Patents Assigned to Cassella Aktiengesellschaft
  • Patent number: 4328326
    Abstract: Partially etherified melamine-formaldehyde resins having a melamine:formaldehyde molar ratio of 1:(1.25 to 1) can be prepared by a condensation reaction under neutral or weakly alkaline conditions if the condensation reaction is carried out in the presence of a glycol monoether of the general formula IR(OCH.sub.2 CH.sub.2).sub.n OH (I)wherein R denotes alkyl having 1 to 4 C atoms and n denotes a number from 1 to 5. The partially etherified melamine-formaldehyde resins are suitable for the production of compression moulding compositions having a high flow and minimal processing shrinkage and after-shrinkage.
    Type: Grant
    Filed: January 9, 1981
    Date of Patent: May 4, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventors: Steffen Piesch, Alfons Wolf
  • Patent number: 4325870
    Abstract: An improved process for producing 2,6-diaminopyridines and azo dyestuffs therefrom involves reacting a 2,6-dihalopyridine with a primary amine in a two-phase system of water and an insoluble or sparingly soluble inert organic solvent in the presence of an inorganic base.
    Type: Grant
    Filed: April 2, 1980
    Date of Patent: April 20, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ulrich Buhler, Ernst Heinrich
  • Patent number: 4323363
    Abstract: Hazy or frosty appearance of mixtures of polyester and cellulosic fibers when dyed with disperse dyes is suppressed by adding to the aqueous dye bath a small amount of low copolymer of acrylamide or the like with a water-soluble maleic or fumaric acid ester, and with or without an additional water-soluble vinyl compound, all as defined infra. The copolymer is normally a liquid miscible with water in all proportions at 10.degree. C. or below. Disperse dye is fixed to the polyester fibers by heating as in the Thermosol process. Dyes for the cellulosic fibers can also be included in the dye bath so that the cellulosic fibers are also dyed in the same treatment. Alternatively the cellulosic fibers can be separately dyed, preferably after the polyester fibers are dyed.
    Type: Grant
    Filed: May 22, 1980
    Date of Patent: April 6, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventors: Gert Brachten, Friedrich Engelhardt, Heinz Helling, Joachim Ribka
  • Patent number: 4322213
    Abstract: Printed textiles and a process for production of resist effects on textile materials of mixed fibers of polyester and cellulose comprising impregnating the materials with a dye liquor containing dischargeable disperse dyestuffs and dischargeable reactive dyestuffs which react with the resisting agents, drying or partially drying the materials and subsequently printing a resist paste on the materials, and heat-treating the materials at temperatures of 100.degree. to 190.degree. C.,the improvement comprises said dischargeable disperse dyestuffs are of the formula ##STR1## p0 wherein n is a number of 1 to 9; said dischargeable reactive dyestuffs being those containing reactive moieties of the formula--SO.sub.2 --CH.sub.2 --CH.sub.2 --hal,--SO.sub.2 --CH.sub.2 --CH.sub.2 --O--SO.sub.3 M,--NH--SO.sub.2 --CH.sub.2 --CH.sub.2 --O--SO.sub.3 M or--SO.sub.2 --CH.dbd.CH.sub.
    Type: Grant
    Filed: May 18, 1981
    Date of Patent: March 30, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventors: Horst Tappe, Horst Kindler, Kurt Roth, Sien L. Ong
  • Patent number: 4320060
    Abstract: The process for the preparation of a 3-(4-hydroxyanilino)carbazole of the formula ##STR1## wherein R is hydrogen, alkyl having 1 to 8 carbon atoms or halogenoalkyl having 1 to 8 carbon atoms, comprising reacting a 3-aminocarbazole of the formula ##STR2## with p-hydroquinone or p-aminophenol or a mixture of p-hydroquinone and p-aminophenol in at least stoichiometric amounts by heating to a temperature of 150.degree. to 300.degree. C. with exclusion of oxygen.
    Type: Grant
    Filed: December 31, 1979
    Date of Patent: March 16, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventors: Steffen Piesch, Friedrich Engelhardt, Herbert Wille, Wolf Weidemuller, Artur Meyer
  • Patent number: 4313872
    Abstract: Azo dyes are very simply made in high purity and very good yield by coupling a diazonium compound with a coupling compound in a mixture essentially of water with a simple alkanol having four to six carbons and soluble in water to the extent of not over about 15% by weight at 15.degree. C. This procedure is particularly effective with compounds that are ordinarily difficult to couple.
    Type: Grant
    Filed: May 8, 1978
    Date of Patent: February 2, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ernst Heinrich, Joachim Ribka
  • Patent number: 4314052
    Abstract: Improved polyesters soluble or dispersible in water having an apparent average molecular weight of 800 to 5,000 and containing phosphonic ester moieties are useful as levelling auxiliaries for uniform dyeing and are produced by esterifying dibasic acids and dihydric alcohols, either or both of which contain phosphonic acid moieties, phosphonic acid ester moieties or both.
    Type: Grant
    Filed: January 7, 1980
    Date of Patent: February 2, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventors: Friedrich Engelhardt, Karl Hintermeier, Joachim Ribka, Walter Dursch, Walter Rupp
  • Patent number: 4310355
    Abstract: An internal release agent and the process of its manufacture aids in releasing thermosetting aminoplast resins from molds and is an aqueous solution or dispersion containing(a) 5-30% by weight of a mixture of 50-100% by weight of a compound of the formula ##STR1## and 0 to 50% by weight of a compound of the formula ##STR2## and an acid salt selected from (b), (c) and (d) wherein (b) is 2-15% by weight of a compound of the formulaR.sup.4 --COOM.sup.3 or R.sup.4 --SO.sub.3 M.sup.3,(c) is 0.5 to 10% by weight of a compound of the formula ##STR3## and (d) is a mixture of (b) and (c);whereinR.sup.1, R.sup.2 and R.sup.3 independently of one another are straight-chain or branched alkyl or alkenyl having 5 to 12 carbon atoms or phenalkyl or naphthalkyl having 7 to 13 carbon atoms;R.sup.
    Type: Grant
    Filed: September 19, 1980
    Date of Patent: January 12, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventors: Peter Dorries, Karl-Heinz Keil
  • Patent number: 4310447
    Abstract: Curable, modified aminotriazine condensation product prepared by reacting an aminotriazine condensation product pre-condensed to a dilutability ratio with water of 1:0.5 to 1:5, with 65 to 500% by weight, relative to the triazine, of a lactam of an aminocarboxylic acid having 3 to 18 carbon atoms, or a diaminedicarboxylate salt of a diamine having 2 to 18 carbon atoms and a dicarboxylic acid having 2 to 18 carbon atoms, or a mixture thereof, at a temperature of no more than 65.degree. C.
    Type: Grant
    Filed: July 23, 1980
    Date of Patent: January 12, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventors: Wilhelm Weber, Wilhelm Adam
  • Patent number: 4309401
    Abstract: The process for recovering recyclable elemental sulfur from a strongly colored solution containing alkali metal sulfides, alkali metal polysulfides, or mixtures thereof comprising(a) mixing said solution at an alkaline pH with a decolorizing amount of an iron or zinc compound which is a hydroxide or the salt of an inorganic acid whereby a precipitate is formed,(b) separating the precipitate to isolate a decolorized solution,(c) precipitating elemental sulfur from the decolorized solution by adding sulfur dioxide or alkali metal thiosulfate under acidic conditions, and(d) separating the precipitated elemental sulfur.
    Type: Grant
    Filed: June 24, 1980
    Date of Patent: January 5, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventor: Georg Daniek
  • Patent number: 4309178
    Abstract: In the processs for isolating solid sulphur dyestuffs from crude sulphur dyestuff melts, the improvement comprises adding 10.sup.-4 to 1% by weight, relative to the amount of dyestuff, of an organic flocculating auxiliary to the crude dyestuff melt to produce a filterable dyestuff precipitate and then separating said precipitate.
    Type: Grant
    Filed: October 17, 1980
    Date of Patent: January 5, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventors: Georg Daniek, Artur Meyer, Wolf Weidemuller
  • Patent number: 4309523
    Abstract: Outstandingly suitable drilling mud additives are water soluble copolymers consisting essentially of a random distribution of(a) 5 to 95% by weight of units of the formula ##STR1## (b) 5 to 95% by weight of units of the formula ##STR2## and (c) 0 to 80% by weight of units of the formula ##STR3## wherein R.sup.1 and R.sup.2 are the same or different and each is hydrogen, methyl or ethyl; and X.sup..sym. is a cation.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: January 5, 1982
    Assignee: Cassella Aktiengesellschaft
    Inventors: Friedrich Engelhardt, Ulrich Riegel, Martin Hille, Heinz Wittkus
  • Patent number: 4306874
    Abstract: A sublimable monoazo dyestuff of the formula ##STR1## wherein X is alkyl of 1-4 carbon atoms is used as the dyestuff in the process for printing synthetic, hydrophobic materials, treated cellulose materials or materials containing both by transfer printing using formulations containing said sublimable monoazo dyestuff.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: December 22, 1981
    Assignee: Cassella Aktiengesellschaft
    Inventors: Horst Tappe, Claus Schuster
  • Patent number: 4303561
    Abstract: Partially etherified melamine-formaldehyde resins having a melamine: formaldehyde molar ratio of 1:(1.25 to 1) can be prepared by a condensation reaction under neutral or weakly alkaline conditions if the condensation reaction is carried out in the presence of a glycol monoether of the general formula IR (OCH.sub.2 CH.sub.2).sub.n OH (I)wherein R denotes alkyl having 1 to 4 C atoms and n denotes a number from 1 to 5. The partially etherified melamine-formaldehyde resins are suitable for the production of compression moulding compositions having a high flow and minimal processing shrinkage and after-shrinkage.
    Type: Grant
    Filed: May 29, 1979
    Date of Patent: December 1, 1981
    Assignee: Cassella Aktiengesellschaft
    Inventors: Steffen Piesch, Alfons Wolf
  • Patent number: 4302582
    Abstract: An improved process for preparation of a condensed product of phenothiazine and p-nitrosophenol which contains more than 60% by weight of indophenol S-oxide of the formula ##STR1## by condensing phenothiazine with p-nitrosophenol in sulphuric acid wherein the improvement comprises the phenothiazine being in 60 to 90% strength sulphuric acid at the time of addition of the p-nitrosophenol.
    Type: Grant
    Filed: January 31, 1980
    Date of Patent: November 24, 1981
    Assignee: Cassella Aktiengesellschaft
    Inventors: Gert Nagl, Joachim Ribka, Ulrich Gotsmann, Heinz Dickmanns
  • Patent number: 4300903
    Abstract: A padding auxiliary is used in a dyeing process using a padding liquor wherein the padding auxiliary is an aqueous solution or dispersion containing(a) 20 to 50 percent by weight of a mixture of 50 to 100 percent by weight of a compound of the following formula ##STR1## and 50 to 0 percent by weight of a compound of the following formula ##STR2## (b) b percent by weight of a compound of the formula ##STR3## and (c) c percent by weight of a compound of the formula ##STR4## wherein b is a number from 0 to 5, c is a number from 0 to 5 and the numbers for b and c are chosen such that the sum of the numbers for b and c is a number from 1 to 10;R.sup.1, R.sup.2 and R.sup.3 are independently an aliphatic moiety with 5 to 12 carbon atoms or an araliphatic moiety with 7 to 13 carbon atoms;X.sym., Y.sym. and Z.sym. is each independently an alkali metal cation, ammonium cation or a cation of an alkylamine or hydroxyalkylamine wherein the alkyl has 1-12 carbon atoms;R.sup.
    Type: Grant
    Filed: July 23, 1980
    Date of Patent: November 17, 1981
    Assignee: Cassella Aktiengesellschaft
    Inventors: Friedrich Engelhardt, Karl-Heinz Keil, Gerhard Weckler, Klaus Sternberger
  • Patent number: 4289665
    Abstract: An agent for conditioning and imparting water repellency to leather comprises a homogeneous mixture of(a) 10 to 35% by weight of a compound of the formula ##STR1## wherein R is linear or branched alkyl or alkenyl each having 14 to 22 carbon atoms, m is a number average from 1.0 to 1.5 and n is 2 minus m;(b) 0 to 10% by weight of non-ionic emulsifiers;(c) 0 to 3% by weight of anionic emulsifiers with the proviso that the sum of (b) and (c) is 0.5 to 10%;(d) 0 to 5% by weight of an epoxide of the formula ##STR2## wherein R' is alkyl or alkenyl having 15 to 40 carbon atoms; (e) 0 to 25% by weight of fat liquors; and(f) 25 to 89.5% by weight of water or a water-miscible organic solvent.
    Type: Grant
    Filed: August 17, 1979
    Date of Patent: September 15, 1981
    Assignee: Cassella Aktiengesellschaft
    Inventors: Gustav Hudec, Karl-Heinz Keil, Volker Kohler, Kurt Rosenbusch
  • Patent number: 4284782
    Abstract: The manufacture of 6-hydroxypyrid-2-ones is achieved by reacting a cyanoacetamide with an acetoacetic acid ester at temperatures of 50.degree. to 200.degree. C. and a pressure of 0.5 to 50 bars in an aqueous solution or suspension in the presence of an amine in a molar amount at least equal to that of the cyanoacetamide reactant.
    Type: Grant
    Filed: September 17, 1979
    Date of Patent: August 18, 1981
    Assignee: Cassella Aktiengesellschaft
    Inventor: Frank Schmidt
  • Patent number: 4273669
    Abstract: A latent curing agent for aminoplast resins produced by reacting diethanolamine with glycidol in a molar ratio of 1:(1 to 1.2) at 0.degree. to 90.degree. C. and then reacting the product with 0.5 to 1 mole of sulfur dioxide per mole of diethanolamine at 0.degree. to 90.degree. C.
    Type: Grant
    Filed: March 17, 1980
    Date of Patent: June 16, 1981
    Assignee: Cassella Aktiengesellschaft
    Inventors: Steffen Piesch, Peter Dorries, Ewald Schmidt, Richard Hensel
  • Patent number: 4271073
    Abstract: The present invention relates to new, pharmacologically valuable 2,4,5,6-tetrahydro-1H-pyrazino-[3,2,1-jk]-carbazoles substituted in the 8-position having the formula I ##STR1## wherein R stands for an alkyl or alkoxy group having 1 to 4 carbon atoms or a fluorine, chlorine or bromine atom comprising reacting a 6,9-disubstituted 1,2,3,4-tetrahydrocarbazol-1-one of the formula II ##STR2## and X denotes a bromine, chlorine or iodine atom or the radical of the formula defined --O--SO.sub.2 --R' and R' is an alkyl radical having 1 to 3 carbon atoms, phenyl or tolyl, with ammonia.
    Type: Grant
    Filed: November 29, 1979
    Date of Patent: June 2, 1981
    Assignee: Cassella Aktiengesellschaft
    Inventors: Heinz Bender, Rudi Beyerle, Karl-Heinz Keil, Heinz G. Greve, Kuno Reh