Patents Assigned to Givaudan Corporation
  • Patent number: 5057158
    Abstract: The ethyl esters of .beta.- and .gamma.-campholenic acids and of .gamma.-campholenic acid in admixture with .alpha.-campholenic acid and the ethyl esters of the corresponding dihydro derivatives have organoleptic properties which make them useful for preparing fragrances and flavors.
    Type: Grant
    Filed: September 30, 1986
    Date of Patent: October 15, 1991
    Assignee: Givaudan Corporation
    Inventors: Martin Rohr, Cormack Flynn
  • Patent number: 5039702
    Abstract: Userful as antimicrobial agents in aqeuous systems are .alpha.-halo.beta.-(substituted)thioacrylonitriles of the formula ##STR1## wherein X represents Cl, Br or I and R represents a lower alkyl, aryl, aralkyl, heterocyclo, or a thiocarbonyl group. The configuration about the double bond may be E or Z or a mixture thereof. These compounds provide effective control of microbial growth. The derivatives of formula I are economically prepared from acrylonitrile via a three-step process involving (a) halogenation, (b) dehydrohalogenation and (c) nucleophilic-type displacement. Except for those compounds wherein X is bromo and R is methyl or phenyl, the compounds of formula I are not mentioned in the prior art.
    Type: Grant
    Filed: April 14, 1989
    Date of Patent: August 13, 1991
    Assignee: Givaudan Corporation
    Inventors: Alyce Brandman, Milton Manowitz, Albert I. Rachlin
  • Patent number: 5030467
    Abstract: The lower alkyl esters of .alpha.-campholenic acid and .alpha.-campholanic acid have organoleptic properties which make them useful for preparing fragrances and flavors.
    Type: Grant
    Filed: July 1, 1986
    Date of Patent: July 9, 1991
    Assignee: Givaudan Corporation
    Inventors: Martin Rohr, Cormack Flynn
  • Patent number: 5023232
    Abstract: Novel mixtures of bicylic ethers of the formulas ##STR1## wherein R represents an alkyl group of from one to four carbon atoms, said mixture having at least a 1.1:1 ratio of 1a to 1b, a process for their manufacture and their use as odorants are described.
    Type: Grant
    Filed: March 2, 1989
    Date of Patent: June 11, 1991
    Assignee: Givaudan Corporation
    Inventors: Georg Frater, Harald Schmidt
  • Patent number: 5015779
    Abstract: A method for the manufacture of the four geometric isomers of 4(2-butenylidene)-3,5,5-trimethyl-2-cyclohexen-1-one is provided. The process comprises pyrolyzing a compound of the formula ##STR1## wherein R represents lower-alkyl-oxycarbonyl, aryl-oxycarbonyl, or, preferably, lower-alkanoyl, benzoyl or substituted benzoyl.
    Type: Grant
    Filed: August 28, 1989
    Date of Patent: May 14, 1991
    Assignee: Givaudan Corporation
    Inventors: Daniel Helmlinger, Frank Kienzle, Erich Widmer
  • Patent number: 5011628
    Abstract: Substituted benzamidines and their hydrochloride salts are useful as ultraviolet light absorbers, the benzamidines having the formula ##STR1## wherein: A.sup.1 and A.sup.2 may be the same or different and represent --COOR.sup.1, --CONR.sup.1 R.sup.2, --C.tbd.N or --C.sub.6 H.sub.5 ;A.sup.3 represents --H, --OH, --OR, --Cl, --NO.sub.2, --C.tbd.N, --C.sub.6 H.sub.5, or an alkyl group of one to five carbon atoms;R.sup.1 and R.sup.2 may be the same or different and represent hydrogen or an alkyl group of one to ten carbon atoms; and,R represents an alkyl group of one to ten carbon atoms.
    Type: Grant
    Filed: April 11, 1989
    Date of Patent: April 30, 1991
    Assignee: Givaudan Corporation
    Inventors: Isaac D. Cohen, Joseph A. Virgilio
  • Patent number: 4966172
    Abstract: Flavor compositions and tobacco products containing 3,5,5,6,8,8-hexamethyl-1,2,3,4,5,6,7,8-octahydro-2-naphthalenone and methods for making same are disclosed.
    Type: Grant
    Filed: March 14, 1986
    Date of Patent: October 30, 1990
    Assignee: Givaudan Corporation
    Inventors: Jean-Pierre Bachmann, Mario Pesaro
  • Patent number: 4963179
    Abstract: The use of a novel system for preserving aqueous systems normally subject to spoilage is disclosed. The system comprises the incorporation of .beta.-bromo-.beta.-nitrostyrene onto a solid maltodextrin or corn syrup solid of low to intermediate dextrose equivalency.
    Type: Grant
    Filed: September 14, 1988
    Date of Patent: October 16, 1990
    Assignee: Givaudan Corporation
    Inventors: Kenneth L. Purzycki, Joseph A. Virgilio
  • Patent number: 4963193
    Abstract: Tobacco products, tobacco flavoring compositions, and methods for improving, modifying or enhancing the organoleptic properties of tobacco products, which comprise adding thereto an effective amount of an oxo-ionyl ester of the formula ##STR1## wherein: RCO represents an acyl group containing from one to eighteen carbon atoms,the dotted line in the side-chain represents an optional bond,one of the dotted lines in the ring represents an additional bond, and,Z represents an oxo group which is in the position .alpha. to the double bond in the ring,said amount being effective to modify the organoleptic properties of said tobacco product or composition.
    Type: Grant
    Filed: September 16, 1985
    Date of Patent: October 16, 1990
    Assignee: Givaudan Corporation
    Inventor: Roman Kaiser
  • Patent number: 4954150
    Abstract: A device for branching gas flows, more particularly in a gas chromatography plant, the device having: an inlet branch connected to the output of a separating column; and two outlet branches which extend from a junction to subsequent parts of the plant, characterised in that one outlet branch is connected by way of a shutoff valve to a device producing a pressure lower than the pressure in the other outlet branch.
    Type: Grant
    Filed: October 7, 1988
    Date of Patent: September 4, 1990
    Assignee: Givaudan Corporation
    Inventor: Franz Etzweiler
  • Patent number: 4948781
    Abstract: The invention is concerned with compounds of the formula: ##STR1## wherein: R represents an alkyl group of one to four carbons, an alkenyl group of two to four carbons or a 1-alkoxy-alkyl group of the formula ##STR2## R.sup.1,R.sup.2 and R.sup.3 may be the same or different and represent hydrogen, methyl or ethyl;R.sup.4 represents hydrogen, an alkyl group of from one to five carbon atoms, an alkenyl group of from two to four carbon atoms or an alkylidene group of from one to four carbon atoms;R.sup.5,R.sup.6 and R.sup.7 may be the same or different and represent hydrogen, methyl or ethyl with the proviso that the sum R.sup.5 +R.sup.6 +R.sup.7 does not exceed two carbon atoms; andR.sup.8 represents methyl or ethyl;with the proviso that at least two, but not more than three of the symbols R.sup.1,R.sup.2,R.sup.3 and R.sup.4 represent hydrogen.This invention is also concerned with odorant and flavoring compositions containing these compounds.
    Type: Grant
    Filed: January 26, 1983
    Date of Patent: August 14, 1990
    Assignee: Givaudan Corporation
    Inventors: Roman Kaiser, Dietmar Lamparsky
  • Patent number: 4947002
    Abstract: Novel compounds of the formula ##STR1## wherein: the symbols R.sup.1, R.sup.2, R.sup.4, R.sup.5 and R.sup.6 represent hydrogen or methyl, with the proviso that only one of R.sup.1, R.sup.2 and R.sup.4 represents methyl, and, when either or both R.sup.5 and R.sup.6 represent methyl, then R.sup.1, R.sup.2 and R.sup.4 represent hydrogen; and,either the symbol (.dbd.O) on the carbon designated by the number 1 or the symbol (.dbd.O) on the carbon designated by the number 3, represents a keto group, such that when the group is present on carbon 1, then carbon 3 may contain a methyl group.and their use as odorants are described.
    Type: Grant
    Filed: November 2, 1988
    Date of Patent: August 7, 1990
    Assignee: Givaudan Corporation
    Inventors: Georg Frater, Urs Muller
  • Patent number: 4913350
    Abstract: An air freshening device which allows a liquid fragrance material to be dispensed into the ambient air of a room or other designated area in a linear fashion, i.e., without distortion of the odor character and without a change in the rate of delivery. More particularly, the device comprices a reservoir, a fragrance material, and an external capillary member, wherein said external capillary member has one or more external capillary cavities, the lower portion of said capillary being in contact with the liquid fragrance material to be dispensed, and the upper portion of said capillary being exposed to the air in the room or area into which it is desired to dispense the fragrance.
    Type: Grant
    Filed: March 18, 1988
    Date of Patent: April 3, 1990
    Assignee: Givaudan Corporation
    Inventor: Kenneth L. Purzycki
  • Patent number: 4910346
    Abstract: The novel odorants, 3-(3-propan-2-ylphenyl)butanal and 3-(3-propen-2-ylphenyl)butanal, are disclosed.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: March 20, 1990
    Assignee: Givaudan Corporation
    Inventor: Alan J. Chalk
  • Patent number: 4908349
    Abstract: Novel odorants of the formula ##STR1## namely, 1,1,2,4,4-pentamethyl-6-formyl-1,2,3,4-tetrahydronaphthalene (1a) and 1,1,2,4,4-pentamethyl-7-formyl-1,2,3,4-tetrahydronaphthalene (1b), possess powerful, very natural-warm, musk-like odor notes.
    Type: Grant
    Filed: July 14, 1988
    Date of Patent: March 13, 1990
    Assignee: Givaudan Corporation
    Inventor: Hans-Ulrich Gonzenbach
  • Patent number: 4892966
    Abstract: The invention is concerned with a novel process for the manufacture of compounds of the formula ##STR1## wherein R.sup.1 signifies C.sub.1-5 -alkyl, especially methyl, ethyl, propyl or isopropyl, and the radicals R.sup.2 each independently represent hydrogen or C.sub.1-5 -alkyl, especially hydrogen or methyl, ethyl, propyl or isopropyl.The process is characterized in that a compound of the formula ##STR2## wherein R stands for C.sub.1-4 -alkoxy, chlorine, bromine or C.sub.1-4 -alkanoyloxy, R.sup.1 and R.sup.2 have the above significance and R.sup.3 represents C.sub.1-4 -alkyl.is hydrolyzed and subjected to an aldol condensation and, where R=C.sub.1-4 -alkoxy, the reaction product is subsequently subjected to an acid treatment.The compounds I are for the most part known flavoring substances.
    Type: Grant
    Filed: July 16, 1987
    Date of Patent: January 9, 1990
    Assignee: Givaudan Corporation
    Inventor: Hans J. Wild
  • Patent number: 4878615
    Abstract: Method and apparatus for the evaporation of a solution into the ambient air. The apparatus contains a reservoir having at least one elastic wall; a first compartment outside the reservoir having an opening to the ambient air; a passage which may be intermittently opened and closed, connecting the reservoir to the first compartment; and, an absorbent material placed on a support which is outside both the reservoir and the first compartment, and which is in contact with the first compartment. By exerting pressure on the elastic wall of the reservoir, solution may be transferred from the reservoir to the first compartment through the passage when it is open. The passage is kept closed during the time intervals between intermittent transfers of the solution. The portion of solution which has been transferred to the first compartment is gradually and continuously transferred to the absorbent material for evaporation to the ambient air.
    Type: Grant
    Filed: May 20, 1988
    Date of Patent: November 7, 1989
    Assignee: Givaudan Corporation
    Inventor: Salvatore A. Losi
  • Patent number: 4877904
    Abstract: Novel odorant and/or flavoring substances are described. These are the compounds of the formula ##STR1## wherein: R.sup.1 represents methyl or ethyl,R.sup.2 represents hydrogen or methyl,the dotted line represents an optional carbon-carbon bond,n is 0 or 1, and,when n is O, R.sup.3 is hydrogen and R.sup.4 represents acetyl or propronyl, and,when n is 1, R.sup.3 represents methyl or ethyl and R.sup.4 represents hydrogen or methyl,with the exception of 1,4,4,7a-tetramethyl-3a,4,5,7a-tetrahydro-7(6H)-ind-1-enone.The compounds of formula I possess organoleptic properties which make them particularly suitable for use as odorant and/or flavoring substances.
    Type: Grant
    Filed: September 9, 1987
    Date of Patent: October 31, 1989
    Assignee: Givaudan Corporation
    Inventor: Peter Naegeli
  • Patent number: 4851050
    Abstract: .alpha.-Campholenic alcohol, dihydro-.alpha.-campholenic alcohol and the lower acyl esters thereof have organoleptic properties which make them useful as tobacco flavorants.
    Type: Grant
    Filed: January 30, 1986
    Date of Patent: July 25, 1989
    Assignee: Givaudan Corporation
    Inventors: Martin Rohr, Richard H. Potter, Richard E. Naipawer
  • Patent number: 4841063
    Abstract: This disclosure relates to a novel class of 2-alkyl-3-haloisothiazolium salts. These salts have been found to be useful in controlling the growth of bacteria and fungi. They have also been found to be useful intermediates in the preparation of novel and known antibacterial and antifungal compounds.
    Type: Grant
    Filed: January 31, 1984
    Date of Patent: June 20, 1989
    Assignee: Givaudan Corporation
    Inventors: Joseph A. Virgilio, Milton Manowitz, Emanuel Heilweil