Abstract: Dihydrothiophenecarboxylates of the formula ##STR1## where R.sup.1 and R.sup.2 have the meanings given in the description, are used for controlling undesirable plant growth.
Type:
Grant
Filed:
March 31, 1983
Date of Patent:
March 20, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Rolf-Dieter Acker, Phillip A. Rossy, Gerhard Hamprecht, Bruno Wuerzer
Abstract: Self-extinguishing molding materials, comprising (A) a polymer of a vinyl-aromatic compound, especially a styrene polymer, which has been made impact-resistant (B) a polyphenylene ether and (C) a flameproofing additive, with or without (D) conventional additives, wherein one part of the soft component of the impact-resistant polymer of the vinyl-aromatic compound has a mean particle size of .ltoreq.1.5 .mu.m and the other part has a mean particle size of .ltoreq.3 .mu.m. Such molding materials not only have good self-extinguishing properties but also give moldings having a particularly uniform matt surface.
Type:
Grant
Filed:
January 29, 1982
Date of Patent:
March 13, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Franz Brandstetter, Volker Muench, Herbert Naarmann, Edmund Priebe
Abstract: A multi-stage reactor for hydrogenating coal slurry in a pressure vessel for pressures of up to 700 bar, preferably of up to 350 bar, with inlets for gas and coal slurry through the reactor bottom, an outlet for sludge, gases and vapors in the reactor top, and dividing trays in the pressure vessel, by means of which trays the individual reaction stages are separated from one another, wherein each dividing tray has a progressively reducing cross-section, with passage orifices, over its entire lower face, so as to prevent coal slurry caking onto the tray in the direction of flow of the reactants (gas and coal slurry).
Type:
Grant
Filed:
January 11, 1982
Date of Patent:
March 13, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Rudi Schulz, Hubert Puestel, Georg Weber, Heribert Kuerten
Abstract: Molding materials containing high molecular weight polyphenylene ethers are produced by a process in which a solution of a polyphenylene ether in an organic solvent, together with another polymer, is freed of solvent by multi-stage evaporation.The solvent is preferably an aromatic compound from the class comprising the hydrocarbons, halohydrocarbons, ethers or esters, the ratio of the other polymer to the polyphenylene ether is advantageously from 99:1 to 20:80 parts by weight, the other polymer is, in particular, a homopolymer or copolymer of styrene or of a homolog thereof, which may be modified with rubber, and the multi-stage evaporation process preferably comprises not less than two and not more than four working up stages.The evaporation is carried out in general at from 120.degree. to 280.degree. C. and under a pressure of from 1 to 3,000 mbar, advantageously in the presence of assistants which reduce the partial pressure, eg. water and/or methanol.
Type:
Grant
Filed:
July 22, 1982
Date of Patent:
March 13, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Klaus Hinselmann, Herbert Naarmann, Adolf Echte, Eduard Heil, Albert Nikles, Rudi W. Reffert, Juergen Hambrecht
Abstract: An improved process for the preparation of fiber-forming polycaprolactam by polymerizing .epsilon.-caprolactam, and an aqueous extract containing .epsilon.-caprolactam and caprolactam oligomers, which extract has been obtained by extracting polycaprolactam with water, wherein the aqueous extract contains from 0.1 to 5.0% by weight of oligomers of caprolactam, based on the monomeric caprolactam in the aqueous extract.
Type:
Grant
Filed:
August 24, 1982
Date of Patent:
March 13, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Hugo Strehler, Werner Hoerauf, Friedrich Urbanek
Abstract: .alpha.-Azolylglycols of the formula ##STR1## where R.sup.1 is alkyl, R.sup.2 is alkyl or unsubstituted or substituted phenyl or biphenyl, R.sup.3 is hydrogen, alkyl, alkenyl, alkynyl or unsubstituted or substituted benzyl and X is CH or N, their plant-tolerated salts and metal complexes, their preparation, and their use as plant growth regulators.
Type:
Grant
Filed:
November 23, 1981
Date of Patent:
March 13, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Bernd Zeeh, Norbert Goetz, Eberhard Ammermann, Johann Jung
Abstract: A process for the preparation of methanol by reacting a gaseous mixture of carbon monoxide, carbon dioxide and hydrogen at an elevated temperature and under superatmospheric pressure over a catalyst which contains zinc, copper and aluminum, the catalyst being prepared from a co-crystalline material of the formulaCu.sub.2.2 Zn.sub.2.8 (OH).sub.6 (CO.sub.3).sub.2,containing aluminum hydroxide as a structual promoter, by calcination and reduction at from 160.degree. to 350.degree. C. The novel catalyst has the advantage of giving a substantially increased space-time yield and having a longer life.
Type:
Grant
Filed:
March 25, 1983
Date of Patent:
March 13, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Franz J. Broecker, Karl-Heinz Gruendler, Laszlo Marosi, Matthias Schwarzmann, Bruno Triebskorn, Guenter Zirker
Abstract: The invention relates to water-dispersible binders which are intended for cationic electropaints and are based on reaction products which are formed from modified epoxy resins and primary and/or secondary amines and which can, if desired, also contain crosslinking agents, pigments, flow-control agents and other customary auxiliaries.
Type:
Grant
Filed:
March 3, 1983
Date of Patent:
March 13, 1984
Assignee:
BASF Farben & Fasern AG
Inventors:
Wolfgang Batzill, Horst Diefenbach, Michael Geist, Eberhard Schupp
Abstract: O-xylene and ethylbenzene are prepared by converting, 2,7-octadien-1-ol, 1,7-octadien-3-ol or mixtures containing these octadienols, or carboxylates of 2,7-octadien-1-ol or of 1,7-octadien-3-ol, or mixtures containing these carboxylates at from 200.degree. to 550.degree. C. over a catalyst.
Type:
Grant
Filed:
January 5, 1982
Date of Patent:
March 13, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Hans-Martin Weitz, Rolf Fischer, Hans H. Pohl
Abstract: Carbonates are prepared by reacting carbamic acid esters with alcohols at above 140.degree. C., the ammonia formed being stripped from the reaction mixture during the reaction by passing an inert gas or vapor therethrough.The carbonates obtainable by the process of the invention are valuable starting materials for the preparation of dyes, crop protection agents and plastics.
Type:
Grant
Filed:
May 28, 1981
Date of Patent:
March 13, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Harder, Franz Merger, Friedrich Towae
Abstract: The subject invention relates to salts of polymaleic acids having a molecular weight between 200 and 1500 and to their use in preventing the corrosion of metal caused by hydrogen sulfide and carbon dioxide in water-in-oil emulsions such as crude oil.
Type:
Grant
Filed:
May 10, 1982
Date of Patent:
March 13, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Knut Oppenlaender, Karl Stork, Klaus Barthold
Abstract: The subject invention relates to storage stable dispersions comprising certain aromatic polyesters dispersed in certain polyhydroxyl compounds and their process of preparation. The dispersions are useful for the preparation of polymers containing urethane and/or isocyanurate linkages.
Type:
Grant
Filed:
March 22, 1982
Date of Patent:
March 6, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter Horn, Anton Hesse, Walter Heckmann, Ulrich Lebert, Alfred Guthmann, Matthias Marx
Abstract: Polyether-ester polyols are prepared by reacting a crude polyether polyol, tetrahydrophthalic anhydride and an alkylene oxide. These polyols may be used in preparing polyrethane products.
Abstract: Salts of polymaleic acids, having molecular weights of from 200 to 1,500, with amines, of the formula ##STR1## where R.sup.1 and R.sup.2 are identical or different and each is hydrogen, C.sub.9 -C.sub.20 -alkyl or C.sub.9 -C.sub.20 -alkenyl and R.sup.3 is C.sub.9 -C.sub.20 -alkyl or C.sub.9 -C.sub.20 -alkenyl.
Type:
Grant
Filed:
September 29, 1981
Date of Patent:
March 6, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Knut Oppenlaender, Karl Stork, Hans-Henning Vogel, Erich Schwartz, Claus P. Jakob
Abstract: A process for the preparation of .beta.-carotene micellar solutions, wherein a non-ionic emulsifier which is suitable for the preparation of micellar solutions is heated at from 160.degree. to 180.degree. C. and a total of from 20 to 30% by weight, based on the emulsifier, of .beta.-carotene is introduced in the presence of a conventional antioxidant, the hot homogeneous mixture is cooled rapidly to below 100.degree. C. by adding water, and the formulation is brought to the desired concentration of from 3 to 6% by weight by adding further water, and the .beta.-carotene micellar solutions obtained by this process. The non-ionic emulsifiers used in this process have an HLB value of from 12 to 16, and are in particular oxyethylated triglycerides of fatty acids of 12 to 18 carbon atoms containing 20-60 oxyethylene units. Parenteral admininstration of the stable .beta.-carotene micellar solutions according to the invention to cattle relieves the disturbed estrus cycle and impaired fertility caused by .beta.
Type:
Grant
Filed:
December 9, 1981
Date of Patent:
March 6, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Peter P. Hoppe, Joachim U. Schneider, Bernhard Schulz, Hubert Tiefenbacher
Abstract: This invention relates to liquefied normally solid forms of polyoxyalkylene block copolymers particularly suitable for use in pesticide concentrates comprising a normally solid polyoxyalkylene block copolymer nonionic surface-active agent and an alkylene glycol having 3 to 5 carbon atoms with or without water.
Abstract: Sulfosiloxane-silicate copolymers are useful corrosion inhibitors in alcohol-based antifreeze compositions. The aliphatic sulfosiloxane-silicate copolymers contain repeating units derived from aliphatic sulfosiloxanes and water-soluble silicates.
Abstract: A process for the preparation of olefins from methanol and/or dimethyl ether by conversion in the presence of a zeolite catalyst, in particular a borosilicate zeolite, at elevated temperature, with the addition of a small amount of an electron donor.
Type:
Grant
Filed:
September 13, 1982
Date of Patent:
February 28, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Wolfgang Hoelderich, Wolf D. Mross, Matthias Schwarzmann
Abstract: This invention relates to liquefied normally solid forms of polyoxyalkylene copolymers particularly suitable for use in pesticide concentrates prepared by dissolving a normally solid polyoxyalkylene copolymer nonionic surface active agent and an alkylene glycol having 2 or 3 to 5 carbon atoms with or without water at a temperature of at least 70.degree. C.