Patents Assigned to Enichem Synthesis S.p.A
  • Patent number: 5010202
    Abstract: Novel silicon-organic compounds containing an oxazolidine group are defined by the general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, X, n and y have the meanings reported in the description. These compounds are capable of co-cross-linking and to act as adhesion promoters on various polar substrates, in compositions based on poly-isocyanates, polyepoxides or polacrylates, in the field of sealants and adhesives.
    Type: Grant
    Filed: May 11, 1990
    Date of Patent: April 23, 1991
    Assignee: Enichem Synthesis S.p.A.
    Inventor: Alberto Greco
  • Patent number: 4996283
    Abstract: A reactive hot melt composition comprises the products of the reaction between (A) an aliphatic or aromatic diisocyanate and (B) a mixture containing: (1) a crystalline polycarbonate diol, (2) an elastomeric polycarbonate diol or an elastomeric polycarbonate copolyester diol, and possibly (3) a vitreous polycarbonate diol or a vitreous polycarbonate copolyester diol. The process for preparing the reactive hot melt composition is also described .
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: February 26, 1991
    Assignees: Enichem Synthesis S.p.A., Boston S.p.A.
    Inventors: Alberto Greco, Sergio Giordano, Enrico Pozzi, Patrizia Blasioli
  • Patent number: 4990578
    Abstract: Polyol-polycarbonates having a molecular weight comprising within the range from 750 to 2500, endowed with good rheologic characteristics and having a low glass transition temperature (Tg), are obtained by means of the reaction, under transesterification conditions, of(a) an organic carbonate;(b) a saturated alifatic .alpha.,.omega.-glycol; and(c) tris-(hydroxyethyl)-isocyanurate.These polyol-polycarbonates are useful as bases for paints in combination with polyisocyanates.Furthermore, the polyol-polycarbonates can be reacted with bicarboxy acids, or with cyclic anhydrides in order to yield the corresponding products with carboxy end groups which are useful as bases for paints in combination with melaminic or epoxy resins.
    Type: Grant
    Filed: June 19, 1989
    Date of Patent: February 5, 1991
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Alberto Greco, Gabriele Lugli
  • Patent number: 4985481
    Abstract: A solid stabilizer composition for synthetic polymers is formed by a solid, continuous phase and by a solid dispersed phase in said continuous phase, wherein the continuous phase is constituted by amorphous 2,2'-oxamido-bis[ethyl-3-(3,5-di-tert.-butyl-4-hydroxyphenyl)-propionate] and the dispersed phase is constituted by an amorphous, or crystalline, or partially amorphous and partially crystalline organic phosphite, with the weight ratio of said continuous phase to said dispersed phase being comprised within the range of from 9:1 to 1:9.The process for preparing said solid composition and its use in the stabilization of synthetic polymers are disclosed.
    Type: Grant
    Filed: September 19, 1989
    Date of Patent: January 15, 1991
    Assignee: Enichem Synthesis, S.p.A.
    Inventors: Carlo Neri, Nereo Nodari, Giovanni Sandre
  • Patent number: 4981945
    Abstract: A linear copolyester, useful as a flame retardant agent, contains in its macromolecule units derived from:(a) terephthalic acid;(b) (C.sub.2 -C.sub.6)-alkylene glycol;(c) phenyl-hydroxymethylene phosphinic acid, in a mutual ratio comprised within the range of from 1:1:0.2 to 1:1:1, and is obtained by placing a linear polyester derived from terephthalic acid and a (C.sub.2 -C.sub.6)-alkylene glycol into contact with a poly(phenylhydroxymethylene phosphinate) (I): ##STR1## wherein: Ph is the phenyl radical;R is a hydrogen atom or a linear or branched alkyl radical containing from 1 to 8 carbon atoms; andD is from 2.5 to 100,under melting conditions, and for a contact time not longer than about 30 minutes.
    Type: Grant
    Filed: March 17, 1989
    Date of Patent: January 1, 1991
    Assignee: Enichem Synthesis, S.p.A.
    Inventors: Gianluigi Landoni, Carlo Neri
  • Patent number: 4957956
    Abstract: A solid stabilizer composition for organic polymers is formed by a solid, continuous phase and by a dispersed phase in said continuous phase, wherein the continuous phase is constituted by amorphous tetrakis-[3-(3,5-di-tert.-butyl-4-hydroxyphenyl)-propionyloxymethyl]-metha ne and the dispersed phase is constituted by an either amorphous or crystalline organic phosphite, in the form of particles with a particle size of from 10 .mu.m to 2 mm, with the weight ratio of said continuous phase to said dispersed phase being comprised within the range of from 9:1 to 1:9.The processes for preparing said solid stabilizer composition and its use in the stabilization of organic polymers are disclosed.
    Type: Grant
    Filed: February 11, 1988
    Date of Patent: September 18, 1990
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Nereo Nodari, Erik Bersanetti, Giovanni Sandre
  • Patent number: 4952619
    Abstract: Reactive stabilizing compounds, able to stabilize organic polymers, contain in their molecule a sterically hindered amino group and a hydrolyzable silyl function.In stabilizing organic polymers, said reactive stabilizing compounds can be hydrolyzed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilizing structures. These latter are added in stabilizing quantities to the polymer to the stabilized.According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilized.According to a further embodiment, the reactive stabilizing compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxyl groups.
    Type: Grant
    Filed: May 14, 1987
    Date of Patent: August 28, 1990
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Alberto Greco, Carlo Busetto, Luigi Cassar, Carlo Neri
  • Patent number: 4946880
    Abstract: Reactive stabilizer compounds, to be used in the stabilization of organic polymers, contain a sterically hindered, N-substituted piperidinic, morpholinic or pyrrolidinic group, and at least a hydrolysable silicic function.Such compounds give rise, by hydrolysis of the silicic function, to complex resinous structures endowed with stabilizing properties.The reactive stabilizer compounds can spontaneously hydrolyse inside the polymer, or they can be stably supported on a solid support, or they can be chemically linked to the polymeric chain to be stabilized.
    Type: Grant
    Filed: October 5, 1987
    Date of Patent: August 7, 1990
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Silvestro Costanzi, Damiano Gussoni, Omero Zavattini, deceased, by Clara Pungiluppi, heir, by Renato Zavattini, heir, Luciano Pallini
  • Patent number: 4943302
    Abstract: A fuel composition with a high energy content, for direct-ignition internal combustion engines contains a gasoline from petroleum and an amount of up to 90% by volume, as referred to the same fuel composition, of hydrocarbon "cubane" or of its alkyl-derivatives, to be defined by means of the formula: ##STR1## wherein R' and R" represent, independently from each other, a hydrogen atom or an alkyl radical containing from 1 to 3 carbon atoms.
    Type: Grant
    Filed: October 11, 1989
    Date of Patent: July 24, 1990
    Assignees: Enichem Synthesis S.p.A., AGIP Petroli S.p.A.
    Inventors: Philip Eaton, Nereo Nodari, Carlo Neri, Luigi Cassar, Fabio Monti, Fausto Alberici
  • Patent number: 4942215
    Abstract: A thermosetting liquid moulding composition comprising:(a) a polyepoxide containing at least two epoxide groups per molecule;(b) a tricarboxylic acid definable by the general formula: ##STR1## where: R.sup.1, R.sup.2 and R.sup.3 have the meaning given in the description; and(c) a diacarboxylic acid anhydride.This composition can be transformed by liquid moulding into manufactured articles particularly useful in the electrical sector.
    Type: Grant
    Filed: November 18, 1988
    Date of Patent: July 17, 1990
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Alberto Greco, Luigi Raisa
  • Patent number: 4942179
    Abstract: A single-phase, either isotropic or anisotropic formulation is disclosed, which contains perfluorinated oil and one or more surfactant(s), is useful as an excipient for cosmetic and dermatologic formulations and is characterized in that at least one surfactant is selected from those having the following general formula: ##STR1## wherein: R.sub.F is an F--(CF.sub.2 --CF.sub.2).sub.i -- group;X is a group selected from: ##STR2## --(CH.sub.2 --O).sub.K --; and --(CH.sub.2 --S).sub.K --; wherein R.sup.I is a (C.sub.1 -C.sub.4)-alkyl;Y is a group selected from: NH.sub.2 (R.sup.II).sub.2 and N(R.sup.II).sub.4 ; wherein R.sup.II is a hydrogen atom, or a group selected from --CH.sub.2 --CH.sub.2 --OH and (C.sub.1 -C.sub.4)-alkyl;i is an integer comprised within the range of from 3 to 8;i is zero or 1;K is 2.l;l is an integer comprised within the range of from 1 to 10;m is 1 or 2.Such composition is spontaneously formed when the components are simply placed into contact with one another.
    Type: Grant
    Filed: June 14, 1988
    Date of Patent: July 17, 1990
    Assignees: Eniricherche S.p.A., Enichem Synthesis S.p.A.
    Inventors: Enrico Borgarello, Filippo M. Carlini, Carlo Neri, Edoardo Platone
  • Patent number: 4935063
    Abstract: Stabilizing inorganic fillers or pigments having simultaneous reinforcing effect and stabilizing effect on organic polymers are obtained by a process comprising the following stages:(a) bringing the inorganic filler or pigment into contact with a solution, in an inert organic solvent, of a sterically hindered amine comprising one or more alkoxysilane groups in its molecule;(b) maintaining the obtained mixture at higher than ambient temperature (20.degree.-25.degree. C.) for a period of at least 0.5 hours;(c) removing the solvent, treating at a temperature of 120.degree.-200.degree. C. and recovering the stabilizing filler or pigment obtained.
    Type: Grant
    Filed: September 9, 1988
    Date of Patent: June 19, 1990
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Silvestro Costanzi, Omero Zavattini, deceased, Ugo Bersellini, Damiano Gussoni
  • Patent number: 4933504
    Abstract: Mono-ethers of hydroquinones of formula (I) ##STR1## wherein R represents alkyl, alkoxy-alkyl, cycloalkyl, aryl-alkyl, or cycloalkyl-alkyl, andR.sup.1 is hydrogen or alkyl, cycloalkyl, aryl-alkyl, or cycloalkyl-alkyl, are prepared by contacting the corresponding hydroquinones with the corresponding alcohols ROH, in the presence of a catalytic mixture consisting of(a) a strong acid(b) a halogen or a hydrohalic acid selected from HBr, HI, I.sub.2, and Br.sub.2, and(c) H.sub.2 O.sub.2 in a molar amount lower than that of the starting hydroquinone.
    Type: Grant
    Filed: November 25, 1988
    Date of Patent: June 12, 1990
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Mariano Correale, Pietro Panseri, Ugo Romano, Francesco Minisci
  • Patent number: 4898946
    Abstract: A process is described for the preparation of N-allyl-2,2,6,6-tetraalkyl-piperidine derivatives which involves reaction of the corresponding 2,2,6,6-tetraalkyl-piperidine with an allylic carbonate in the presence of palladium catalysts. The products which are thus obtained are useful as polymer stabilizers and chemical intermediates.
    Type: Grant
    Filed: June 3, 1987
    Date of Patent: February 6, 1990
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Silvestro Costanzi, Damiano Gussoni, Luciano Pallini
  • Patent number: 4810579
    Abstract: Solid organic phosphites in powder form, used to endow organic polymers with stability characteristics are made resistant to hydrolysis by treating said powder phosphites with a silane containing in its molecule at least two alkoxy groups and causing the silane to hydrolyze, and the formation and deposition of a siliconic polymer on the surface of powder particles to occur.
    Type: Grant
    Filed: February 11, 1988
    Date of Patent: March 7, 1989
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Nereo Nodari, Erik Bersanetti, Giovanni Sandre