Abstract: In a process for the catalytic gas-phase oxidation of propene to acrolein, the reaction gas starting mixture is passed with a propene loading of ≧160 l(S.T.P.)/l·h over a fixed-bed catalyst which is housed in two spatially successive reaction zones A,B, the reaction zone B being kept at a higher temperature than the reaction zone A.
Type:
Grant
Filed:
September 10, 2001
Date of Patent:
May 28, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Heiko Arnold, Signe Unverricht, Ulrich Hammon, Hans-Peter Neumann, Klaus Harth, Andreas Tenten
Abstract: 6-(2-Trifluoromethyl-phenyl)-triazolopyrimidines of formula I 1
Type:
Application
Filed:
December 12, 2000
Publication date:
May 23, 2002
Applicant:
BASF Corporation
Inventors:
Klaus-Juergen Pees, Frank Schieweck, Jordi Tormo I Blasco, Hubert Sauter, Oliver Cullman, Bernd Muller, Thomas Grote, Andreas Gypser, Joachim Rheinheimer, Ingo Rose, Peter Schafer, Eberhard Ammermann, Siegried Strathmann, Gisela Lorenz, Reinhard Stierl
Abstract: The present invention provides a process for preparing polymer powders by evaporating the volatile constituents from aqueous dispersions of film-forming polymers P in the presence of drying assistants T selected from the salts of oligomeric arylsulfonic acid-formaldehyde condensates wherein prior to the evaporation of the volatile constituents the aqueous polymer dispersion comprises at least 1.5% by weight, preferably at least 1.7% by weight, based on the polymer in the dispersion, of at least one anionic surface-active compound AO having at least one C6-C32 alkyl group; the polymer powders obtainable by the process; and their use in binding mineral building materials.
Type:
Application
Filed:
August 21, 2001
Publication date:
May 23, 2002
Applicant:
BASF Akitengesellshaft
Inventors:
Mario Sandor, Joachim Pakusch, Heinrich Sack, Markus Koppers, Hans-Juergen Denu, Rolf Gulden
Abstract: A reactor apparatus comprises at least two same-type tubular reactors which are filled with solid particles, at least one tubular reactor containing a temperature measuring unit, the tubular reactors being designed such that both the ratio of the mass of the solid particles to the free cross-sectional area of the respective tubular reactor and the pressure drop measured by an inert gas being conducted transversely to the free cross-sectional area are identical across the respective tubular reactor. The apparatus is suitable for treating fluid masses while generating or consuming thermal energy, the temperature being measured.
Abstract: The invention provides novel mixtures of quaternary ammonium salts having plant growth-regulating properties.
Type:
Application
Filed:
November 20, 2001
Publication date:
May 23, 2002
Applicant:
BASF Aktiengesellschaft
Inventors:
Reiner Kober, Karl Heinrich Schneider, Hans Ziegler, Mary Elizabeth Callan, Charles W. Finch, Reinhold Stadler, Peter Hofmeister, Wilhelm Rademacher, Elmar Kibler, Reimer Gottsche
Abstract: The present invention discloses a polyol resin composition containing a polyether polyol blend, a polyester polyol, and a hydrocarbon blowing agent. The polyether polyol blend has at least a diamine initiated polyol, a propylene oxide polyol, and a polyethylene terephthalate initiated polyol having a functionality of from 2.3 to 3.0. The polyester polyol is preferably a phthalic anhydride initiated polyester polyol. The blowing agent is a C4-C6 hydrocarbon.
Type:
Application
Filed:
November 28, 2001
Publication date:
May 23, 2002
Applicant:
BASF Corporation
Inventors:
Walter R. White, Robert E. Riley, Jimmy L. Patterson, James A. Mullins
Abstract: A process for coating surfaces in apparatuses or apparatus parts for plant construction, preferably for chemical plant construction, involves optionally first hydrophobicizing a polymer film having a microstructured and optionally additionally macrostructured surface and then fixing it on the apparatus or apparatus part to be coated, and also apparatuses and apparatus parts thus coated.
Type:
Application
Filed:
October 25, 2001
Publication date:
May 23, 2002
Applicant:
BASF Aktiengesellschaft
Inventors:
Harald Keller, Ekkehard Jahns, Christian Lach, Stephan Hueffer, Thilo Krebs, Yi Thomann, Thomas Frechen
Abstract: A resinous binder useful in clear coat compositions comprises a) a polyepoxide such as a copolymer of an ethylenically unsaturated epoxide with other (meth)acrylate(s) or styrene, b) a polyacid such as a carboxyl-terminated polyester, and c) a polyisocyanate.
Abstract: Surface-treated superabsorbent polymer particles obtained by mixing 100 parts by weight of superabsorbent polymer particles with 0.001 to 10 parts by weight of a hydroxyalkylamide, and heating the surface-treated superabsorbent polymer particles to crosslink molecular chains existing at least in the vicinity of the surfaces of the superabsorbent polymer particles is disclosed. Surface crosslinking the superabsorbent polymer particles with a hydroxyalkylamide substantially increases both the rate of liquid absorption and the quantity of liquid absorbed and retained by the superabsorbent particles.
Type:
Grant
Filed:
May 25, 2000
Date of Patent:
May 21, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Michael A. Mitchell, David Eckert, Thomas W. Beihoffer
Abstract: The invention provides a powder slurry composition comprising a first solid particulate component (a) dispersed in a crosslinking component (b) having at least one crosslinking resin which is liquid at 20° C. First component (a) is in solid particulate form having an average particle size of from 3 to 30 microns. Component (a) has a compound (i) having a Tg>40° C. and at least one carbamate or urea functional group, or a group convertible to a carbamate or urea group appended thereto. Crosslinking component (b) has at least one crosslinking resin (i) which is liquid at 20° C. Most preferably, crosslinking component (b) will further include a self-crosslinking aminoplast resin (ii) having at least two aminoplast groups and at least two groups which are nonreactive with solid particulate first component (a) but which are reactive with said aminoplast groups. The powder slurry composition of the invention has a VOC of less than 1.0 lbs.
Type:
Grant
Filed:
August 7, 2000
Date of Patent:
May 21, 2002
Assignee:
BASF Corporation
Inventors:
Paul J. Harris, Walter H. Ohrbom, John W. Rehfuss
Abstract: The present invention provides a coating composition containing a two-stage polymer emulsion. The two-stage emulsion polymer contains composite polymeric particles of a first stage polymer prepared from about 0.25% to about 5% by weight monomer having at least two polymerizable ethylenically unsaturated groups, about 2.5% to about 10% by weight hydroxyl monomer, preferably at least about 50% by weight of non-functional monomer of hydrophobic monomer, and preferably without addition of any acid-functional monomer; and a second stage polymer having a theoretical glass transition temperature of at least about 50° C. prepared using, by weight, about 25% to about 50% by weight hydroxyl monomer, about 3% to about 9% carboxylic acid monomer, and preferably at least 25% by weight of non-functional monomer of hydrophobic monomer;. The composite polymeric particles have a theoretical glass transition temperature of not more than about 30° C., preferably not more than about 0° C., and include from about 0.
Type:
Grant
Filed:
July 24, 2000
Date of Patent:
May 21, 2002
Assignee:
BASF Corporation
Inventors:
David Law, Walter H Ohrbom, S. Kendall Scott, Sergio E. Balatan, Thomas E. St. Henry, Robert Weise
Abstract: Sunscreen combinations which comprise, as constituent which absorbs in the UV-A region, 4,4′-diarylbutadienes, and at least one further sunscreen which absorbs in the UV-A region, UV-B region or in both regions, chosen from a group defined in detail in the Description of the Invention below as photostable UV filter combination in cosmetic and pharmaceutical preparations for protecting the human epidermis or human hair against UV radiation, specifically in the range from 320 to 400 nm.
Type:
Grant
Filed:
March 14, 2001
Date of Patent:
May 21, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Heidenfelder, Thorsten Habeck, Thomas Wünsch
Abstract: The present invention provides a curable coating composition that includes a film-forming polymer, a polymeric additive having at least one bound surface protecting group, and a crosslinker that is reactive with the film-forming polymer. The polymeric additive is substantially free of groups reactive with the crosslinker and has comonomer units with aryl groups, alkyl groups having, on average, four or more carbon atoms, or combinations of the aryl and alkyl groups. When the coating composition is cured to form a cured coating layer, the concentration of the polymeric additive in the upper about 50% of the cured coating layer thickness is at least about 10% higher than the concentration of the polymeric additive in the rest of the cured coating layer.
Type:
Grant
Filed:
March 22, 2000
Date of Patent:
May 21, 2002
Assignee:
BASF Corporation
Inventors:
John E. Boisseau, Donald L. St. Aubin, Walter H Ohrbom
Abstract: An improved process for the production of high quality unsaturated dimethylesters by reacting dicarboxylic anhydrides, typically maleic anhydride or phthalic anhydride, with methanol. The process is characterized by the fact that the esterification is performed in two steps, the step 1 consisting in a non catalytic reaction of formation of monomethylesters, and the step 2 consisting in the catalytic reaction of formation of dimethylesters from the monomethylester, the said catalytic reaction taking place in a reactor consisting of a multi-tray column where the liquid phase containing the mono and diester mixture flows downwards from each tray coming to contact with a progressively drier upflowing stream of vapors in countercurrent, which continuously removes the water formed in the reaction from the liquid phase. The process uses an alkylbenzene sulfonic acid with an alkyl radical containing from 10 to 13 carbon atoms as esterification catalyst.
Abstract: This invention provides an apparatus and method for injecting an additive directly into a polymer melt stream. The method comprises supplying a melt flow of a polymeric host material to a die assembly having a thin-plate assembly and injecting at least one additive into at least one predetermined location in a cross-section of the melt flow of the polymeric host material while the melt flow passes through the die assembly. The method achieves uniform dosing of the one or more additives in the extrusion direction in the polymeric host material without homogeneously mixing the one or more additives and the polymeric host material. The apparatus for directly injecting one or more additives into a polymer melt stream comprises a pumping system, a die assembly having a thin-plate assembly, and a distribution line.
Type:
Grant
Filed:
December 8, 2000
Date of Patent:
May 21, 2002
Assignee:
BASF Corporation
Inventors:
Charles F. Helms, Jr., Dominick A. Burlone, James L. Huff, Thomas Kessler, Herman Brandt, Walter Gotz, Jürgen Hofmann
Abstract: The invention thus provides a curable coating composition comprising (A) a polymer resin comprising at least one primary carbamate group, (B) a curing agent having groups that are reactive with said functional groups on (A), and (C) a reactive additive comprising at least one compound having a molecular weight of from 131 to 2000 and comprising at least one primary carbamate group and at least one alkyl group selected from the group consisting of straight chain alkyl groups of more than 10 carbons, branched alkyl groups of from 5 to 30 carbons, and mixtures thereof, wherein one or both of (A) and (B) comprise groups that are reactive with the primary carbamate group of (C). The invention also provides a method of making a preferred embodiment of the reactive additive (C) and the reactive additive (C).
Abstract: At least two different liquid streams are sub-divided into a dense plurality of individually separated parallel pixels oriented in respective misregistered arrays. Therefore, an individual pixel of one of the liquid stream arrays will be surrounded by pixels of the other liquid stream array. These individual pixel arrays are then bought into contact with one another to form a multi-pixel liquid stream comprised of the misregistered pixel arrays of the two different liquid streams. The “pixelated” liquid stream—that is, the liquid stream containing in cross-section the misregistered pixel arrays of the two different liquid streams—may then be further processed. For example, the pixelated liquid stream may be subjected to further mixing by being directed along a tortuous flow path.
Type:
Grant
Filed:
December 30, 1999
Date of Patent:
May 21, 2002
Assignee:
BASF Corporation
Inventors:
Karl H. Buchanan, Wendel L. Burton, Charles F. Helms, Jr., John A. Hodan, Gary W. Shore