Abstract: An antistatic expandable styrene polymer in bead form, containinga) a styrene polymer,b) from 0.5 to 3% by weight, based on a), of a coating containingb1) from 10 to 70% by weight of finely divided silica;b2) from 20 to 80% by weight of a hydroxy-containing quaternary ammonium saltand, if desired, p1 b3) from 0.05 to 20% by weight of a conventional coupling agent and/orc) from 1 to 8% by weight, based on a), of a C.sub.3 to C.sub.6 hydrocarbon as blowing agent,and, if desired,d) conventional additives in effective amounts.
Type:
Grant
Filed:
August 5, 1991
Date of Patent:
May 5, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Manfred Walter, Karl-Heinz Wassmer, Maria Lorenz
Abstract: N-Aryl-substituted 2-amino-alkyl-2-hydroxyalkylamines and N-aryl-substituted piperazines Ia and Ib respectively ##STR1## (Ar=aryl; R.sup.1 =hydrogen, methyl, identical or different, R.sup.2 =hydrogen, alkyl) are prepared by reacting an N,N-di(2-hydroxyalkyl)-N-arylamine II ##STR2## with ammonia or a primary amine IIIH.sub.2 N-R.sup.2 IIIat elevated temperature and under elevated pressure in the presence of hydrogen and of a catalyst which is a supported catalyst whose active mass predominantly contains copper and/or nickel and/or cobalt in the form of the metal or an oxide.
Abstract: A hair-setting preparation which contains(1) a solution of at least one terpolymer in an anhydrous or water-containing organic solvent, the terpolymer having been prepared by the copolymerization of(a) an N-alkylacrylamide or N-alkylmethacrylamide having 1 to 4 carbon atoms in the alkyl moiety, with(b) a C.sub.1 -C.sub.4 -alkyl ester or C.sub.1 -C.sub.4 -hydroxyalkyl ester of acrylic acid or methacrylic acid, and with(c) an .alpha.,.beta.-unsaturated moncarboxylic acid or dicarboxylic acid, and at least 50% of the carboxyl groups in the terpolymer having been neutralized by a lower organic base, and(2) a propellent which consists of at least 30% by weight, based on the total propellent, of a halogen-free propellent gas, in particular a hydrocarbon.
Abstract: A method for making low density (0.8-1.1 lb/cu.ft.) expanded polymeric products uses blowing agent in an amount of only from 2 to 4.4 weight percent. The process uses 2 to 5 expansion steps together with a polymer having a particular polydispersity, weight average molecular weight and M.sub.z :M.sub.n, this polymer having a greater expandability than conventional polymers. The process requires only about half of the amount of blowing agent currently being used in commercially viable processes for making expanded polystyrene products. The process can be used with or without a molding step.
Type:
Grant
Filed:
November 26, 1990
Date of Patent:
May 5, 1992
Assignee:
BASF Corporation
Inventors:
William H. Harclerode, William E. Volz, John V. Wiman, John C. Voss, Barry J. Pekich, John C. Knutsen
Abstract: A radiation-sensitive mixture, essentially consisting ofa) a binder or binder mixture which is insoluble in water but soluble in aqueous alkaline solutions,b) a compound which forms a strong acid on exposure to radiation andc) an organic compound which contains an acid-cleavable carbamate unit,is suitable for the production of relief structures.
Abstract: 2,2'-Thienylbenzothiophenes of the general formula I ##STR1## where R.sup.1 and R.sup.3 independently of one another are each halogen, alkyl, haloalkyl, alkoxy or haloalkoxy, R.sup.2 is hydrogen, halogen, alkyl, haloalkyl, alkoxy or haloalkoxy, n is 0, 1 or 2, and the radicals may be different when n is 2, and m is 0, 1, 2, 3 or 4, and the radicals may be different when m is 2, 3 or 4, processes for their preparation, pesticides containing them and the use thereof.
Type:
Grant
Filed:
July 30, 1991
Date of Patent:
May 5, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Reiner Kober, Hans Theobald, Uwe Kardorff, Christoph Kuenast, Peter Hofmeister, Rainer Seele, Gerhard Wagenblast
Abstract: A method for making low density (0.8-1.1 lb/cu. ft.) expanded polymeric products uses blowing agent in an amount of only from 2 to 4.4 weight percent. The process uses 2 to 5 expansion steps together with a polymer having a particular polydispersity, weight average molecular weight and M.sub.z :M.sub.n, this polymer having a greater expandability than conventional polymers. The process requires only about half of the amount of blowing agent currently being used in commercially viable processes for making expanded polystyrene products. The process can be used with or without a molding step.
Type:
Grant
Filed:
October 15, 1991
Date of Patent:
May 5, 1992
Assignee:
BASF Corporation
Inventors:
William H. Harclerode, William E. Volz, John V. Wiman, John C. Voss, Barry J. Pekich, John C. Knutsen
Abstract: A process for the production of a recording material consisting of a layer support and one or more recording layers cast thereon, for example a magnetic layer or photographic layers, is characterized in that the flexible layer support in the form of a tape contains at least one liquid crystalline polymer. The recording material thus produced is distinguished by excellent properties and in addition affords the advantage that after production of the layer support, the recording layers can be applied on line at a high casting velocity by means of known casting processes.
Abstract: A process for the preparation of purified indigo comprises extracting the aqueous alkaline indoxylate solution arising from the synthesis with an inert water-insoluble solvent in the absence of oxygen before oxidizing the indoxylate solution to give indigo.
Type:
Grant
Filed:
July 15, 1991
Date of Patent:
April 28, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Reinhold Kohlhaupt, Manfred Gaeng, Lothar Haas, Guenter Engelhardt, Walter Bieg, Matthias Fankhaenel
Abstract: A process for the preparation of lower polyhydric alcohols by catalytic hydrogenation of aqueous saccharose solutions at elevated temperature and pressure using a catalyst of which the catalytically active material essentially contains the metals cobalt, copper and manganese in the following concentrations, the total weight of said metals being standardized as 100%:from 0 to 100% w/w of cobalt,from 0 to 85% w/w of copper andfrom 0 to 80% w/w of manganese,this said metal content of said catalytically active material comprising either cobalt alone or at least two of said metals, which active material may also contain added inorganic poly acids and/or heteropoly acids, wherein from 0.01 to 5% w/w of one or more base-acting metal compounds of metals from the first and second main groups and from group IIIA of the Periodic Table are added to the saccharose solution to be hydrogenated.
Abstract: A metal/metal oxide electrode for determining chlorine in aqueous solutions comprises a metallic tantalum core on which there is non-porous tantalum suboxide.
Type:
Grant
Filed:
August 23, 1990
Date of Patent:
April 21, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Habermann, Axel Anderlohr, Wolfgang Steiner
Abstract: Foam sheets of high heat distortion resistance contain a) from 80 to 99% by weight of a styrene polymer and b) from 1 to 20% by weight of poly-1,4-phenylene sulfide, and, if desired, conventional additives and are produced by extrusion using a low-boiling blowing agent.
Type:
Grant
Filed:
February 15, 1991
Date of Patent:
April 21, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Reinhold Weber, Gerhard Alicke, Manfred Weilbacher, Uwe Guhr, Klaus Hahn
Abstract: The preparation of 2-formyl-2-methyl succinates by reacting itaconates with carbon monoxide and hydrogen in contact with a catalyst system comprising rhodium and a tertiary phosphorus compound, wherein the reaction is carried out under a pressure of from 90 to 325 bar.
Abstract: The novel compound 2-neopentylanthraquinone which is prepared by Friedel-Crafts acylation of neopentylbenzene with phthalic anhydride and subsequent cyclization of the resulting 2-(4-neopentylbenzoyl)-benzoic acid in the presence of a strong, anhydrous acid, is a catalyst for the preparation of hydrogen peroxide.
Type:
Grant
Filed:
May 23, 1989
Date of Patent:
April 21, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Manfred Eggersdorfer, Jochen Henkelmann, Walter Grosch
Abstract: Thiadiazabicyclononane derivatives of the formula I ##STR1## (R.sup.1 =H, F; R.sup.2 =halogen; R.sup.3 =H, C.sub.1 -C.sub.4 -alkyl; R.sup.4 =H, C.sub.1 -C.sub.8 -alkoxycarbonyl, C.sub.3 -C.sub.6 -alkenyloxycarbonyl or C.sub.3 -C.sub.5 -alkynyloxycarbonyl, and these 3 groups may additionally bear C.sub.1 -C.sub.4 -alkoxy; X, Y, Z=O,= S; a=C.sub.2 -C.sub.3 -alkylene chain which in addition to R.sup.4 may bear up to 3 identical or different radicals R.sup.5 : OH, COOH, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.6 -alkoxycarbonyl, and the last two radicals may in turn bear up to 5 halogen atoms or one of the following substituents; OH, CN, SH, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkenylthio, C.sub.3 -C.sub.6 -alkynyloxy, C.sub.3 -C.sub.6 -alkynylthio, C.sub.1 -C.sub.6 -alkylcarbonyloxy, C.sub.1 -C.sub.6 -alkoxycarbonyl, C.sub.1 -C.sub.6 -alkoxycarbonyl-C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.6 -alkoxycarbonyl-C.sub.1 -C.sub.4 -alkylthio).
Type:
Grant
Filed:
August 2, 1990
Date of Patent:
April 21, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Lothar Rueb, Karl Eicken, Karl-Otto Westphalen, Bruno Wuerzer
Abstract: A process for the preparation of a quinophthalone of the formula ##STR1## in which X is hydrogen, chlorine or bromine and n is an integer from 1 to 4, by condensing 8-aminoquinaldine with a phthalic anhydride, optionally monosubstituted or polysubstituted by chlorine or bromine, in the presence of molten benzoic acid acting as diluent.
Abstract: A mixture consisting of a) a triazolylmethyldiphenyloxirane derivate and b) fenpropimorph, fenpropidin or tridemorph and which exhibits a synergistic fungicidal action, and methods of combating fungi with this mixture.
Type:
Grant
Filed:
October 19, 1990
Date of Patent:
April 21, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Rainer Seele, Friedrich Loecher, Reinhold Saur, Eberhard Ammermann, Gisela Lorenz
Abstract: Methods of combating pests with substituted pyrimidines of the formula I ##STR1## where R.sup.1 is alkyl, cycloalkyl, haloalkyl, alkoxy, alkylthio or substituted or unsubstituted aryl, R.sup.2 is halogen or hydrogen, A is oxygen or sulfur, and X is CH or N, and pyrimidines of the general formula Ia ##STR2## where A is oxygen or sulfur and X is CH or N, and pesticides containing these compounds.
Type:
Grant
Filed:
April 29, 1991
Date of Patent:
April 21, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Franz Schuetz, Siegbert Brand, Jochen Wild, Thomas Kuekenhoehner, Peter Hofmeister, Christoph Kuenast
Abstract: This invention deals with novel copolymers having K values from 5 to 80 prepared by the radical polymerization of:(A) 20 to 80 weight percent, based on the total weight of (A) and (B), of at least one olefinic unsaturated polyoxyalkylene alcohol adduct or a polyester alcohol adduct;(B) 80 to 20 weight percent, based on the total weight of (A) and (B), of at least one vinyl monomer selected from the group consisting of N-vinylformamide, N-vinyl-2-pyrrolidone, N-vinyl-piperidone, N-vinyl-2-caprolactam, N-vinylimidazole, N-vinyl-2-ethylene-urea and N-vinyl-2-propylene-urea;(C) 0 to 40 parts by weight of glycidyl acrylate and/or glycidyl methacrylate;(D) 0 to 10 parts by weight of at least one .alpha.,.beta.-monoolefinic unsaturated acid; and(E) 0 to 30 parts by weight of at least one olefinic unsaturated carboxylic acid amide and or carboxylic acid ester and/or styrene;whereby the parts by weight of (C), (D) and (E) are each based on 100 parts by weight of monomers (A) and (B).
Type:
Grant
Filed:
November 1, 1989
Date of Patent:
April 21, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Horn, Gerd Rehmer, Heinz-Dieter Lutter, Gerhard Ramlow
Abstract: Phenyloxadiazolylanilines are prepared by reaction of a benzonitrile in an aqueous reaction medium first with hydroxylamine or an acid addition salt thereof to give a benzamideoxime and then with an isatoic anhydride to give a non-cyclic compound and subsequent cyclization, the reaction sequence being carried out in the presence of an anionic surfactant.