Abstract: Selective reduction methods for halogenated carbosilanes and carbodisilanes are disclosed. More particularly, high yields of the desired carbosilanes and carbodisilanes are obtained by reduction of their halogenated counterparts using a reducing agent and tetrabutylphosphonium chloride (TBPC) as a catalyst.

Abstract: A device for filling a tank or tanks with pressurized gas comprising a circuit comprising a plurality of upstream ends connected respectively to separate pressurized gas sources, at least one compressor, at least one buffer storage, a set of controlled valves and at least one downstream end intended to be connected to the tank(s) to be filled, the device further comprising an electronic control member configured to control the valves and/or the compressor in order to ensure a transfer of gas into the tank from at least one source and/or at least one buffer storage and/or via the compressor, the device comprising a set of sensors for measuring the pressure in the sources and the buffer storages, the control member comprising member for receiving or generating signal representative of the filling demand from a relatively high demand to a relatively low demand, the control member being configured to ensure the transfer of gas into the tank according to at least a first transfer mode using the source having the h

Abstract: Proposed is a process for producing methanol from synthesis gas by means of multi-stage, for example 2-stage, heterogeneously catalyzed methanol synthesis, wherein the product stream of a synthesis stage is applied to the downstream synthesis stage as a feed stream or after removal of a purge stream recycled to the first synthesis stage as a recycle stream. According to the invention a substream is removed from the synthesis gas fresh gas and introduced into the second methanol synthesis reactor as a bypass stream.

Abstract: Proposed is a process for producing methanol from synthesis gas by means of multi-stage, for example 2-stage, heterogeneously catalyzed methanol synthesis, wherein the methanol product formed in every synthesis stage is removed by condensation and the remaining residual gas is applied to the downstream synthesis stage or after removal of a purge stream recycled to the first synthesis stage as a recycle stream. According to the invention a substream is removed from the synthesis gas fresh gas and introduced into the second methanol synthesis reactor as a bypass stream.

Abstract: Device for filling with liquefied gas comprising a fluid circuit provided with a first pipe for liquid transfer comprising a first end that is intended to be connected to a source of liquefied gas and a second end that is intended to be connected to a tank to be filled, a second pipe for gas transfer comprising a first end that is intended to be connected to the source of liquefied gas and a second end that is intended to be connected to said tank to be filled, the circuit comprising at least one third transfer pipe connecting the first and second transfer pipes, and a vent device connected to the first and second transfer pipes via a set of one or more safety valves, the circuit comprising a set of one or more valves for controlling the streams of fluid in the pipes of the circuit, the device comprising a system for gas flushing of the circuit, characterized in that the flushing system comprises a first source of pressurized gas, and a first set of one or more flushing pipes connecting the first source of pr

Abstract: Lanthanide-containing film forming compositions comprising Lanthanide precursors having the general formulae: wherein Ln is a Lanthanide; A is independently N, Si, B, P or O; each E is independently C, Si, B or P; m and n are independently 0, 1 or 2; m+n>1; each R is independently an H or a C1-C4 hydrocarbyl group; L is a ?1 anionic ligand selected from the group consisting of NR?2, OR?, Cp, amidinate, ?-diketonate, or keto-iminate, wherein R? is an H or a C1-C4 hydrocarbon group; and L? is NR? or O, wherein R? is an H or a C1-C4 hydrocarbon group. Also disclosed are methods of synthesizing and using the disclosed precursors to deposit Lanthanide-containing films on one or more substrates via vapor deposition processes.

Abstract: A process and a plant for the continuous conversion of a hydrocarbonaceous feed gas into a synthesis gas comprising carbon monoxide and hydrogen, wherein the H2/CO molar ratio of the product gases can be varied within a wide range. This is achieved in that at least a part of a methane-rich gas obtained during the fractionation of the raw synthesis gas is admixed to the feed gas mixture, and that in the alternative at least a part of the H2 product gas and/or a fraction of a hydrogen-rich gas increased with respect to the normal operation of the process is admixed to the heating gas mixture, in order to lower the H2/CO ratio, or at least a part of the CO product gas and/or a fraction of a carbon monoxide-rich gas increased with respect to the normal operation of the process is admixed to the heating gas mixture, in order to increase the H2/CO ratio.

Abstract: The invention relates to a tank for storing a two-phase cryogenic mixture of liquid and gas, comprising a first casing, at least one drawing pipe, a tank filling circuit, the tank comprising a sensor assembly measuring the pressure in the first casing, the tank comprising a pipe for pressurizing the internal casing, comprising an upstream end connected to the lower end of the first casing and a downstream end connected to the upper part of the first casing, the pressurization line comprising at least one regulating valve and a heater, in particular a vaporization heat exchanger. The invention is characterized in that the regulating valve is configured to automatically maintain the pressure in the first casing at a minimum value by ensuring, when the pressure in the first casing is lower than said first value, a circulation of liquid taken from the first casing in the heater and a re-injection of said heated fluid into the first casing.

Abstract: Method for filling a liquefied gas tank with pressurized liquefied gas from a source of liquefied gas using a filling apparatus comprising a transfer circuit that is provided with first and second pipes, each connecting between the source via respective first ends and the tank via respective second ends, third and fourth pipes each connecting between the first and second pipes, and a set of valves controlling flows of fluid in the pipes. The tank is depressurized and at least part of the circuit is cooled by transferring pressurized vaporization gas from the tank to the first end of the second pipes via the second end of the second pipe, the third pipe, the first pipe, and the fourth pipe.

Abstract: Cryogenic fluid storage tank comprising a pipe for drawing off vaporized gas, which pipe is connected to a first casing and comprises a vaporizer and at least one control valve, a first filling pipe connected to the lower portion of the first casing, a second pipe for filling a downstream end connected to the upper portion of the first casing, a distribution valve assembly configured to enable distribution of the fluid from the fluid source in the filling pipes, a pressurization pipe connected to the lower end of the first casing and a second end connected to the upper portion of the first casing and at least one control valve and a heater, the tank further comprising an air vent regulator, the valve assembly for distribution in the filling circuit, the valve for controlling the pressurization pipe, the valve for controlling the drawing-off circuit and the air vent regulator being integrated into the same valve module, which shares at least one valve element.

Abstract: Methods of selectively synthesizing n-tetrasilane are disclosed. N-tetrasilane is prepared by pyrolysis of silane (SiH4), disilane (Si2H6), trisilane (Si3H8), or mixtures thereof. More particularly, the disclosed synthesis methods tune and optimize the n-tetrasilane:i-tetrasilane isomer ratio. The isomer ratio may be optimized by selection of process parameters, such as temperature, residence time, and the relative amount of starting compounds. The disclosed synthesis methods allow facile preparation of n-tetrasilane.

Abstract: In a method for producing a series of at least a first and a second plate-fin heat exchangers, several elongate fluid distribution tanks are installed on the matrix unit, each tank capping just some of the openings assigned to the first fluid and to the second fluid, each tank having its axis in the direction of stacking and each being connected to a pipe so that the number of openings assigned to the first fluid differs from the number of openings assigned to the first fluid, and for preference, the number of openings assigned to the second fluid differs from the number of openings assigned to the second fluid for the at least first and second exchangers of the series.

Abstract: Device and method for filling pressurized gas tanks, particularly vehicle pressurized hydrogen tanks, the device comprising a liquefied gas source, a transfer circuit comprising two parallel transfer lines each having an upstream end linked to the liquefied gas source, at least two separate downstream ends intended to be each removably connected to a tank to be filled, each of the two transfer lines comprising: a pump, a vaporizer for evaporating the pumped fluid, a branch for bypassing the vaporizer and a distribution valve(s) set configured to control the flow of fluid pumped and distributed between the vaporizer and the branch line, the device further comprising a storage buffer(s), which storage buffer(s) is(are) connected in parallel to each of the two transfer lines via a set of valves.

Abstract: The invention relates to a method for manufacturing a brazed plate type heat exchanger comprising the following steps: a) stacking, with a clearance, a plurality of plates parallel to each other so as to define, between said plates, a plurality of passages suitable for the flow of at least one fluid, said passages being delimited by peripheral edges and at least one passage comprising at least one zone to be supported emerging towards the outside of the passage through at least one opening of a peripheral edge; b) arranging at least one support member in the zone to be supported; c) brazing the stack of plates comprising the support member; and d) removing the support member from the zone to be supported through the opening. According to the invention, the support member is deformable and, in step d), a traction force is exerted on the support member so as to cause a deformation in at least one part of the support member and a translation movement of the support member towards the outside of the passage.

Abstract: The invention relates to a method and facility for manufacturing a cross-linked fiberglass material, in which melted glass is produced in a melting furnace heated via combustion of a fuel with an oxygen-rich oxidant. The melted glass is converted into glass filaments, the filaments are bonded, a sheet is made from the bonded filaments, and the sheet is then cross-linked. The fumes from the melting furnace are used to preheat a combustion reagent in two steps: a first step in which air is heated via heat exchange with the fumes, and a second step in which the combustion reagent is preheated via heat exchange with the hot air. The air is then used in the cross-linking step of the method for converting the melted glass into a fiberglass material.

Abstract: Installation for membrane permeation treatment of feed gas flow containing at least methane and carbon dioxide including first, second, and third membrane separation units and at least one compressor B for aspirating the second permeate, a permeate from the first membrane separation unit being fed to the third membrane separation unit, a retentate from the first membrane separation unit being fed to the second membrane separation. After measuring the aspiration pressure and methane concentration of the second permeate before it is recycled to the feed, the pressure of the second permeate is adjusted according to the measured aspiration pressure and methane concentration.

Abstract: A heat exchanger with several plates arranged in parallel is provided. The heat exchanger has a first series of passages for channeling at least one first fluid and a second series of passages for channeling at least one second fluid. The second fluid being in a heat-exchange relationship with at the first fluid. A mixer is arranged in the passage of the first series. The mixer has at least one first channel for the flow of a first phase of the first fluid in a flow direction. The mixer has at least one second channel for the flow of a second phase of the first fluid. The mixer has at least one opening fluidically connecting the first channel to the second channel.

Abstract: A reformer tube for producing synthesis gas by steam reforming of hydrocarbon-containing input gases is proposed where an outer shell tube is divided by means of a separating tray into a reaction chamber and an exit chamber, a dumped bed of a steam-reforming-active solid catalyst is arranged in the reaction chamber, at least one heat exchanger tube is arranged inside the reaction chamber and inside the dumped catalyst bed, whose entry end is in fluid connection with the dumped catalyst bed and whose exit end is in fluid connection with the exit chamber, the exit end of the heat exchanger tube is fed through the separating tray and opens out into a corrosion-protected inner tube which is disposed in the interior of the shell tube and is in fluid connection with a collection conduit for the synthesis gas product, and a gas-permeable thermal insulation layer is arranged between the inner wall of the shell tube and the outer wall of the inner tube.