Abstract: Copolymers of monoalkyl maleates or maleic acid and salts thereof and vinyl alkyl ethers are prepared by free radical copolymerization of maleic anhydride and vinyl alkyl ethers and subsequent reaction with an alkanol or water and optionally metal hydroxides and/or oxides in a process wherein at every stage of the polymerization the vinyl alkyl ether component is present in excess in the reaction mixture, the free radical copolymerization is carried out in acetone and the acetone is removed by distillation during or after the esterification or hydrolysis, which comprises using a peroxyester of a carboxylic acid of 8 or more carbon atoms as polymerization initiator. The copolymers obtained are used in cosmetic preparations.
Type:
Grant
Filed:
June 3, 1991
Date of Patent:
October 13, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Harald Meyer, Axel Sanner, Hans-Juergen Raubenheimer, Franz Frosch
Abstract: A platinum-on-graphite catalyst having a platinum content of from 0.01 to 5% w/w, wherein the graphite support has an apparent density of from 1.7 to 2.2 g/ml and the use thereof as a hydrogenation catalyst.
Type:
Grant
Filed:
July 16, 1991
Date of Patent:
October 13, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Werner Steigleiter, Wolfgang Hoelderich, Franz-Josef Weiss, Hugo Fuchs, Luc Guns, Gerald Neubauer, Josef Ritz
Abstract: Stabilized aqueous C.sub.14 -C.sub.22 -alkyldiketene emulsions containing, as essential components:(a) from 10 to 60% w/w of at least one C.sub.14 -C.sub.22 -alkyldiketene,(b) from 1 to 10% w/w of at least one protective colloid and(c) from 0.1 to 20% w/w of at least one ester of formula I ##STR1## in which R.sup.1 and R.sup.2 each denote C.sub.14 -C.sub.22 -alkyl, R.sup.1 differing in this case from R.sup.2 by at least 4 carbon atoms in the alkyl chain, and/or the same or different C.sub.14 -C.sub.22 -alkenyl groups, or at least one ester of the formula R.sup.3 --O--CO--O--R.sup.4 (II), in which R.sup.3 and R.sup.4 are alkyl or alkenyl radicals of from 2 to 22 carbon atoms or at least one urethane of formula III ##STR2## in which R.sup.5, R.sup.6 and R.sup.7 are the same or different alkyl or alkenyl radicals of from 2 to 22 carbon atoms and one of the substituents R.sup.5, R.sup.6 and R.sup.
Type:
Grant
Filed:
January 9, 1991
Date of Patent:
October 13, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Ksoll, Erwin Hahn, Peter Wittmer, Andreas Hohmann, Arnold De Clercq, Ulrich Riebeling
Abstract: Cyclohexenone derivatives of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3, Y and Z have the meanings given in the disclosure, processes for their manufacture, herbicidal and growth-regulating agents containing the novel active ingredients, and processes for combating unwanted plant growth and for regulating plant growth.
Type:
Grant
Filed:
August 14, 1991
Date of Patent:
October 13, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Norbert Meyer, Johann Jung, Wilhelm Rademacher, Dieter Kolassa, Rainer Becker, Dieter Jahn, Michael Keil, Ulrich Schirmer, Bruno Wuerzer
Abstract: Low levels (2-6 percent active) of ethylene oxide/propylene oxide block copolymers have been found to significantly enhance the oily and particular soil removal of detergents containing anionic surfactants and ethoxylated alcohols or other oxyalkylate surfactants.
Abstract: The present invention relates to a process for the production of elastic, compact or cellular moldings based on elastomers containing N-benzylurea groups in bound form, by reactinga) one or more organic and/or modified organic polyisocyanates withb) N-benzylpolyoxyalkylene-polyamines or mixtures of N-benzylpolyoxyalkylene-polyamines and polyoxyalkylene-polyamines containing from 2 to 4 primary amino groups andc) one or more alkyl-substituted aromatic polyamines having a molecular weight of up to 500,in the presence or absence ofd) catalystsand, if desired,e) blowing agents,f) auxiliaries and/org) additives,and to the N-benzylpolyoxyalkylene-polyamines and mixtures of N-benzylpolyoxyalkylene-polyamines and polyoxyalkylene-polyamines containing from 2 to 4 primary amino groups which can be used for this purpose, and to the elastomers prepared.
Type:
Grant
Filed:
January 24, 1992
Date of Patent:
October 6, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Johannes Becker, Guenther Matzke, Hans U. Schmidt, Willibald Schoenleben
Abstract: A process for the production of magnetic recording media having stochastic orientation of the magnetic anisotropic particles in the magnetic layer with the aid of a magnetic drum rotating above the still fluid dispersion layer and containing radially arranged permanent magnets of alternating polarity, and a corresponding apparatus for carrying out the process.
Type:
Grant
Filed:
October 8, 1991
Date of Patent:
October 6, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Ronald J. Veitch, Gerhard Soehring, Helmut Jakusch, Volker Koch
Abstract: Thermoplastic molding materials which are free of cyanuric acid or cyanuric acid derivatives contain as essential components,(A) from 5 to 95% by weight of a toughened polyamide ofa1) from 70 to 98% by weight, based on (A), of a polyamide anda2) from 2 to 30% by weight, based on (A), of an emulsion polymer whose particles do not have a hard outer shell, and(B) from 5 to 95% by weight of a functionalized polyphenylene ether.
Type:
Grant
Filed:
February 21, 1990
Date of Patent:
October 6, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Muehlbach, Graham E. McKee, Ehrenfried Baumgartner
Abstract: 9-Amino-2-phenylbicyclo-[3.3.1]nonanes and 9-amino-2-phenylbicyclo[3.3.1]non-2-enes of the formula I ##STR1## where R.sup.1 and R.sup.2 are identical or different and each is hydrogen, halogen, alkyl, alkoxy, dialkylamino, trifluoromethyl, hydroxyl, alkylthio, alkylsulfonyl or nitro, R.sup.3 and R.sup.4 are identical or different and each is hydrogen, alkyl or 1 to 5 or alkenyl or alkynyl of 2 to 5 carbon atoms, or benzyl, it also being possible for R.sup.3 and R.sup.4 together to form a saturated chain which contains from three to seven carbon atoms and can be substituted by phenyl, and where is a single or double bond, are used for producing drugs which act, in particular, on the central nervous system.
Type:
Grant
Filed:
June 11, 1991
Date of Patent:
October 6, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Rainer Schlecker, Hans P. Hofmann, Laszlo Szabo
Abstract: A method of crosslinking protein comprises making a composition which comprises a protein, a sugar, a water-soluble salt of a carboxylic acid, water, and an additional ingredient which is to be encapsulated or entrapped within the crosslinked protein matrix. The composition is thereafter heated while maintaining the moisture content at a level of at least about 3 weight percent, based on the weight of the composition.A product comprises a protein which is crosslinked to degree at which it is substantially insoluble upon being placed in water at 100.degree. C. for at least 3 minutes, a sugar, a water-soluble salt of a carboxylic acid, water, and an additional ingredient which is encapsulated or entrapped within the crosslinked protein matrix.
Type:
Grant
Filed:
January 10, 1991
Date of Patent:
October 6, 1992
Assignee:
BASF Corporation
Inventors:
Frederick K. Chaundy, David K. Bower, Terence K. Kilbride, Jr.
Abstract: Aminobenzophenones have the formula ##STR1## where the ring A may be benzofused,X.sup.1 is hydrogen or hydroxysulfonyl,X.sup.2 is hydrogen, hydroxysulfonyl, hydroxysulfonylphenyl, hydroxysulfonylbenzyl or hydroxysulfonylphenylethyl,R.sup.1, R.sup.2 and R.sup.3 are each independently of the others hydrogen, halogen, C.sub.1 -C.sub.12 -alkyl, cyclohexyl or C.sub.1 -C.sub.4 -alkoxy, or one of them may also be the radical of the formula ##STR2## where L is a chemical bond, C.sub.1 -C.sub.4 -alkylene or --O--CH.sub.2 -- and Y.sup.1, Y.sup.2 and Y.sup.3 are each independently of the others hydrogen, halogen, C.sub.1 -C.sub.12 -alkyl or C.sub.1 -C.sub.4 -alkoxy and R.sup.4, X.sup.1, X.sup.2 and the ring A are each as defined above, andR.sup.4 is hydrogen or chlorine,with the proviso that X.sup.1 and X.sup.2 are not both hydrogen, their intermediates having the formula ##STR3## where L is as defined above.
Abstract: Copolymers selectively hydrogenated on the olefinic double bond and composed ofA) 50 to 65% by weight styrene,B) 35 to 50% by weight butadiene andC) 0 to 5% by weight other copolymerizable monomers are used in cosmetic and pharmaceutical compositions.
Type:
Grant
Filed:
June 13, 1991
Date of Patent:
October 6, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Friedrich Vogel, Franz Frosch, Horst Westenfelder
Abstract: 3-Isoxazolylbenzyl esters of the general formulae Ia and Ib ##STR1## where R is halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.2 --C.sub.4 -alkenyl, C.sub.2 -C.sub.4 -haloalkenyl, C.sub.2 -C.sub.4 -alkynyl, C.sub.2 -C.sub.4 -haloalkynyl, unsubstituted or substituted phenylethenyl, C.sub.3 -C.sub.8 -cycloalkyl, aryl, hetaryl, CO.sub.2 R.sup.3 or CONR.sup.4 R.sup.5,R.sup.3, R.sup.4 and R.sup.5 are each hydrogen or C.sub.1 -C.sub.6 -alkyl,n is 0, 1 or 2, and the radicals R may be different when n is 2,R.sup.1 is halogen or C.sub.1 -C.sub.4 -alkyl,R.sup.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -alkenyl, C.sub.2 -C.sub.4 -alkynyl or cyano andA is the carbonyl radical of an acid component usually found in pyrethroids, are contained in pesticides.
Type:
Grant
Filed:
May 14, 1991
Date of Patent:
September 29, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Stefan Mueller, Hans Theobald, Bernd Wolf, Peter Hofmeister, Uwe Kardorff, Christoph Kuenast
Abstract: A process for the preparation of dialkyl carbonates of the general formula I ##STR1## in which R.sup.1 denotes C.sub.1 -C.sub.10 -alkyl, by reaction of alcohols R.sup.1 OH with a gaseous carbon monoxide/oxygen mixture in the presence of a copper catalyst and a co-solvent at elevated temperature and pressure wherein the co-solvent used is a cyclic urea of the general formula II ##STR2## in which n is equal to 2, 3 or 4 and R.sup.2 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl.
Type:
Grant
Filed:
August 6, 1990
Date of Patent:
September 29, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Joerg, Rudolf Kummer, Franz-Josef Mueller
Abstract: A benzofurancarboxamide of the formula: ##STR1## where: X is hydrogen or methoxy,R.sup.1 is a radical of the formula: ##STR2## wherein R.sup.3 to R.sup.5 are each, independently of one another, hydrogen or C.sub.1-6 alkyl, R.sup.6 is a branched or unbranched C.sub.1-6 alkyl, or benzyl which may be methyl- or halogen-substituted on the nucleus, and is a single or double bond.
Abstract: Perylimides useful as monomers have the formula ##STR1## wherein R.sup.1 is C.sub.1 -C.sub.20 -alkyl which may be interrupted by one or more oxygen atoms or is substituted phenyl,R.sup.2 has the meanings hydrogen, chlorine or substituted or unsubstituted phenoxy independently of one another in its four appearances,X is a chemical bond or a radical of the formula ##STR2## where R.sup.3 and R.sup.4 are each independently of the other hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen m is 1 or 2, and n is 0 or 1,Y is C.sub.6 -C.sub.14 -alkylene which may be interrupted by one or more oxygen atoms or by one or more imino or C.sub.1 -C.sub.4 -alkylimino groups, andZ is vinyl, acryloyloxy or acryloxylamino.
Type:
Grant
Filed:
October 12, 1990
Date of Patent:
September 29, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Karin H. Beck, Karl-Heinz Etzbach, Hans-Werner Schmidt
Abstract: A process for preparing 2-methylbenzoxazole by cyclizing acetamidophenol with the simultaneous elimination of the water of reaction. The process involves the drying and melting of the acetamidophenol, the cyclization of acetamidophenol to 2-methylbenzoxazole, and the removal of the water of reaction and the 2-methylbenzoxazole from the reaction mixture after the cyclization step by distillation. All the steps are carried out in a dryer.
Type:
Grant
Filed:
March 11, 1991
Date of Patent:
September 29, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Manfred Gaeng, Heinz Saukel, Wolfgang Hoffmann, Josef Koenig
Abstract: Benzene derivatives of the general formula ##STR1## where Hal is halogen, R.sup.1 is a hydrocarbon radical of 1 to 18 carbon atoms, R.sup.2 is hydrogen or alkyl of 1 to 6 carbon atoms and X is hydrogen or halogen, are prepared by a process in which a toluene derivative of the general formula ##STR2## is electrochemically oxidized in the presence of an acid of the formula R.sup.2 --COOH (III). Novel benzene derivatives of the general formula ##STR3## where R.sup.3 is hydrogen or an R.sup.2 --CO-- radical but R.sup.1 cannot be methyl if X is hydrogen, and of the general formula ##STR4## where R.sup.4 is a branched or cyclic alkyl radical of 3 to 12 carbon atoms, but R.sup.4 cannot be isopropyl if X is hydrogen. The compounds of formulas IV and VI are intermediates for crop protecting agents, e.g. pyrethroids.
Type:
Grant
Filed:
June 12, 1989
Date of Patent:
September 29, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Dieter Hermeling, Dieter Degner, Albrecht Harreus, Norbert Goetz, Jochen Wild, Hans Theobald, Bernd Wolf
Abstract: Phenoneazo dyes of the formula ##STR1## where R.sup.1 is substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or substituted phenyl,R.sup.2 is cyano, carbamoyl or acetyl,R.sup.3 is substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or C.sub.3 -C.sub.12 -alkyl which is interrupted by from 1 to 3 oxygen atoms and may be substituted, andR.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl,are useful for thermal transfer processes and for dyeing or printing synthetic fabrics.
Type:
Grant
Filed:
August 16, 1990
Date of Patent:
September 29, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Volker Bach, Guenter Hansen, Gunther Lamm, Ruediger Sens