Patents Assigned to Enichem Synthesis S.p.A
  • Patent number: 5498811
    Abstract: Polymeric fuels are produced from saturated C.sub.4 hydrocarbons by a process comprising:(A) dehydroisomerizing a gas mixture comprising predominantly of n-butane and hydrogen in a catalytic reactor containing a catalyst (a) of platinum supported on alumina, whose surface is coated with silica, and, optionally, a solid acidic catalyst (b) selected from the group consisting of alumina, whose surface is coated with silica, and Boralite B, with an effluent being obtained which comprises a mixture of predominantly of unreacted n-butane, butenes and isobutene, all of which components of the mixture have a carbon atom content less than 5;(B) separating the mixture of olefins and parafins from hydrogen and aromatic byproducts; and(C) oligomerizing said mixture in the presence of a catalyst consisting of amorphous silica-alumina gel, as determined by X-rays, having a silica:alumina molar ratio within the range of 30:1 to 500:1, with a surface area of from 500 to 1000 m.sup.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: March 12, 1996
    Assignees: Eniricerche S.p.A., Enichem Synthesis S.p.A.
    Inventors: Carlo Perego, Stefano Peratelo
  • Patent number: 5489316
    Abstract: Process for marking industrial organic solvents miscible with water and petroleum products gaseous at atmospheric pressure and room temperature and liquid when compressed at low pressure, by the addition to the above solvents of a primary nitroderivative having the general formulaR-CH.sub.2 -NO.sub.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: February 6, 1996
    Assignee: Enichem Synthesis S.p.A.
    Inventor: Enrico Traverso
  • Patent number: 5462984
    Abstract: Solid stabilizers for polymers comprises a blend of (a) organic polymer and (b) at least one silicon-containing compound having a sterically hindered amine group in the molecule in quantities of between 40% and 50% by weight of the final solid blend.
    Type: Grant
    Filed: February 24, 1995
    Date of Patent: October 31, 1995
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Silvestro Costanzi, Mariangela Angaroni
  • Patent number: 5457037
    Abstract: The structural gene encoding isoamylase from Pseudomonas SMP 1 is obtained. Also described are vectors comprising the isoamylase gene and host microorganisms transformed by these vectors. The transformed host microorganisms are capable of expressing and/or secreting mature isoamylase having biological activity.
    Type: Grant
    Filed: January 8, 1993
    Date of Patent: October 10, 1995
    Assignee: Enichem Synthesis, S.p.A.
    Inventors: Angelo Tognoni, Paolo Carrera, Barbara Camerini, Giuliano Galli, Giuseppe Lucchese, Guido Grandi, Carlo Di Gennaro
  • Patent number: 5457213
    Abstract: Catalytic procedure for the preparation of an organic carbonate having general formula (I): ##STR1## wherein R represents a C.sub.1 -C.sub.10 alkyl radical, linear or branched, or a C.sub.5 -C.sub.8 cycloalkyl radical; or of a cyclic organic carbonate having general formula (II): ##STR2## wherein R' represents a C.sub.2 -C.sub.5 alkylene radical, linear or branched; including the reacting of an aliphatic or cyclo-aliphatic alcohol having general formula (III):R--OH (III)or an aliphatic diol having general formula (IV):HO--R'--OH (IV)wherein R and R' have the meaning described above, with carbon monoxide and oxygen, in the presence of a catalyst composed of a cobalt(II) or cobalt(III) ion and an organic binder containing at least one oxygen atom, characterized in that the process is carried out in the presence of at least one reaction coadjuvant selected from the following groups of linear or cyclic compounds: ureas, nitriles, amides, phosphoramides, sulphones, sulphoxides, carbamates.
    Type: Grant
    Filed: June 8, 1993
    Date of Patent: October 10, 1995
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Daniele Delledonne, Franco Rivetti, Ugo Romano
  • Patent number: 5447991
    Abstract: Polyolefinic fibres and films are made flame-resistant by the addition of a flame-resistant additive made up of a copolyester containing units deriving from: a) terephthalic acid; b) alkylenic glycol (C.sub.2 --C.sub.6) ; and c) phenyl hydroxymethylene phosphinic acid.These fibres and films are prepared by the transformation into its molten state of a mixture of polyolefin and flame-resistant additive.
    Type: Grant
    Filed: May 12, 1994
    Date of Patent: September 5, 1995
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Gianluigi Landoni, Carlo Neri
  • Patent number: 5423994
    Abstract: Compounds which can be defined by the formula (I):CF.sub.3 --C.sub.n F.sub.2n --C.sub.m H.sub.2m --CH.sub.3 (I)wherein:n is a numeral comprised within the range of from 1 to 21;m is a numeral comprised within the range of from 3 to 25;n+m is a numeral equal to, or higher than, 18;with the chain of carbon atoms being either linear or branchedare used as agents affording sliding characteristics (ski-waxes) for skis, to be applied onto the ski sole, and/or to be incorporated inside the ski sole.A sliding composition is also disclosed, which contains a paraffinic wax and at least one compound with formula (I).
    Type: Grant
    Filed: March 26, 1993
    Date of Patent: June 13, 1995
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Enrico Traverso, Antonio Rinaldi
  • Patent number: 5395949
    Abstract: Organic carbonates and cyclic organic carbonates are prepared by reacting an aliphatic or cycloaliphatic alcohol, or, respectively, an aliphatic diol, with carbon monoxide and oxygen, by operating in the presence of a complex catalyst of cobalt with organic ligands bearing one or more oxygen functional groups, as electron donors.
    Type: Grant
    Filed: January 8, 1993
    Date of Patent: March 7, 1995
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Daniele Delledonne, Franco Rivetti, Ugo Romano
  • Patent number: 5350786
    Abstract: Stabilizers for organic polymers, consisting of one or more compounds of the classis of the sterically hindered amines (HALS) are directly added to the reaction mixture during the (co)polymerization of the .alpha.-olefins or of their mixtures with other unsaturated monomers.The so-obtained polymeric compositions result perfectly stabilized and show a thermo- and photo-oxidative resistance higher than that of the same polymeric compositions to which the same stabilizers are added by a traditional route.
    Type: Grant
    Filed: March 4, 1993
    Date of Patent: September 27, 1994
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Silvestro Costanzi, Damiano Gussoni, Luciano Pallini
  • Patent number: 5338787
    Abstract: A new group of pentaerythryl diphosphonates and poly(pentaerythryl diphosphonates) are described. Flame-retardant compositions are also described, which include a thermoplastic polymer and a certain amount of self-extinguishing agent consisting of one of the above-mentioned pentaerythryl diphosphonates or poly(pentaerythryl diphosphonates).
    Type: Grant
    Filed: November 9, 1993
    Date of Patent: August 16, 1994
    Assignee: Enichem Synthesis, S.p.A.
    Inventors: William Giroldini, Gianluigi Landoni, Antonio Rinaldi, Carlo Neri
  • Patent number: 5322958
    Abstract: Catalytic procedure in gas phase for the preparation of a symmetrical or asymmetrical organic carbonate having the general formula (I): ##STR1## wherein R and R', the same or different, represent a C.sub.1 -C.sub.4 alkyl radical, linear or branched, which includes reacting at least one alcohol having the general formula (II):R--OH or R'--OHwith carbon monoxide and oxygen in the presence of a catalyst composed of oxides, salts or complexes of cobalt.
    Type: Grant
    Filed: February 22, 1993
    Date of Patent: June 21, 1994
    Assignee: Enichem Synthesis, S.p.A.
    Inventors: Daniele Dreoni, Franco Rivetti, Daniele Delledonne
  • Patent number: 5315034
    Abstract: Multistep process for the preparation of alkyl mono and diisocyanates consisting in reacting the corresponding aliphatic amine or diamine with dimethylcarbonate and, substantially, in partially vaporizing and converting the urethane thus formed in an evaporator to subsequently terminate the cracking in a II.degree. reactor, and finally subjecting the cracking product to fractional distillation at reduced pressure, recycling the unconverted part to the partial vaporization step.
    Type: Grant
    Filed: May 11, 1993
    Date of Patent: May 24, 1994
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Franco Mizia, Franco Rivetti, Ugo Romano
  • Patent number: 5310841
    Abstract: A liquid composition, polymerizable by free-radical polymerization to yield organic glasses which are endowed with characteristics of low water absorption and high thermal stability, is constituted by the product of transesterification of diallyl-carbonate with a cycloaliphatic diol or a mixture of cycloaliphatic diols, from among said diols 1,4-cyclohexane-di-methanol and 3(4),8(9)-bis-(hydroxymethyl)tricyclo[5.2.1.0.sup.2.6 ]decane being preferred.
    Type: Grant
    Filed: September 26, 1990
    Date of Patent: May 10, 1994
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Fiorenzo Renzi, Franco Rivetti, Ugo Romano
  • Patent number: 5302735
    Abstract: Polysiloxanic compounds, containing sterically hindered phenol groups and oxamidic groups in the molecule, obtained by the copolymerization of monomers having general formula (I):(R.sup.1).sub.n (R.sup.2).sub.3-n Si--R.sup.
    Type: Grant
    Filed: April 21, 1993
    Date of Patent: April 12, 1994
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Daniele Fabbri, Luciano Pallini
  • Patent number: 5296521
    Abstract: The present invention relates to fast-crystallizing polyester compositions comprising: (a) a thermoplastic polyester resin; (b) a nucleating agent of the formula: ##STR1## wherein: R is an alkali or alkaline-earth metal; m is 1, 2 or 3; n takes an average value within the range of 1 to 5; said nucleating agent being optionally admixed with the compound of formula (I) wherein R is a hydrogen atom, linear alkyl radial or branched alkyl radical each having from 1 to 6 carbon atoms; with the proviso that at least 50% mole of said nucleating agent is in the salt form. This nucleating additive raises the crystallization temperature upon cooling (T.sub.cc) of the polyester so that crystallization occurs rapidly during molding.
    Type: Grant
    Filed: June 3, 1993
    Date of Patent: March 22, 1994
    Assignees: Istituto Guido Donegani S.P.A., Enichem Synthesis S.P.A.
    Inventors: John W. Gilmer, Gianluigi Landoni
  • Patent number: 5290533
    Abstract: A crystalline, porous, synthetic material is disclosed, together with its related preparation process.Such a material of zeolitic character, containing silicon, titanium and iron oxides, corresponds, in its calcined and anhydrous state, to the following empi rical formulapHFeO.sub.2.qTiO.sub.2.SiO.sub.2wherein p has a value greater than zero and lower than or equal to 0.050, q has a value greater than zero and lower than or equal to 0.025, and the H.sup.+ of HFeO.sub.2 can be at least partly replaceable or replaced by cations.
    Type: Grant
    Filed: August 16, 1991
    Date of Patent: March 1, 1994
    Assignees: Eniricerche S.p.A., Enichem Synthesis S.p.A., Snamprogetti S.p.A.
    Inventors: Giuseppe Bellussi, Mario G. Clerici, Aldo Giusti, Franco Buonomo
  • Patent number: 5288869
    Abstract: A new group of pentaerythryl diphosphonates and poly(pentaerythryl diphosphonates) are described. Flame-retardant compositions are also described, which include a thermoplastic polymer and a certain amount of self-extinguishing agent consisting of one of the above-mentioned pentaerythryl diphosphonates or poly(pentaerythryl diphosphonates).
    Type: Grant
    Filed: August 6, 1992
    Date of Patent: February 22, 1994
    Assignee: Enichem Synthesis S.p.A.
    Inventors: William Giroldini, Gianluigi Landoni, Antonio Rinaldi, Carlo Neri
  • Patent number: 5288839
    Abstract: Diol-polycarbonates having the general formulaHO--(Ri--O--CO--O).sub.x ----(R.sub.2 --O--CO--O--).sub.y --R.sub.3 --OH (I)where R.sub.1, R.sub.2, R.sub.3, X and Y have the meaning specified in the text, are used in the synthesis of prepolymers which in turn can be used in reactive adhesive and/or sealing formulations of the hygro-, photo- or thermosetting type, and the procedure for their preparation. The sealing compositions deriving from these diolterminated-polycarbonates are mainly used in transport industry, in the textile and wood industry, for cellular products and in the bookbinding industry.
    Type: Grant
    Filed: September 15, 1992
    Date of Patent: February 22, 1994
    Assignee: Enichem Synthesis S.p.A.
    Inventor: Alberto Greco
  • Patent number: 5286816
    Abstract: An organic glass with improved impact strength and with a refractive index equal or similar to that of mineral glass (crown glass), is composed of the product of the radicalic polymerization of the polymerizable liquid composition obtained by the transesterification of:(A) diallyl carbonate with a mixture of polyols:(B) bis(2-hydroxyethylether) of bisphenol-A,(C) diethylene glycol, and(D) tris(hydroxyethyl) isocyanurate,where for every 100 parts b.w. of the sum of polyols (B), (C) and (D), polyol (B) is present in a quantity of from 20 to 60% b.w., polyol (C) is present in a quantity of from 20 to 60% b.w. and polyol (D) is present in a quantity of from 10 to 40% b.w.; and where the molar ratio between the diallyl carbonate and the sum of polyols (A)/(B)+(C)+(D) is equal to or higher than 3/1.
    Type: Grant
    Filed: April 20, 1993
    Date of Patent: February 15, 1994
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Franco Rivetti, Fiorenzo Renzi, Claudio Gagliardi
  • Patent number: 5280051
    Abstract: Artificial marble or granite having excellent aesthetic properties, patterns and tonalities which cannot be found in natural materials are prepared from a composition containing a polymerizable poly(allyl carbonate) of a polyol and mineral filler, where the mineral filler is a carbonate type in the case of marble, and silicate or silica type in the case of granite, and is in the form of particles of which at least 40% to 100% by weight have a particle size greater than 0.5 mm. The artificial marble and granite produced by the process of the invention require a limited quantity of polymerizable poly(allyl carbonate) binder, have excellent aesthetic properties and high aging resistance, making them suitable for external use.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: January 18, 1994
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Enrico Traverso, Fiorenzo Renzi