Abstract: Partially etherified melamine-formaldehyde resins having a melamine:formaldehyde molar ratio of 1:(1.25 to 1) can be prepared by a condensation reaction under neutral or weakly alkaline conditions if the condensation reaction is carried out in the presence of a glycol monoether of the general formula IR(OCH.sub.2 CH.sub.2).sub.n OH (I)wherein R denotes alkyl having 1 to 4 C atoms and n denotes a number from 1 to 5. The partially etherified melamine-formaldehyde resins are suitable for the production of compression moulding compositions having a high flow and minimal processing shrinkage and after-shrinkage.
Abstract: An improved process for producing 2,6-diaminopyridines and azo dyestuffs therefrom involves reacting a 2,6-dihalopyridine with a primary amine in a two-phase system of water and an insoluble or sparingly soluble inert organic solvent in the presence of an inorganic base.
Abstract: Hazy or frosty appearance of mixtures of polyester and cellulosic fibers when dyed with disperse dyes is suppressed by adding to the aqueous dye bath a small amount of low copolymer of acrylamide or the like with a water-soluble maleic or fumaric acid ester, and with or without an additional water-soluble vinyl compound, all as defined infra. The copolymer is normally a liquid miscible with water in all proportions at 10.degree. C. or below. Disperse dye is fixed to the polyester fibers by heating as in the Thermosol process. Dyes for the cellulosic fibers can also be included in the dye bath so that the cellulosic fibers are also dyed in the same treatment. Alternatively the cellulosic fibers can be separately dyed, preferably after the polyester fibers are dyed.
Type:
Grant
Filed:
May 22, 1980
Date of Patent:
April 6, 1982
Assignee:
Cassella Aktiengesellschaft
Inventors:
Gert Brachten, Friedrich Engelhardt, Heinz Helling, Joachim Ribka
Abstract: Printed textiles and a process for production of resist effects on textile materials of mixed fibers of polyester and cellulose comprising impregnating the materials with a dye liquor containing dischargeable disperse dyestuffs and dischargeable reactive dyestuffs which react with the resisting agents, drying or partially drying the materials and subsequently printing a resist paste on the materials, and heat-treating the materials at temperatures of 100.degree. to 190.degree. C.,the improvement comprises said dischargeable disperse dyestuffs are of the formula ##STR1## p0 wherein n is a number of 1 to 9; said dischargeable reactive dyestuffs being those containing reactive moieties of the formula--SO.sub.2 --CH.sub.2 --CH.sub.2 --hal,--SO.sub.2 --CH.sub.2 --CH.sub.2 --O--SO.sub.3 M,--NH--SO.sub.2 --CH.sub.2 --CH.sub.2 --O--SO.sub.3 M or--SO.sub.2 --CH.dbd.CH.sub.
Type:
Grant
Filed:
May 18, 1981
Date of Patent:
March 30, 1982
Assignee:
Cassella Aktiengesellschaft
Inventors:
Horst Tappe, Horst Kindler, Kurt Roth, Sien L. Ong
Abstract: The process for the preparation of a 3-(4-hydroxyanilino)carbazole of the formula ##STR1## wherein R is hydrogen, alkyl having 1 to 8 carbon atoms or halogenoalkyl having 1 to 8 carbon atoms, comprising reacting a 3-aminocarbazole of the formula ##STR2## with p-hydroquinone or p-aminophenol or a mixture of p-hydroquinone and p-aminophenol in at least stoichiometric amounts by heating to a temperature of 150.degree. to 300.degree. C. with exclusion of oxygen.
Type:
Grant
Filed:
December 31, 1979
Date of Patent:
March 16, 1982
Assignee:
Cassella Aktiengesellschaft
Inventors:
Steffen Piesch, Friedrich Engelhardt, Herbert Wille, Wolf Weidemuller, Artur Meyer
Abstract: Azo dyes are very simply made in high purity and very good yield by coupling a diazonium compound with a coupling compound in a mixture essentially of water with a simple alkanol having four to six carbons and soluble in water to the extent of not over about 15% by weight at 15.degree. C. This procedure is particularly effective with compounds that are ordinarily difficult to couple.
Abstract: Improved polyesters soluble or dispersible in water having an apparent average molecular weight of 800 to 5,000 and containing phosphonic ester moieties are useful as levelling auxiliaries for uniform dyeing and are produced by esterifying dibasic acids and dihydric alcohols, either or both of which contain phosphonic acid moieties, phosphonic acid ester moieties or both.
Type:
Grant
Filed:
January 7, 1980
Date of Patent:
February 2, 1982
Assignee:
Cassella Aktiengesellschaft
Inventors:
Friedrich Engelhardt, Karl Hintermeier, Joachim Ribka, Walter Dursch, Walter Rupp
Abstract: An internal release agent and the process of its manufacture aids in releasing thermosetting aminoplast resins from molds and is an aqueous solution or dispersion containing(a) 5-30% by weight of a mixture of 50-100% by weight of a compound of the formula ##STR1## and 0 to 50% by weight of a compound of the formula ##STR2## and an acid salt selected from (b), (c) and (d) wherein (b) is 2-15% by weight of a compound of the formulaR.sup.4 --COOM.sup.3 or R.sup.4 --SO.sub.3 M.sup.3,(c) is 0.5 to 10% by weight of a compound of the formula ##STR3## and (d) is a mixture of (b) and (c);whereinR.sup.1, R.sup.2 and R.sup.3 independently of one another are straight-chain or branched alkyl or alkenyl having 5 to 12 carbon atoms or phenalkyl or naphthalkyl having 7 to 13 carbon atoms;R.sup.
Abstract: Curable, modified aminotriazine condensation product prepared by reacting an aminotriazine condensation product pre-condensed to a dilutability ratio with water of 1:0.5 to 1:5, with 65 to 500% by weight, relative to the triazine, of a lactam of an aminocarboxylic acid having 3 to 18 carbon atoms, or a diaminedicarboxylate salt of a diamine having 2 to 18 carbon atoms and a dicarboxylic acid having 2 to 18 carbon atoms, or a mixture thereof, at a temperature of no more than 65.degree. C.
Abstract: The process for recovering recyclable elemental sulfur from a strongly colored solution containing alkali metal sulfides, alkali metal polysulfides, or mixtures thereof comprising(a) mixing said solution at an alkaline pH with a decolorizing amount of an iron or zinc compound which is a hydroxide or the salt of an inorganic acid whereby a precipitate is formed,(b) separating the precipitate to isolate a decolorized solution,(c) precipitating elemental sulfur from the decolorized solution by adding sulfur dioxide or alkali metal thiosulfate under acidic conditions, and(d) separating the precipitated elemental sulfur.
Abstract: In the processs for isolating solid sulphur dyestuffs from crude sulphur dyestuff melts, the improvement comprises adding 10.sup.-4 to 1% by weight, relative to the amount of dyestuff, of an organic flocculating auxiliary to the crude dyestuff melt to produce a filterable dyestuff precipitate and then separating said precipitate.
Type:
Grant
Filed:
October 17, 1980
Date of Patent:
January 5, 1982
Assignee:
Cassella Aktiengesellschaft
Inventors:
Georg Daniek, Artur Meyer, Wolf Weidemuller
Abstract: Outstandingly suitable drilling mud additives are water soluble copolymers consisting essentially of a random distribution of(a) 5 to 95% by weight of units of the formula ##STR1## (b) 5 to 95% by weight of units of the formula ##STR2## and (c) 0 to 80% by weight of units of the formula ##STR3## wherein R.sup.1 and R.sup.2 are the same or different and each is hydrogen, methyl or ethyl; and X.sup..sym. is a cation.
Type:
Grant
Filed:
August 1, 1980
Date of Patent:
January 5, 1982
Assignee:
Cassella Aktiengesellschaft
Inventors:
Friedrich Engelhardt, Ulrich Riegel, Martin Hille, Heinz Wittkus
Abstract: A sublimable monoazo dyestuff of the formula ##STR1## wherein X is alkyl of 1-4 carbon atoms is used as the dyestuff in the process for printing synthetic, hydrophobic materials, treated cellulose materials or materials containing both by transfer printing using formulations containing said sublimable monoazo dyestuff.
Abstract: Partially etherified melamine-formaldehyde resins having a melamine: formaldehyde molar ratio of 1:(1.25 to 1) can be prepared by a condensation reaction under neutral or weakly alkaline conditions if the condensation reaction is carried out in the presence of a glycol monoether of the general formula IR (OCH.sub.2 CH.sub.2).sub.n OH (I)wherein R denotes alkyl having 1 to 4 C atoms and n denotes a number from 1 to 5. The partially etherified melamine-formaldehyde resins are suitable for the production of compression moulding compositions having a high flow and minimal processing shrinkage and after-shrinkage.
Abstract: An improved process for preparation of a condensed product of phenothiazine and p-nitrosophenol which contains more than 60% by weight of indophenol S-oxide of the formula ##STR1## by condensing phenothiazine with p-nitrosophenol in sulphuric acid wherein the improvement comprises the phenothiazine being in 60 to 90% strength sulphuric acid at the time of addition of the p-nitrosophenol.
Type:
Grant
Filed:
January 31, 1980
Date of Patent:
November 24, 1981
Assignee:
Cassella Aktiengesellschaft
Inventors:
Gert Nagl, Joachim Ribka, Ulrich Gotsmann, Heinz Dickmanns
Abstract: A padding auxiliary is used in a dyeing process using a padding liquor wherein the padding auxiliary is an aqueous solution or dispersion containing(a) 20 to 50 percent by weight of a mixture of 50 to 100 percent by weight of a compound of the following formula ##STR1## and 50 to 0 percent by weight of a compound of the following formula ##STR2## (b) b percent by weight of a compound of the formula ##STR3## and (c) c percent by weight of a compound of the formula ##STR4## wherein b is a number from 0 to 5, c is a number from 0 to 5 and the numbers for b and c are chosen such that the sum of the numbers for b and c is a number from 1 to 10;R.sup.1, R.sup.2 and R.sup.3 are independently an aliphatic moiety with 5 to 12 carbon atoms or an araliphatic moiety with 7 to 13 carbon atoms;X.sym., Y.sym. and Z.sym. is each independently an alkali metal cation, ammonium cation or a cation of an alkylamine or hydroxyalkylamine wherein the alkyl has 1-12 carbon atoms;R.sup.
Type:
Grant
Filed:
July 23, 1980
Date of Patent:
November 17, 1981
Assignee:
Cassella Aktiengesellschaft
Inventors:
Friedrich Engelhardt, Karl-Heinz Keil, Gerhard Weckler, Klaus Sternberger
Abstract: An agent for conditioning and imparting water repellency to leather comprises a homogeneous mixture of(a) 10 to 35% by weight of a compound of the formula ##STR1## wherein R is linear or branched alkyl or alkenyl each having 14 to 22 carbon atoms, m is a number average from 1.0 to 1.5 and n is 2 minus m;(b) 0 to 10% by weight of non-ionic emulsifiers;(c) 0 to 3% by weight of anionic emulsifiers with the proviso that the sum of (b) and (c) is 0.5 to 10%;(d) 0 to 5% by weight of an epoxide of the formula ##STR2## wherein R' is alkyl or alkenyl having 15 to 40 carbon atoms; (e) 0 to 25% by weight of fat liquors; and(f) 25 to 89.5% by weight of water or a water-miscible organic solvent.
Type:
Grant
Filed:
August 17, 1979
Date of Patent:
September 15, 1981
Assignee:
Cassella Aktiengesellschaft
Inventors:
Gustav Hudec, Karl-Heinz Keil, Volker Kohler, Kurt Rosenbusch
Abstract: The manufacture of 6-hydroxypyrid-2-ones is achieved by reacting a cyanoacetamide with an acetoacetic acid ester at temperatures of 50.degree. to 200.degree. C. and a pressure of 0.5 to 50 bars in an aqueous solution or suspension in the presence of an amine in a molar amount at least equal to that of the cyanoacetamide reactant.
Abstract: A latent curing agent for aminoplast resins produced by reacting diethanolamine with glycidol in a molar ratio of 1:(1 to 1.2) at 0.degree. to 90.degree. C. and then reacting the product with 0.5 to 1 mole of sulfur dioxide per mole of diethanolamine at 0.degree. to 90.degree. C.
Type:
Grant
Filed:
March 17, 1980
Date of Patent:
June 16, 1981
Assignee:
Cassella Aktiengesellschaft
Inventors:
Steffen Piesch, Peter Dorries, Ewald Schmidt, Richard Hensel
Abstract: The present invention relates to new, pharmacologically valuable 2,4,5,6-tetrahydro-1H-pyrazino-[3,2,1-jk]-carbazoles substituted in the 8-position having the formula I ##STR1## wherein R stands for an alkyl or alkoxy group having 1 to 4 carbon atoms or a fluorine, chlorine or bromine atom comprising reacting a 6,9-disubstituted 1,2,3,4-tetrahydrocarbazol-1-one of the formula II ##STR2## and X denotes a bromine, chlorine or iodine atom or the radical of the formula defined --O--SO.sub.2 --R' and R' is an alkyl radical having 1 to 3 carbon atoms, phenyl or tolyl, with ammonia.