Patents Assigned to Johnson Matthey PLC
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Patent number: 9056295Abstract: A method for installing a monitoring device with the simultaneous loading of a particulate catalyst into a vertical catalyst tube includes (i) introducing a monitoring device into the tube, (ii) introducing monitoring device alignment apparatus into the tube, (iii) introducing catalyst loading apparatus into the tube, (iv) loading catalyst particles into the top of the tube whereinafter they contact said catalyst loading apparatus as they pass down the tube, forming a uniform bed of catalyst beneath said catalyst loading apparatus and alignment apparatus and around said monitoring device, and (v) simultaneously removing the catalyst loading apparatus and alignment apparatus from the catalyst tube in timed relationship to the catalyst loading. The monitoring device alignment apparatus includes a ring member and two or more spacing members affixed to the ring member such that the ring member and the monitoring device are centrally positioned within the tube.Type: GrantFiled: July 7, 2010Date of Patent: June 16, 2015Assignee: Johnson Matthey PLCInventors: John Robert Brightling, Jumal Ahmad Shah
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Patent number: 9057036Abstract: A process for reducing the thiophene content in a synthesis gas mixture, comprises the steps of (i) passing a synthesis gas mixture comprising hydrogen and carbon oxides and containing thiophene over a copper-containing sorbent disposed in a sorbent vessel at an inlet temperature in the range 200-280° C., (ii) withdrawing a thiophene depleted synthesis gas containing methanol from the sorbent vessel, and (iii) adjusting the temperature of the methanol-containing thiophene-depleted synthesis gas mixture. The resulting gas mixture may be used for production of chemicals, e.g. methanol production or for the Fischer-Tropsch synthesis of liquid hydrocarbons, for hydrogen production by using water gas shift, or for the production of synthetic natural gas.Type: GrantFiled: October 17, 2011Date of Patent: June 16, 2015Assignee: Johnson Matthey PLCInventors: Peter Edward James Abbott, Norman Macleod, Gordon Edward Wilson
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Patent number: 9035259Abstract: An instrument adapted for the determination of fluid levels within a vessel by the comparison of the density of the fluid along the length of the instrument, said instrument comprising: (i) at least one generally linear source array comprising a plurality of sources of penetrating radiation, shielding and collimation means and a source supporting structure for supporting the sources and shielding and collimation means in a linear array (ii) at least one generally linear detector array comprising a plurality of radiation detectors, supported on a detector support structure, capable of detecting radiation emitted by the sources, and (iii) means to position the source and a respective detector array such that (a) radiation emitted from each of the sources is capable of following a linear path from the source, through the vessel and material to at least a respective one of the detectors forming a part of the respective detector array, and (b) the linear axis of the source array and the linear axis of its respectiType: GrantFiled: September 18, 2009Date of Patent: May 19, 2015Assignee: Johnson Matthey PLCInventors: Paul David Featonby, Peter Jackson, Benjamin Metcalfe, Thomas John Partington
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Patent number: 9017642Abstract: A process for reducing free oxygen in a hydrocarbon gas stream comprises the steps of (i) forming a gas mixture containing hydrogen from a hydrocarbon, (ii) mixing the hydrogen gas mixture with a gaseous hydrocarbon stream containing free oxygen, and (iii) passing the resulting hydrocarbon gas mixture over a conversion catalyst that converts at least a portion of the free oxygen present in the gaseous hydrocarbon to steam.Type: GrantFiled: March 5, 2007Date of Patent: April 28, 2015Assignee: Johnson Matthey PLCInventors: Peter John Herbert Carnell, Martin Fowles, Raymond Anthony Hadden, Suzanne Rose Ellis
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Patent number: 8980785Abstract: A catalyst structure suitable for use in an ammonia oxidation process is described including a plurality of shaped catalyst units supported on one or more members in a spaced relationship that allows the structure to flex.Type: GrantFiled: January 13, 2011Date of Patent: March 17, 2015Assignee: Johnson Matthey PLCInventor: Duncan Roy Coupland
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Patent number: 8969240Abstract: A sorbent, suitable for removing heavy metals, particularly mercury, from fluid streams containing a reductant such as hydrogen and/or carbon monoxide, is in the form of a shaped unit containing ?0.1% by weight in total of heavy metal selected from mercury, arsenic, lead, cadmium and antimony, and 4-75% by weight of copper in the form of one or more reduced copper sulphides which have a sulphur to copper atomic ratio of ?0.6:1.Type: GrantFiled: November 9, 2009Date of Patent: March 3, 2015Assignee: Johnson Matthey PLCInventors: Lucy Jane Hetherington, Matthew John Cousins
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Patent number: 8956428Abstract: A process for treating offshore natural gas includes processing the natural gas on an off-shore processing facility by, (i) liquefying and fractionating the natural gas to generate a liquefied natural gas stream and a higher hydrocarbon stream, (ii) vaporizing at least a portion of the higher hydrocarbon stream, (iii) passing the vaporized higher hydrocarbon stream and steam over a steam reforming catalyst to generate a reformed gas mixture comprising methane, steam, carbon oxides and hydrogen, (iv) passing the reformed gas mixture over a methanation catalyst to generate a methane rich gas, and (v) combining the methane-rich gas with the natural gas prior to the liquefaction step.Type: GrantFiled: June 15, 2009Date of Patent: February 17, 2015Assignee: Johnson Matthey PLCInventors: Peter John Herbert Carnell, Ginny Yuen Che Ng
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Patent number: 8957117Abstract: A methanol synthesis process includes reacting a process gas containing hydrogen, carbon dioxide and carbon monoxide over a catalyst including shaped units formed from a reduced and passivated catalyst powder the powder including copper in the range 10-80% by weight, zinc oxide in the range 20-90% by weight, alumina in the range 5-60% by weight and optionally one or more oxidic promoter compounds selected from compounds of Mg, Cr, Mn, V, Ti, Zr, Ta, Mo, W, Si and rare earths in the range 0.01-10% by weight, to form a product gas, and condensing methanol, water and oxygenate by-products therefrom, wherein the total oxygenate by-product level in the condensate is below 500 ppm.Type: GrantFiled: May 24, 2010Date of Patent: February 17, 2015Assignee: Johnson Matthey PLCInventors: Colin William Park, Brian Peter Williams, Gordon James Kelly, Terence James Fitzpatrick
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Patent number: 8945497Abstract: The invention concerns a process for the oxidation of organic compounds contained in a gas stream and comprises the step of introducing the gas stream containing the organic compounds together with sufficient oxygen to effect the desired amount of oxidation into an oxidation reactor containing an oxidation catalyst and maintaining the temperature of said gas stream at a temperature sufficient to effect oxidation, characterised in that the oxidation catalyst contains at least 0.01% by weight of ruthenium, cobalt or manganese.Type: GrantFiled: September 17, 2009Date of Patent: February 3, 2015Assignee: Johnson Matthey PLCInventors: Gareth Headdock, Kenneth George Griffin, Peter Johnston, Martin John Hayes
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Publication number: 20140361222Abstract: An opposed axial flow reaction vessel includes a process fluid collection system within the body of the vessel in fluid communication with one or more of the ports; a bed of particulate catalyst or sorbent containing a layer of inert particulate material around the process fluid collection system; and the one or more of the ports are configured such that a process fluid fed to the vessel is passed axially and in the opposite direction through the fixed bed of catalyst or sorbent and is collected by the process fluid collection system disposed centrally within the bed and in fluid communication with one or more of the ports.Type: ApplicationFiled: August 21, 2014Publication date: December 11, 2014Applicant: Johnson Matthey PLCInventors: Charles William Hooper, Michael Peter Roberts
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Patent number: 8906698Abstract: A method of measuring the fluorescence of a fluorescent marker compound dissolved or dispersed in a bulk material includes: (a) measuring a characteristic of the fluorescence of a mixture of said bulk material and said fluorescent marker compound; (b) quenching the fluorescence of the fluorescent marker compound to produce a quenched mixture; (c) measuring the characteristic of the fluorescence of the quenched mixture; (d) comparing the fluorescent characteristic of the mixture with the fluorescent characteristic of the quenched mixture; and (e) correcting the measured fluorescent emission characteristic for the effects of the absorbance of the bulk material. The measurement may be further corrected to account for the absorbance of the material which is also known to have an effect on the measured fluorescence. A method of tagging and identifying a bulk material with a fluorescent marker compound, and an apparatus for carrying out the methods are also described.Type: GrantFiled: February 2, 2010Date of Patent: December 9, 2014Assignee: Johnson Matthey PLCInventors: Vincent Brian Croud, Duncan William John McCallien, Ian Stuart Edworthy
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Patent number: 8895931Abstract: The invention comprises an apparatus comprising a water-proof housing assembly comprising a housing (20) and a display panel (10, 32), and incorporating an enclosure (30) containing electrical apparatus, wherein said display panel is formed from a clear material (16) encapsulating a visual display (12) and/or a light-source (34) and said apparatus is capable of operating in water at a pressure of at least 300 bar without ingress of water into the enclosure. The apparatus may be used as an instrument or a lighting unit in sub-sea environments. The invention comprises further a light-source attachment for a powered apparatus comprising a light source embedded within a block of clear material (16) and means for mounting said block on the powered apparatus such that a connector connects the light source to a power source within the powered apparatus.Type: GrantFiled: June 24, 2011Date of Patent: November 25, 2014Assignee: Johnson Matthey PLCInventors: Geoffrey Stuart Howe, David Charles Banks
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Publication number: 20140332727Abstract: A process for the steam reforming of hydrocarbons comprises partially oxidising a feedgas comprising a hydrocarbon feedstock with an oxygen-containing gas in the presence of steam to form a partially oxidised hydrocarbon gas mixture at a temperature >1200° C. and passing the resultant partially oxidised hydrocarbon gas mixture through a bed of steam reforming catalyst, wherein the bed comprises a first layer and a second layer, each layer comprising a catalytically active metal on an oxidic support wherein the oxidic support for the first layer is a zirconia.Type: ApplicationFiled: May 22, 2014Publication date: November 13, 2014Applicant: Johnson Matthey PLCInventors: Peter William Farnell, Martin Fowles
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Patent number: 8859631Abstract: A process is described for the conversion of synthesis gas into hydrocarbons including the steps of; (i) passing a synthesis gas comprising hydrogen and carbon monoxide over a cobalt catalyst at elevated temperature and pressure to produce a first reaction product mixture comprising hydrocarbons, steam, carbon monoxide and hydrogen, (ii) condensing and separating water from the first reaction product mixture to produce a de-watered first reaction product mixture, (iii) passing the de-watered first reaction product mixture over a supported ruthenium catalyst at elevated temperature and pressure to produce a second reaction product mixture containing hydrocarbons, and (iv) recovering the hydrocarbons from the second reaction product mixture.Type: GrantFiled: December 16, 2010Date of Patent: October 14, 2014Assignee: Johnson Matthey PLCInventor: Mark McKenna
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Patent number: 8852537Abstract: A method of adapting an axial flow reaction vessel having opposed ports to an opposed axial flow reaction vessel includes installing a process fluid collection system within the body of the vessel in fluid communication with one or more of the ports; providing the vessel with a bed of particulate catalyst or sorbent containing a layer of inert particulate material around the process fluid collection system; and adapting the feed to the vessel through one or more of the ports such that a process fluid fed to the vessel is passed axially and in the opposite direction through the fixed bed of catalyst or sorbent and is collected by the process fluid collection system disposed centrally within the bed and in fluid communication with one or more of the ports.Type: GrantFiled: September 26, 2011Date of Patent: October 7, 2014Assignee: Johnson Matthey PLCInventors: Charles William Hooper, Michael Peter Roberts
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Publication number: 20140296573Abstract: A method for preparing 1-adamantyltrimethylammonium hydroxide is disclosed. The method comprises reacting 1-adamantyldimethylamine with dimethyl carbonate to produce 1-adamantyltrimethylammonium methylcarbonate, which is then reacted with calcium hydroxide or magnesium hydroxide in the presence of water to produce 1-adamantyltrimethylammonium hydroxide.Type: ApplicationFiled: March 27, 2014Publication date: October 2, 2014Applicant: Johnson Matthey PLCInventors: Richard Charles BRYAN, Ronald Henry JONES, Nigel ROBINSON
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Publication number: 20140275566Abstract: Wet bendamustine hydrochloride monohydrate may be dried by a two stage process wherein rapid drying is first carried out to provide a partially dried product, which is then further dried using an inert gas of controlled relative humidity to yield dry bendamustine hydrochloride monohydrate.Type: ApplicationFiled: March 12, 2014Publication date: September 18, 2014Applicant: JOHNSON MATTHEY PLCInventors: Xing Fu, Jeremy Clinton Wilt
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Publication number: 20140275567Abstract: An alkyl ester of 4-(5-(bis(2-hydroxyethyl)amino)-1-methyl-1H-benzo[d]imidazol-2-yl)butyric acid, such as ethyl 4-(5-(bis(2-hydroxyethyl)amino)-1-methyl-1H-benzo[d]imidazol-2-yl)butanoate, is obtained by reacting an alkyl ester of 4-(5-amino-1-methyl-1H-benzo[d]imidazol-2-yl)butyric acid with 2-hydroxyacetaldehyde under reducing conditions.Type: ApplicationFiled: March 13, 2014Publication date: September 18, 2014Applicant: JOHNSON MATTHEY PLCInventors: Xing Fu, Saroop Singh Matharu
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Patent number: 8822680Abstract: A substituted paracyclophane is described of formula (I) wherein X1 and X2 are linking groups comprising between 2 to 4 carbon atoms, Y1 and Y2 are selected from the group consisting of hydrogen, halide, oxygen, nitrogen, alkyl, cycloalkyl, aryl or heteroaryl and Z is a substituted or unsubstituted alkyl group, aryl group or heteroaryl group. Preferably X1 and X2 are —(C2H4)— and Z is a substituted aryl group. The substituted paracyclophane provides transition metal catalysts that are useful in C—C and C—N bond formation and asymmetric hydrogenation reactions.Type: GrantFiled: August 21, 2008Date of Patent: September 2, 2014Assignee: Johnson Matthey PLCInventors: Jianliang Xiao, Jiwu Ruan
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Patent number: 8815097Abstract: An adsorbent suitable for heavy metal adsorption is described, comprising a thiol functionalized support wherein the adsorbent has a BET surface area in the range 200-500 m2/g, a pore diameter in the range 70-150 Angstroms and a pore volume ?0.25 cm3/g. The adsorbent may be used to remove heavy metals e.g. mercury and/or arsenic, from wastewater streams such as produced water or flue gas scrubber waters.Type: GrantFiled: August 12, 2009Date of Patent: August 26, 2014Assignee: Johnson Matthey PLCInventors: Matthew John Cousins, Kevin Young