Patents Assigned to Dai-Ichi Kogyo Seiyaku Co., Ltd.
  • Patent number: 6528577
    Abstract: The present invention provides a polyurethane hydrogel prepared by crosslinking and curing a terminal isocyanate-containing polyurethane resin (C) in the presence of water at a water:resin (C) weight ratio of more than 9:1, the resin (C) being a reaction product of a polyisocyanate (A) and a liquid polyol (B), and the polyol (B) containing 70 wt. % or more of a random copolymer prepared by copolymerization of ethylene oxide (a) and propylene oxide (b) at an ethylene oxide (a): propylene oxide (b) weight ratio of 50:50 to 90:10. The present invention further provides a production process and use of the polyurethane hydrogel.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: March 4, 2003
    Assignees: Kansai Paint Co., Ltd., Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Osamu Isozaki, Toshiki Noda
  • Patent number: 6518354
    Abstract: There is provided a dispersing emulsion excellent in storage stability and mechanical stability, particularly an asphalt modifier of an water based dispersing emulsion, which can be mixed with a hot asphalt or an asphalt emulsion, and can improve rutting resistance, toughness, and flexibility at a low temperature without losing workability. There is provided a dispersing emulsion of a thermoplastic elastomer, which is emulsified and dispersed in the presence of at least one nonionic emulsifier selected from the group consisting of a styrenated phenol poly(alkylene oxide), a poly(alkylene polyamine) poly(alkylene oxide), polyalcohol fatty acid esters, polyalcohol fatty acid esters poly(alkylene oxide), and a benzylated phenol poly(alkylene oxide).
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: February 11, 2003
    Assignees: JSR Corporation, Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Ginpei Suzuki, Yukihiro Okubo, Toshiyuki Nishitani, Masayo Kuze
  • Patent number: 6488813
    Abstract: Paper with increased wet strength is produced by adding to the stock a water soluble blocked urethane prepolymer having a plurality of blocked isocyanate groups and hydrophilic groups. The blocking agent is a phenol compound having an electron-attracting group at the ortho- or para-position. The blocked urethane prepolymer is capable of unblocking under such conditions that encounter in the drying part of conventional paper making machines.
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: December 3, 2002
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Takeshi Doi, Naofumi Saiuchi, Masahiro Kouchi
  • Patent number: 6486281
    Abstract: A process for preparing a high purity vinylpyrrolidone polymer which dissolves clearly in an organic solvent can be provided. The process for preparing a high purity vinylpyrrolidone polymer, wherein vinylpyrrolidone is polymerized by using a redox initiator comprising an organic peroxide and a sulfite, and thereafter the product is contacted with an anion exchange resin to be purified.
    Type: Grant
    Filed: August 24, 2001
    Date of Patent: November 26, 2002
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Akira Kitada, Keiichi Fujise, Itsuko Hamaguchi
  • Patent number: 6465592
    Abstract: A vinylpyrrolidone polymer which is little colored, gives off a bad smell little, and contains extremely little impurities is provided. The polymerization is performed by adding a water-soluble organic peroxide and a sulfite to a vinylpyrrolidone aqueous solution.
    Type: Grant
    Filed: August 3, 2001
    Date of Patent: October 15, 2002
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Akira Kitada, Keiichi Fujise, Itsuko Hamaguchi
  • Publication number: 20020088583
    Abstract: Paper with increased wet strength is produced by adding to the stock a water soluble blocked urethane prepolymer having a plurality of blocked isocyanate groups and hydrophilic groups. The blocking agent is a phenol compound having an electron-attracting group at the ortho- or para-position. The blocked urethane prepolymer is capable of unblocking under such conditions that encounter in the drying part of conventional paper making machines.
    Type: Application
    Filed: July 31, 2001
    Publication date: July 11, 2002
    Applicant: Dai-ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Takeshi Doi, Naofumi Saiuchi, Masahiro Kouchi
  • Patent number: 6399254
    Abstract: Provided is a solid electrolyte having a reduced amount of non-crosslinked monomers, capable of being cured rapidly to have good film-forming ability, and having high electroconductivity. The solid electrolyte is prepared by crosslinking a composition that consists essentially of a polymer compound, a solvent and an electrolytic salt through exposure to active radiations and/or under heat, in which the polymer compound has four functional polymer chains of formula (I): R1 and R2 each represent a hydrogen atom or a lower alkyl group, R3 represents a hydrogen atom or a methyl group, m and n each represent 0 or an integer of 1 or more, and m+n≧35 in one polymer chain.
    Type: Grant
    Filed: January 4, 2000
    Date of Patent: June 4, 2002
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Michiyuki Kono, Eriko Ishiko
  • Patent number: 6329103
    Abstract: A solid electrolyte is disclosed, which comprises a crosslinked product of an alkylene oxide polymer having a polymerizable double bond at the terminal and/or in the side chain, and an electrolytic salt. In this, the alkylene oxide polymer is thermally crosslinked in the presence of an organic peroxide initiator having an activation energy of at most 35 Kcal/mol and having a half-value period of 10 hours at a temperature not higher than 50° C.
    Type: Grant
    Filed: July 15, 1999
    Date of Patent: December 11, 2001
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Eriko Ishiko, Michiyuki Kono
  • Patent number: 6307069
    Abstract: The decomposition reactive emulsifier of this invention is a compound of formula (I): wherein R1 and R2 are the same or different and each represents an alkyl or alkenyl group of from 1 to 20 carbon atoms or a hydrogen atom and both R1 and R2 are not concurrently a hydrogen; R3 is a hydrogen atom or a methyl group; A is an alkylene or substituted alkylene group of 2 to 4 carbon atoms; n is an integer of from 1 to 100 when X is a hydrogen atom or n is an integer of from 0 to 100 when X is an ionic hydrophilic group, said ionic hydrophilic group being anionic, cationic or amphoteric and when n is 2 or greater (AO)n is a homopolymer or a block copolymer or a random copolymer.
    Type: Grant
    Filed: July 29, 1999
    Date of Patent: October 23, 2001
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Masayuki Hashimoto, Toshiyuki Nishitani
  • Patent number: 6299790
    Abstract: An electric double layer capacitor capable of functioning over a broad temperature range with a reduced incidence of electrolyte leakage and a low rate of self discharge is formed from a solid electrolyte containing (A) a crosslinking product of a polyoxyalkylene having a double bond terminally and/or in its side chain, (B) an electrolyte salt, (C) a low molecular weight polar solvent, and (D) polyacrylonitrile. The above-mentioned polyoxyalkylene (A) is, for example, a compound of the formula (1) below. In formula (1), Z is an active hydrogen compound residue; k is an integer from 1 to 6; R1 is an alkyl group having 1 to 8 carbon atoms; Y1 is an acryloyl or methacryloyl group; m is an integer from 0 to 460 and n is an integer from 0 to 350, excluding the case in which both m and n are simultaneously equal to 0.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: October 9, 2001
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Michiyuki Kono, Yoshiharu Matsuda
  • Patent number: 6190804
    Abstract: A solid battery using a solid electrolyte obtained by dissolving a tetrafunctional high-molecular compound and an electrolyte salt in a solvent and crosslinking the solution by the irradiation of an actinic radiation and/or by heating, wherein the solid electrolyte is one obtained by using a tetrafunctional terminal acryloyl-modified alkylene oxide polymer having a high-molecular chain represented by following formula (I) as the above-described tetrafunctional high-molecular compound, compounding the solvent with the polymer at a ratio of from 220 to 1,900% by weight to the above-described tetrafunctional high-molecular compound, and crosslinking the compounded mixture: wherein R1 and R2 each represents a hydrogen atom or a lower alkyl group; R3 represents a hydrogen atom or a methyl group; m and n each represents 0 or an integer of at least 1; in one high-molecular chain, m+n≧35.
    Type: Grant
    Filed: December 1, 1998
    Date of Patent: February 20, 2001
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Eriko Ishiko, Michiyuki Kono, Tsutomu Sada
  • Patent number: 6159265
    Abstract: The object is to provide a powdered metal injection compacting composition adapted to give compacts free from deformation, cracking or blistering without being compromised in compactability or debinder characteristic and without the aid of a special jig.This composition comprises a metal powder and an organic binder comprising (A) a crystalline resin having a melting point of not less than 150.degree. C., (B) an organic compound the weight loss on heating of which begins at a temperature below 150.degree. C. and (C) a composite acrylic resin, the composite acrylic resin mentioned above being a resin obtainable by dispersing a solution comprising the following components (C1).about.(C3) in an aqueous medium containing a dispersant and carrying out a suspension polymerization reaction:(C1) an ethylene-vinyl acetate copolymer or an ethylene-ethyl acrylate copolymer,(C2) a (meth)acrylic ester monomer or a mixture of a (meth)acrylic ester monomer and a styrenic monomer, and(C3) a polymerization initiator.
    Type: Grant
    Filed: February 11, 2000
    Date of Patent: December 12, 2000
    Assignees: Dai-Ichi Kogyo Seiyaku Co., Ltd., Dai-Ichi Ceramo Ltd.
    Inventors: Hiromitsu Kinoshita, Tetsuo Shiraiwa, Hidetaka Uraoka, Nobuo Ochiai
  • Patent number: 6093783
    Abstract: This invention relates to a water-soluble fiber and a method of manufacturing the fiber. The water-soluble fiber of the invention is composed of a high molecular compound with a weight average molecular weight of not less than 10,000, which high molecular compound is obtainable by reacting a polyalkylene oxide compound, which is obtainable by addition polymerization of an ethylene oxide-containing alkylene oxide and an organic compound containing two active hydrogen atoms, with a polycarboxylic acid, an anhydride thereof, a lower alkyl ester thereof, or a diisocyanate and is manufactured by spinning the same high molecular compound. The water-soluble fiber of the invention is not only high in elongation and tensile strength but is readily soluble in water.
    Type: Grant
    Filed: January 18, 1996
    Date of Patent: July 25, 2000
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Takeshi Fujita, Chuzo Isoda, Sejin Pu
  • Patent number: 6075142
    Abstract: A process for producing tris(tribromophenoxy)-s-triazine. The process is characterized in that cyanuric chloride and an aqueous tribromophenolate solution are subjected to reaction in the presence of a tertiary amine. According to this process, the reaction goes to completion in a short time and the yield and purity of the product are high.
    Type: Grant
    Filed: May 25, 1999
    Date of Patent: June 13, 2000
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Setsuo Nishibori, Hideto Kondo
  • Patent number: 6019908
    Abstract: An ion-conductive polymer electrolyte comprises an organic polymer, a soluble electrolyte salt and an organic solvent. The organic polymer is a compound obtained by crosslinking an organic compound having an average molecular weight of 500 to 50,000 and a structure of the following general formula 1,Z--[(E).sub.m --(A).sub.n --Y].sub.k 1in which Z is a residue of a compound having at least one active hydrogen; Y is an active hydrogen group or polymerizable functional group; k is an integer of 1 to 12; E is a structure of the following general formula 2, ##STR1## wherein p is an integer of 0 to 25 and R is an alkyl, alkenyl, aryl or alkylaryl group having 1 to 20 carbon atoms; A is --(CH.sub.2 --CH.sub.2 --O)--; m is an integer of 1 to 220; n is an integer of 1 to 240 and m+n.gtoreq.4; and E and A are random-copolymerized. The organic solvent is at least one selected from the group consisting of tetrahydrofuran, 2-methyltetrahydrofuran, 1,3-dioxolan, 4,4-dimethyl-1,3-dioxolan, .gamma.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: February 1, 2000
    Assignee: Dai-Ichi Kogyo Seiyaku, Co., Ltd.
    Inventors: Michiyuki Kono, Kenji Motogami, Shigeo Mori
  • Patent number: 5977490
    Abstract: A conductive paste compound for via hole filling includes a conductive filler at 80 to 92 weight percent with an average particle size of from 0.5 to 20 .mu.m and specific surface of from 0.1 to 1.5 m.sup.2 /g, a liquid epoxy resin at 4.5 to 20 weight percent containing 2 or more epoxy groups with room temperature viscosity of 15 Pa.sec or less, and a hardener at 0.5 to 5 weight percent, wherein the viscosity is 2,000 Pa.sec or less and the volatile amount is 2.0 weight percent or less. A filling paste and a printed circuit board with use thereof are provided which can conduct an inner-via-hole connection between electrode layers without using a through-hole plating technique.The conductive paste comprises a metallic particle such as copper, an epoxy resin, a hardener, and if necessary, a dispersant. The paste having low viscosity and low volatility under high shear is used to fill holes disposed in a laminated substrate.
    Type: Grant
    Filed: January 8, 1997
    Date of Patent: November 2, 1999
    Assignees: Matsushita Electric Industrial Co., Ltd., Dai-Ichi Kogyo Seiyaku Co. Ltd., Dowa Mining Co., Ltd.
    Inventors: Kouji Kawakita, Seiichi Nakatani, Tatsuo Ogawa, Masatoshi Suehiro, Kouichi Iwaisako, Hideo Akiyama
  • Patent number: 5972539
    Abstract: A flame retardant solid electrolyte comprising an ion conductive polymer matrix having moieties capable of imparting flame retardance to the polymer matrix and ether bonds in the molecule and an electrolyte salt dispersed in the polymer matrix. The flame retardant solid electrolyte may be one which comprises a non-ion-conductive polymer matrix and a liquid electrolyte consisting of an electrolyte salt dissolved in a solvent therefor, which is dispersed in the polymer matrix. The flame retardance-imparting moieties are derived from halogen or phosphorus-bearing compounds.
    Type: Grant
    Filed: August 18, 1997
    Date of Patent: October 26, 1999
    Assignees: Denso Corporation, Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Jun Hasegawa, Hiromochi Muramatsu, Hirohiko Saito, Michiyuki Kono, Hirohito Komori
  • Patent number: 5930949
    Abstract: The germination of seeds is improved by treating the seeds with a solid-form super absorbent polymer that has absorbed water. Super absorbent polymer particles that contain an amount of water such as about 5 to 7 times their weight that is significantly less than the amount of water they are able to absorb such as about 80-120 times their weight and do not substantially adhere to each other are mixed with seeds to form a mixture that may contain a volume ratio of seeds to polymer particles of 0.2 to 5:1. The mixture is stirred while supplying air or gaseous oxygen into the mixture for a time and at a temperature sufficient to cause the seeds to imbibe sufficient water to enhance their vigor for sprouting, but insufficient to cause sprouting. The mixture is sieved to obtain seeds having essentially no adhering polymer residue of the particles, after which the seeds may be dried. The polymer particles may be spherical, and before absorbing water have a size of 50 to 300 .mu.m.
    Type: Grant
    Filed: September 29, 1997
    Date of Patent: August 3, 1999
    Assignees: Takii Shubyo Kabushiki Kaisha, T.S. Plant Science Institute Co. Ltd., Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Takeo Tsujimoto, Hiroshi Sato, Shinya Matsushita
  • Patent number: 5918413
    Abstract: The present invention is characterized by coating a seed with from 0.1 to 25% by weight of a powder (A) composed of one or both of montmorillonite and bentonite and having an average particle diameter of 30 .mu.m or less and from 99.9 to 75% by weight of a powder (B) composed of a material other than montmorillonite and bentonite and having an average particle diameter of at least 10 .mu.m and at most 30 .mu.m using a polyvinyl alcohol aqueous solution having an aqueous solution viscosity at 25.degree. C. of 50 mPa.multidot.s or less as a binder. Consequently, a coated seed obtained by coating a seed, especially a light-favoured seed, easily absorbs water in sowing and is easily cracked in absorbing water. Further, the easy cracking thereof remains unchanged with the course of time. In the coating, formation of by-product seedless spherical pellets is little observed.
    Type: Grant
    Filed: June 9, 1998
    Date of Patent: July 6, 1999
    Assignees: Dai-Ichi Kogyo Seiyaku Co., Ltd., Takii Shubyo Kabushiki Kaisha
    Inventors: Takamitsu Otani, Hiroyuki Nakata, Toshikazu Akao, Yoshihiro Maeda
  • Patent number: 5917693
    Abstract: The electrically conductive polymer composition of this invention comprises (A) a polyaniline, (B) at least one member selected from the class consisting of homopolymers, block copolymers and random copolymers of alkylene oxide monomers and crosslinking products thereof, and (C) at least one member selected from the class consisting of protonic acid anions, electron acceptors, alkali metal salts and alkaline earth metal salts. This composition affords a choice of electronic conductance or ionic conductance, or both, according to the intended application. Furthermore, since it is highly processable and flexible, the composition finds application in a variety of uses.
    Type: Grant
    Filed: October 14, 1997
    Date of Patent: June 29, 1999
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Michiyuki Kono, Shigeo Mori