Abstract: Compounds of Formula II ##STR1## wherein R.sub.3 is --COCH.sub.3, --COCH.sub.3 or --COCH.sub.2 CH.sub.3 and R.sub.4 is hydrogen or R.sub.3 is hydrogen and R.sub.4 is --OCH.sub.3, --OCH.sub.2 CH.sub.3, --OCH.sub.2 CH.sub.2 OH or --OCH.sub.2 CH.sub.2 OCH.sub.3 are storage stable and can be used in oxidative hairdye systems in place of the storage unstable 2-methyl-1-naphthol. Advantageously, it has been found to produce the same colors as 2-methyl-1-naphthol.
Type:
Grant
Filed:
September 14, 1995
Date of Patent:
June 25, 1996
Assignee:
Clairol Incorporated
Inventors:
Mu-Ill Lim, Yuh-Guo Pan, Linas R. Stasaitis, John D. O'Donoghue
Abstract: A process for preparing dye compositions which comprises hydrolyzing an O-protected 5,6-dihydroxyindole with an alkaline material under anaerobic condition and the products made by such process.
Type:
Grant
Filed:
May 31, 1995
Date of Patent:
May 14, 1996
Assignee:
Clairol Incorporated
Inventors:
Bryan P. Murphy, Keith C. Brown, Thomas M. Schultz, Alice A. Meyer
Abstract: A process for preparing dye compositions which comprises hydrolyzing an O-protected 5,6-dihydroxyindole with an alkaline material under substantially anaerobic condition and the products made by such process.
Type:
Grant
Filed:
January 5, 1990
Date of Patent:
February 20, 1996
Assignee:
Clairol Incorporated
Inventors:
Bryan P. Murphy, Keith C. Brown, Thomas M. Schultz, Alice A. Meyer
Abstract: A process for increasing the amount of melanin formation following hair dyeing by ferricyanide oxidation of a dopa species hair colorant utilizing a post-oxidant such as sodium periodate at a controlled pH and compositions and kits for use in the process.
Abstract: A process of dyeing hair by preparing and applying to the hair an aqueous reaction medium comprising an aminoethanethio substituted dihydroxybenzene and a periodate, iodate, ferricyanide or persulfate oxidizing agent, the composition optionally containing a color modifier selected from the group consisting of direct dyes, primary intermediates, couplers, cysteine, dopa species and mixtures thereof, additionally containing a buffer to maintain the pH in the range from 2 to 11 during the oxidation reaction; and removing the aqueous reaction medium from the hair after formation of the desired color and compositions and kits for practicing such processes. The reaction medium may be formed by simultaneous addition of the dihydroxybenzene and the oxidant to the hair or by addition of the dihydroxybenzene followed by addition of the oxidant.
Abstract: Aqueous dye compositions containing sodium chlorite together with 5,6-dihydroxyindoline or 5,6-dihydroxyindole, its analogs, homologs or derivatives, methods of using the compositions to color hair and packages containing such compositions.
Abstract: A process of dyeing hair by preparing and applying to the hair an aqueous reaction medium comprising dihydroxybenzothiazine and a periodsate, iodate, ferricyanide or persulfate oxidizing agent, the composition optionally containing a color modifier selected from the group consisting of direct dyes, primary intermediates, couplers, cysteine, dopa species and mixtures thereof, additionally containing a buffer to maintain the pH in the range from 2 to 11 during the oxidation reaction; and removing the aqueous reaction medium from the hair after the desired color is attained and compositions and kits for practicing such processes. The reaction medium may be formed by simultaneous addition of the benzothiazine and the oxidant to the hair or by addition of the benzothiazine followed addition of the oxidant.
Abstract: The invention provides methods, compositions and kits for oxidative hair dyeing utilizing an oxidative hair dye precursor, and an alkali metal chlorite together with a water soluble copper, iron, manganese or cobalt salt, a chelate of said salts or a mixture of said salts and chelates.
Type:
Grant
Filed:
April 20, 1993
Date of Patent:
November 29, 1994
Assignee:
Clairol Incorporated
Inventors:
Alexander Chan, Gottfried Wenke, Ciuseppe Prota
Abstract: Process for dyeing human hair by the sequential treatment of the hair with a metal ion and particularly transition metal ion containing composition and with a dye composition containing 5,6-dihydroxyindole-2-carboxylic acid.
Type:
Grant
Filed:
April 14, 1993
Date of Patent:
September 13, 1994
Assignee:
Clairol Incorporated
Inventors:
Thomas M. Schultz, Keith C. Brown, Leszek J. Wolfram, Giuseppe Prota
Abstract: In a method for oxidatively dyeing hair, a pretreatment which comprises contacting hair with an aqueous solution of an effective amount of particular metal/chelate complexes followed by treatment with oxidative dye mixtures is disclosed. The process serves to conform the oxidative dyeing rate of virgin hair to that of the normally noncongruent rate of nonvirgin hair, so as to enhance the efficiency of the oxidative dyeing process, without reducing the intensity or variety of color available.
Abstract: Direct dyes having a quaternary center with a long aliphatic chain, compositions containing those dyes, and the process of using them to dye hair are disclosed. These dyes have a higher affinity for hair and are more shampoo stable than conventional direct dyes, and produce pleasing uniform dyeing.
Abstract: A hair clip for heating and styling clasped hair, whether damp or dry, into a linear configuration in the scalp area of a user. The clip comprises a pair of biasable jaws including a pair of plates for storing heat and releasing such heat to style clasped hair held between the pair of plates. Supports extend laterally from the hair clip to permit it to freestand and heat and style the hair in a perpendicular fashion to the scalp, giving the remaining hair lift away from the scalp. The hair clips are heated by biasably gripping a heated plate positioned within a base structure of an electric heating unit. The heated hair clips are used in a method of styling dry or damp hair into a linear configuration generally perpendicular to the scalp.
Abstract: A process for dyeing hair by preparing and thereafter applying to the hair an aqueous reaction medium comprising dopa and an oxidant, said aqueous reaction medium further containing at least one hair dyeing agent selected from the group consisting of primary intermediates and couplers and also containing a buffer to maintain the pH in the range from 6 to 10 during the reaction, and removing said aqueous reaction medium from the hair within about one hour following its preparation.
Type:
Grant
Filed:
July 31, 1992
Date of Patent:
January 18, 1994
Assignee:
Clairol Incorporated
Inventors:
Giuseppe Prota, Leszek Wolfram, Gottfried Wenke
Abstract: A process for dyeing hair by preparing and thereafter applying to the hair an aqueous reaction medium comprising a substituted dopa species and an oxidant which is a ferricyanide salt, said aqueous reaction medium further containing a buffer to maintain the pH in the range from 6 to 10 during the reaction, and removing said aqueous reaction medium from the hair within about one hour following its preparation.
Type:
Grant
Filed:
July 13, 1992
Date of Patent:
January 18, 1994
Assignee:
Clairol Incorporated
Inventors:
Giuseppe Prota, Leszek Wolfram, Gottfried Wenke
Abstract: A process for dyeing hair by preparing and thereafter applying to the hair an aqueous reaction medium comprising dopa and an oxidant selected from ferricyanide and permanganate salts, said aqueous reaction medium further containing a buffer to maintain the pH in the range from 6 to 10 during the reaction, and removing said aqueous reaction medium from the hair within about one hour following its preparation
Type:
Grant
Filed:
September 26, 1991
Date of Patent:
December 28, 1993
Assignee:
Clairol Incorporated
Inventors:
Giuseppe Prota, Leszek J. Wolfram, Gottfried Wenke
Abstract: Quaternized monoalkylenediamine nitrobenzene compounds of general formula ##STR1## wherein one of Z or Y is the quaternized group ##STR2## the other of Y or Z being H, alkyl, hydroxyalkyl or hydroxyalkoxy when it is not said quaternized group, and the use of said compounds in the dyeing of keratinaceous fibers.
Abstract: Novel isothiuronium surfactant salts are useful as hair conditioning agents. Aqueous composition containing such salts, and method of using the salts are disclosed.
Abstract: Processes for conditioning human hair by treatment with selected quaternary ammonium halides, compositions useful for such processes and novel quaternary halides useful in the processes.