Patents Assigned to Cassella Aktiengesellschaft
  • Patent number: 4168145
    Abstract: Dyeing with disperse dyes is made more uniform when there is used as a levelling agent a branched polyester which has an apparent average molecular weight of from about 600 to about 5,000, disperses itself in water, and is essentially an ester-linked combination of hydrocarbyloxy groups and carboxyl-derived acyl groups, the groups being linked together as a branched chain by the ester linkages and relative to the carboxy-derived acyl groups the polyester contains from about 5 to about 50 mol.% of COOH or COOM groups and less than 5 mol.% of SO.sub.3 M groups, wherein M denotes the cation of an alkali metal, the ammonium ion or the cationic radical of an organic amine, the number of branches on an interesterified group being not over three and at least 50 mol.% of the hydrocarbyloxy groups are in diethylene glycol or triethylene glycol groups.
    Type: Grant
    Filed: September 30, 1977
    Date of Patent: September 18, 1979
    Assignee: Cassella Aktiengesellschaft
    Inventors: Karl Hintermeier, Fritz Engelhardt, Joachim Ribka, Helmut Beutler
  • Patent number: 4167395
    Abstract: Water-soluble polyester having an apparent molecular weight between about 600 and about 5,000 and a SO.sub.3 M group content between about 5 to about 40 mol percent based on the number of mols of dicarboxylic and/or polycarboxylic acids esterified in the polyester, and an at least trifunctional alcohol and/or an at least trifunctional carboxylic acid content between about 1 to about 40 mol percent based on the number of mols of dicarboxylic and/or polycarboxylic acids esterified in the polyester so that the polyester is correspondingly branched and M denotes a cation of an alkali metal, the ammonium ion or the cationic radical of an organic amine. The improved polyester is particularly suited as a levelling agent in the disperse dyeing of polyester fibers or the like.
    Type: Grant
    Filed: May 12, 1977
    Date of Patent: September 11, 1979
    Assignee: Cassella Aktiengesellschaft
    Inventors: Friedrich Engelhardt, Karl Hintermeier, Joachim Ribka, Helmut Beutler
  • Patent number: 4163835
    Abstract: Electrolyte-free etherified methylolaminotriazines are directly prepared by reacting together in the absence of electrolyte, the aminotriazine, formaldehyde and certain ether-alcohols. When the formaldehyde to aminotriazine mol ratio is sufficiently high and the etherification sufficiently extensive, the resulting products are particularly desirable in that they are quite stable and thermoset to exceptionally elastic, cured products having high electrical, moisture, and temperature resistance.
    Type: Grant
    Filed: January 19, 1977
    Date of Patent: August 7, 1979
    Assignee: Cassella Aktiengesellschaft
    Inventor: Steffen Piesch
  • Patent number: 4158670
    Abstract: A process for the manufacture of esters of aromatic sulphonic acids and aromatic aminohydroxy compounds, of the formula Ih.sub.2 n--a--o--so.sub.2 --b (i)comprising reacting an aromatic aminohydroxy compound of the formula IIh.sub.2 n--a--oh (ii)having a pK.sub.a value of from 8.5 to 10.1, with a sulphochloride of the formula IIIcl--SO.sub.2 --B (III)whereinA is phenylene, substituted phenylene, naphthylene or substituted naphthylene,B is phenyl, substituted phenyl, naphthyl or substituted naphthyl, and both A and B are free from --COOH and --SO.sub.3 H substituents;The reaction taking place in a reaction medium consisting essentially of water and a water-immiscible organic solvent for the sulphochloride,At a temperature of from 0.degree. to 95.degree. C., at a pH which is determined from and associated with the pK.sub.a value of said aromatic aminohydroxy compound of formula II by the equationpK.sub.a -pH=0.5 to -1.5,and in the presence of a phase transfer catalyst.
    Type: Grant
    Filed: February 22, 1978
    Date of Patent: June 19, 1979
    Assignee: Cassella Aktiengesellschaft
    Inventors: Rolf Muller, Joachim Ribka, Horst Tappe
  • Patent number: 4157446
    Abstract: A .beta.,.beta.,.beta.-trihalo-.alpha.-hydroxyethyl (e.g. --CHOH--CCl.sub.3) group is introduced into a 2,6-dihydroxy pyridine. The 3-formyl-4-methyl-2,6-dihydroxy pyridine produced by splitting off haloform from the trihalohydroxyethyl product, is a desirable intermediate for the making of dyes and other products, and the alkali metal or alkaline earth metal salts of the formyl compound are more stable forms of this intermediate.
    Type: Grant
    Filed: July 29, 1977
    Date of Patent: June 5, 1979
    Assignee: Cassella Aktiengesellschaft
    Inventor: Horst Tappe
  • Patent number: 4149979
    Abstract: Conditioning and water-repellent compositions containing agents for cellulose-containing textiles or leather comprising sulphonylureas of the formula ##STR1## wherein R is alkyl or alkenyl having 10-30 carbon atoms; B is a member selected from the group comprising ##STR2## wherein R.sup.1 is alkyl having 1-4 carbon atoms, R.sup.2 is hydrogen or alkyl having 1-4 carbon atoms and n is 2, 3 or 4;And X is .beta.-halogenoalkyl or alkenyl with 2 to 4 carbon atoms each. Also disclosed are novel sulphonylureas per se and a method of use for sulphonylureas as conditioning and water repellent compositions.
    Type: Grant
    Filed: June 26, 1978
    Date of Patent: April 17, 1979
    Assignee: Cassella Aktiengesellschaft
    Inventors: Gustav Hudec, Karl-Heinz Keil, Volker Kohler, Joachim Ribka, Kurt Rosenbusch
  • Patent number: 4144231
    Abstract: A water soluble trisazo dyestuff of the formula B.sub.1 --N.dbd.N--Z-N.dbd.N-M-N.dbd.N-B.sub.2 is useful for dyeing substances containing nitrogen or hydroxyl wherein M is ##STR1## B.sub.1 and B.sub.2 are the same or different and are selected from the group consisting of ##STR2## 2,4-dihydroxy-3-quinolyl and 2,6-diamino-5-pyridyl; Z is ##STR3## X is --O-- or --S--; R.sub.1 is hydrogen, alkyl having 1 to 4 carbon atoms, phenyl or benzyl; R.sub.3 is hydrogen, chloro or alkyl or alkoxy having 1 to 4 carbon atoms;R.sub.4 is hydrogen chloro, alkyl or alkoxy having 1 to 4 carbon atoms, hydroxy, alkanoylamino having 1 to 4 carbon atoms, benzoylamino, naphthoylamino, oxalylamino, carboxyalkylamino having 2 to 5 carbon atoms, sulphoalkylamino having 1 to 4 carbon atoms or oxyalkylamino having 1 to 4 carbon atoms;R.sub.5 is hydrogen or alkyl having 1 to 8 carbon atoms; R.sub.6 is --CN, --COOH, --CONH.sub.2 or --SO.sub.3 H; R.sub.7 is hydrogen, or alkyl having 1 to 4 carbon atoms, R.sub.
    Type: Grant
    Filed: May 10, 1977
    Date of Patent: March 13, 1979
    Assignee: Cassella Aktiengesellschaft
    Inventors: Wolfgang Bauer, Joachim Ribka
  • Patent number: 4144230
    Abstract: A water-soluble trisazo dyestuff of the formula B.sub.1 --N.dbd.N--Z--N.dbd.N--M--N.dbd.N--B.sub.2 is useful for dyeing substances containing nitrogen or hydroxyl wherein Z is ##STR1## M has the formula ##STR2## B.sub.1 and B.sub.2 are the same or different and are selected from the group consisting of ##STR3## X is ##STR4## --O-- or --s--; R.sub.1 is hydrogen, alkyl having 1 to 4 carbon atoms, phenyl or benzyl; R.sub.2 is hydrogen, alkyl or alkoxy having 1 to 4 carbon atoms; R.sub.3 and R.sub.
    Type: Grant
    Filed: May 10, 1977
    Date of Patent: March 13, 1979
    Assignee: Cassella Aktiengesellschaft
    Inventors: Wolfgang Bauer, Joachim Ribka
  • Patent number: 4143033
    Abstract: Very desirable water-soluble disazo dyes have the structure ##STR1## WHERE ONE OF A and A.sup.1 is a selected N-substituted amino naphthol.
    Type: Grant
    Filed: March 16, 1977
    Date of Patent: March 6, 1979
    Assignee: Cassella Aktiengesellschaft
    Inventors: Wolfgang Bauer, Joachim Ribka
  • Patent number: 4143016
    Abstract: A process for the preparation of a substantially monomeric methylolmelamine etherified by methanol which contains per mol of melamine, more than 5 mols of formaldehyde and more than 4 mols of methyl-etherified methylol groups which has a viscosity of less than 10 Pa.s at 25.degree. C. at a solids content of at least 95%, said process comprising reacting melamine and formaldehyde in a molar ratio of from 1 : 6.2 to 1 : 8, at a temperature of from 40 to 60.degree. C., in the presence of a basic catalyst in a reaction mixture which contains from 10 to 40% by weight of water and from 40 to 20% by weight of methanol thereby producing a suspension of methylolmelamine, and then etherifying the methylol melamine in the presence of from 15 to 30 mols of methanol per mol of melamine, at a temperature of from 25 to 50.degree. C., in the presence of a strong acid.
    Type: Grant
    Filed: February 6, 1978
    Date of Patent: March 6, 1979
    Assignee: Cassella Aktiengesellschaft
    Inventors: Hans Honel, Karlfried Keller, Walter Michel, Manfred Schon
  • Patent number: 4137228
    Abstract: Trisazo dyes of high tinctorial strength and excellent fastness have the structure ##STR1## where one of M and M.sup.1 is ##STR2## as more fully set out below.
    Type: Grant
    Filed: November 26, 1976
    Date of Patent: January 30, 1979
    Assignee: Cassella Aktiengesellschaft
    Inventors: Wolfgang Bauer, Joachim Ribka