Patents Assigned to L'Exploitation Des
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Patent number: 10888834Abstract: The invention relates to an exchanger-reactor comprising at least three stages with at least one stage comprising both: millimetric channels at least partially covered with a catalyst for stimulating a steam reforming reaction, and millimetric channels at least partially covered with a catalyst for stimulating a water gas reaction.Type: GrantFiled: August 19, 2016Date of Patent: January 12, 2021Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Matthieu Flin, Marie Basin, Olivier Dubet, Daniel Gary, Laurent Prost, Solène Valentin, Marc Wagner
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Patent number: 10890376Abstract: In a method for separating a synthesis gas containing carbon monoxide and hydrogen, a synthesis gas flow from a synthesis gas source is compressed in a compressor and separated into at least three gaseous products. If there is insufficient synthesis gas, at least three separation products are recycled in the compressor in order to separate said products.Type: GrantFiled: October 28, 2016Date of Patent: January 12, 2021Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Bertrand Demolliens, Antoine Hernandez, Jean-Marc Tsevery
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Publication number: 20210003253Abstract: Device and method for filling pressurized-gas tanks, comprising a fluid transfer circuit provided with an upstream end intended to be connected to a source of gas and at least two parallel downstream ends intended to be connected to distinct tanks that are to be filled, the transfer circuit comprising a temperature regulating member for regulating the temperature of the gas transferred from the source towards the downstream ends, the gas temperature regulating member being positioned in the transfer circuit upstream of the at least two downstream ends, which means to say that the gas temperature regulating member is common to the at least two downstream ends, characterized in that the at least two downstream ends of the circuit each comprise a respective control member for controlling the flow rate and/or the pressure of the transferred gas and configured to control the flow rate and/or the pressure in each of the downstream ends independently.Type: ApplicationFiled: July 2, 2020Publication date: January 7, 2021Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Anh Thao THIEU, Louis DEBESOMBES, Vincent FAIRY
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Patent number: 10882744Abstract: An apparatus and method for purifying a raw hydrogen gas stream of chloramines and chlorine is provided. The explosive chloramines compounds can be effectively captured by the carbon adsorbent without accumulating on the carbon surface. Rather, the chloramines are converted via decomposition, into non-explosive products with catalytic effect of the carbon material. Chlorine reacts with impregnated reducing agent on the carbon surface to form the solid products, which can be adsorbed on the carbon surface. The purified hydrogen gas contains little to no trace of chloramines and chlorine impurities, thereby making the hydrogen gas suitable for liquid hydrogen production.Type: GrantFiled: November 15, 2018Date of Patent: January 5, 2021Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Richard Pawulski, Sylvain Houle, Brian Fillion, Yudong Chen, Graeme William Norval
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Publication number: 20200407653Abstract: Facility for the treatment of a feed gas stream comprising at least methane and carbon dioxide, said facility comprising: an oil-lubricated or water-lubricated vane-type compressor making it possible to compress the feed gas stream, and a membrane separation unit capable of receiving the compressed gas stream and of separating the methane from the carbon dioxide.Type: ApplicationFiled: June 26, 2020Publication date: December 31, 2020Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Francois BARRAUD
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Publication number: 20200408466Abstract: The invention concerns a heat exchanger comprising several plates arranged parallel to one another and to a longitudinal direction so as to define a first series of passages for channeling at least one first fluid and a second series of passages for channeling at least one second fluid which is to be brought into a heat-exchange relationship with at least said first fluid, a mixer device being arranged in said at least one passage of the first series and comprising at least one first channel for the flow of a first phase of the fluid in the longitudinal direction, at least one second channel for the flow of a second phase of the fluid, and a plurality of orifices fluidically connecting the first channel to the second channel, said orifices occupying successive positions in the longitudinal direction. According to the invention, the distances between two successive positions, measured parallel to the longitudinal direction, are variable.Type: ApplicationFiled: March 21, 2019Publication date: December 31, 2020Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Marine ANDRICH, Natacha HAIK-BERAUD, Philippe GRIGOLETTO, Jean-Marc PEYRON, Ahlem DELEGUE
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Patent number: 10874983Abstract: There is proposed an efficient recovery of methanol from waste gases loaded with methanol in an integrated flow chart for the production and processing of methanol. The methanol fractions separated from the waste gases are recovered within the already existing, distillative processing of the crude methanol to pure methanol, so that no separate apparatuses are required for the recovery of the methanol from the loaded scrubber waste waters. The valuable substance methanol is recovered and the impact on the environment is reduced. By means of particular aspects of the invention the need for water as washing agent can be reduced further.Type: GrantFiled: December 6, 2016Date of Patent: December 29, 2020Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Karin Huder, Veronika Gronemann, Tobias Oelmann
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Patent number: 10875767Abstract: A process and a plant for cooling a synthesis gas produced by catalytic steam reformation of a hydrocarbonaceous feed gas, which is cooled by heat exchange with boiler feed water for its conversion into steam, by separating the resulting aqueous condensate, wherein the further cooling is effected in that the gas passes through several series-connected cooling stages and comprises the heat exchange with the feed gas, with degassed and non-degassed boiler feed water for generating the steam required for the steam reformation, and with ambient air, and wherein condensate obtained after the last cooling stage is separated from the gas and the gas is discharged for the further treatment, wherein at least after a further cooling stage upstream of the last cooling stage a hot aqueous condensate is separated from the gas.Type: GrantFiled: July 4, 2016Date of Patent: December 29, 2020Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Jean-Philippe Tadiello, Yue Chen
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Publication number: 20200398217Abstract: At least some VOCs are removed from a feed gas in an adsorption unit comprising at least three adsorbers following a pressure cycle with a phase shift, wherein the feed gas comprises at least methane, carbon dioxide and volatile organic compounds (VOCs). The VOC depleted gas is fed to at least one membrane separation to produce a carbon dioxide-enriched permeate and a methane-enriched retentate. The flow of the feed gas stream is adjusted based upon one or both of a pressure or methane concentration of the gas stream entering the membrane separation unit and/or a pressure in the adsorption unit.Type: ApplicationFiled: June 18, 2020Publication date: December 24, 2020Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Francois BARRAUD, Jean-Marc CHAREYRE
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Publication number: 20200395221Abstract: A method of an embodiment includes (i) a step of supplying a first gas to a chamber, wherein the first gas is perfiuorotetraglyme gas, and (ii) a step of generating plasma of a second gas for etching of a porous film in order to etch the porous film at the same time as the step of supplying a first gas or after the step of supplying a first gas. Partial pressure of the first gas in the chamber or pressure of the first gas in the chamber when only the first gas is supplied to the chamber is higher than critical pressure causing capillary condensation of the first gas in the porous film and is lower than saturated vapor pressure of the first gas at a temperature of the workpiece during execution of the step of supplying a first gas.Type: ApplicationFiled: May 9, 2018Publication date: December 17, 2020Applicants: Tokyo Electron Limited, L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, UNIVERSITE D'ORLEANS, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventors: Shigeru TAHARA, Keiichiro URABE, Peng SHEN, Christian DUSSARRAT, Jean-Francois DE MARNEFFE, Remi DUSSART, Thomas TILLOCHER
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Publication number: 20200395212Abstract: The invention relates to a process for the preparation of a semiconductor material comprising at least one entirely monocrystalline semiconductor layer, said process comprising the steps of preparation of the surface of a first substrate to receive a monocrystalline silicon layer; deposition by Plasma-Enhanced Chemical Vapor Deposition (PECVD) of a layer of monocrystalline silicon by epitaxial growth with a growth rate gradient on the silicon layer monocrystalline obtained in step (i); and epitaxial growth of a monocrystalline layer of a semiconductor material on the monocrystalline silicon layer obtained in step (ii), to thus obtain a material comprising at least one entirely monocrystalline semiconductor layer. The invention also relates to a multilayer material comprising a monocrystalline layer of semiconductor material.Type: ApplicationFiled: November 15, 2018Publication date: December 17, 2020Applicants: Centre national de la recherche scientifique, INSTITUT PHOTOVOLTAÏQUE D'lLE DE FRANCE (IPVF), ECOLE POLYTECHNIQUE, L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE, TOTAL SA, ELECTRICITE DE FRANCEInventors: Père ROCA I CABAROCCAS, Wanghua CHEN, Romain CARIOU
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Patent number: 10865351Abstract: The invention relates to a process and an apparatus for producing an olefin-containing feed stream for a steam reforming plant. According to the invention, the olefin-containing hydrocarbon starting material is for this purpose heated, vaporized and catalytically hydrogenated. The hydrogenation product stream obtained is separated in a separation apparatus into a gaseous reforming feed stream, which is fed to a steam reforming plant, and a gaseous recycle stream. Here, the entry temperature of the hydrogenation input stream into the hydrogenation reactor is regulated via the degree to which it is heated and/or via the size of the recycle stream. Safe operation of the hydrogenation reactor over a wide range of olefin contents in the hydrocarbon feed is made possible in this way.Type: GrantFiled: November 17, 2017Date of Patent: December 15, 2020Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Swatantra Kumar Shrivastava, Mrityunjoy Samaddar
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Patent number: 10866024Abstract: Method for separating air by cryogenic distillation, wherein at least part of the air to be distilled is boosted in an air booster, compressed air is allowed to expand in at least one expansion turbine and, if the pressure drop between two points of the booster passes under a threshold and/or a flow of the booster passes under a minimum flow of the booster, part of the air boosted in the booster is allowed to expand without having been cooled between the booster and the expansion turbine and the boosted expanded air is sent upstream or downstream of the at least one turbine, without having been cooled in the heat exchanger, after having been boosted.Type: GrantFiled: August 3, 2018Date of Patent: December 15, 2020Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Cavagne Patrice, Nicolas Chamontin, Benedicte Dos Santos, Laurent Richaume
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Publication number: 20200385269Abstract: In a helium purification process, a stream containing at least 10% of helium, at least 10% of nitrogen in addition to hydrogen and methane is separated to form a helium-enriched stream containing hydrogen, a first stream enriched in nitrogen and in methane and a second stream enriched in nitrogen and in methane, the helium-enriched stream is treated to produce a helium-rich product and a residual gas containing water, the residual gas is treated by adsorption (TSA) to remove the water and the regeneration gas from the adsorption is sent to a combustion unit (O).Type: ApplicationFiled: June 5, 2020Publication date: December 10, 2020Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Erwan LE GULUDEC, Antoine HERNANDEZ
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Publication number: 20200386486Abstract: The invention relates to a heat exchanger for vaporizing a coolant fluid by heat exchange with a calorigenic fluid, said exchanger comprising several parallel plates defining a plurality of passages between them which are suitable for the coolant fluid or calorigenic fluid to flow, a first wave and a second wave extending between two successive plates so as to define a plurality of channels within the same passage, said first and second waves comprising two adjacent edges, at least one assembly member extending from one edge to the other so as to connect the waves to one another.Type: ApplicationFiled: April 12, 2018Publication date: December 10, 2020Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Guillaume CARDON, Frederic CRAYSSAC, Philippe GRIGOLETTO, Natacha HAIK-BERAUD, Frederic ROUSSEAU, Marc WAGNER
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Patent number: 10858271Abstract: Disclosed are methods for continuous production of ozone strong water, the methods comprising the steps of injecting an acidification agent into a pressurized feed water to maintain a pH value of the pressurized feed water below 7, diffusing a two-phase mixture of O2-O3 gas and recirculated water into a body of acidic pressurized water to dissolve ozone into the acidic pressurized water. The disclosed methods include simultaneously maintaining a start-up mode in an upper portion of the dissolution column that favors high efficiency of ozone mass transfer into the acidic pressurized water and a steady state mode in a lower portion of the dissolution column that favors a high concentration of dissolved ozone in the acidic pressurized water coexistent in the body of the acidic pressurized water, wherein an ozone concentration gradient is formed along a height of the body of the acidic pressurized water.Type: GrantFiled: July 26, 2018Date of Patent: December 8, 2020Assignees: L'Air Liquide, SociétéAnonyme pour l'Etude et l'Exploitation des Procédés Claude, American Air Liquide, Inc.Inventors: Jan Mante, Vasuhi Rasanayagam, Midhun Joy, Rovshan Mahmudov, Siavash Isazadeh
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Patent number: 10859210Abstract: A device for supplying pressurized fluid, including a first valve accommodating an internal fluid circuit, the device including a second valve including an internal circuit, the second valve forming a separate physical entity from the first valve, the first valve and the second valve including respective coupling members that form a male/female quick-connection system for removably connecting the second valve to the first valve, the internal circuits including a set of valves configured to allow or prevent the flow of the fluid towards an outlet of the device when the second valve is coupled to the first valve via the quick-connection system.Type: GrantFiled: February 11, 2020Date of Patent: December 8, 2020Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Renaud Ligonesche, Antoine Frenal, Benjamin Fischer
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Publication number: 20200376508Abstract: The invention relates to a device for injecting a fluid, in particular a cryogenic fluid, the device comprising a fluid feed head and a fluid dispenser body, detachably mounted on said feed head, said feed head comprising a groove for circulating the fluid fed to said body, said groove being closed when the body is mounted on the feed head and said groove being open when the feed head and the body are detached from one another.Type: ApplicationFiled: November 30, 2017Publication date: December 3, 2020Applicants: Air Liquide France Industrie, L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges ClaudeInventors: Jo ALGOET, Alain BRANGEON, Michel PICHOU, Christian REYMOND
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Patent number: 10851000Abstract: Disclosed are systems for continuous production of ozone strong water, the systems comprising an injection device that injects an acidification agent into a pressurized feed liquid, a diffuser device that injects ozone into a body of the acidic pressurized feed water, and injection nozzles each controlled by a valve that adjust a flow rate of the ozone strong water discharged from a dissolution column to match a flow rate of the acidic pressurized feed water fed to the dissolution column, thereby maintaining a start-up mode in an upper portion of the dissolution column that favors a high efficiency of ozone mass transfer and a steady-state mode in a lower portion of the dissolution column that favors a high dissolved ozone concentration coexistent in the body of the acidic pressurized liquid, wherein a concentration gradient of dissolved ozone is formed along a height of the body of the acidic pressurized liquid.Type: GrantFiled: July 26, 2018Date of Patent: December 1, 2020Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc.Inventors: Jan Mante, Vasuhi Rasanayagam, Midhun Joy, Rovshan Mahmudov, Siavash Isazadeh
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Patent number: 10852066Abstract: A single-component exchanger-reactor including, from bottom to top in the direction of manufacture a distribution region, an inlet connector and an outlet connector, each in the form of a half cylinder and adjoining the distribution region on either side; an inlet located on the front face of the inlet connector, an outlet located on the front face of the outlet connector; an exchange region consisting of reactive channels and product channels; with each connector including supports in the inner upper part thereof.Type: GrantFiled: November 23, 2017Date of Patent: December 1, 2020Assignee: L'Air Liquide, Société Anonyme pour l'Etude at l'Exploitation des Procédés Georges ClaudeInventors: Raphaël Faure, Olivier Dubet, Pascal Del Gallo, Matthieu Flin