
December 1, 1992
Assignee:
BASF Corporation
Inventors:
Richard C. Rossio, Mark A. Easterle, Michael L. Jackson