Abstract: A thickened, uncrosslinked molding composition which has a long shelf life and can be cured above 50.degree. C. comprises a liquid reactive system, a thickener, a polymerization initiator and conventional additives. The thickener is a combination of a primary aromatic amine and an isocyanate. The molding compositions, which are, in particular, SMCs or BMCs, can be processed into moldings by compression molding, injection molding or transfer molding and subsequent curing.
Abstract: 4-Chloropyrazoles of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each independently of the others hydrogen or a radical which is inert under the reaction conditions, are prepared by reacting pyrazoles of the general formula II ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each as defined above, with 0.95-10 equivalents of hypochloric acid, or salts thereof, in the substantial absence of any carboxylic acid.
Abstract: Hotmelt contact adhesives which are crosslinkable with UV light in the air are based on copolymers which contain tetrahydrofurfur-2-yl (meth)acrylate and/or N-2-tetrahydrofurfuryl (meth)-acrylamide and/or alkoxyalkyl (meth)acrylates and/or N-alkoxyalkyl (meth)acrylamides as copolymerized units and added benzophenone and/or benzophenone derivatives as photosensitizers.
Abstract: Cable insulation having high resistance to the formation or growth of water trees and high aging resistance consists of an ethylene polymer (I) and from 0.5 to 20% by weight of an ethylene polymer (II), which is an ethylene/C.sub.1 -C.sub.8 -alkyl-C.sub.3 -C.sub.6 -alkene carboxylate/C.sub.3 -C.sub.6 -alkenecarboxylic acid terpolymer.
Type:
Grant
Filed:
March 5, 1987
Date of Patent:
September 10, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Johannes Schlag, Ernst Koehnlein, Peter Bauer, Ludwig Koessler
Abstract: An optical recording medium contains silicon naphthalocyanines of the formula ##STR1## where Nc is the radical of a naphthalocyanine system which may be substituted by alkyl, alkoxy, aryl or aralkyl, andR.sup.1 and R.sup.2 are each independently of the other a radical of the formula (O).sub.n R.sup.3, where n is 0 or 1 and R.sup.3 is an unsubstituted radical, or ##STR2## where R.sup.3 is as defined above and R.sup.4 and R.sup.5 are each independently of the other alkyl, alkoxy or (O).sub.n R.sup.3 or R.sup.1 is alkyl.
Type:
Grant
Filed:
August 22, 1989
Date of Patent:
September 10, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernhard Albert, Peter Neumann, Sibylle Brosius
Abstract: 3-Amino-2-cyanoacrylonitrile derivatives of the formula ##STR1## where R is substituted C.sub.1 -C.sub.10 -alkyl, substituted or unsubstituted styryl, substituted or unsubstituted phenyl or aromatic heterocyclyl, are prepared by treating a nitrile in an inert organic diluent at from 0.degree. to +30.degree. C. with a substituted or unsubstituted C.sub.1 -C.sub.6 -alkanol in the presence of a hydrogen halide and reacting the resulting iminoester hydrohalide directly or after isolation with malodinitrile in an inert organic diluent at from 20.degree. to 100.degree. C. in the presence of a base.
Abstract: Phosphoric acid is separated from aqueous solutions of thiamine phosphates which are obtained in the phosphorylation of thiamine, with or without subsequent partial hydrolysis, by a process in which the phosphoric acid is converted with a virtually water-insoluble or only slightly water-soluble tertiary amine into the corresponding salt and the latter is extracted with a virtually water-immiscible or only slightly water-miscible solvent of moderate polarity. In a particularly advantageous procedure, the phosphoric acid is extracted with a mixture of a virtually water-insoluble or only slightly water-soluble tertiary amine and a virtually water-immiscible or only slightly water-miscible solvent of moderate polarity.
Abstract: A flow cell through which the sample stream is passed surrounded by an enveloping stream is equipped with a laser-optical measuring means. For use in pressurized systems the inlet of the cell for the enveloping stream medium is connected on the upstream side to a constant pressure and flow means and the outlet from the cell is connected on the downstream side to a regulating means for the sample and enveloping stream flow rate.
Abstract: Methods of combating pests with substituted pyrimidines of the formula I ##STR1## where R.sup.1 is alkyl, cycloalyl, haloalkyl, alkoxy, alkylthio or substituted or unsubstituted aryl, R.sup.2 is halogen or hydrogen, A is oxygen, or sulfur, and X is CH or N, and pyrimidines of the general formula Ia ##STR2## where A is oxygen or sulfur and X is CH or N, and pesticides containing these compounds.
Type:
Grant
Filed:
July 12, 1990
Date of Patent:
September 10, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Franz Schuetz, Siegbert Brand, Jochen Wild, Thomas Kuekenhoener, Peter Hofmeister, Christoph Kuenast
Abstract: Phenylsulfones of the formula ##STR1## in which R.sup. is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, nitro, hydroxysulfonyl, carboxyl,the radical --NR.sup.3 R.sup.4,in which R.sup.3 and R.sup.4 are the same or different and denote hydrogen or C.sub.1 -C.sub.4 alkyl, which may or not be substituted,or the radical S(O).sub.n R.sup.5,in which n is 0 or 2 and R.sup.5 denotes C.sub.1 -C.sub.4 -alky which may or may not be substituted,R.sup.2 is hydroxy, mercapto or the radical R.sup.1,X is the radical ##STR2## or, with R.sup.2 in the ortho-position relative to the group SO.sub.2 --X,R.sup.2 and X together denote the radial ##STR3## in which Z.sup.1 is hydroxy, chlorine, C.sub.1 -alkanoyloxy- C.sub.1 -C.sub.4 -alkylsulfonyloxy penylsulfonyloxy, o- or p-tolylsulfonyloxy or sulfato andZ.sup.2 is oxygen, sulfur, imino or optionally substituted C.sub.1 -C.sub.4 -alkylimino, andY denotes amino, C.sub.1 -C.sub.4 -alkanoylamino or nitro, and a process for the preparation thereof.
Type:
Grant
Filed:
March 13, 1990
Date of Patent:
September 10, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Manfred Patsch, Klaus Pandl, Martin Fischer
Abstract: Amino resin solutions having an electrical conductivity of <100 .mu.S/cm for impregnating paper are obtainable byA) methylolation of melamine with aqueous formaldehyde in a molar ratio of from 1:2 to 1:5 in the presence of a tertiary organic amine at a pH of from 7 to 12,B) etherification with a molar excess, based on the methylol groups, of a C.sub.1 -C.sub.4 -alcohol in the presence of an unsubstituted or substituted dicarboxylic acid and/or polycarboxylic acid at a pH of from 3 to 6,C) neutralization of the reaction mixture with an inorganic base and removal of the volatile components by distillation, except for a water content of <10% by weight, based on the reaction mixture, andD) addition of a C.sub.1 -C.sub.4 -alcohol to give a solids content of from 40 to 90% by weight, based on the amino resin solution, and removal of insoluble components by filtration.
Type:
Grant
Filed:
February 8, 1990
Date of Patent:
September 10, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Gerd Busse, Jakob Decher, Wolfgang Eisele, Edgar Haeussler, Otto Wittmann
Abstract: The preparation of 2-cyano-3,3-diarylacrylates I ##STR1## (in which Ar.sup.1 and Ar.sup.2 are aromatic radicals and R is an aliphatic radical having from 3 to 30 carbon atoms) by reacting a 2-cyano-3,3-diarylacrylate II ##STR2## (in which R.sup.1 is methyl or ethyl) with an alcohol IIIR--OH (III)in the presence of a basic catalyst with removal of the alcohol R.sup.1 -OH formed.The esters of formula I are valuable UV absorbing agents for, say, plastics materials.
Abstract: A waterborne pigmented liquid coating composition and method of making and using same which is substantially devoid of any surfactant dispersing and/or emulsifying agents thereby substantially eliminating flash-rusting upon application to ferrous substrates and improved resistance to deterioration on exposure to high moisture environments. The coating composition contains as its essential constituents one or a combination or mixture of substantially uniformly dispersed pigment particles, a film forming constituent comprising a mixture of substantially uniformly dispersed acrylic hydrosol particles and an aqueous soluble salt of a dispersant resin having acid functionality, and a liquid constituent comprising a mixture of water and organic solvents, the organic solvents functioning as coalescing agents for the film forming constituents.
Type:
Grant
Filed:
October 14, 1988
Date of Patent:
September 10, 1991
Assignee:
BASF Corporation
Inventors:
Richard A. Cowles, Nick Georgalas, Shailesh C. Shah
Abstract: Derivatives of N-phenyl-3,4,5,6-tetrahydrophthalimide of formulae I and/or II ##STR1## where A, R, E.sub.n, Y, and R.sup.16 have the meanings stated in the description, which compounds are used for the dessication and abscission of plant organs.
Type:
Grant
Filed:
February 20, 1990
Date of Patent:
September 3, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Grossmann, Christiaan E. G. Mulder, Bruno Wuerzer
Abstract: Foam particles of propylene polymers which have shrunk from 40 to 95% of their original volume and have a bulk density of from 10 to 30 g/1 can be expanded if they are treated with air or nitrogen under superatmospheric pressure, subsequently decompressed. If desired post-foamed by heating and, after aging, re-treated with air or nitrogen under superatmospheric pressure, subsequently decompressed and aged under atmospheric pressure until the pressure in the cells has dissipated.
Type:
Grant
Filed:
July 6, 1990
Date of Patent:
September 3, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Isidoor De Grave, Udo Haardt, Wolfram Koegel, Fritz E. Krueckau, Hermann Tatzel
Abstract: The present invention relates to transparent essentially non-cellular polyurethane casting compositions that are sterilizable with superheated steam which are prepared by reacting:(A) modified diphenylmethane diisocyanates (A) liquid at 23.degree. C. obtained by reacting(A1) 4,4'-diphenylmethane diisocyanate or(A2) 2,4'-diphenylmethane diisocyanate or(A3) a diphenylmethane diisocyanate mixture with(A4) at least one polyoxypropylene polyol and/or(A5) at least one polyoxypropylene polyoxyethylene polyol containing 1 to 80 weight percent of ethylene oxide units whereby (A4) and (A5) have a functionality of 4 to 8 and a hydroxyl number of 150 to 500 and are obtained while using sucrose and/or preferably sorbitol as initiator molecules(A6) a mixture of (A4) and/or (A5) and at least one polyoxypropylene polyol and/or polyoxyethylene polyol initiated with glycerine and/or trimethylolpropane in a NCO:OH group ratio of 2.
Type:
Grant
Filed:
August 8, 1990
Date of Patent:
September 3, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Horn, Werner Hinz, Walter Heckmann, Falko Ramsteiner, Friedrich Gerold
Abstract: 1-Aryl- and 1-hetarylimidazolecarboxylic esters of the general formulae Ia and Ib ##STR1## where R.sup.1 is halogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl;R.sup.2 is substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl; C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or C.sub.3 -C.sub.6 -cycloalkyl;R.sup.3 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.4 is substituted or unsubstituted phenyl or 5- or 6-membered heteroaromatic,processes for their manufacture, and agents containing them.
Type:
Grant
Filed:
January 9, 1990
Date of Patent:
August 27, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Ulrich Wriede, Gerhard Hamprecht, Hermann Koehler, Bruno Wuerzer
Abstract: Octadienols are prepared by reacting 1,3-butadiene with water in the presence of a catalyst system comprising a palladium compound, a triorganophosphorus compound and carbon dioxide and in the additional presence of a triorganophosphine oxide.
Abstract: Flame-resistant, expandable styrene polymers containing a styrene (co)polymer, from 0.4 to 6% by weight of hexabromocyclododecane having a mean particle size of from 1 to 50 .mu.m, the particles being provided with a firm coating which has a thickness of from 1/100 to 1/10 of the particle diameter and is insoluble in water and styrene, from 1 to 10% by weight of a C.sub.3 - to C.sub.6 -hydrocarbon as blowing agent, and, if desired, customary additives, are distinguished by a reduced internal water content and can be processed to form foams which have an improved foam structure and high UV stability.
Type:
Grant
Filed:
December 11, 1990
Date of Patent:
August 27, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Hahn, Uwe Guhr, Hans Hintz, Dietmar Wittenberg, Peter Gleich
Abstract: A pressure spring for tape cassettes which consists of a spring steel strip which is, in particular, narrow and is of roughly uniform width comprises a flat central part and curved spring arms adjacent to said part and having a continuous curve. The flat central part has, as fastening parts, holes with indented fastening collars which, together with rivet pegs and recesses in a housing wall, form a roughly projection-free spring fastening, the riveted peg ending roughly at the spring surface. The pressure spring exhibits a straight line with a defined slope in the operating region of its spring characteristic. The pressure spring can be used for tape cassettes of all types, in particular for video cassettes.
Type:
Grant
Filed:
March 16, 1990
Date of Patent:
August 27, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Schoettle, Juergen Dreyer, Siegfried Riegger, Willi Schuhmacher