Abstract: Polyimidesulfone and polyimideketone resins are rendered moldable while still retaining solvent resistance and high temperature physical and mechanical properties by incorporating an aromatic diaminopolysiloxane at a level between about 1 and about 20 mole % of the total diamine content, into the polymer.
Abstract: A functional chromium electroplating bath and process is disclosed. The bath comprises chromic acid, sulfoacetic acid, iodate and a nitrogen organic compound. Such a bath gives chromium deposits which are both bright and adherent.
Abstract: A method of treating a chromium electroplating bath which contains an alkyl sulfonic acid to prevent heavy scale build-up of lead dioxide on lead or lead alloy anodes used therein is described herein. The method involves applying a voltage across the electrodes in said bath which is greater than the normal operating voltage during electrodeposition of chromium.
Abstract: The present invention relates to reaction mixtures and processes which employ an .omega.-phase catalyst for carrying out displacement reactions at a substantially enhanced rate.
Abstract: An apparatus for applying a phototool to a light sensitive substrate by means of a roller for applying the phototool to the substrate and a vacuum restraining means for restraining the phototool to maintain it under tension during application of the phototool to the substrate.
Abstract: What is described herein is a process of making a U.V. stabilized PVC article wherein the surface region of the article is modified with a U.V. stabilizer and the treated surface is substantially free of residual stabilizer thereon. The process includes the steps of (a) applying a solution of a U.V. stabilizer in a solvent which is capable of swelling the PVC but is otherwise non-aggressive thereto, and (b) displacing residual solution remaining on said thus treated surface by a liquid which is non-miscible with said solvent.In the preferred form of the invention, step (b) is carried out by contacting the treated surface with water to cause physical removal of the residual solution out of its position on the treated surface, such as by agitation, a jet stream, ultrasonics, and the like.
Abstract: Haze-free tin oxide coatings are made from an organotin compound which ordinarily gives only hazy coatings. The improvement comprises first forming an undercoat of a haze-free tin oxide film on a substrate, preferably by decomposition of monophenyltin trichloride. Thereafter the tin oxide overcoating assumes the haze-free characteristics of the undercoat film.
Abstract: Improved nebulizable coating compositions for making high quality, fluorine-doped tin oxide coatings having a low sheet resistance and high visible light transmission includes a mixture of less than 95 wt. % of monobutyltin trichloride, less than 50 wt. % of an inorganic fluorine dopant, which is ammonium fluoride, ammonium bifluoride or dibutyltin difluoride, and the rest is a mixture of solvents.
Abstract: A process for modifying the surface region of a polymer article by incorporating one or more ingredients therein. Such ingredients may be ultraviolet light stabilizers, antioxidants, anti-static agents, pigments and the like. The polymer article, e.g. a sheet of polyvinyl chloride, is immersed in a liquid (e.g. water) and the immersed article is contacted with a solution of the ingredient in a solvent. The liquid must be one which is non-aggressive towards the article and must also be immiscible with the solvent. Any residual solution remaining on the contacted surface may be displaced therefrom, preferably by directing a jet of water onto the contacted surface, while avoiding escape of any solvent into the atmosphere.
Abstract: An improved process and composition for the preparation of nickel or nickel alloy electrodeposits is provided. The process involves passing current from a anode to a cathode through an aqueous acidic electroplating solution containing zinc ions as impurities with the combination of at least one nickel compound, saccharin, and a sulfonated acetylenic compound or salt thereof, particularly propyne sulfonic acid.The invention is particularly useful for electroplating nickel onto a zinc die cast substrate, where zinc ion impurity build-up in the bath occurs.
Abstract: A composition including a mixture of UV curable urethane acrylate and a urethane diacrylate compounds provides an aqueous alkaline developable, flexible solder mask having excellent electrical insulation resistance under hydrolytic testing conditions at elevated temperatures.
Abstract: What is described herein is a method of electroplating an adherent chromium deposit on a chromium substrate. The process is characterized by chemically oxidizing the chromium substrate before starting the electrodeposition of chromium thereon. A suitable chemical oxidizing agent is hydrogen ion, which can be furnished by a dilute acid solution. The invention is applicable to any chromium electroplating bath, including high energy efficient chromium baths, such as HEEF-40 baths, which are presently in commercial use.
Abstract: A composition including a mixture of UV curable urethane acrylate and a urethane diacrylate compounds provides an aqueous alkaline developable, flexible solder mask having excellent electrical insulation resistance under hydrolytic testing conditions at elevated temperatures.
Abstract: High photo resolution of over 100 lines is obtained for solder masks of thicknesses greater than 0.002 in. (0.005 cm) with liquid photopolymers of special compositions deposited from mesh screens over printed wiring board traces and photoexposed with a phototool image in contact with the photopolymer. Special interrelated properties of the liquid photopolymer interacting in an explicit process of screen depositing two adjacent liquid polymer layers include freedom from volatiles, a paste-like viscosity permitting use with mesh screens of about 60 mesh to obtain a uniform thickness layer free of bubbles and mesh marks, solder mask insulator and heat resistance characteristics, an ability to photo flash through a phototool image in contact with one layer surface and the other surface exposed to air to polymerize through a significant thickness of about one-third of the layer thickness, photo response to polymerize to a depth of about 0.02 in. (0.
Abstract: A tin oxide coated article characterized by including a transparent, haze-free tin oxide coating on a substrate, such as glass. The tin oxide coating is formed by deposition from a liquid coating composition including an organotin compound, such as an alkyltin trichloride, and a haze-reducing additive, such as a fluorocarboxylic acid or acid anhydride.
Abstract: Transparent, non-iridescent, infrared-reflecting glass window structures which are haze-free are provided herein. These structures comprise a glass sheet, an infrared-reflecting tin oxide coating on one major surface of the sheet, and an iridescence-reducing tin oxide coating on the opposed major surface of the sheet. The iridescence-reducing tin oxide coating is particularly characterized by being haze-free by virtue of its being made by contacting said sheet with monophenyltin trichloride in an oxygen-containing atmosphere.
Abstract: Polyimides or poly(amide-imides), especially those containing a polysiloxane unit are improved by heating such polymers or their polyamic acid precursors with a polyfunctional aromatic compound. The polyfunctional aromatic compound is one which contains at least two reactive groups which may be --NH.sub.2, --COOH, --OH or secondary amino groups with at least one of the reactive groups being --NH.sub.2 or --COOH.
Abstract: An improved liquid coating composition for producing high quality, high performance fluorine-doped tin oxide coatings by chemical vapor deposition includes the reaction product of a reactive fluorine dopant compound and an organotin compound, preferably 1-30 wt. % of the fluorine dopant and 70-99 wt. % of the organotin compound. The preferred liquid coating composition includes the reaction product of trifluoroacetic acid and monobutyltin trichloride.
Type:
Grant
Filed:
July 18, 1986
Date of Patent:
March 15, 1988
Assignee:
M&T Chemicals Inc.
Inventors:
David A. Russo, Georg H. Lindner, Marinus K. Schilders
Abstract: This invention relates to organotin compounds containing fluorine which are particularly useful for forming fluorine-doped tin oxide coatings by the chemical vapor deposition method. In the preferred embodiment, the compound is monobutyldichlorotin trifluoroacetate, which is prepared by reaction of monobutyltin trichloride and trifluoroacetic acid.