Patents Assigned to L'Exploitation Des
  • Patent number: 10704737
    Abstract: A method for filling or withdrawing from a pressurized gas tank. The tank having a wall having a cylindrical overall shape with dimensions and thermophysical properties that are given and known. The method including the regulation of the flow rate of the introduced or withdrawn gas, and/or of the temperature of the introduced gas, to avoid a situation in which the tank reaches a given high temperature threshold or a given low temperature threshold. The method including a step of estimating, by calculating in real time, at least one tank temperature from: the average temperature of the tank wall, the maximum temperature reached by the tank wall, the minimum temperature reached by the tank wall, and in that the flowrate of gas or the temperature of the gas is regulated depending on the calculated tank temperature.
    Type: Grant
    Filed: May 4, 2016
    Date of Patent: July 7, 2020
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Thomas Bourgeois, Fouad Ammouri, Mathilde Weber, Elena Vyazmina
  • Patent number: 10703631
    Abstract: A neon recovering/purifying system including: a recovery vessel that is arranged on an exhaust gas route and stores exhaust gas, the exhaust gas route being branched and extending from a discharge line; a compressor that increases a pressure of the exhaust gas sent out from the recovery vessel, to a third pressure; an exhaust gas flow rate regulating unit that regulates a flow rate of the exhaust gas whose pressure has been increased by the compressor; a first impurity removing unit that removes a first impurity from the exhaust gas; a second impurity removing unit that removes a second impurity from the exhaust gas from which the first impurity has been removed; a pressure increasing vessel that stores purified gas that has been processed by the first impurity removing unit and the second impurity removing unit; a pressure reducing valve that reduces a pressure of the purified gas sent out from the pressure increasing vessel, to the first pressure; and a purified gas flow rate regulating unit that regulates
    Type: Grant
    Filed: September 13, 2016
    Date of Patent: July 7, 2020
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Sayaka Suzuki, Terumasa Koura, Fumikazu Nozawa
  • Publication number: 20200206674
    Abstract: Disclosed in the present invention is a purification system having pipelines arranged at different levels in a height direction, comprising: a first purifier and a second purifier disposed side by side symmetrically; an air input pipeline, an air output pipeline and a waste nitrogen input pipeline, wherein the air input pipeline, the air output pipeline and the waste nitrogen input pipeline are disposed at different heights, the gap between pairs of pipelines being determined so as to facilitate overhaul of three-stem valves, a value W being smaller than a value W when the air input pipeline, the air output pipeline and the waste nitrogen input pipeline are arranged in parallel on the ground, and the purification system further comprises: a three-stem valve platform formed by a framework structure in a number of levels, to facilitate overhaul of the three-stem valves.
    Type: Application
    Filed: December 21, 2019
    Publication date: July 2, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Wenjuan XIANG, Zhiqiang LI, Yunqing SHI, Wenhua WANG
  • Publication number: 20200209113
    Abstract: An apparatus for analyzing the content of at least one contaminant in a liquid cryogen comprising a cylindrical enclosure, an annular enclosure arranged around the cylindrical enclosure, means for dividing a flow of liquid cryogen in two, means for delivering a first part of the liquid cryogen to the cylindrical enclosure, means for delivering a second part of the liquid cryogen to the annular enclosure, a pipe connected to the cylindrical enclosure to allow vaporized liquid to pass through, a pipe connected to the annular enclosure to allow vaporized liquid to pass through, a heater for heating the cylindrical enclosure vessel and means for stopping the delivery of liquid cryogen to the cylindrical enclosure.
    Type: Application
    Filed: May 18, 2018
    Publication date: July 2, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Patrick LE BOT, Frederic CRAYSSAC, Benoit DAVIDIAN, Mathieu LECLERC
  • Publication number: 20200208912
    Abstract: Disclosed in the present invention are a heat exchanger assembly and a method for assembling the heat exchanger assembly.
    Type: Application
    Filed: December 21, 2019
    Publication date: July 2, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventor: Remy KURTZ
  • Patent number: 10696922
    Abstract: A process and a plant are specified, with which free fatty acids can be obtained in a simple manner by hydrolysis of fatty acid alkyl esters, especially fatty acid methyl esters (FAME), or alternatively of fatty acid triglycerides present in oils and fats of vegetable and animal origin. According to the invention, a portion of the free fatty acids already produced is recycled back into the reaction mixture, which results in self-acceleration of the hydrolysis reaction.
    Type: Grant
    Filed: June 27, 2017
    Date of Patent: June 30, 2020
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Ingo Bauer, Armin Brandner, Gunter Brauner, Matthias Kasper, Peter Potschacher
  • Publication number: 20200200473
    Abstract: A method for reducing heat bumps following regeneration of adsorbers in an air separation unit is provided. The air separation unit can include a front end purification unit, a main air compressor, a main heat exchanger, a distillation column system, a regeneration gas heater, and a regeneration gas cooler, wherein the front end purification unit comprises a first adsorber and a second adsorber. The method can include the steps of: regenerating the first adsorber while the second adsorber operates in an adsorption cycle, wherein the step of regenerating the first adsorber further includes the steps of heating the first adsorber and then cooling the first adsorber, wherein during the step of cooling the first adsorber, a regeneration gas sourced from the distillation column system and cooled in the main heat exchanger is further cooled in a regeneration gas cooler prior to being used to cool the first adsorber.
    Type: Application
    Filed: December 21, 2018
    Publication date: June 25, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Paul KONG, Minh Huy PHAM
  • Publication number: 20200197890
    Abstract: A reactor for conducting exothermic equilibrium reactions, especially for the performance of methanol synthesis by heterogeneously catalysed conversion of synthesis gas, is proposed, which enables readjustment and hence optimization of the reaction conditions along the longitudinal coordinate of the reactor. For this purpose, in accordance with the invention, the reactor is divided into a multitude of series-connected reaction cells, each of which comprises a preheating zone, a cooled reaction zone, one or more cooling zones and a deposition zone for condensable reaction products. In this way, the reaction conditions are adjustable to the respective, local composition of the reaction mixture and variable over the reactor length.
    Type: Application
    Filed: April 26, 2018
    Publication date: June 25, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Frank CASTILLO-WELTER, Stephane HAAG, Robert FRIND, Timm SCHUHMANN, Andreas OCHS, Marc WAGNER, Solene VALENTIN
  • Publication number: 20200200472
    Abstract: A method for reducing process disturbances during pressurization of an adsorber in an air separation unit is provided, in which the air separation unit includes a front end purification unit and an air buffer tank. In one embodiment, the method can include the steps of: pressurizing a first adsorber while a second adsorber operates in an adsorption cycle, wherein the step of pressurizing the first adsorber further includes the steps of withdrawing a pressurized air stream from the air buffer tank and introducing the pressurized air stream to the first adsorber until the first adsorber is at a target pressure, wherein the air buffer tank is in fluid communication with the booster air compressor, wherein the method further includes the step of continually sending a first portion of air flow from the booster air compressor to the air buffer tank and continually sending a second portion of air flow from the booster air compressor to a system of columns within a cold box for rectification therein.
    Type: Application
    Filed: December 21, 2018
    Publication date: June 25, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Paul KONG, Minh Huy PHAM
  • Publication number: 20200199054
    Abstract: A process for conducting exothermic equilibrium reactions, especially for the performance of methanol synthesis by heterogeneously catalysed conversion of synthesis gas, is proposed, which enables readjustment and hence optimization of the reaction conditions along the longitudinal coordinate of the reactor. For this purpose, in the process according to the invention, a reactor is used which is divided into a multitude of series-connected reaction cells, each of which comprises a preheating zone, a cooled reaction zone, one or more cooling zones and a deposition zone for condensable reaction products. In this way, the reaction conditions are adjustable to the respective, local composition of the reaction mixture and variable over the reactor length.
    Type: Application
    Filed: April 26, 2018
    Publication date: June 25, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Frank CASTILLO-WELTER, Stephane HAAG, Robert FRIND, Timm SCHUHMANN, Andreas OCHS, Marc WAGNER, Solene VALENTIN
  • Patent number: 10689405
    Abstract: Titanium-containing film forming compositions comprising titanium halide-containing precursors are disclosed. Also disclosed are methods of synthesizing and using the disclosed precursors to deposit Titanium-containing films on one or more substrates via vapor deposition processes.
    Type: Grant
    Filed: May 1, 2018
    Date of Patent: June 23, 2020
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Antonio Sanchez, Jean-Marc Girard, Grigory Nikiforov, Nicolas Blasco
  • Patent number: 10690406
    Abstract: The invention relates to a method for low-temperature cooling/liquefaction of a working fluid, in particular a working fluid including helium or consisting of pure helium by means of a refrigerator/liquefier that includes a working circuit provided with a compressor station and a cold box. The refrigerator/liquefier subjects the working gas within the working circuit to a cycle that includes, in series: compressing the working fluid within the compressor station, cooling and decompressing the working fluid in the cold box, and heating the working fluid with a view to the return thereof to the compressor station. The compressor station includes one or more compression levels, each one using one or more compressors mounted on landings.
    Type: Grant
    Filed: November 4, 2010
    Date of Patent: June 23, 2020
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Jean-Marc Bernhardt, Frederic Andrieu, Franck Delcayre, Fabien Durand, Veronique Grabie
  • Publication number: 20200188843
    Abstract: Facility and method for membrane permeation treatment of a feed gas stream containing at least methane and carbon dioxide including first, second, and third membrane separation units each including at least one membrane that is more permeable to carbon dioxide than to methane, wherein a permeate from the first membrane separation unit is fed to the third membrane separation unit and a retentate from the first membrane separation unit is fed to the second membrane separation unit. A compressor B adjusts the third-permeate suctioning pressure as a function of the feed gas stream pressure and the second retentate methane concentration.
    Type: Application
    Filed: December 12, 2019
    Publication date: June 18, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Francois BARRAUD, Jean-Marc CHAREYRE
  • Publication number: 20200188841
    Abstract: Installation for membrane permeation treatment of feed gas containing methane and carbon dioxide that includes first, second, and third membrane separation units. The permeate from the first membrane separation unit is fed to the third membrane separation unit and the retentate from the first membrane separation unit is fed to the second membrane separation unit. The aspiration pressure of the second permeate is adjusted with a compressor according to the aspiration pressure of the second permeate before recycling thereof to the feed gas flow fed to the first membrane separation unit.
    Type: Application
    Filed: December 12, 2019
    Publication date: June 18, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Francois BARRAUD, Jean-Marc CHAREYRE
  • Publication number: 20200188838
    Abstract: The invention relates to a process for regenerating a laden scrubbing medium from a gas scrubbing for purifying raw synthesis gas in which the laden scrubbing medium is at least partially freed of bound gas constituents in a regeneration stage to obtain a regenerated scrubbing medium. According to the invention it is provided that after withdrawal from the regeneration stage the regenerated scrubbing medium is supplied to an intermediate vessel and the regenerated scrubbing medium is withdrawn from the intermediate vessel and supplied to an absorption apparatus for purifying raw synthesis gas.
    Type: Application
    Filed: December 12, 2019
    Publication date: June 18, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Sophia SCHMIDT, Alfred GUBRINSKI, Christian FREY, Dorit RAPPOLD, Sharon CORBET
  • Publication number: 20200191478
    Abstract: Disclosed in the present invention are a cold box steel structure and method for prefabricating and transporting the cold box steel structure.
    Type: Application
    Filed: December 17, 2019
    Publication date: June 18, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Remy KURTZ, Lasad JAOUANI, Vincent GUERET
  • Publication number: 20200191689
    Abstract: The invention relates to a method for analyzing the content of at least one contaminant in a cryogenic liquid, wherein a known amount of liquid L constituting the initial liquid is injected at the pressure P into an enclosure; a predetermined fraction of the liquid present in the enclosure is vaporized by heating same; the vapor thus generated is discharged from the vaporizing enclosure to maintain a pressure no higher than the pressure P during the vaporization phase; the amount of liquid thus vaporized, less than L, is precisely controlled so that the amount of contaminant in the residual liquid present in the enclosure is substantially equal to that of the initial liquid, which implies that the concentration thereof is multiplied by a previously determined factor; a sample of residual liquid is collected; the contaminant content is measured after total vaporization of the residual liquid sample; and the contaminant content in the initial liquid is deduced from the measurement of contaminant in the residual
    Type: Application
    Filed: May 18, 2018
    Publication date: June 18, 2020
    Applicant: l'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Patrick LE BOT, Frédéric CRAYSSAC, Benoit DAVIDIAN, Mathieu LECLERC
  • Publication number: 20200191334
    Abstract: In a method for reheating an atmospheric vaporizer, a cryogenic liquid is vaporized by heat exchange with ambient air in the atmospheric vaporizer and to reheat the vaporizer, a gas is sent thereto at a temperature of at least 0° C., this gas originating from a cryogenic distillation air separation unit.
    Type: Application
    Filed: February 21, 2020
    Publication date: June 18, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Jean-Marc PEYRON, Fabrice RIVOAL, Lian-Ming SUN
  • Patent number: 10682621
    Abstract: A plant and a process for carrying out the continuous production of fatty alcohol from fatty acid ester by catalytic trickle-bed hydrogenation, comprising shaft reactors each containing at least one catalyst fixed bed, which are connected with each other via pipe conduits such that they can be traversed by the educt/product mixture one after the other, in freely selectable order.
    Type: Grant
    Filed: October 14, 2016
    Date of Patent: June 16, 2020
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Armin Brandner, Manfred Hoffmann, Fredrik Pomrehn, Peter Potschacher
  • Patent number: 10683221
    Abstract: A device and method for injection of oxygen-rich gas into a body of liquid with oxygen recycling are disclosed. The device comprises a rotary hollow shaft vertically passing through a float partially immersed in the liquid, an impeller attached to the lower end of the rotary hollow shaft, a columnar structure, surrounding the rotary hollow shaft, mounted on the bottom side of the float and vertically extending into the liquid, a gas diffusion chamber formed by the columnar structure, the float and the liquid surface under the float, and a gas injection conduit passing through the float for delivering the oxygen gas into the gas diffusion chamber, wherein a vacuum is generated in the body of the liquid around the impeller when the impeller is driven to rotate, so that the oxygen-rich gas in the gas diffusion chamber is sucked into the body of the liquid and mixed therein.
    Type: Grant
    Filed: December 5, 2018
    Date of Patent: June 16, 2020
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc.
    Inventors: Milson Carvalho, Maicon Neryz, Ivan Pajolli, Joerg Schwerdt, Vasuhi Rasanayagam, Chunqiong Shi