Abstract: Finely divided, transparent, metal-free X-phthalocyanine has a specific surface area of from 75 to 120 m.sup.2 g and not less than 80% by weight of the phthalocyanine particles have a Stokes-equivalent diameter of .ltoreq.0.12 .mu.m.The phthalocyanine is very useful as a pigment for printing inks and finishes.
Abstract: High resiliency polyurethane foams are typically prepared by reaction of polyols blends comprising conventional and polymer containing polyols with aromatic polyisocyanates. Improved physical properties such as tensile strength, tear strength, and elongation of these foams can be achieved by incorporating 0.5 to 3.0 parts 2,3-dibromopropanol into the foam formulation.
Abstract: A process for the preparation of carbonyl compounds by oxidation of alcohols in the gas phase with a gas containing oxygen in the presence of catalysts containing copper or silver and a phosphorus compound that is volatile under the conditions of the reaction, the ratio of the mass of phosphorus to the mass of the alcohol being less than 0.5 ppm.
Type:
Grant
Filed:
December 9, 1987
Date of Patent:
March 21, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Fritz Graf, Heinz Engelbach, Leopold Hupfer, Harald Schultheiss, Michael J. Sprague
Abstract: An optical recording material possesses a light-absorbing layer on a base, the said layer containing one or more colorants of the formula (I) ##STR1## where M is two hydrogen atoms or Fe, Cu, Co, Ni, Pb, Cr, Mn, VO, TiO, ZrO, Nb, Ta, Pd, SiCl.sub.2, Sn or SnX.sub.2, X is Cl, Br or I, and A is a divalent radical of an unsaturated, unsubstituted or substituted carbocyclic ring system.The colorants (I) present on the novel recording materials have a high absorption in the range from 650 to 850 nm and accordingly can be written on and read by means of a laser. The colorants can be applied as 20-1000 nm layers on a suitable base by vapor deposition or as a solution or dispersion, with or without the addition of a polymeric binder, by a conventional method.The layers are very stable to atmospheric influences and daylight.
Abstract: The subject of this invention is a process for the preparation of lightweight, planar molded articles, e.g. those having a thickness from 0.1 to 40 mm and having a density of 0.015 to 0.25 g/cm.sup.3, by treating porous materials, preferably open celled or flexible or semi-rigid polyurethane foams, with an effective amount of an aqueous dispersion or emulsion of organic compounds containing NCO groups and allowing the isocyanate compound to cure, optionally while molding, at a temperature from 25.degree. C. to 180.degree. C. and optionally at a pressure of 1 to 50 bar. The invention also relates to molded articles prepared according to this process which have special mechanical properties.
Type:
Grant
Filed:
December 23, 1987
Date of Patent:
March 14, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Dietrich Scherzer, Erwin Zahn, Wolfram Frank
Abstract: Cyclohexenone derivative of the formula ##STR1## where A is oxygen or NOR.sup.8, where R.sup.8 is alkyl, alkenyl, alkynyl, haloalkyl or haloalkenyl, chlorothienyl or alkoxyalkylB is O, S, SO or SO.sub.2,X is hydrogen or methoxycarbonyl,R.sup.1 is hydrogen, carbonylalkyl, benzoyl or a cation,R.sup.2 is alkyl,R.sup.3 and R.sup.4 are hydroxyl, chlorine, bromine, thioalkylcarboxyl, thiocarbonylalkyl, alkylcarbonyloxy, alkoxy, or alkylthio, or R.sup.3 and R.sup.4 together epoxy,R.sup.5 and R.sup.6 are hydrogen or methyl or R.sup.5 and R.sup.6 are together methyleneoxyethylene, andR.sup.7 is hydrogen or methyl,and herbicides containing these compounds.
Type:
Grant
Filed:
December 24, 1986
Date of Patent:
March 14, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Dieter Jahn, Michael Keil, Dieter Kolassa, Ulrich Schirmer, Bruno Wuerzer, Norbert Meyer, Johann Jung, Wilhelm Rademacher
Abstract: A highly sensitive strain gage containing a thin discontinuous metal layer whose conduction effect is based predominantly on the tunnel effect and which is applied uniformly onto a thin, nonmetallic, dielectric or semiconducting substrate such as uniaxially oriented or partially crystalline plastic film, an ordered ultrathin layer or a silicone-coated plastic film, the diffusion processes in the applied metal layer being reduced and its structural stability improved as a result of interaction of the substrate with the metal layer.
Type:
Grant
Filed:
February 5, 1987
Date of Patent:
March 14, 1989
Assignee:
Basf Aktiengesellschaft
Inventors:
Harald Fuchs, Herbert Gleiter, Stephan Trapp, Juergen Petermann
Abstract: Bifunctional compounds of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each alkyl of 1 to 6 carbon atoms, R.sup.2 and R.sup.3 may furthermore be hydrogen, R.sup.2 is furthermore alkoxy and R.sup.4 is hydrogen, alkyl of 1 to 6 carbon atoms or alkoxy, and a double bond may be present between carbon atoms 2 and 3, are prepared by converting a tetraalkoxyalkane or a dialkoxyalkanoate of the formulae ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the above meanings, in the presence of a catalyst, such as a zeolite, in particular one of the pentasil type, and/or a phosphate and/or phosphoric acid on a carrier.
Type:
Grant
Filed:
August 6, 1987
Date of Patent:
March 14, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Hoelderich, Norbert Goetz, Leopold Hupfer
Abstract: Copolymers containing from 5 to 50 mol % of monomers having o-nitrocarbinol ester groups, from 95 to 50 mol % of O-substituted p-hydroxystyrene and from 0 to 30 mol % of other copolymerizable monomers are useful for producing positive-working photoresists and light-sensitive coating materials.
Abstract: Covered polyurethane foam panels have incorporated in them an adhesion enhancer which is composed of a polyester polyol and a heteric polyether polyol. The polyester polyol is preferably an adduct of adipic acid with ethylene glycol and butanediol. The heteric polyether polyol contains from about 35 weight percent to about 75 weight percent ethylene oxide, the remainder being propylene or butylene oxide and has a functionality from about 2 to about 3.
Type:
Grant
Filed:
November 19, 1987
Date of Patent:
March 14, 1989
Assignee:
BASF Corporation
Inventors:
James E. Shrewsburg, Edward W. Cole, III
Abstract: N-(3,5-Dichlorophenyl)-oxazolidine-2,4-diones of the formula ##STR1## where R.sup.1 is haloalkenyl, alkenyl, chloromethyl, CN, CO--O-alkyl, alkoxyalkyl or alkylthioalkyl and R.sup.2 is haloalkenyl, alkenyl, hydrogen or alkyl, are prepared by a process in which 3,5-dichlorophenyl isocyanate is reacted with a glycolate of the formula ##STR2## where R.sup.1 and R.sup.2 have the above meanings and R.sup.3 is alkyl or cyclohexyl, in the presence of a tin(II) salt of the formula ##STR3## where R.sup.4 and R.sup.5 are identical or different and are each hydrogen, alkyl, alkenyl or unsubstituted or alkyl-substituted cycloalkyl, or benzyl or phenyl, or R.sup.4 and R.sup.5 together form --CH.sub.2 --CH.sub.2 --, --CH.dbd.CH-- or o-phenylene, at from 0.degree. to 110.degree. C., the product is heated in the presence of an alcohol of the formulaR.sup.6 --OHwhere R.sup.
Abstract: The invention pertains to flame retardant polyurethane foams prepared by the reaction of a polyoxyalkylene polyether polyol with toluene diisocyanate and a blowing agent wherein the flame retardant compound is selected from the group consisting of dicyandiamide, oxamide and biuret. The amount of flame retardant may range from about 25 weight percent of about 75 weight percent of the total composition.
Type:
Grant
Filed:
October 23, 1987
Date of Patent:
March 7, 1989
Assignee:
BASF Corporation
Inventors:
Pauls Davis, Oscar M. Grace, Steven E. Wujcik
Abstract: A right parallelepiped cassette is provided with a guide insert as a separate housing part which can be produced and machined separately and very precisely, contains important guide elements of the cassette and can be oriented in a predetermined manner on reference surfaces of the remainder of the cassette housing and fastened thereon. In a particular embodiment, the cassette contains detachably fastened spacing elements for measuring the alignment of the guide elements. The cassette can advantageously be used for any type of recording media in tape or strip form.
Abstract: This invention relates to an aqueous gel comprising a specified capped polyether polymer and a surfactant. Preferred capped polyether polymers can be obtained by modifying a conventional polyether polyol with an alpha-olefin epoxide having an average of about 20 to 45 carbon atoms or mixtures thereof.
Abstract: Apparatus for clamping printing plates for rotary printing presses, having one or more clamping strips which are arranged so that they are laterally displaceable in a cylinder recess, which grip under an end region of the plate to be clamped and whose outer contour has a curvature corresponding to the cylinder curvature and is bordered by a pressure surface which engages a bent-over edge claw of the plate to be clamped, an insertable, resilient strip being inserted between the pressure surfaces of the clamping strips and a compression strip which is adjustable radially with respect to the cylinder circumference, wherein the clamping strip is adjustable in the clamping direction of the printing plates by means of two or more hydraulic cylinders which are supported at their rear and on the adjacent cylinder wall.
Abstract: Glycol-based coolant mixtures which are free of nitrites and phosphates contain alkali metal salts of bis(carboxyalkyloxyphenyl)-2,2-propane and stabilized silicate and also further corrosion-inhibiting additives.
Type:
Grant
Filed:
February 26, 1988
Date of Patent:
March 7, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Charalampos Gousetis, Knut Oppenlaender, Gert Liebold, Guenter Frey
Abstract: Pyridinol carbamate is prepared by a process in which a carbamate of the formulaH.sub.3 C--NH--CO--O--Rwhere R is methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl or tert.-butyl, is reacted with 2,6-bis-(hydroxymethyl)-pyridine in the presence of a transesterification catalyst of the Lewis acid type in the liquid phase at elevated temperatures.
Abstract: Pyridine or methylpyridines or mixtures thereof are recovered from methyl butanedicarboxylate containing reaction mixtures obtained by reaction of methyl pentenoate with carbon monoxide and methanol in the presence of pyridine, methylpyridines or mixtures thereof and also cobalt catalysts at elevated temperatures and under superatmospheric pressure and subsequent treatment with molecular oxygen containing gases in aqueous acetic acid by(a) separating the reaction mixture on the one hand into an aqueous phase containing cobalt acetate, pyridine, methylpyridines or mixtures thereof, acetic acid and methanol and on the other an organic phase containing methyl butanedicarboxylate, by-products, unconverted methyl pentenoate, acetic acid and also pyridine, methylpyridines or mixtures thereof,(b) extracting the organic phase obtained in step (a) with aqueous acetic acid to obtain an aqueous extract containing pyridine or methylpyridines or mixtures thereof as well as acetic acid,(c) combining the aqueous extract obt
Type:
Grant
Filed:
November 12, 1987
Date of Patent:
March 7, 1989
Assignee:
BASF Aktiengesellschaft
Inventors:
Hubert Lendle, Paul Panitz, Wilfried Seyfert, Peter Stops
Abstract: Superparamagnetic solid particles of the general formula IM.sub.v Mn.sub.w Zn.sub.x Fe.sub.y O.sub.z (I)where M is Co and/or Ni, v and w are each from 0 to 0.998, x is from 0.001 to 0.998, y is from 2.001 to 2.998, z is from 3.001 to 4, v+w+x is from 0.002 to 0.999, v+w+x+y is 3, v.noteq.0 if w=0 and w.noteq.0 or v=0, polar and nonpolar superparamagnetic liquids which contain the surfactant-coated superparamagnetic solid particles I in the form of a colloidal dispersion in polar or nonpolar liquid media, and processes for the preparation of polar and nonpolar superparamagnetic liquids.
Abstract: A solid material useful for producing hexagonal ferrites comprises a homogeneous mixture of the cations of the composition (I) and one or more anions comprising one or more thermally decomposable anions.