Patents Assigned to Japan Synthetic Rubber Co., Ltd.
  • Patent number: 4882403
    Abstract: A non-hydrous soft contact lens comprising a copolymer comprising, as monomer units:(a) from 33.9 to 89 mol % of an acrylate represented by the general formula (I) shown below;(b) from 4.9 to 65 mol % of a methacrylate represented by the general formula (II) shown below;(c) from 1 to 20 mol % of at least one selected from an unsaturated carboxylic acid and its particular esters;(d) from 0 to 20 mol % of a particular acrylic acid ester having a straight chain alkyl or fluoroalkyl group;(e) from 0 to 20 mol % of a methacrylic acid ester having a straight-chain alkyl group;(f) from 0.1 to 10 mol % of a crosslinking monomer.General formula (I): ##STR1## wherein R.sub.1 is a particular straight-chain alkyl or fluoroalkyl group. General formula (II): ##STR2## wherein R.sub.2 is a particular straight-chain fluoroalkyl group; and a process for preparing the same. This contact lens has good oxygen permeability, mechanical strength, etc.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: November 21, 1989
    Assignees: Japan Synthetic Rubber Co., Ltd., Ricky Contact Lens, Inc.
    Inventors: Tetsuo Itoh, Noboru Satoh, Kazuhiko Takahashi, Taro Suminoe, Takao Shimizu
  • Patent number: 4877835
    Abstract: A thermoplastic resin composition with superior chemical resistance and impact resistance is disclosed. The composition comprises: 50 to 90% by weight of a rubber-modified styrene thermoplastic resin containing 10 to 60% by weight of .alpha.-methyl styrene, 5 to 48% by weight of an aromatic polyester, and 2 to 10% by weight of an aromatic polycarbonate.
    Type: Grant
    Filed: September 8, 1988
    Date of Patent: October 31, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Yusuke Tsuda, Takashi Kurata, Yoshinobu Suzuki, Yuji Yamamoto
  • Patent number: 4866131
    Abstract: Disclosed is a novel rubber composition for the treads of high-performance tires including racing tires. The elastomer component of the rubber composition consists essentially of 10-60 wt % of a low molecular weight copolymer of an aliphatic diene, e.g. butadiene, and an aromatic vinyl compound, e.g. styrene, and the balance of a conventional diene rubber such as a high styrene styrene-butadiene rubber. The copolymer is the product of solution copolymerization reaction of the aliphatic and aromatic monomers in a hydrocarbon solvent using an organic lithium compound as the initiator, and the molecular weight of the copolymer is from about 2000 to about 50000. The rubber composition provides very high road gripping ability and is sufficiently high also in rupture strength, heat resistance and wear resistance.
    Type: Grant
    Filed: September 2, 1987
    Date of Patent: September 12, 1989
    Assignees: Bridgestone Corporation, Japan Synthetic Rubber Co., Ltd.
    Inventors: Tatsuo Fujimaki, Noboru Oshima
  • Patent number: 4861931
    Abstract: A process for producing a 5-alkylidenenorbornene, which comprises contacting a 5-alkenylnorbornene with an organolithium compound and at least one compound selected from the group consisting of ammonia, a hydrazine compound and an aliphatic amine compound wherein at least one nitrogen atom in the molecule bonds to at least one hydrogen atom to isomerize the 5-alkenylnorbornene. This process enables the easy and efficient production of a 5-alkylidenenorbornene from an easily available raw material.
    Type: Grant
    Filed: June 20, 1988
    Date of Patent: August 29, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Yasuo Hara, Ryuji Oashi, Yoshitaka Kawahara, Mikio Takeuchi
  • Patent number: 4861851
    Abstract: A substantially random, linear vinylidene fluoride-acrylic acid ester copolymer comprising:(A) 5-85% by weight of a vinylidene fluoride unit,(B) 15-95% by weight of at least one unit selected from the group consisting of an alkyl acrylate unit and an alkoxy-substituted alkyl acrylate unit, and(C) optionally 10% by weight or less, based on the total weight of (A), (B) and (C), of a crosslinking monomer unit, and having an intrinsic viscosity of 0.01-10 dl/g as measured at 30.degree. C. in N,N-dimethylformamide. Said copolymer has not only excellent heat resistance, ozone resistance and sour gasoline resistance but also excellent resistance to gasoline permeation.
    Type: Grant
    Filed: January 19, 1988
    Date of Patent: August 29, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Toshio Miyabayashi, Nobuyuki Sakabe, Shinichiro Zen
  • Patent number: 4849478
    Abstract: An oil-resistant rubber composition comprising (A) 90 to 10 parts by weight of an unsaturated nitrile-conjugated diene rubber having a .DELTA.Tg of 58.degree. C. or more and an average bound nitrile content of 15 to 50% by weight, (B) 10 to 90 parts by weight of at least one rubber selected from the group consisting of an ethylene-propylene type copolymer rubber, a natural rubber and a polyisoprene and (C) 0 to 50 parts by weight, per 100 parts by weight of the total of (A) and (B), of at least one component (C) selected from the group consisting of a styrene polymer and a polyalkenamer. Said rubber composition is oil-resistant and excellent in mechanical properties such as tear strength, resistance to crack growth, etc.
    Type: Grant
    Filed: February 16, 1988
    Date of Patent: July 18, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Yoji Mori, Yoshiaki Kawamura, Hironori Matsumoto, Yasuhiko Takemura
  • Patent number: 4839410
    Abstract: A flame-retardant rubber-modified styrene resin composition comprising, as essential components, (A) a rubber-modified styrene resin, (B) a halogenated bisphenol type polycarbonate oligomer, (C) a halogenated bisphenol type compound, and (D) a halogenated polyolefin compound. The resin composition contains these components (A), (B), (C), and (D) at specific proportions, and its contents of the components (B) and (C) must be at a specified ratio. The resin composition is not only flame-retardant but also possesses such excellent characteristics as a high degree of light resistance, heat resistance, impact resistance and fluidity when it is molded. It can be molded into articles of various shapes and has a wide variety of applications in business machines, electric appliances, and automobile parts.
    Type: Grant
    Filed: February 9, 1988
    Date of Patent: June 13, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Seiichi Atomori, Teruo Inagaki, Tateki Furuyama, Akira Kamiya
  • Patent number: 4839425
    Abstract: A thermoplastic resin composition obtained by melt-mixing:(a) 4 to 95% by weight of a polyphenylene ether resin,(b) 4 to 95% by weight of a polyamide,(c) 1 to 50% by weight of a rubbery polymer, and(d) if necessary, 91% by weight or less of a styrene resin (d)[the sum of the (a), (b), (c) and (d) components is 100% by weight] in the presence of 0.001 to 10% by weight, based on the total weight of the (a), (b), (c) and (d) components, of at least one functional group-containing unsaturated compound having at least one group selected from the class consisting of carboxyl group, acid anhydride group, epoxy group, hydroxyl group, amino group and amido group and 0.001 to 5% by weight, based on the total weight of the (a), (b), (c) and (d) components, of a peroxide. This thermoplastic resin composition is excellent in balance of impact strength of thin molded product, moldability and heat resistance.
    Type: Grant
    Filed: March 30, 1987
    Date of Patent: June 13, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Masaaki Mawatari, Tetsuo Itoh, Syuji Tsuchikawa, Shinichi Kimura
  • Patent number: 4829830
    Abstract: In an apparatus for measuring viscoelasticity, dies are provided in their working face with a plurality of grooves arranged in a radial pattern, each groove cut to increase in width toward the periphery of the die face. Because of this groove design, air bubbles are unlikely to remain in the specimen. In addition, the specimen is far much less likely to slip between the opposed die faces in rotational oscillation generated therein for purposes of measurement, so that reduction in oscillatory angle, lessening of torque and friction disturbances that might otherwise occur as a result of slippage, are prevented. Since the shearing stresses generated in the specimen are transmitted to a torque detection die accurately as torques, precise detection of torque as a function of the viscoelastic stress in the specimen becomes possible.
    Type: Grant
    Filed: April 19, 1988
    Date of Patent: May 16, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventor: Chikao Tosaki
  • Patent number: 4830672
    Abstract: A zirconia-based coating composition comprising a mixture obtained by mixing:(a) at least one compound selected from the group consisting of (a') a zirconium compound represented by the general formula (I):Zr(OR).sub.4 (I)wherein R is an alkyl group having 2-5 carbon atoms or the general formula (I'):Zr(OR).sub.4.ROH (I')wherein R has the same means as defined above, (a") a partial hydrolyzate of the zirconium compound (a'), and (a'") a partial condensate of the partial hydrolyzate (a"),(b) a .beta.-diketone or .beta.-ketoester represented by the general formula (II):R.sup.1 COOH.sub.2 COR.sup.2 (II)wherein R.sup.1 is an alkyl group having 1-5 carbon atoms, R.sup.2 is an alkyl group having 1-5 carbon atoms or an alkoxy group having 1-4 carbon atoms),(c) water, and(d) a hydrophilic organic solvent.
    Type: Grant
    Filed: February 17, 1988
    Date of Patent: May 16, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Kinji Yamada, Masaki Nagata, Siniti Suyama, Momoko Okamura
  • Patent number: 4828955
    Abstract: Microencapsulated particles each consisting of a mother particle of a core substance and a coating layer of daughter particles formed on the surface of said mother particle, which are obtained by stirring mother particles of a core substance having a number average particle diameter of 1 to 200 .mu.m and either or both of daughter particles (1) of a coating layer-forming material having a number average particle diameter of 1/5 of less of that of the mother particles and fragile daughter particles (2) of a coating layer-forming material having a number average particle diameter of more than 1/5 of that of the mother particles but having a fragility index (Fr) as defined in the specification of 5 or more, at a high speed in an air stream. Said microencapsulated particles can be used in various application fields such as coatings, electronic components and electronograph.
    Type: Grant
    Filed: October 20, 1987
    Date of Patent: May 9, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Kiyoshi Kasai, Masayuki Hattori, Tatsuya Shimizu, Hiroshi Tadenuma
  • Patent number: 4828945
    Abstract: A solid electrolyte sheet comprising an ion-conductive inorganic solid electrolyte and an insulating elastomer, wherein the inorganic solid electrolyte powder is uniformly dispersed in the insulating elastomer in a volume fraction of 55-95% and which sheet has a hardness (ASTM A) of 65-96 and a thickness of 10-250 .mu.m, or a solid electrolyte sheet comprising a non-conductive reticulate material and a mixture of an ion-conductive inorganic solid electrolyte powder and an insulating elastomer, in which mixture the solid electrolyte powder is uniformly dispersed in the insulating elastomer in a volume fraction of 55-95%, at least the openings of the reticulate material being filled with said mixture. Said solid electrolyte sheets are superior in ion-conductivity, processability, productivity, storage stability and flexibility and are suitable for use in thin and large electrochemical elements.
    Type: Grant
    Filed: March 23, 1988
    Date of Patent: May 9, 1989
    Assignees: Japan Synthetic Rubber Co., Ltd., Matsushita Electric Industrial Co., Ltd.
    Inventors: Masaki Nagata, Naoshi Yasuda, Shigeo Kondo, Tadashi Sotomura
  • Patent number: 4824908
    Abstract: A butadiene-based rubber composition is disclosed, which contains not less than 20% by weight of a butadiene-based homopolymer or copolymer having a glass transition temperature (Tg) of not less than -105.degree. C., but less than -70.degree. C. and a Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 10 to 150. The butadiene-based homopolymer or copolymer is obtained by polymerizing butadiene or random-copolymerizing butadiene with at least one kind of a monomer selected from the group consisting of another conjugated diene and an aromatic vinyl compound, and then reacting polymerization-active terminals thereof with an isocyanate compound and/or an isothiocyanate compound. The butadiene-based rubber composition has excellent resilience, fracture strength, and wear resistance as a vulcanizate as well as excellent processability as an unvulcanized rubber, and can be used as tire applications such as tire treads, undertreads, sidewalls, bead portions, etc.
    Type: Grant
    Filed: March 24, 1987
    Date of Patent: April 25, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Fumio Tsutsumi, Mitsuhiko Sakakibara, Noboru Shimada, Yoshihisa Fujinaga, Noboru Oshima, Tatsuro Hamada, Tatsuo Fujimaki
  • Patent number: 4822654
    Abstract: A vulcanizable rubber composition comprising (1) 100 parts by weight of a polymer composition comprising(I) a vinylidene fluoride resin,(II) at least one rubber selected from the group consisting of acrylic rubbers, .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers and hydrides of .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubbers, said acrylic rubber consisting of (A) 30 to 99.9% by weight of an alkyl acrylate and/or an alkoxy-substituted alkyl acrylate, (B) 0.1 to 10% by weight of a crosslinkable monomer and (C) 0 to 70% by weight of another ethylenically unsaturated compound copolymerizable with (A) and (B) (the sum of (A), (B) and (C) is 100% by weight) and said .alpha.,.beta.-unsaturated nitrile-conjugated diene copolymer rubber consisting of (D) 10 to 60% by weight of an .alpha.,.beta.
    Type: Grant
    Filed: March 10, 1988
    Date of Patent: April 18, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Yasuhiko Takemura, Shinichiro Zen, Yoshiaki Zama, Hiroji Enyo
  • Patent number: 4814388
    Abstract: A rubber-modified thermoplastic resin composition obtained by copolymerizing an aromatic vinyl compound and optionally other monomers copolymerizable therewith in the presence of an ethylene-.alpha.-olefin type rubbery polymer having a molecular weight distribution parameter Mw/Mn of 1.2 to 4.5. Said polymer preferably has Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 40 or less. Said composition is excellent not only in weather resistance and impact resistance but also in rigidity, surface gloss and molded product appearance.
    Type: Grant
    Filed: February 13, 1986
    Date of Patent: March 21, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Hisao Nagai, Yuzi Nakagawa, Katsurou Oomura, Shinichi Kimura
  • Patent number: 4812525
    Abstract: A rubber composition is disclosed which contains, as a rubber component, 20-100% by weight of (A) polybutadiene polymerized by using a lithium initiator and 80 to 0% by weight of (B) another rubber component. The polybutadiene has the following physical properties (i)-(v):(i) The molecular weight distribution of Mw/Mn is 1.4 to 3.0 in which Mw and Mn are a weight average molecular weight and a number average molecular weight, respectively;(ii) A polymer component having the molecular weight being not more than 10.sup.5 when calculated as polystyrene is from 7 to 25%;(iii) The content of bound vinyl groups is from 10 to 25%;(iv) The content of tin atoms bonded to the polymer by tin-carbon bonds is not less than 50 ppm;(v) Mooney viscosity (ML.sub.1+4, 100.degree. C.) is from 20 to 70.
    Type: Grant
    Filed: July 16, 1987
    Date of Patent: March 14, 1989
    Assignees: Japan Synthetic Rubber Co., Ltd., Bridgestone Corporation
    Inventors: Noboru Oshima, Yoshishige Chikatsu, Toshiaki Fukuhori, Tatsuro Hamada, Tatsuo Fujimaki
  • Patent number: 4810599
    Abstract: A structure comprising a pair of electrode sheets and an electrolyte sheet, the latter being sandwiched in between the former, wherein each of the pair of electrode sheets comprises a mixture comprising an insulating elastomer and an electrode active substance powder and/or an inorganic solid electrolyte powder, in which mixture the electrode active substance powder and/or the inorganic solid electrolyte powder are dispersed in a volume fraction of 75-95% in the insulating elastomer, and said electrolyte sheet comprises a mixture of an inorganic solid electrolyte powder and an insulating elastomer and optionally an electrode active substance powder, in which mixture the inorganic solid electrolyte powder and optionally the electrode active substance powder are dispersed in a volume fraction of 55-95% in the insulating elastomer. Each of said electrode sheet and said electrolyte sheet may further comprise a reticulate material sheet, the openions of which are filled with the mixture.
    Type: Grant
    Filed: March 23, 1988
    Date of Patent: March 7, 1989
    Assignees: Japan Synthetic Rubber Co., Ltd., Matsushita Electric Industrial Co., Ltd.
    Inventors: Shigeo Kondo, Naoshi Yasuda, Masaki Nagata, Tadashi Sotomura
  • Patent number: 4798691
    Abstract: Capsule-shaped polymer particles and a process for the production thereof are described. In one embodiment of the process, a polymerizable monomer component containing a cross-linkable monomer and a hydrophilic monomer, and an oily substance are finely dispersed in water to prepare an oil-in-water emulsion and then the polymerizable monomer component is polymerized, whereupon capsule-shaped polymer particles containing the oily substance as a core material are obtained. Upon removal of the oily substance in the particles, there are obtained capsule-shaped hollow polymer particles. These capsule-shaped polymer particle are excellent in such properties as mechanical strength and heat resistance, and thus can find many applications.
    Type: Grant
    Filed: May 23, 1986
    Date of Patent: January 17, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Kiyoshi Kasai, Masayuki Hattori, Hiromi Takeuchi, Nobuo Sakurai
  • Patent number: 4792585
    Abstract: A thermoplastic resin composition consisting essentially of:(A) 20 to 80% by weight of a polycarbonate having a viscosity-average molecular weight of 14,000 to 27,000,(B) 10 to 70% by weight of a maleimide resin obtained by polymerizing 95 to 35 parts by weight of a monomer mixture consisting of 10 to 70% by weight of a maleimide compound, 25 to 80% by weight of an aromatic alkenyl compound, 5 to 40% by weight of an alkenyl cyanide compound and optionally 50% by weight or less of a monomer copolymerizable therewith, in the presence of 5 to 65 parts by weight of at least one rubber-like polymer selected from the group consisting of an ethylene-propylene-nonconjugated diene rubber, an ethylene-propylene rubber and an acrylic rubber, and(C) 5 to 70% by weight of a styrene resin obtained by polymerizing 95 to 20 parts by weight of a monomer mixture consisting of 5 to 40% by weight of an alkenyl cyanide compound, 10 to 95% by weight of an aromatic alkenyl compound and optionally 0 to 70% by weight of at least one
    Type: Grant
    Filed: December 1, 1987
    Date of Patent: December 20, 1988
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Kazuhiko Yamamoto, Kenji Nobuhara, Hodaka Mizuno, Atsuko Yanagawa
  • Patent number: 4782119
    Abstract: A rubber composition containing at least 20% by weight of a styrene-butadiene block copolymer consisting of a block (A) and a block (B) characterized in that: (i) the block (A) is a styrene-butadiene copolymer block having the content of styrene of 10-80% by weight and the average content of the vinyl bonds in the butadiene portion of 30-70% by weight; (ii) the block (B) is a polybutadiene block with the average content of the vinyl bonds in the butadiene portion being not more than 60% by weight (iii) the styrene-butadiene block copolymer contains at least 20% by weight of each of the block (A) and the block (B); (iv) the average content of the vinyl bonds in the butadiene portion of the block (A) is greater by at least 5% by weight than that of the block (B); (v) the glass transition temperature of the block (A) is higher by at least 30.degree. C.
    Type: Grant
    Filed: August 27, 1985
    Date of Patent: November 1, 1988
    Assignees: Japan Synthetic Rubber Co., Ltd., Bridgestone Corporation
    Inventors: Fumio Tsutsumi, Akio Iakashima, Mitsuhiko Sakakibara, Noboru Oshima, Tatsuo Fujimaki, Yoshiyuki Morimoto