Patents Assigned to L'Exploitation Des
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Publication number: 20210283548Abstract: A facility and method for membrane permeation treatment of a feed gas flow containing at least methane and carbon dioxide that includes a compressor, a pressure measurement device, at least one valve, and first, second, third, and fourth membrane separation units for separation of CO2 from CH4 to permeates enriched in CO2 and retentates enriched in CH4, respectively. A temperature of the first retentate is adjusted at an inlet of the second membrane separation unit with at least one heat exchanger as a function of the measured CH4 concentration in such a way so as to reduce the determined difference.Type: ApplicationFiled: June 1, 2021Publication date: September 16, 2021Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Marc CHAREYRE, Veronique GRABIE, Golo ZICK
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Publication number: 20210283549Abstract: A facility and method for membrane permeation treatment of a feed gas flow containing at least methane and carbon dioxide that includes a compressor, a pressure measurement device, at least one valve, and first, second, third, and fourth membrane separation units for separation of CO2 from CH4 to permeates enriched in CO2 and retentates enriched in CH4, respectively. The at least one valve adjusts the number of membranes combined and connected to the flow of gas entering into at least one of the membrane separation units as a function of the pressure recorded by the pressure measurement device.Type: ApplicationFiled: June 1, 2021Publication date: September 16, 2021Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Jean-Marc CHAREYRE, Veronique GRABIE, Golo ZICK
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Publication number: 20210278132Abstract: An air separation device can include: a first compressor and a second compressor for compressing feed air; a first refrigerator and a second refrigerator for cooling the feed air; a pre-purification unit for pre-purifying the feed air; a flow rate measuring unit for measuring the flow rate of the feed air; a main heat exchanger for subjecting the feed air to heat exchange; a purification portion into which the feed air led out from the main heat exchanger is fed, and which separates and purifies product nitrogen and/or product oxygen from the feed air; and a compressor control unit for controlling the feed quantity of the feed air in accordance with an increase or decrease in the production quantity of product nitrogen and/or product oxygen.Type: ApplicationFiled: March 4, 2021Publication date: September 9, 2021Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Takuya KANEDA, Tsuyoshi SUGITANI
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Patent number: 11097953Abstract: Synthesis of silanes with more than three silicon atoms are disclosed (i.e., (SinH(2n+2) with n=4-100). More particularly, the disclosed synthesis methods tune and optimize the isomer ratio by selection of process parameters such as temperature, residence time, and the relative amount of starting compounds, as well as selection of proper catalyst. The disclosed synthesis methods allow facile preparation of silanes containing more than three silicon atoms and particularly, the silanes containing preferably one major isomer. The pure isomers and isomer enriched mixtures are prepared by catalytic transformation of silane (SiH4), disilane (Si2H6), trisilane (Si3H8), and mixtures thereof.Type: GrantFiled: October 11, 2018Date of Patent: August 24, 2021Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc.Inventors: Grigory Nikiforov, Guillaume Husson, Gennadiy Itov, Yang Wang
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Patent number: 11092292Abstract: In a method for reheating an atmospheric vaporizer, a cryogenic liquid is vaporized by heat exchange with ambient air in the atmospheric vaporizer and to reheat the vaporizer, a gas is sent thereto at a temperature of at least 0° C., this gas originating from a cryogenic distillation air separation unit.Type: GrantFiled: February 21, 2020Date of Patent: August 17, 2021Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Jean-Marc Peyron, Fabrice Rivoal, Lian-Ming Sun
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Publication number: 20210247027Abstract: Method for delivering liquefied gas, especially hydrogen, by means of at least one mobile storage facility, especially a storage facility transported by lorry, comprising a step of filling the mobile storage facility with liquefied gas at a source plant, the mobile storage facility containing, after filling, liquefied gas and a fraction of the vaporized gas, the method comprising a movement of the mobile storage facility from the source plant to a receiving station and a transfer of liquefied gas from the mobile storage facility to the receiving station, characterized in that it comprises a step of interim cooling of the liquefied gas contained in the mobile storage facility between the source plant and the receiving station by means of a cooling device comprising a liquefied gas tank and a refrigerating element.Type: ApplicationFiled: February 5, 2021Publication date: August 12, 2021Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Laurent ALLIDIERES, Thomas FAYER, Pierre BARJHOUX
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Patent number: 11084744Abstract: Disclosed are systems and methods for mixing a gas-free liquid oxidant with a process liquid to form a homogeneous and gas-free mixture with minimized degassing. The mixing system comprises an injection device, integrating with a pipe through which a process liquid flows, configured and adapted to inject a gas-free liquid oxidant into the process liquid, and a mixer, fluidly connected to the pipe and the injection device, configured and adapted to mix the process liquid and the gas-free liquid oxidant therein to form a homogeneous and gas-free mixture of the process liquid and the gas-free liquid oxidant with minimal degassing. The method comprises the steps of a). injecting the gas-free liquid oxidant into the process liquid, and b). mixing the gas-free liquid oxidant and the process liquid to form the homogeneous and gas-free mixture. The gas-free liquid oxidant is ozone strong water.Type: GrantFiled: March 28, 2018Date of Patent: August 10, 2021Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc.Inventors: Jan Mante, Vasuhi Rasanayagam, Midhun Joy
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Patent number: 11083991Abstract: Installation for membrane permeation treatment of feed gas containing methane and carbon dioxide that includes first, second, and third membrane separation units. The permeate from the first membrane separation unit is fed to the third membrane separation unit and the retentate from the first membrane separation unit is fed to the second membrane separation unit. The aspiration pressure of the second permeate is adjusted with a compressor according to the aspiration pressure of the second permeate before recycling thereof to the feed gas flow fed to the first membrane separation unit.Type: GrantFiled: December 12, 2019Date of Patent: August 10, 2021Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Francois Barraud, Jean-Marc Chareyre
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Patent number: 11079177Abstract: The present invention relates to a skid-mounted cold box and its prefabricated structure and assembly method. Each prefabricated structure includes a framework and a first panel that is used to enclose sides of the framework. Ring beams of two adjacent prefabricated structures are connected through bolts on site. A second panel connected through bolts encloses the gap between ring beams of the two adjacent prefabricated structures from sides. The present invention cancels all field welding seams and omits the field welding and nondestructive testing operations. The crane can be dismissed after the upper prefabricated structure of the cold box is lifted into place and bolts corresponding to columns on ring beams are connected. The present invention guarantees the connection strength of steel structures relying on bolt-based connection between ring beams and the second panel connected through bolts guarantees the airtightness of the cold box. This effectively reduces field assembly work and saves time and cost.Type: GrantFiled: December 30, 2016Date of Patent: August 3, 2021Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Chenxi Gao, Remy Kurtz, Alain Briglia, Jia Ding
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Patent number: 11079067Abstract: The present invention is to provide a hydrogen refueling system capable to cool down the H2 pre-cooling heat exchanger fast enough when a FCV enters the HRS, so that there is no or very minimal waiting time for the customer before starting refueling. A hydrogen refueling system including a cryogenic fluid tank that stores a cryogenic fluid, a dispenser that supplies H2 to a vehicle, including a heat exchanger that cools H2 with the cold and/or cryogenic fluid provided from the cryogenic fluid tank, an inlet line that sends the cold and/or cryogenic fluid to the heat exchanger from the cryogenic fluid tank, an outlet line that collects the cryogenic fluid fed from the heat exchanger, and an injection valve that is provided in the inlet line.Type: GrantFiled: December 6, 2016Date of Patent: August 3, 2021Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Etienne Werlen, Thierry Ott
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Patent number: 11078141Abstract: The invention relates to a process for producing methanol and to a plant for producing methanol. A first fresh gas suitable for production of methanol is precompressed by a first compressor stage to obtain a second fresh gas. The second fresh gas is merged with a recycle gas stream and further compressed to synthesis pressure in a second compressor stage. Catalytic conversion of the thus obtained synthesis gas stream in a plurality of serially arranged reactor stages with intermediate condensation and separation of the crude methanol reduces the recycle gas amount in the synthesis circuit to such an extent that recycle gas may be directly recycled to the second fresh gas stream, thus ensuring that no recycle gas compressor stage is required and that the total compressor power may be reduced.Type: GrantFiled: August 18, 2020Date of Patent: August 3, 2021Assignee: L'Air Liquide, Socie,été Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Timm Schuhmann
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Patent number: 11079069Abstract: The present invention is to provide a hydrogen refueling system capable to cool down the H2 pre-cooling heat exchanger fast enough when a FCV enters the HRS, so that there is no or very minimal waiting time for the customer before starting refueling. A hydrogen refueling system includes a chiller including a cooling unit that cools a circulating refrigerant by a cooling medium, a dispenser that supplies H2 to a vehicle, including a heat exchanger that cools H2 with the circulating refrigerant provided from the chiller, a circulation line that circulates the circulating refrigerant between the cooling unit and the heat exchanger, a chiller compressor that is provided in the chiller; a cold generation valve that is provided close to an inlet of the heat exchanger in the circulation line.Type: GrantFiled: December 6, 2016Date of Patent: August 3, 2021Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Etienne Werlen, Thierry Ott
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Publication number: 20210231263Abstract: A device for filling a tank or tanks with pressurized gas comprising a circuit comprising a plurality of upstream ends connected respectively to separate pressurized gas sources, at least one compressor, at least one buffer storage, a set of controlled valves and at least one downstream end intended to be connected to the tank(s) to be filled, the device further comprising an electronic control member configured to control the valves and/or the compressor in order to ensure a transfer of gas into the tank from at least one source and/or at least one buffer storage and/or via the compressor, the device comprising a set of sensors for measuring the pressure in the sources and the buffer storages, the control member comprising member for receiving or generating signal representative of the filling demand from a relatively high demand to a relatively low demand, the control member being configured to ensure the transfer of gas into the tank according to at least a first transfer mode using the source having the hType: ApplicationFiled: May 13, 2019Publication date: July 29, 2021Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Francois THIBAUT
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Patent number: 11075084Abstract: Methods for fabricating a 3D NAND flash memory are disclosed. The method includes the steps of forming a hardmask pattern on the hardmask layer, and using the hardmask pattern to form apertures in the alternating layers by selectively plasma etching the alternating layers versus the hardmask layer using a hydrofluorocarbon etching gas selected from the group consisting of 1,1,1,3,3,3-hexafluoropropane (C3H2F6), 1,1,2,2,3,3-hexafluoropropane (iso-C3H2F6), 1,1,1,2,3,3,3-heptafluoropropane (C3HF7), and 1,1,1,2,2,3,3-heptafluoropropane (iso-C3HF7), wherein the first etching layer comprises a material different from that of the second etching layer.Type: GrantFiled: August 31, 2017Date of Patent: July 27, 2021Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Peng Shen, Keiichiro Urabe, Jiro Yokota, Nicolas Gosset
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Patent number: 11073245Abstract: Installation and method for storing and dispensing liquefied hydrogen involving a source of gaseous hydrogen, a liquefier, and two storage reservoirs for liquid hydrogen at determined respective storage pressures, wherein the liquefier includes an inlet connected to the source and an outlet connected in parallel, via a set of valves, to a respective inlet of each storage reservoir.Type: GrantFiled: November 12, 2019Date of Patent: July 27, 2021Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Jean-Marc Bernhardt, Francois Lagoutte
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Publication number: 20210222949Abstract: The invention relates to a system for controlling an argon flow rate of a fluid at the outlet of an assembly of at least one distillation column in order to reach a target dioxygen level (SP).Type: ApplicationFiled: May 22, 2019Publication date: July 22, 2021Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventor: Marc BASTID
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Publication number: 20210222948Abstract: A liquefaction apparatus that automatically adjusts the load on the liquefaction apparatus correspondingly with an upper limit value of contracted power in different time slots, and which is capable of maximizing the amount of liquefied product produced and of achieving optimum operating efficiency is provided.Type: ApplicationFiled: January 22, 2021Publication date: July 22, 2021Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventor: Takuya KANEDA
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Publication number: 20210222832Abstract: Station for filling one or more tank(s) with pressurized gas, in particular pressurized hydrogen, comprising at least two pressurized gas source stores, a transfer pipe having an upstream end connected parallel to the source stores and a downstream end intended to be connected to a tank to be filled, the station comprising a valve assembly for controlling the transfer of gas between the sources and the tank to be filled and an electronic controller connected to the valve assembly and configured to control the valve assembly, the electronic controller being configured to implement successive transfers of gas between the source stores and the tank to be filled via successive pressure balancing sequences, the electronic controller being configured to determine the temperature attained by the gas in the source stores or by the source stores during transfers of gas and, when said attained temperature is below a determined threshold, to prevent or to interrupt this transfer of gas or to reduce the flow of gas transType: ApplicationFiled: January 20, 2021Publication date: July 22, 2021Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Laurent ALLIDIERES, Mathilde WEBER, Etienne WERLEN
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Patent number: 11066319Abstract: The invention relates to a method and facility for manufacturing a fiberglass material, in which melted glass is produced in a melting furnace heated via combustion of a fuel with an oxygen-rich oxidant. The fumes generated are used to preheat a combustion reagent in two steps: a first step in which air is heated via heat exchange with the fumes, and a second step in which the combustion reagent is preheated via heat exchange with the hot air. The air is then used in the method for converting the melted glass into a fiberglass material.Type: GrantFiled: July 28, 2016Date of Patent: July 20, 2021Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Luc Jarry, Youssef Joumani, Gregoire Beasse
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Patent number: 11066300Abstract: A method for achieving a gas with a variable hydrogen to carbon monoxide ratio in a system including splitting a warm raw syngas stream into a first portion and a second portion, the second portioning having a portion flowrate. Sending the first portion of the warm raw syngas stream a carbon monoxide separator, thereby producing a first hydrogen enriched stream and a carbon monoxide rich stream. Sending the second portion of the warm raw syngas stream to a water/gas shift reactor, thereby producing a shifted syngas stream. Combining the first hydrogen enriched stream and the second hydrogen enriched stream and sending the combined stream to a hydrogen separator, thereby producing a product hydrogen stream having a hydrogen flowrate, and varying the hydrogen flowrate by increasing the portion flowrate.Type: GrantFiled: December 6, 2019Date of Patent: July 20, 2021Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Heon-Yong Poh, Alexander Roesch, Joseph T. Stroffolino, IV