Abstract: The treatment of proteinaceous or other substrates to render them more manageable and more stable against chemical treatment involves the use of aqueous compositions containing cationic (meth)acrylic copolymers.
Type:
Grant
Filed:
October 16, 1990
Date of Patent:
February 16, 1993
Assignee:
Clairol Incorporated
Inventors:
Richard DeMarco, Raymond Feinland, Janusz Jachowicz
Abstract: N.sup.1 -Trifluoroalkyl substituted 2-nitro-p-phenylenediamines, compositions containing same, and their use as direct dyes for keratinous fibers are disclosed.
Abstract: The present invention concerns the aminophenols (I) as novel couplers ##STR1## wherein R.sub.1 and R.sub.2 may be the same or different and are hydrogen, alkyl and hydroxyalkyl of from 1 to about 6 carbons in the alkyl moiety, or R.sub.1 and R.sub.2 can also form, together with the nitrogen atom to which they are attached, a morpholine, piperidine or pyrrolidine ring, and R.sub.3 and R.sub.4 are hydrogen, alkyl, acyl and hydroxyalkyl having from 1 to about 6 carbons, and oxidative hair dye compositions containing same along with at least one primary dye intermediate in aqueous or hydroalcoholic media.
Type:
Grant
Filed:
October 23, 1990
Date of Patent:
February 2, 1993
Assignee:
Clairol Incorporated
Inventors:
Yuh-Guo Pan, Alexander Chan, Lana Hochman
Abstract: A hair dyeing process which comprises of steps of contacting the hair to be dyed with an aqueous solution of a metal salt that promotes melanogenses in air. Before or after the aforementioned step contacting the hair with a solution of 5,6-dihydroxyindole, rinsing the hair between the two contacting steps, maintaining the contact with the second-used solution until a desired darker color is obtained, rinsing or shampooing the hair, then contacting the hair with a solution of hydrogen peroxide until the desired color shade is obtained, and then again rinsing the hair.
Type:
Grant
Filed:
January 29, 1991
Date of Patent:
December 22, 1992
Assignee:
Clairol Incorporated
Inventors:
Keith Brown, Bryan P. Murphy, Leszek J. Wolfram
Abstract: The novel hair dye compositions containing a compound of the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 which may be identical or different, are hydrogen, alkyl, hydroxyalkyl, polyhydroxyalkyl, alkoxyalkyl, hydroxyalkoxyalkyl aminoalkyl and dialkylaminoalkyl, each alkyl group and each alkoxy group having from about 1 to about 6 carbons and R.sub.5 is hydrogen or alkyl containing from about 1 to about 6 carbon atoms are disclosed. More specifically, the present invention concerns the inclusion of such compounds of formula I in hair dye compositions as direct dyes, and especially the novel compound 4-(2-hydroxyethylamino)-3-nitrobenzamide. The compounds, some of which are novel, provide a yellow dye base for the hair dyeing compositions.
Abstract: This invention relates to a multi-fluid mixing and automatic mettering dispenser for co-dispensing a pressurized permanent hair dye composition, having a first container containing a hair dye and propellant material, a second container disposed within the first container and containing a dye developer material, a nozzle structure defining a discharge passageway and a valve structure having first and second valves for controlling passage of the materials through the nozzle. The nozzle structure permits concurrent operation of the first and second valves to permit simultaneous flow of the materials form the first and second containers through the discharge passageway under the influence of the propellant, such that the materials exit from the dispenser at an overall flow rate not greater than about 1.8 gm/sec, and the flow ratio of the hair dye and propellant material exiting the first valve to the dye developer material exiting the second valve is in the range of about 1.9 to 2.5:1.
Abstract: A process for simultaneously cold waving and coloring hair in which the neutralization of the hair waving composition is accomplished in two stages, the second stage of which involves the use of a neutralizing composition containing a hair dye.
Abstract: A composition for treating keratinaceous substrates which contains a cationic polymer having units of formula I: ##STR1## wherein: (a) R.sup.1, R.sup.2 and R.sup.3 are each independently selected from the group consisting of H, halogen, alkyl, C.sub.1-6 alkoxy, C.sub.1-6 aminoalkyl, C.sub.1-6 haloalkyl, phenyl, C.sub.1-6 alkylphenyl, C.sub.1-6 alkoxyphenyl, halophenyl containing 1 to 5 halogen atoms, and aminophenyl containing 1 to 5 amino groups;(b) R.sup.4 and R.sup.5 are each independently C.sub.1-20 alkylene linkages bearing from 0 to 10 halogen or C.sub.1-6 alkoxy substituents;(c) X is --O-- or --NH--;(d) R.sup.6, R.sup.7, and R.sup.8 are each independently C.sub.1-20 alkyl, with the proviso that at least one of R.sup.6, R.sup.7, and R.sup.8 contains a C.sub.10-20 groups; and(e) Y is a halide ion or C.sub.1-6 alkyl sulfate ion;in the presence of a non-polymeric surfactant selected from the group consisting of amphoteric surfactants, anionic surfactants and mixtures thereof.
Abstract: Quaternized monoalkylenediamine nitrobenzene compounds of general formula ##STR1## wherein one of Z or Y is the quaternized group ##STR2## the other of Y or Z being H, alkyl hydroxyalkyl or hydroxyalkoxy when it is not said quaternized group, and the use of said compounds in the dyeing of keratinaceous fibers.
Abstract: In a method for oxidatively dyeing hair, a pretreatment which comprises contacting hair with an aqueous solution of an effective amount of particular metal/chelate complexes followed by treatment with oxidative dye mixtures is disclosed. The process serves to conform the oxidative dyeing rate of virgin hair to that of the normally noncongruent rate of nonvirgin hair, so as to enhance the efficiency of the oxidative dyeing process, without reducing the intensity or variety of color available.
Abstract: A bobbin or spool type hair curler having a cylindrical hair roller portion formed between a pair of opposing parallel flanges and provided with a pliable, integrally formed, cup-shaped closure member. The closure member is axially aligned to one of the end flanges of the spool shaped hair roller portion. The wall of the cup-shaped closure member extends away from the spool shaped portion and, after the hair is wound upon the spool shaped portion, the wall may be flipped substantially 180.degree. about its point of attachment to its corresponding flange in order to place the rim of the cup-shaped closure member proximate to the other flange to thereby retain the hair around the spool shaped portion. The invention additionally includes a method for curling hair with the aforementioned device and, in one embodiment the hair curler is provided with an axial throughbore and the invention further includes a method for heating same.
Abstract: The present invention concerns the aminophenols (I) as novel couplers ##STR1## wherein R.sub.1 and R.sub.2 may be the same or different and are hydrogen, alkyl and hydroxyalkyl of from 1 to about 6 carbons in the alkyl moiety, or R.sub.1 and R.sub.2 can also form, together with the nitrogen atom to which they are attached, a morpholine, piperidine or pyrrolidine ring, and R.sub.3 and R.sub.4 are hydrogen, alkyl, acyl and hydroxyalkyl having from 1 to about 6 carbons, and oxidative hair dye compositions containing same along with at least one primary dye intermediate in aqueous or hydroalcoholic media.
Type:
Grant
Filed:
October 23, 1990
Date of Patent:
December 17, 1991
Assignee:
Clairol Incorporated
Inventors:
Yuh-Guo Pan, Alexander Chan, Lana Hochman
Abstract: Novel benzoxazine compounds of the structure ##STR1## wherein X and Y are independently selected from the group hydrogen, alkyl, alkoxyalkyl, aminoalkyl, hydroxyalkyl and hydroxyaminoalkyl, each alkyl moiety having 1 to 6 carbons, and m=1, 2 or 3, have been found suitable as hair dyes.
Abstract: Compositions containing certain indoles and quaternary ammonium salts are useful for imparting a tan to skin without prolonged exposure to the sun.
Type:
Grant
Filed:
November 22, 1989
Date of Patent:
September 17, 1991
Assignee:
Clairol Incorporated
Inventors:
Thomas M. Schultz, George Serban, Alexander C. Chan