Patents Assigned to BASF
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Patent number: 6494924Abstract: The dyes have an average particle size within the range from 5 nm to 1 &mgr;m and a variance of less than 50%. They are especially useful for ink-jet ink preparations.Type: GrantFiled: October 3, 2000Date of Patent: December 17, 2002Assignee: BASF AktiengesellschaftInventors: Helmut Auweter, Heribert Bohn, Robert Heger, Dieter Horn, Bernd Siegel, Karl Siemensmeyer
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Patent number: 6495729Abstract: The compounds are (+)- and (−)-2-cyclododecylpropanol and (+)- and (−)-2-cyclododecylpropionic acid, and salts thereof. (−)-2-cyclododecylpropanol is suitable as a fragrance while the virtually odorless (+) enantiomer is suitable as a fixative for other fragrances. The two enantiomers of 2-cyclododecylpropanol are prepared by reduction of the acid function of the enantiomers of 2-cyclododecylpropionic acid.Type: GrantFiled: May 3, 2001Date of Patent: December 17, 2002Assignee: BASF AktiengesellschaftInventors: Klaus Ebel, Wolfgang Krause, Ulrich Schäfer-Lüderssen
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Patent number: 6494164Abstract: A process and an apparatus are described for adding additives during the conditioning of animal feed. The feed is transferred from a container (1) into a conditioner (3) via a feed screw (2) at an inlet point (M). In the conditioner (3), the feed is transported by a mixing screw (12) from an inlet point (M) along a path (A) to an exit point (N), and is exposed to vapor in the course of this. One or more additives (5) which are introduced into the conditioner (3) through one or more ports (10) are added to the feed which, has passed through x% of the path (A) in the conditioner (3). The feed and the additives (5) added through one or more ports (10) are mixed on the remaining (100-x)% of the path (A) to form a mixture (6). The mixture (6) leaving the conditioner (3) at the exit point (N) is transferred to a pelleting press (7), where the mixture (6) is formed into pellets (8). The pellets (8) are finally transferred to a cooling device (9).Type: GrantFiled: September 28, 2001Date of Patent: December 17, 2002Assignee: BASF AktiengesellschaftInventors: Wolfgang Heinzl, Jörg Braun, Roland Betz, Barton Cousins, Hans-Peter Harz, Ulrich Heindl
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Patent number: 6495728Abstract: A two-step process for the preparation of fluoroolefin compounds of formula I wherein R is hydrogen or alkyl, and R1 is alkyl or cyclopropyl, or R and R1 are taken together with the carbon atom to which they are attached to form a cyclopropyl group; Ar is phenyl or naphthyl both of which are optionally substituted; Ar1 is phenoxyphenyl, biphenyl, phenyl, benzylphenyl, or benzoylphenyl, all of which may be optionally substituted, comprising reacting fluorobromoolefin compounds of formula II with organozinc compounds of formula III or IV in the presence of a palladium catalyst and a solvent, which compounds of formula II are obtained by reacting aldehyde compounds of formula V with (a) fluorotribromomethane, (b) a tri(substituted)phosphine or a hexaalkylphosphoramide or a mixture thereof, and (c) zinc, in the presence of a solvent, compounds of formula II.Type: GrantFiled: September 12, 2001Date of Patent: December 17, 2002Assignee: BASF AktiengesellschaftInventor: William Wakefield Wood
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Patent number: 6495634Abstract: Propylene polymers containing a matrix of a propylene homopolymer and a copolymer of propylene and other alkenes, wherein, during the separation of the propylene polymers according to tacticity and comonomer distribution of the polymer chains, by first dissolving the propylene polymers in boiling xylene, then cooling the solution at a cooling rate of 10° C./h to 25° C. and thereafter, increasing the temperature, separating the propylene polymers into fractions of different solubility, either one or more of the conditions that i) more than 20% by weight of the matrix remain undissolved on further heating to 112° C. or ii) more than 8% by weight of the matrix remain undissolved on further heating to 117° C. or iii) more than 1% by weight of the matrix remain undissolved on further heating to 122° C. are fulfilled by the matrix which remains undissolved on heating the cooled propylene polymer solution to 80° C.Type: GrantFiled: June 16, 1998Date of Patent: December 17, 2002Assignee: BASF AktiengesellschaftInventors: Stephan Hüffer, Joachim Rösch, Franz Langhauser, Dieter Lilge, Roland Hingmann
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Patent number: 6495611Abstract: The polyisocyanate polyaddition products comprise hydrophobic compounds plus at least one further compound selected from the group consisting of: (i) organic, cyclic compounds having a molecular weight of from 200 to 3000 g/mol, (ii) salts of metals of transition groups I, II and/or VIII, (iii) organic and/or inorganic acid anhydrides, (iv) cyclic sulfonic esters and/or sulfones, (v) lactones, lactams and/or cyclic esters and/or (vi) &agr;,&bgr;-unsaturated carboxylic acids, &agr;,&bgr;-unsaturated carboxylic acid derivatives, &agr;,&bgr;-unsaturated ketones and/or &agr;,&bgr;-unsaturated aldehydes.Type: GrantFiled: January 24, 2001Date of Patent: December 17, 2002Assignee: BASF AktiengesellschaftInventors: Andreas Arlt, Sarbananda Chakrabarti, Martin Kreyenschmidt, Dieter Rodewald
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Patent number: 6495714Abstract: A process for preparing alkanesulfonic acids from dialkyl sulfites comprises the following steps: rearrangement of dialkyl sulfite in the presence of a suitable catalyst to form the corresponding alkyl alkanesulfonate and hydrolysis of the resulting alkyl alkanesulfonate to give the corresponding alkanesulfonic acid.Type: GrantFiled: August 3, 2001Date of Patent: December 17, 2002Assignee: BASF AktiengesellschaftInventors: Klaus Halbritter, Hans-Josef Sterzel, Matthias Eiermann, Eva Freudenthaler
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Patent number: 6495652Abstract: Prepolymers which contain isocyanate groups, have an NCO content of at least 30.0% by weight and can be prepared by reacting an isocyanate mixture consisting predominantly of diphenylmethane diisocyanates and polyphenylpolymethylene polyisocyanates and having a proportion of two-ring isomers of not more than 74% by weight with at least 4-functional polyols or a mixture of polyols having a mean functionality of at least 4, where the polyols or polyol mixtures have a hydroxyl number of from 200 to 1650 mg KOH/g and a number average molecular weight of less than 1100 g/mol.Type: GrantFiled: October 9, 2000Date of Patent: December 17, 2002Assignee: BASF AktiengesellschaftInventors: Michael Reichelt, Udo Rotermund, Renate Hempel, Peter Falke, Peter von Malotki, Holger Seifert
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Publication number: 20020188093Abstract: Water-soluble polymers of esters made from acrylic acid and alkylpolyalkylene glycols, obtainable by azeotropic esterification of a mixture of acrylic acid and alkylpolyalkylene glycol in a molar ratio of from 2 to 3:1 in the presence of at least 85% by weight, based on the alkylpolyalkylene glycol, of an organic solvent which forms an azeotrope with water, followed by free-radical polymerization, in an aqueous medium, of the mixture obtained during the esterification, where the organic solvent is distilled off azeotropically from the reaction mixture during the polymerization, and the water removed by distillation is returned to the mixture or replaced by a feed of fresh water, and preparation and use of these polymers as an additive to cementitious systems.Type: ApplicationFiled: May 2, 2002Publication date: December 12, 2002Applicant: BASF AktiengesellschaftInventors: Matthias Kroner, Karl-Heinz Buchner, Gregor Brodt
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Publication number: 20020185768Abstract: A process prepares expandable propylene polymer beads by mixing propylene polymer melt with a volatile organic blowing agent and with a nucleating agent in an extruder, whereupon the extrusion and pelletization of the extrudate takes place in a water bath under conditions of temperature and pressure at which practically no foaming of the pellets takes place.Type: ApplicationFiled: November 5, 2001Publication date: December 12, 2002Applicant: BASF AktiengesellschaftInventors: Christian Maletzko, Klaus Hahn, Isidor De Grave, Gerd Ehrmann, Franz-Josef Dietzen
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Publication number: 20020187913Abstract: Methods for cleaning screw extruder, especially powder-coating extruders, include filling the extruder barrel with a gel purge formulation comprised of a high-boiling pyrrolidone or piperidone (lactam) solvent (most preferably N-methyl pyrrolidone (NMP)), thickened with 5-50 wt. % of a thermoplastic resin thickening agent, most preferably polystyrene (PS). Once the extruder barrel is filled with the gel purge formulation, the screws are stopped and the gel allowed to soak for between about 10 to about 30 minutes. The screws are then restarted and the gel is discharged from the extruder. Immediately after the gel purge formulation exits the machine, a small amount of a thermoplastic “rinse” polymer (e.g., polyethylene) may be added so as to remove any vestigial amount of the gel purge formulation therefrom.Type: ApplicationFiled: April 25, 2002Publication date: December 12, 2002Applicant: Basf CorporationInventor: Mark W. Waldrop
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Patent number: 6492317Abstract: Hard surface cleaning formulations include an associative thickener and a blend of at least two nonionic surfactants selected from the group consisting of ethoxylated alcohols and ethoxylated fatty acids. The formulations exhibit an advantageously high foam volume of at least about 150 cc when a 100 ml aqueous solution containing about 0.1 wt. % of the formulation is agitated at 2,500 rpm for a cumulative agitation period of about 1200 seconds. The formulations also exhibit satisfactory foam stability sufficient to clean at least about 25 plates (ASTM D4009-92). Preferably, the associative thickener is the reaction product of a C6 or greater epoxide compound with a polyoxyalkylene polyol. The ethoxylated alcohols and ethoxylated fatty acids each most preferably contain C8 to C18 carbon chains which are ethoxylated with between about 3 to about 20 moles of ethylene oxide.Type: GrantFiled: May 19, 2000Date of Patent: December 10, 2002Assignee: BASF CorporationInventors: Charles O. Kerobo, Michael C. Welch, Richard J. Holland, Susanne M. Gessner, Sonia J. Patterson, Chacji Thankachan
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Patent number: 6491861Abstract: A process for the production of a molding containing at least one zeolite, wherein the at least one zeolite contains a titanium-, zirconium-, chromium-, niobium-, iron- or vanadium-containing zeolite: (I) adding a mixture consisting of at least one alcohol selected from the group consisting of methanol, ethanol, propanol or butanol, and water to a mixture containing said zeolite or a mixture of two or more thereof, and (II) kneading, molding, drying and calcining the mixture from (I); wherein the molding is useful as a catalyst, particularly in epoxidation reactions.Type: GrantFiled: December 6, 1999Date of Patent: December 10, 2002Assignee: BASF AktiengesellschaftInventors: Georg Heinrich Grosch, Ulrich Müller, Andreas Walch, Norbert Rieber, Wolfgang Harder
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Patent number: 6492451Abstract: A pigment-comprising formulation for coating substrates, comprising: (i) an aqueous dispersion of at least one water-insoluble polymer P which has phosphonate groups, as a binder, said polymer P having a glass transition temperature Tg in the range of −60° to 80° C., (ii) at least one inorganic pigment, (iii) optionally, one or more inorganic fillers, and (iv) at least one auxiliary, wherein water-insoluble polymer P is obtained by free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers comprising: 90 to 99.9% by weight of at least one monomer a, which is selected from the group consisting of vinylaromatic monomers, the esters of acrylic acid with C1-C12-alkanols, the vinyl esters of aliphatic C1-C12-monocarboxylic acids, ethylene and vinylchloride, and 0.1 to 10% by weight of at least one phosphonate group containing monomer.Type: GrantFiled: May 11, 2000Date of Patent: December 10, 2002Assignee: BASF AktiengesellschaftInventors: Rolf Dersch, Joachim Roser, Bernhard Schlarb, Cheng-Le Zhao
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Patent number: 6492442Abstract: Described is a stabilizer composition comprising a 3-arylacrylic ester, a polymeric compound having a molecular weight of at least 2000 which carries, on a polymeric framework, side groups having secondary amine functions, all substituents positioned to the amine nitrogen being other than hydrogen, a chroman derivative, and an organic phosphite and/or phosphonite. The stabilizer composition is particularly suitable for stabilizing thermoplastic polyurethane against light, oxygen and heat.Type: GrantFiled: October 2, 2000Date of Patent: December 10, 2002Assignee: BASF AktiengesellschaftInventors: Manfred Appel, Hubert Trauth, Jürgen Krockenberger, Alexander Aumüller
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Patent number: 6492558Abstract: Process for the preparation of n-butylamines where n-butenylamines are firstly prepared by reacting 1,3-butadiene in the form of a 1,3-butadiene containing mixture obtained during the cracking of petroleum fractions or during the dehydrogenation of LPG or LNG or from GTL technology with a primary amine and/or a secondary amine under hydroaminating conditions, and the resulting butenylamine(s) are then reacted in a second process stage under hydrogenating and transalkylating conditions.Type: GrantFiled: December 26, 2001Date of Patent: December 10, 2002Assignee: BASF AktiengesellschaftInventors: Frank Funke, Ulrich Steinbrenner, Peter Zehner, Ralf Böhling, Wolfgang Harder
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Patent number: 6489397Abstract: The present invention relates to crosslinked, water-soluble or water-dispersible polyurethanes of A) at least one water-soluble or water-dispersible polyurethane prepolymer having terminal isocyanate groups of a) at least one compound having a molecular weight in the range from 56 to 300 which contains two active hydrogen atoms per molecule, b) at least one polymer containing two active hydrogen atoms per molecule, c) at least one compound which contains two active hydrogen atoms and at least one ionogenic or ionic group per molecule, d) at least one diisocyanate, B) at least one polymer containing groups which are reactive toward isocyanate groups, chosen from hydroxyl, and primary and secondary amino and/or carboxyl groups, or the salts thereof.Type: GrantFiled: April 25, 2001Date of Patent: December 3, 2002Assignee: BASF AktiengesellschaftInventors: Son Nguyen Kim, Axel Sanner, Peter Hössel, Volker Schehlmann
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Patent number: 6489360Abstract: A fungicidal mixture comprises a1) a phenyl benzyl ether derivative of the formula I.a, I.b or I.c and/or a2) a carbamate of the formula Id where X is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, or one of its salts or adducts, and b) a dinitrophenol derivative of the formula II.a or II.b where n is 0, 1 or 2 in a synergistically effective amount.Type: GrantFiled: January 3, 2002Date of Patent: December 3, 2002Assignee: BASF AktiengesellschaftInventors: Klaus Schelberger, Maria Scherer, Hubert Sauter, Bernd Müller, Erich Birner, Joachim Leyendecker, Eberhard Ammermann, Gisela Lorenz, Siegfried Strathmann, Reinhold Saur
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Patent number: 6489503Abstract: The present invention provides a liquid methylene bis(phenylisocyanate) composition including a high concentration of methylene bis(phenylisocyanate) which has an improved storage stability. The invention further provides a method of making the liquid methylene bis(phenylisocyanate) compositions of the present invention.Type: GrantFiled: November 9, 1999Date of Patent: December 3, 2002Assignee: BASF CorporationInventors: Thirumurti Narayan, Anthony Lunato, Jon S. Speier, David D. Peters, Cynthia Loop, Filip Nevejans
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Patent number: 6489422Abstract: Use of neutralized or partially neutralized copolymers obtainable from A) from 50 to 99% by weight of monoethylenically unsaturated carboxylic acid and B) from 1 to 50% by weight of at least one comonomer chosen from the groups a) to d) or also mixtures of different monomers from groups a) to d) a) monoethylenically unsaturated carboxylic acid esters with a saturated C8- to C30-alcohol b) N-alkyl- or N,N-dialkyl-substituted carboxamides, the alkyl radicals independently of one another being aliphatic or cycloaliphatic alkyl radicals having at least 8 to 18 carbon atoms, c) vinyl esters of aliphatic C8- to C30-carboxylic acids, d) C8- to C18-alkyl vinyl ethers, for the preparation of hair cleansers.Type: GrantFiled: March 14, 2002Date of Patent: December 3, 2002Assignee: BASF AktiengesellschaftInventors: Helmut Meffert, Kristin Tiefensee