Patents Assigned to Enichem Synthesis S.p.A
  • Patent number: 6642172
    Abstract: A catalyst in the form of extruded bodies is disclosed, which consists of an inert binding agent and a catalytically active phase of a silica/alumina gel. The catalyst is particularly active in acid-catalysed reactions.
    Type: Grant
    Filed: January 25, 1995
    Date of Patent: November 4, 2003
    Assignees: Eniricerche S.p.A., Agip Petroli S.p.A., Enichem Synthesis S.p.A.
    Inventors: Carlo Perego, Gianluca Bassi, Gianni Girotti
  • Patent number: 6180011
    Abstract: A method for removing hydrocarbon products from water surfaces, which entails contacting the hydrocarbon products with a crystalline polypropylene, which when observed under a microscope of 2500 magnetization, exhibits a spongy surface having relatively homogeneous intercommunicating pores, with dimensions of between about 3 &mgr;m and 20 &mgr;m in diameter.
    Type: Grant
    Filed: June 16, 1997
    Date of Patent: January 30, 2001
    Assignee: Enichem Synthesis S.p.A
    Inventors: Carlo Neri, Silvestro Costanzi, Franco Groppelli
  • Patent number: 6084143
    Abstract: A catalytic composition is described for the alkylation or transalkylation of aromatic compounds consisting of zeolite Beta, as such or modified by the isomorphic substitution of aluminium with boron, iron or gallium or by the introduction of alkaline/earth-alkaline metals following ion exchange processes, and of an inorganic ligand, wherein the extrazeolite porosity, i.e. the porosity obtained by adding the mesoporosity and macroporosity fractions present in the catalytic composition itself, is such as to be composed for a fraction of at least 25% of pores with a radius higher than 100 .ANG..
    Type: Grant
    Filed: July 15, 1998
    Date of Patent: July 4, 2000
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Gianni Girotti, Oscar Cappellazzo
  • Patent number: 5888466
    Abstract: An amorphous, micro/mesoporous silica-alumina gel with controlled pore size, having a surface area of at least 500 m.sup.2 /g and with a molar ratio of SiO.sub.2 :Al.sub.2 O.sub.3 of at least 30:1, is prepared by hydrolysing and causing a tetra-alkyl ammonium hydroxide, an aluminum trialkoxide, and a tetra-alkyl orthosilicate to gelate, by operating at a temperature equal to, or higher than, the boiling temperature, under atmospheric pressure, of any alcohols which are developed as a by-product from said hydrolysis reaction, without said alcohols being removed, or being substantially removed, from the reaction media; and the so produced gel being dried and fired.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: March 30, 1999
    Assignees: Eniricerche S.p.A., Agip Petroli S.p.A., Enichem Synthesis S.p.A.
    Inventors: Carlo Perego, Stefano Peratello, Roberto Millini
  • Patent number: 5888471
    Abstract: A synthetic, crystalline, porous material is disclosed, together with the related preparation process. Such material of zeolitic nature containing oxides of silicon, titanium and gallium corresponds, in the calcined and anhydrous state, to the following empyrical formula:pHGaO.sub.2.qTiO.sub.2.SiO.sub.2,wherein p has a value greater than zero and smaller than or equal to 0.050, and q has a value greater than zero and smaller than or equal to 0.025, and the H.sup.+ of HGaO.sub.2 can be at least partially replaceable or replaced by cations.
    Type: Grant
    Filed: October 28, 1996
    Date of Patent: March 30, 1999
    Assignees: Eniricerche S.p.A., Enichem Synthesis S.p.A., Snamprogetti
    Inventors: Giuseppe Bellussi, Mario Gabriele Clerici, Angela Carati, Antonio Esposito
  • Patent number: 5811612
    Abstract: A catalytic composition is described for the alkylation or transalkylation of aromatic compounds consisting of zeolite Beta, as such or modified by the isomorphic substitution of aluminium with boron, iron or gallium or by the introduction of alkaline/earth-alkaline metals following ion exchange processes, and of an inorganic ligand, wherein the extrazeolite porosity, i.e. the porosity obtained by adding the mesoporosity and macroporosity fractions present in the catalytic composition itself, is such as to be composed for a fraction of at least 25% of pores with a radius higher than 100 .ANG..
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 22, 1998
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Gianni Girotti, Oscar Cappellazzo
  • Patent number: 5730908
    Abstract: A description follows of photochromatic and thermochromatic compounds, belonging to the group of spiro-indoline-oxazines, and their application in polymeric materials.
    Type: Grant
    Filed: March 24, 1994
    Date of Patent: March 24, 1998
    Assignee: Enichem Synthesis S.P.A.
    Inventors: Nereo Nodari, Pietro Allegrini, Luciana Crisci
  • Patent number: 5685957
    Abstract: Acidic and salt impurities are removed from a condensed phase obtained from dimethyl carbonate synthesis by obtaining the condensed phase from the effluent of a reactor in which carbon monoxide, oxygen and methanol are reacted to form dimethyl carbonate, the condensed phase containing acid and salt impurities, and partially evaporating the condensed phase in an evaporator thereby preparing an evaporated stream substantially free of impurities and a residual bottom stream.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: November 11, 1997
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Franco Rivetti, Daniele Delledonne
  • Patent number: 5686644
    Abstract: Dialkyl carbonate is prepared by reacting an alcohol with a gaseous mixture of carbon monoxide and oxygen in the presence of cuprous chloride as catalyst and hydrochloric acid as in situ regenerator of the catalyst.
    Type: Grant
    Filed: April 21, 1994
    Date of Patent: November 11, 1997
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Franco Rivetti, Ugo Romano
  • Patent number: 5672799
    Abstract: Process for the preparation of cumene by the alkylation of benzene with propylene, catalyzed by zeolite Beta into which certain quantities of suitable alkaline, alkaline-earth or metallic cations have been introduced by ion exchange.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: September 30, 1997
    Assignees: Eniricerche S.p.A., Enichem Synthesis S.p.A.
    Inventors: Carlo Perego, Giannino Pazzuconi, Gianni Girotti, Giuseppe Terzoni
  • Patent number: 5631395
    Abstract: Method for removing the acidic impurities contained in a vaporized stream consisting of an alkanol, an alkyl carbonate, water and still other organic species in minor amounts, which method consists in sending said stream to a solid adsorption reactor comprising alumina or activated charcoal.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: May 20, 1997
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Franco Rivetti, Daniele Delledonne
  • Patent number: 5625108
    Abstract: An amorphous, micro/mesoporous silica-alumina gel with controlled pore size, having a surface area of at least 500 m.sup.2 /g and with a molar ratio of SiO.sub.2 :Al.sub.2 O.sub.3 of at least 30:1, is prepared by hydrolysing and causing a tetra-alkyl ammonium hydroxide, an aluminum trialkoxide, and a tetra-alkyl orthosilicate to gelate, by operating at a temperature equal to, or higher than, the boiling temperature, under atmospheric pressure, of any alcohols which are developed as a by-product from said hydrolysis reaction, without said alcohols being removed, or being substantially removed, from the reaction media; and the so produced gel being dried and fired. So obtained gel is an active catalyst in hydrocarbon conversion reactions, in particular in light olefin isomerization and oligomerization processes, e.g., in propylene oligomerization processes to yield useful liquid hydrocarbons for gasoline and jet fuel formulation.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: April 29, 1997
    Assignees: Eniricerche S.p.A., AGIP Petroli S.p.A., Enichem Synthesis S.p.A.
    Inventors: Carlo Perego, Stefano Peratello, Roberto Millini
  • Patent number: 5602212
    Abstract: A linear copolyester is prepared by polycondensation of an aromatic bicarboxylic acid with an alkylene glycol and with a carboxyphosphinic acid or anhydride which produces monomeric units having the formula: ##STR1## wherein R.sub.1 is an alkylene or phenyl radical and R.sub.2 is an alkyl or phenyl radical.This copolyester can be used as a flame-retardant additive for organic polymers.
    Type: Grant
    Filed: May 28, 1996
    Date of Patent: February 11, 1997
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Gianluigi Landoni
  • Patent number: 5599876
    Abstract: A polymerizable liquid composition includesa polymerizable poly(allyl carbonate) of an aliphatic or cyclo-aliphatic polyol;an organic peroxide generator of free radicals selected from the group of perketals, and possiblyan organic dye and/or an organic photochromic compound.The compositions can be transformed, by bulk polymerization, into an organic glass which is colorless, or colored or photochromic, having good optical and mechanical characteristics.
    Type: Grant
    Filed: October 27, 1993
    Date of Patent: February 4, 1997
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Fiorenzo Renzi, Claudio Gagliardi, Franco Rivetti, Pietro Allegrini
  • Patent number: 5580916
    Abstract: A description follows of vulcanizable compositions of nitrile rubbers containing a plasticizer, a vulcanizing agent and normal additives, wherein the plasticizer is an organic carbonate selected from those which can be defined with the formula (I): ##STR1## or with the formula (II): ##STR2## wherein R, R.sup.1, R.sup.2, X and n are as defined in the description.
    Type: Grant
    Filed: March 9, 1994
    Date of Patent: December 3, 1996
    Assignee: Enichem, Synthesis S.p.A.
    Inventors: Enrico Traverso, Franco Rivetti, Lucio Spelta
  • Patent number: 5550207
    Abstract: A linear copolyester is prepared by polycondensation of an aromatic bicarboxylic acid with an alkylene glycol and with a carboxyphosphinic acid or anhydride which produces monomeric units having the formula: ##STR1## wherein R.sub.1 is an alkylene or phenyl radical and R.sub.2 is an alkyl or phenyl radical. This copolyester can be used as a flame-retardant additive for organic polymers.
    Type: Grant
    Filed: May 23, 1994
    Date of Patent: August 27, 1996
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Gianluigi Landoni
  • Patent number: 5536864
    Abstract: The reaction between methanol, carbon monoxide and oxygen for preparing dimethyl carbonate, in the presence of cuprous chloride as the catalyst, is carried out in a special reactor constituted by two parallel, vertical tubes, at the base of one of which the fresh gas and the recycle gas are fed; the reaction products are separated by partially condensing the recirculate vapors.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: July 16, 1996
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Giancarlo Paret, Gianni Donati, Maurizio Ghirardini
  • Patent number: 5527943
    Abstract: A method is described enabling HCl and possible entrained CuCl particulate to be removed from a gas-vapor stream leaving a dimethylcarbonate synthesis reactor. The contaminant removal is effected by one of the process fluids used in a small quantity.
    Type: Grant
    Filed: July 8, 1994
    Date of Patent: June 18, 1996
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Franco Rivetti, Ugo Romano, Guido Garone, Maurizio Ghirardini
  • Patent number: 5514254
    Abstract: An alkyl-aromatic compound is selectively photochlorinated in the side chain in a cyclic reaction system wherein said compound is continuously circulated between a container and photochlorination reactor.The compound is partially chlorinated after each passage through the photochlorination reactor, the number of passages depending on the degree of chlorination required.The procedure is particularly useful for the preparation of benzyl chloride, benzal chloride and benzotrichloride, and the corresponding halogen-substituted derivatives of the nucleus.
    Type: Grant
    Filed: February 18, 1994
    Date of Patent: May 7, 1996
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Ribaldo, Giuseppe Contardi, Vittorio Messori
  • Patent number: 5505869
    Abstract: A carbonate ester of an aliphatic triol or tetraol which can be defined with the following formula: ##STR1## wherein R.sub.1, R.sub.2, R' and p are as defined in the description, is used as a lubricating base with a low quantity of smoke for two-phase engines with internal combustion.Lubricating compositions are described which contain a carbonate ester (1) together with one or more products selected from solvents, bright stock, or other anti-seizing additives, plus normal additives.
    Type: Grant
    Filed: July 18, 1994
    Date of Patent: April 9, 1996
    Assignees: Euron S.p.A., Enichem Synthesis S.p.A.
    Inventors: Franco Berti, Franco Rivetti, Ugo Romano, Umberto Sgambato