Abstract: A stackable modular element comprises a parallelepipedal caisson, the caisson comprising at least one layer of thermal insulation of thickness less than one-third of the width of the caisson, the layer of insulation covering at least the lateral and frontal faces of the caisson and surrounding at least one chamber having a parallelepipedal volume within the caisson, the chamber containing at least one body of material that permits the exchange of mass and/or of heat, the body being parallelepipedal in shape and filling at least part of the chamber, the chamber having an opening on the upper face and/or an opening on the lower face to allow fluid to be transferred to the body from outside the element and/or from the body to outside the element.

Abstract: A method for starting up an air separation plant having a higher-pressure column, a lower-pressure column, and a falling film vaporizer disposed within a lower section of the lower-pressure column is provided. The method can include the steps of: introducing a cooled and compressed air stream into the higher pressure column; withdrawing an oxygen-enriched liquid stream from a bottom section of the higher-pressure column and introducing said oxygen-enriched liquid stream to an upper section of the lower-pressure column; and exchanging heat between nitrogen gas coming from a top section of the higher-pressure column and liquid oxygen from the lower-pressure column within the falling film vaporizer. During a start-up period, flow of liquid oxygen is at least reduced to the closed core. This reduces the available heat exchange area during start up, which increases ?T and ?P in the condenser/reboiler.

Abstract: A plate fin heat exchanger assembly (S) for a cryogenic air separation unit, comprising: a heat exchanger having at least two cryogenic liquid inlets (B,C) at least two cryogenic liquid outlets (B,C), at least one nitrogen-rich stream inlet (D) at a first end of the heat exchanger and at least one nitrogen-rich stream outlet at a second end of the heat exchanger, the heat exchanger configured to receive a flow of at least one nitrogen-rich stream (WN,LPGAN) of the air separation unit at the at least one nitrogen-rich stream inlet and separate flows of at least two cryogenic liquids (LOX,LIN,LR) at the at least two cryogenic liquid inlets; wherein the inlet of the first of the cryogenic liquids is closer to the first end than the outlet of the second of the cryogenic liquids.

Abstract: A method for operating an air separation unit during an unexpected disturbance is provided. The method can include the steps of: determining that a process disturbance has occurred; starting-up a liquid back-up system that is configured to deliver a product gas at a desired product pressure; and introducing compressed air from an air accumulator into the air separation unit at a location that is downstream a main air compressor and upstream a cold box, wherein the compressed air is introduced in an amount that is effective for maintaining nominal operation of the air separation unit during the process disturbance and until the liquid back-up system is delivering the product gas at the desired product pressure.

Abstract: A facility and method for membrane permeation treatment of a feed gas flow containing at least methane and carbon dioxide that includes a compressor, a gas analyser, at least one valve, and first, second, third, and fourth membrane separation units for separation of CO2 from CH4 to permeates enriched in CO2 and retentates enriched in CH4, respectively. A pressure of the feed gas flow is adjusted according to a CH4 concentration of the second retentate.

Abstract: Solid or liquid N—H free, C-free, and Si-rich perhydropolysilazane compositions comprising units having the following formula [—N(SiH3)x(SiH2—)y], wherein x=0, 1, or 2 and y=0, 1, or 2 when x+y=2; and x=0, 1 or 2 and y=1, 2, or 3 when x+y=3 are disclosed. Also disclosed are synthesis methods and applications for the same.

Abstract: To provide a film forming material and a film forming process for forming, at a lower temperature, a Ge-containing Co film including a desired amount of Ge.

Abstract: The invention relates to a tank for storing a cryogenic mixture of liquid and gas, comprising a first casing, a draw-off pipe for drawing off fluid, which has an upstream end connected to said first casing, a filling circuit comprising a first filling pipe with an upstream end to be connected to a fluid source and a downstream end connected to the lower portion of the first casing, said filling circuit comprising a second filling pipe connected to the fluid source and a downstream end connected to the upper portion of the first casing, wherein the upstream ends of said first and second filling pipes are designed to be connected to the same fluid source simultaneously, and a distribution valve assembly which is configured to allow distribution of the fluid in said filling pipes, wherein the tank comprises a sensor assembly which measures the pressure in the first casing, said distribution valve assembly being configured to automatically adjust the pressure in the first casing, during filling, to a predetermine

Abstract: Device and method for filling pressurized-gas tanks, comprising a fluid transfer circuit provided with an upstream end intended to be connected to a source of gas and at least two parallel downstream ends intended to be connected to distinct tanks that are to be filled, the transfer circuit comprising a temperature regulating member for regulating the temperature of the gas transferred from the source towards the downstream ends, the gas temperature regulating member being positioned in the transfer circuit upstream of the at least two downstream ends, which means to say that the gas temperature regulating member is common to the at least two downstream ends, characterized in that the at least two downstream ends of the circuit each comprise a respective control member for controlling the flow rate and/or the pressure of the transferred gas and configured to control the flow rate and/or the pressure in each of the downstream ends independently.

Abstract: In a method for separating air by cryogenic distillation using a column system consisting of a higher pressure column operating at a first pressure and a lower pressure column operating at a second pressure, a first air flow constituting between 75% and 98% of the air sent to the column system compressed to a third pressure above the first pressure, is sent to the higher pressure column, a second air flow constituting between 5% and 25% of the air sent to the column system is compressed to a fourth pressure above the second pressure but lower than the third pressure, is sent to the lower pressure column, a third column separates an argon-enriched flow and the air sent to the lower pressure column constitutes between 10% and 25% of the total air sent to the column system.

Abstract: In a process for supplying oxygen and/or nitrogen and also argon to a geographic zone, the geographic zone comprising n units for air separation by cryogenic distillation, of which a first unit and n-1 second units produce oxygen and/or nitrogen but do not produce argon, the oxygen and/or nitrogen for at least certain clients come from at least one of the n-1 second, non-argon-producing units, and argon for these clients comes from the first unit, where the first unit operates by means of a column system comprising a double column composed of a higher pressure column operating at a first pressure and a lower pressure column, whose bottom is connected thermally to the top of the higher pressure column, operating at a second pressure, which is lower than the first pressure, and of an argon-producing column and a mixing column, wherein the mixing column is fed at the bottom with an auxiliary gas consisting of gaseous nitrogen from the first or the lower pressure column, and at the top with a liquid which is rich

Abstract: Method and device for transferring cryogenic fluid comprising a first tank for distributing cryogenic fluid, a second, receiving cryogenic tank accommodating a cryogenic fluid, a fluid transfer circuit connecting the first and the second tank, the transfer circuit comprising a first pipe that connects the upper parts of the first and second tanks and comprises at least one valve, the transfer circuit comprising a second pipe that connects the lower part of the first tank to the second tank, the second transfer pipe comprising a pump that comprises an inlet connected to the first tank and an outlet connected to the second tank and the pump and the at least one valve of the first pipe being configured to place the upper parts of the first and second tanks in fluidic communication by opening the at least one valve during a transfer of liquid from the first tank to the second tank by way of the pump.

Abstract: A method of co-producing a nitrogen containing stream and a methanol stream, including producing at least an oxygen enriched stream and a nitrogen enriched stream in an air separation unit, introducing at least a portion of the oxygen enriched stream into an oxygen-based reformer, thereby producing a first syngas stream, introducing at least a portion of the first syngas stream into a methanol synthesis reactor, thereby producing at least a hydrogen containing stream and a methanol containing stream, introducing at least a portion of the methanol containing stream into a methanol distillation system, thereby producing a methanol product stream, introducing at least a portion of the nitrogen enriched stream, at least a portion of the first enriched hydrogen containing stream, and at least a portion of the second enriched hydrogen containing stream into an ammonia synthesis reactor, thereby producing an ammonia product stream.

Abstract: In a helium purification process, a stream containing at least 10% of helium, at least 10% of nitrogen in addition to hydrogen and methane is separated to form a helium-enriched stream containing hydrogen, a first stream enriched in nitrogen and in methane and a second stream enriched in nitrogen and in methane, the helium-enriched stream is treated to produce a helium-rich product and a residual gas containing water, the residual gas is treated by adsorption (TSA) to remove the water and the regeneration gas from the adsorption is sent to a combustion unit (O).

Abstract: The invention relates to a method for storing and distributing liquefied hydrogen using a facility that comprises a store of liquid hydrogen at a predetermined storage pressure, a source of hydrogen gas, a liquefier comprising an inlet connected to the source and an outlet connected to the liquid hydrogen store, the store comprising a pipe for drawing liquid, comprising one end connected to the liquid hydrogen store and one end intended for being connected to at least one mobile tank, the method comprising a step of liquefying hydrogen gas supplied by the source and a step of transferring the liquefied hydrogen into the store characterized in that the hydrogen liquefied by the liquefier and transferred into the store has a temperature lower than the bubble temperature of hydrogen at the storage pressure.

Abstract: Disclosed are methods of synthesizing and using Titanium-containing film forming compositions comprising titanium halide-containing precursors to deposit Titanium-containing films on one or more substrates via vapor deposition processes.

Abstract: The invention relates to a method for storing and distributing liquefied hydrogen using a facility that comprises a store of liquid hydrogen at a predetermined storage pressure, a source of hydrogen gas, a liquefier comprising an inlet connected to the source and an outlet connected to the liquid hydrogen store, the store comprising a pipe for drawing liquid, comprising one end connected to the liquid hydrogen store and one end intended for being connected to at least one mobile tank, the method comprising a step of liquefying hydrogen gas supplied by the source and a step of transferring the liquefied hydrogen into the store, characterized in that the hydrogen liquefied by the liquefier and transferred into the store has a temperature lower than the bubble temperature of hydrogen at the storage pressure.

Abstract: A measured quantity of gas is introduced into a gas reservoir via a filling station including a flow meter. The quantity of gas transferred by the filling station to the reservoir is measured by the flow meter. The measured quantity of gas is reduced or increased by a predetermined corrective amount to yield a corrected gas quantity.