Abstract: Hydrogen storage materials are provided of a ternary alloy of the formula:ZrMnFe.sub.xwherein x has a value from 1.2 to 1.3, and their hydrides.

Abstract: A rotary vane valve having a cylindrical housing with a pair of opposed end bells and an interior axial shaft. Opposed inlet and outlet openings on the side of the cylindrical housing allow transverse fluid flow through the housing and radial vanes project from the axial shaft to facilitate the transfer of fluid from the inlet at one pressure to the outlet at a different pressure. A pair of spaced shroud structures are fixed to the shaft at the ends of the vanes to generally separate the interior of the cylindrical housing from the end bells.

Abstract: An alloy consisting of zirconium, chromium, iron and optionally titanium is characterized in having C14 hexagonal crystal structure and ZrCr.sub.2 stoichiometry. Members of a preferred class of compounds, represented by the empirical formula Zr.sub.1-x Ti.sub.x Cr.sub.2-y Fe.sub.y wherein "x" has a value between 0.0 and 0.9 and "y" has a value of 0.1 to 1.5, are particularly suitable for use as hydrogen storage materials.

Abstract: A rotary vane valve having a cylindrical housing with a pair of opposed end bells and an interior axial shaft. A pair of spaced shroud structures are fixed to the shaft at the ends of the vanes to generally separate the interior of the cylindrical housing from the end bells. These shroud structures are spaced from the cylindrical housing at their outer peripheral edges, but an annular throttle plate is spaced axially outwardly at a close distance from these shrouds and adjacent at its outer edge to the cylindrical housing to increase the velocity of purge gas flowing inwardly between the cylindrical housing and the outer peripheral edge of the shroud so that the escape of gas from the interior of the cylindrical housing is effectively prevented. The inner lateral surface of the annular throttle plate is divided into a low pressure zone adjacent the inlet opening and a high pressure zone adjacent the outlet opening in situations where the inlet opening is at a lower pressure than the outlet opening.

Abstract: In a pressurized materials processing system, separation of solid particulates from a gaseous process fluid is beneficially accomplished by use of a swept orifice discharger comprised of a cylindrical housing that is closed at one end and open at the other end. The housing contains an impeller within its interior and has a selected, presized orifice in its cylindrical side wall. In operation, the solid material and gaseous fluid are received in the swept orifice discharger housing and the solid material is continuously centrifugally urged toward the housing side wall so that it separates from the gaseous process fluid and collects on the housing side wall.

Abstract: A hog granulator for plastic material in which a plurality of longitudinal knives are arranged on a rotor inside a cutting chamber to engage in a cooperative cutting action with bed knives on the cutting chamber walls. A plurality of spaced, longitudinal pockets in the peripheral surface of the rotor bring cooling air to the cutting surfaces, and ribs are arranged across these pockets to reduce power requirements by preventing excessively large pieces of plastic material to be reduced from being received into and taking up residence in these pockets.

Abstract: The present invention is directed to aqueous phenol formaldehyde resoles that have particular application in manufacturing phenolic foam insulation. The resoles are essentially phenol formaldehyde condensation polymers having molar ratios of formaldehyde to phenol of from about 1.7:1 to 2.3:1, preferably from 1.75:1 to 2.25:1 and most preferably about 2:1. The resoles have a weight average molecular weight greater than 800 and preferably from 950-1500. The resoles also have a number average molecular weight greater than 350 and preferably from about 400 to about 600 and a dispersivity greater than about 1.7, preferably from 1.8 to 2.6. Phenol formaldehyde resoles having these characteristics are processable into phenolic foams having a low k value and having other physical characteristics which make the phenolic foam especially useful as an insulation material.

Abstract: A car for charging a coke oven battery with coal. This car carries a plurality of integral coal hoppers. A particular space frame construction is disclosed to support these hoppers, and because of this construction a significant savings in the weight of the car is realized. This space frame includes a pair of horizontally spaced lower front and rear parallel transverse beams and upper front and rear parallel transverse beams. Longitudinally extending beams connect both ends of the upper and lower front transverse beams with the corresponding rear transverse beams. The above described structure is mounted on four wheel housings by means of four truss structures. Two of these wheel housings are positioned slightly in front of the front transverse beams and two are mounted slightly behind the front transverse beams.

Abstract: Quaternary hyperstoichiometric alloys of the formula: ZrCrFeT.sub.x and their hydrides are provided, characterized as having MgZn.sub.2 hexagonal crystal structure wherein T is selected from Mn, Fe, Co, Ni and Cu, and X is a number from 0.1 to 1.0. These alloys readily form hydrides at low hydrogen pressure and are suitable for use as hydrogen storage materials.

Abstract: A process is disclosed for separating 3,5-xylenol or 3,4-xylenol from other closely boiling polymethylated phenolics by treating a mixture of the phenolics with a metal halide salt. The metal halide salt preferentially forms a complex with the xylenol over other related phenolics in the mixture. The preferentially-formed complex of the xylenol may then be isolated from the mixture and the complex decomposed to provide a product substantially enriched in, or substantially entirely composed of the xylenol.

Abstract: A process is disclosed for separating nitrated phenolic compounds from other nitrated and unnitrated phenolics by treating a mixture of the phenolics with a metal halide salt. The metal halide salt preferentially forms a complex with one of the phenolics over other related phenolics in the mixture. The preferentially-formed complex of one of the phenolics may then be isolated from the mixture and the complex decomposed to provide a product substantially enriched in, or substantially entirely composed of, one phenolic. The process is particularly suitable for resolving a mixture comprising phenol or cresol from their ortho-nitrated derivatives, or a mixture of two isomeric nitrated phenols or cresols or a mixture of mono- and dinitrated phenols or cresols.

Abstract: An apparatus and method for applying a multi-component liquid adhesive. A liquid resin reservoir and a liquid hardener reservoir are connected by separate conduit means to resin and hardener mix chamber which is positioned adjacent to a dispenser so that the adhesive can be spread at substantially the same time as it is mixed. Separate resin and hardener pumps are each driven by their own variable output capacity power sources and means are provided for sensing the instantaneous speed of these pumps. These sensors are connected to separate control means for the power sources so that the power output to both of the pumps will be proportional to their respective instantaneous speeds. This apparatus compensates for temperature induced changes in viscosity of the resin or hardener so as to allow mixing proportions to remain constant.

Abstract: A method and apparatus for mixing granular, particulate or pulverant material is disclosed. An unhomogenous mixture of two or more such materials is introduced into and moved through a preferably inclined trough structure having rigid side walls and a flexible floor member. At one or more isolated positions on this floor member it is subjected to relatively intense vibrational motion. It is found that such restricted use of vibrational motion results in a thorough yet gentle mixing of granular, particulate or pulverant materials.

Abstract: A method of oxidizing an element in both compartments of an electrolytic cell is provided. The method comprises reducing O.sub.2 to H.sub.2 O.sub.2 in the cathodic compartment with a reducing agent such as a cobalt porphyrin, cobalt phthalocyanine, or hydroquinone, and oxidizing the element in both compartments preferably in the presence of a halide. Yields of up to 200 percent are obtainable.

Abstract: The invention discloses a method of impregnating a porous catalyst carrier with a partially hydrolyzed aqueous methanol solution of titanium tetrachloride, and completing the hydrolysis to titanium dioxide under controlled conditions of temperature and by-product removal to obtain the desired anatase, rutile or combination anatase/rutile polymorphic form of titanium dioxide.

Abstract: Phenols alkylated in the ortho and/or para positions are produced in good yields and in the absence of isomers from phenolic compounds having at least two alkylateable ortho-ortho or ortho-para positions open. The phenolic compound is first partially chlorinated or brominated and the desired halogenated phenol having at least one open position ortho or para is reacted with an aldehyde having one to four carbon atoms and a secondary non-aromatic amine. The reaction is conducted in the liquid phase with a stoichiometric amount of the phenolic compound and stoichiometric or excess of stoichiometric amounts of the aldehyde and the amine. The reaction is performed at a temperature of from about 0.degree. C. to about 100.degree. C. to produce an aminoalkylated halogenated phenolic compound. This aminoalkylated halogenated phenolic compound is contacted with hydrogen in the presence of a metal catalyst at a temperature of about 100.degree. C. to about 175.degree. C.

Abstract: The present invention is directed to a method of preparing a phenolic foam that has cell walls which are substantially free of perforations. The method comprises using certain anhydrous aryl sulfonic acids as the foaming and curing catalysts. The useful anhydrous aryl sulfonic acids are those which have a pKa of less than about 2.0 and which change the compatibility of the phenolic resole with water. The preferred anhydrous aryl sulfonic acid is a combination of toluene sulfonic acid and xylene sulfonic acid. The invention is also directed to a phenolic foam having cell walls which are substantially free of perforations and to foamable phenolic resole compositions for preparing the phenolic foam.

Abstract: A process is disclosed for separating nitrated phenolic compounds from other nitrated and unnitrated phenolics by treating a mixture of the phenolics with a metal halide salt. The metal halide salt preferentially forms a complex with one of the phenolics over other related phenolics in the mixture. The preferentially-formed complex of one of the phenolics may then be isolated from the mixture and the complex decomposed to provide a product substantially enriched in, or substantially entirely composed of, one phenolic. The process is particularly suitable for resolving a mixture comprising phenol or cresol from their ortho-nitrated derivatives, or a mixture of two isomeric nitrated phenols or cresols or a mixture of mono-and dinitrated phenols or cresols.

Abstract: Ortho- or para-monoalkylated phenols or 2,4- or 2,6-dialkylphenols can be produced from phenolic compounds in good yields and in the absence of isomers. The starting phenol which has at least two available ortho or para positions unsubstituted is converted to a t-alkylated phenol having at least one ortho or para position unsubstituted. The desired t-alkylated phenolic compound is reacted with an aldehyde having one to four carbon atoms and a secondary aliphatic or alicyclic amine. The reaction is conducted in the liquid phase with a stoichiometric amount of the phenolic compound and stoichiometric or excess of stoichiometric amounts of the aldehyde and the secondary amine. The reaction is conducted at a temperature in the range of about 0.degree. C., to about 100.degree. C. and the reaction produces an aminoalkylated t-alkylated phenol. The aminoalkylated phenol is contacted with hydrogen in the presence of a metal catalyst at a temperature of about 100.degree. C. to about 175.degree. C.

Abstract: An improved hub retention device for retaining the coupling hub in proper position on the shaft of a spindle coupling when the roll ends are removed from the coupling sleeve. The hub retention device is comprised of a split-ring member fitted in a circumferential groove formed on the coupling shaft and a continuous ring member shrunken over the split-ring member.