Patents Assigned to Mitsui Petrochemical Industries, Ltd.
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Patent number: 5641548Abstract: In accordance with the present invention, there are provided blow molded articles which are composed of specific copolyesters or specific polyester resin compositions and which are highly oriented so that the stretch index as defined by the following equations becomes not less than 130 cm. ##EQU1## The blow molded articles thus provided are excellent in transparency and also excellent in moldability and gas barrier properties and, moreover, excellent also in economical efficiency.Type: GrantFiled: September 9, 1994Date of Patent: June 24, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuhito Yamamoto, Hiroji Niimi, Yoji Yamamoto, Susumu Hatabu
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Patent number: 5641843Abstract: A process for producing an alpha-olefin polymer, which comprises polymerizing an alpha-olefin in the presence of a catalyst formed from(A) a solid catalyst component comprising an inorganic carrier and deposited thereon a compound of a transition metal of Group IVB of the periodic table treated with an organometallic compound, and(B) an aluminoxane.Type: GrantFiled: November 17, 1995Date of Patent: June 24, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Toshiyuki Tsutsui, Akinori Toyota, Norio Kashiwa
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Patent number: 5639829Abstract: Disclosed are a polypropylene composition comprising 95-55 parts by weight of polypropylene (A) and 5-45 parts by weight of an ethylene/1-butene random copolymer (B-1) which contains constituent units derived from 1-butene in an amount of 15 to 25% by mol; and a polypropylene composition comprising 95-55 parts by weight of polypropylene (A) and 5-45 parts by weight of an ethylene/1-octene random copolymer (B-2) which contains constituent units derived from 1-octene in an amount of 8 to 20% by mol. Each of the random copolymers (B-1) and (B-2) has an intrinsic viscosity [.eta.] of 1.5 to 3.5 dl/g as measured in decalin, a glass transition temperature (Tg) of not higher than -50.degree. C., a crystallinity of less than 20% as measured by X-ray diffractometry, a randomness parameter (B value) of 1.0 to 1.4 as measured by .sup.13 C-NMR spectroscopy. With respect to a melting point as measured by a differential scanning calorimeter (DSC) as the main peak, the copolymer (B-1) has a value of not higher than 60.Type: GrantFiled: June 7, 1995Date of Patent: June 17, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Masayoshi Yamaguchi, Akio Ishimoto, Hiroshi Wakumoto, Masahiro Sugi
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Patent number: 5639719Abstract: A lubricating oil containing an aromatic ether compound represented by the general formula, (R.sup.1).sub.n Ph--O-- (R.sup.2 O).sub.m --R.sup.3, wherein R.sup.1 stands each independently for a particular hydrocarbon group, an etheric oxygen-containing hydrocarbon group, an alkoxyl group, or a halogen-substituted hydrocarbon group, R.sup.2 stands each independently for an alkylene group having 2 to 4 carbon atoms, R.sup.3 stands for a hydrocarbon group having 1 to 12 carbon atoms, Ph stands for an aromatic substituent, n stands for an integer of from 1 to 5, and m stands for an integer of from 1 to 30. The lubricating oil has excellent lubricating property, cleaning property and electrically insulating property, exhibits excellent sealing property owing to its high viscosity and wear resistance, and further exhibits excellent compatibility with R-134a, etc. The lubricating oil can be favorably used for the refrigerators such as of electric refrigerators and room air conditioners that use R-134a as a coolant.Type: GrantFiled: March 6, 1996Date of Patent: June 17, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Masahide Tanaka, Masayasu Ishibashi, Takashi Hayashi, Hajime Oyoshi, Tetsuo Hayashi, Kinya Mizui
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Patent number: 5639816Abstract: Disclosed are a polypropylene composition comprising 95-55 parts by weight of polypropylene (A) and 5-45 parts by weight of an ethylene/1-butene random copolymer (B-1) which contains constituent units derived from 1-butene in an amount of 15 to 25% by mol; and a polypropylene composition comprising 95-55 parts by weight of polypropylene (A) and 5-45 parts by weight of an ethylene/1-octene random copolymer (B-2) which contains constituent units derived from 1-octene in an amount of 8 to 20% by mol. Each of the random copolymers (B-1) and (B-2) has an intrinsic viscosity [.eta.] of 1.5 to 3.5 dl/g as measured in decalin, a glass transition temperature (Tg) of not higher than -50.degree. C., a crystallinity of less than 20% as measured by X-ray diffractometry, a randomness parameter (B value) of 1.0 to 1.4 as measured by .sup.13 C-NMR spectroscopy. With respect to a melting point as measured by a differential scanning calorimeter (DSC) as the main peak, the copolymer (B-1) has a value of not higher than 60.Type: GrantFiled: June 7, 1995Date of Patent: June 17, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Masayoshi Yamaguchi, Akio Ishimoto, Hiroshi Wakumoto, Masahiro Sugi
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Patent number: 5639842Abstract: In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from .alpha.-olefin of 3.about.20 carbon atoms, said ethylene copolymers having[A] a density of 0.85.about.0.92 g/cm.sup.3,[B] an intrinsic viscosity [.eta.] as measured in decalin at 135.degree. C. of 0.1-10 dl/g,[C] a ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) as measured by GPC of 1.2.about.4, and[D] a ratio (MFR.sub.10 /MFR.sub.2) of MFR.sub.10 under a load of 10 kg to MFR.sub.2 under a load of 2.16 kg at 190.degree. C. of 8.about.50, and being narrow in molecular weight distribution and excellent in flowability.Type: GrantFiled: May 20, 1996Date of Patent: June 17, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Akinori Toyota
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Patent number: 5637484Abstract: This invention relates to a method of producing a taxane-type diterpene(s) wherein tissues or cells of a plant which produces taxane-type diterpene(s) are cultured in the presence of at least one member selected from the group consisting of jasmonic acids, wherein the tissues or the cells of the plant are cultured by controlling the oxygen concentration in a gas phase in a culture vessel to less than the oxygen concentration in the atmosphere from the initial stage of the culture, or by controlling the dissolved oxygen concentration in a fluid medium which is in contact with the tissue or the cell to less than the saturated dissolved oxygen concentration at that temperature from the initial stage of the culture, while oxygenic gas containing 0.Type: GrantFiled: July 14, 1995Date of Patent: June 10, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yukihito Yukimune, Yasuhiro Hara, Yosuke Higashi, Naoto Ohnishi, Homare Tabata, Chuzo Suga, Kouichi Matsubara
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Patent number: 5633967Abstract: The device is constructed by an optical waveguide having an incident port for receiving incidence of energy lights from plural systems, an inner reflection surface which is a closed surface provided from the incident port to the rear thereof and an irradiation port formed on the rear end part of the inner reflection surface for irradiating the energy lights and an optical fiber disposed on the rear side of this optical waveguide for receiving incidence of the energy lights irradiated from this irradiation port. Thus, it is possible to couple energy lights from plural systems in single focus without needing any precise arrangement of optical elements.Type: GrantFiled: April 10, 1995Date of Patent: May 27, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Koichi Haruta
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Patent number: 5633099Abstract: A novel carbonate compound represented by the general formula [I]:R.sup.3 CH.sub.2 O-CO-OCH.sub.2 R.sup.4 [I]wherein R.sup.3 represents an alkyl group or an alkyl group substituted with one or more halogen atoms, and R.sup.4 represent an alkyl group having no hydrogen atom at the .beta.-position thereof or an alkyl group substituted with one or more halogen atoms having no hydrogen atom at the .beta.-position thereof, with the proviso that R.sup.3 is not identical to R.sup.4, which has excellent properties as solvent, is disclosed. A non-aqueous electrolytic solution and a battery utilizing the novel carbonate compound are also disclosed.Type: GrantFiled: June 5, 1995Date of Patent: May 27, 1997Assignees: Mitsui Petrochemical Industries, Ltd., Sony CorporationInventors: Keiichi Yokoyama, Akio Hiwara, Shigeru Fujita, Atsuo Omaru
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Patent number: 5633320Abstract: There is provided a thermoplastic polyester resin composition comprising a thermoplastic polyester resin (A) and a graft modified product (B) of a mixture of two different specific ethylene.1-butene random copolymers in a weight ratio of 95/5 to 50/50. A molded article having excellent impact resistance at low temperatures and mechanical strength can be obtained from this composition.Type: GrantFiled: May 7, 1996Date of Patent: May 27, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yasuo Tanaka, Yohji Hayakawa
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Patent number: 5628844Abstract: A topsheet for use in body fluid absorptive articles is so improved that collapse and clogging of liquid passages therein may be reliably avoided. The topsheet includes an upper sheet, provided with skin-contacting areas and liquid passages, and a lower sheet provided with skin-non-contacting areas, areas welded to the liquid passages, and exposed areas. The exposed areas are welded to each of the liquid passages around lower openings thereof so as to protect the liquid passage against collapse and clogging. The exposed areas define a skin-contacting surface which rises up into each of the liquid passages without extending above the upper surface of the skin-contacting areas. The upper sheet cooperates with the lower sheet to define cavities extending in the direction of the topsheet thickness.Type: GrantFiled: November 30, 1994Date of Patent: May 13, 1997Assignees: Mitsui Petrochemical Industries, Ltd., Uni-Charm CorporationInventors: Kazunari Nishino, Shigeyuki Motomura, Shizuo Shimizu, Takamitsu Igaue, Tsutomu Kido, Hisashi Takai
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Patent number: 5629361Abstract: An emulsion of a polymer, in which the polymer comprises (a) a recurring unit derived from a (meth)acrylate and (b) a recurring unit derived from a vinyl compound having a group of --SO.sub.3 R in which R is a hydrogen atom, an alkali metal atom or ammonium ion. The emulsion forms a film on an adherend to decrease the infiltration into the adherend, exhibits an adhesion force to a hydroxyapatite structure, a cement, a metal or a mineral when it is applied thereto to form a film by only drying around room temperature without washing it with water, and exhibits excellent affinity to a radical-polymerizable acrylic resin composition.Type: GrantFiled: May 31, 1995Date of Patent: May 13, 1997Assignees: Mitsui Petrochemical Industries, Ltd., Nobuo NakabayashiInventors: Nobuo Nakabayashi, Kazuhiko Ishihara, Yasukazu Saimi
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Patent number: 5627117Abstract: Disclosed in an olefin polymerization catalyst comprising a transition metal compound having at least two transition metals in which at least one of said metals is bonded to a ligand having a cyclopentadienyl skeleton, at least one of said metals is selected from Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W and lanthanoid metals and at least on of the others is selected from the specific transition metals; and an organoaluminum oxy-compound or an organoboron compound. Corresponding to the kind of the metal combined with said metal selected from Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W and lanthanoid metals, the olefin polymerization catalyst exhibit a property to give polymers having a wide molecular weight distribution in spite of the catalyst system using one kind of a transition metal compound, or to give polymers having high molecular weight and be excellent in the polymerization activity at low polymerization temperature.Type: GrantFiled: December 27, 1994Date of Patent: May 6, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Teruaki Mukaiyama, Makoto Mitani, Kunihiro Oouchi
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Process for preparing surface-modified biaxially oriented film of high molecular weight polyethylene
Patent number: 5624627Abstract: The biaxially oriented films of high molecular weight polyethylene is formed and its surface modified to provide a hydrophilic property to the resulting film. The film is prepared by melt-kneading the high molecular weight polyethylene with an ordinarily solid hydrocarbon plasticizer and a raw fabric sheet is formed from the resulting molten mixture. After the hydrocarbon plasticizer is extracted the resulting unstretched sheet is stretched under conditions providing a stretched film having a specific surface area of 70 m.sup.2 /g or more and a fibril structure. This stretched film is then heated under standard length constraint conditions to reduce the specific surface area of the stretched film by at least 20 m.sup.2 /g to obtain a biaxially oriented film of high molecular weight polyethylene.Type: GrantFiled: June 5, 1995Date of Patent: April 29, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuo Yagi, Hitoshi Mantoku, Akinao Hashimoto, Isaburo Higashi, Yoshinori Akana -
Patent number: 5624585Abstract: A laser beam having a circular cross section is irradiated obliquely with respect to a line vertical to a irradiating surface of material including a metal or by shaping the laser beam through an optical system of an irradiation unit, and then the laser beam having an elliptical shape is irradiated on the irradiating surface to thereby suppress weld defects such as weld cracks in weld joints of a difficult-to-weld material such as aluminum alloy.Type: GrantFiled: October 22, 1993Date of Patent: April 29, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Koichi Haruta, Yuichiro Terashi
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Patent number: 5624996Abstract: Disclosed is a dispersion of fine particles of modified polyethylene, which comprises a hydrocarbon organic solvent and fine particles of an ethylene polymer or ethylene polymer composition dispersed in the solvent, wherein the ethylene polymer or ethylene polymer composition has an acid value of 0.3 to 75 mg-KOH/g as a whole and a crystallinity of at least 45% as determined by the X-ray diffractometry and has an average dispersed particle size of 0.3 to 20 .mu.m and a concentration of 15 to 60% by weight.Type: GrantFiled: May 31, 1995Date of Patent: April 29, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Akio Morinaga, Takeo Kigami, Kunihiko Yorihiro, Toshihiko Okada
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Patent number: 5623033Abstract: Disclosed is a titanium catalyst component for ethylene polymerization obtained by contacting [A] a solid magnesium aluminum complex containing magnesium, halogen, aluminum and an alkoxy group and/or alcohol having at least 6 carbon atoms, with [B] a tetravalent titanium compound. The solid magnesium aluminum complex [A] is obtained by contacting (a-1) a magnesium solution formed from a halogen-containing magnesium compound, an alcohol having at least 6 carbon atoms and a hydrocarbon solvent, with (a-2) an organoaluminum compound. Also disclosed is a process for ethylene polymerization comprising polymerizing ethylene or copolymerizing ethylene with an .alpha.-olefin having 3 to 20 carbon atoms in the presence of a catalyst for ethylene polymerization comprising [I] the above-mentioned titanium catalyst component for ethylene polymerization and [II] an organoaluminum compound catalyst component.Type: GrantFiled: June 2, 1995Date of Patent: April 22, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Mamoru Kioka, Tsuneo Yashiki
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Patent number: 5620712Abstract: A topsheet for use in body fluid absorptive articles is so improved that collapse and clogging of liquid passages therein may be reliably avoided. The topsheet includes an upper sheet, provided with skin-contacting areas and liquid passages, and a lower sheet provided with skin-non-contacting areas, areas welded to the liquid passages, and exposed areas. The exposed areas are welded to each of the liquid passages around lower openings thereof so as to protect the liquid passage against collapse and clogging. The exposed areas define a skin-contacting surface which rises up into each of the liquid passages without extending above the upper surface of the skin-contacting areas. The upper sheet cooperates with the lower sheet to define cavities extending in the direction of the topsheet thickness.Type: GrantFiled: November 30, 1994Date of Patent: April 15, 1997Assignees: Mitsui Petrochemical Industries, Ltd, Uni-Charm CorporationInventors: Kazunari Nishino, Shigeyuki Motomura, Shizuo Shimizu, Takamitsu Igaue, Tsutomu Kido, Hisashi Takai
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Patent number: 5618886Abstract: The present invention provides olefin polymerization catalysts and processes for preparing a polypropylene and a propylene block copolymer using said olefin polymerization catalysts.The olefin polymerization catalyst (1) of the invention is formed from:[I-1] a contact product obtained by contacting:(A) a solid titanium catalyst component,(B) an organometallic compound catalyst component, and(C) a specific organosilicon compound;[II-1] (D) a specific polyether compound; and optionally,[III] an organometallic compound catalyst component.The olefin polymerization catalyst (2) of the invention is formed from:[I-2] a contact product obtained by contacting:(A) a solid titanium catalyst component,(B) an organometallic compound catalyst component, and(D) a specific polyether compound;[11-2] (C) a specific organosilicon compound.Type: GrantFiled: July 31, 1996Date of Patent: April 8, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Tetsunori Shinozaki, Mamoru Kioka
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Patent number: 5616663Abstract: Disclosed is a novel transition metal compound represented by the following formula: ##STR1## wherein M is a transition metal, X is halogen or the like, R.sup.1 is a hydrocarbon group or the like, R.sup.2 is an aryl group substituted with a halogenated hydrocarbon group, and Y is a divalent silicon-containing group or the like.Also disclosed are an olefin polymerization catalyst component comprising the transition metal compound, an olefin polymerization catalyst comprising the olefin polymerization catalyst component, and a process for olefin polymerization using the olefin polymerization catalyst.An olefin polymerization catalyst component having high polymerization activity can be formed from the transition metal compound. By the use of the olefin polymerization catalyst or the process for olefin polymerization, polyolefins having a high melting point and a high molecular weight can be prepared with high polymerization activity.Type: GrantFiled: November 10, 1994Date of Patent: April 1, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Junichi Imuta, Daisuke Fukuoka, Masayasu Yoshida, Junji Saito, Terunori Fujita, Takashi Tashiro, Koji Kawaai, Takashi Ueda, Yoshihisa Kiso