Patents Assigned to Mitsui
  • Patent number: 6132622
    Abstract: The present invention relates to an absorbent comprising at least one cycloolefin copolymer which contains polymerized units which are derived from at least one cyclic and at least one acyclic olefin.
    Type: Grant
    Filed: June 12, 1998
    Date of Patent: October 17, 2000
    Assignees: Ticona GmbH, Mitsui Petrochemical Ind. Ltd.
    Inventors: Freddy Helmer-Metzmann, Alexandra Jacobs
  • Patent number: 6133406
    Abstract: The present invention relates to a process for preparing an aromatic polyamide which comprises:(A) a dicarboxylic acid component unit comprising 30 to 100 mol % of a terephthalic acid component unit, and, as required, 0 to 70 mol % of a cyclic dicarboxylic acid component unit other than the terephthalic acid and, as required, 0 to 15 mol % of an aliphatic dicarboxylic acid having 7 to 20 carbon atoms; and(B) a diamine unit comprising 50 to 100 mol % of a component unit derived from an aliphatic alkylene diamine having 4 to 25 carbon atoms, and 0 to 50 mol % of a component unit derived from an alicyclic diamine having 3 to 25 carbon atoms; said process comprising:a step (i) of preparing a solid low-degree condensation product having an intrinsic viscosity [.eta.].sub.1 of from 0.05 to 0.2 dl/g is prepared by the polycondensation reaction of the dicarboxylic acid with the diamine;a step (ii) of solid-phase polymerizing said low-degree condensation product at a temperature of not higher than 195.degree. C.
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: October 17, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masaki Kosaka, Yukio Muranaka, Kenji Wakatsuru
  • Patent number: 6132640
    Abstract: Quinoline compound, zinc halogenide complex and zinc complex suited for use in an electro-luminescence (EL) element, a fluorescent material and an ultraviolet absorption material, and a preparation process for these compounds are described. These compounds and a tautomer of the same have a strong luminescent intensity and are used for an EL material, the compound of zinc halogenide complex and zinc complex and a tautomer of the same has absorption at a wave length of 400 nm or less and is used for an ultraviolet absorption material, and further the quinoline compound and a tautomer has a strong luminescent intensity and is used for a fluorescent material. The zinc halogenide complex and zinc complex can be prepared by related preparation processes directly from a quinoline derivative and a phthalimide derivative, or by way of the quinoline compound which is obtained from these derivatives.
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: October 17, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tadashi Okuma, Hideki Ikuta, Tatsuya Nagayoshi, Akira Ogiso, Hisato Ito
  • Patent number: 6133490
    Abstract: A dispersant for pigments for aromatic polymers, which is superior not only in the ability of dispersing pigments in aromatic polymers but also in attaining high transparency and stability of the resulting color, while avoiding grafting step and attaining a lower production cost. The dispersant for pigments for aromatic polymers comprises a wax composed of a random copolymer of ethylene with an aromatic vinyl compound, which has a content of structural unit derived from ethylene of 99-10% by weight and a content of structural unit derived form the aromatic vinyl compound of 1-90% by weight and exhibiting an intrinsic viscosity of 0.04-0.6 dl/g.
    Type: Grant
    Filed: September 29, 1998
    Date of Patent: October 17, 2000
    Assignee: Mitsui Chemicals Inc.
    Inventors: Hideo Toyoda, Hideki Sakai, Kenichi Morizono, Toshiyuki Tsutsui
  • Patent number: 6129045
    Abstract: A spherical object transport apparatus of the invention brings a spiral stream into contact with a first atmosphere containing a spherical object, selectively sucks the first atmosphere outward so as to engulf in the spiral stream for diffusing the first atmosphere outward, guides the spherical object so that the spherical object passes through the center of the transport apparatus, supplies a second atmosphere to the spherical object, and sends the spherical object together with the second atmosphere to the following step.
    Type: Grant
    Filed: July 7, 1998
    Date of Patent: October 10, 2000
    Assignees: Mitsui High-tec Inc., Nippon Pneumatics/Fluidics System Co., Ltd.
    Inventors: Katsumi Amano, Tashiro Arai
  • Patent number: 6130346
    Abstract: A process for preparing an organic compound, comprising conducting an organic reaction in the presence of a phosphine oxide represented by formula (1); ##STR1## where R.sup.1 is the same or different and each represents a hydrogen or hydrocarbon group with 1 to 10 carbon atoms, and x is the amount of water as a molar ratio which is 0 to 5.0, exhibiting a high catalytic performance especially in an organic reaction involving an alkylene oxide.
    Type: Grant
    Filed: April 13, 1999
    Date of Patent: October 10, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tadahito Nobori, Takaomi Hayashi, Isao Hara, Shinji Kiyono, Atsushi Shibahara, Katsuhiko Funaki, Tatsuhiro Urakami, Keisuke Takuma, Usaji Takaki
  • Patent number: 6130312
    Abstract: A process for producing an aromatic polyamide which comprises:(a) a dicarboxylic acid component which consists of 30-100 mol % of terephthalic acid and optionally 0-70 mol % of at least one dicarboxylic acid other than terephthalic acid, and(b) a diamine component which consists of 50-100 mol % of an aliphatic alkylenediamine of 4-25 carbons and optionally 0-50 mol % of at least one alicyclic diamine of 3-25 carbons, said process comprising a first step of performing melt reaction of said dicarboxylic acid with said diamine, thereby giving a low molecular weight condensate having an intrinsic viscosity [.eta.] of 0.05-0.6 dl/g, a second step of subjecting it to solid phase polymerization, thereby giving an aromatic polyamide precursor having an intrinsic viscosity [.eta.] of 0.5-1.0 dl/g, and a third step of subjecting it to melt polymerization, thereby giving an aromatic polyamide having a desired intrinsic viscosity [.eta.] of 0.8-2.5 dl/g.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: October 10, 2000
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hidetatsu Murakami, Satoshi Omori, Kenji Wakatsuru
  • Patent number: 6127583
    Abstract: A preparation process of an acetylene derivative comprising reacting a compound having a skeleton represented by the formula (1): ##STR1## in the molecular formula with a compound represented by the formula (2): ##STR2## wherein R.sup.1, R.sup.2 R.sup.3 and R.sup.4 are individually an alkyl group having 1 to 6 carbon atoms and can be the same or different, R.sup.1 and R.sup.3 can bond each other to form a ring, and R.sup.1 and R.sup.2 or R.sup.3 and R.sup.4 can be bond each other to form one or two heterocyclic rings: or with a compound represented by the formula (3): wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same as in the formula (2), and X.sub.1 is a ##STR3## chlorine, bromine or iodine atom.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: October 3, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hiroshi Sonoda, Kazunari Okada, Kenichi Goto, Kouki Fukumura, Junko Naruse, Hidetoshi Hayashi, Teruyuki Nagata, Akira Takahashi
  • Patent number: 6127511
    Abstract: A preparation process of phenol aralkyl resin from phenol compound and aralkyl compound by controlling the temperature of reaction mass in the range of 70 to 240.degree. C. and simultaneously controlling the temperature of vapor phase potion and vapor-liquid interface portion of manufacturing equipment so as to keep the wall surface of the vapor phase portion and vapor-liquid interface portion in a wet state. The invention can prevent scale adhesion to the interior of manufacturing equipment, remarkably reduce the number of washing and scale removing procedures on the manufacturing equipment, and enable efficient manufacture of phenol aralkyl resin. When the phenol aralkyl resin obtained is used for a molding material, molded articles having excellent heat resistance and high reliability can be provided.
    Type: Grant
    Filed: December 3, 1998
    Date of Patent: October 3, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tomoyuki Kawabata, Yuzo Ono, Teruo Yuasa, Yukio Fukui
  • Patent number: 6126212
    Abstract: A vehicle door latch device comprises a connecting member for connecting a lock pin with a lock lever. The connecting member has a lever side member connected to a lock lever, a pin side member connected to a lock pin, and a connecting spring for elastically connecting the lever side member with the pin side member. The connecting member changes length thereof against the elasticity of the spring to allow the lock lever to be displaced to an unlocked position from a locked position, when the lock pin cannot be displaced from a disengagement position to an engagement position by a displacement of the lock lever from a locked position toward an unlocked position while the open lever is in a door-opening position.
    Type: Grant
    Filed: May 12, 1999
    Date of Patent: October 3, 2000
    Assignee: Mitsui Kinzoku Kogyo Kabushiki Kaisha
    Inventor: Yoshihiko Fujihara
  • Patent number: 6124426
    Abstract: A method for removing volatile materials, comprises adding a blowing aid to a polymer composition containing volatile materials, mixing them in a static mixing apparatus, and extruding the resultant mixture by an extruding apparatus into a devolatilizing tank, thereby the mixture is made to be blown, to cause removal of the volatile materials. First, the blowing aid (6) is discharged with an addition nozzle apparatus (2), in a direction opposite to the direction of the flow of the polymer composition (1), to be added, and the polymer composition is introduced into the static mixing apparatus (3), at a pressure at which the blowing does not take place, thereby mixing them. Then, using the extruding apparatus (11), the resultant mixture is extruded into the devolatilizing tank (4), so that the polymer is made into a blown product at such a temperature and a pressure that the blowing coefficient B is 1.4 or more, thereby causing the removal of volatile materials.
    Type: Grant
    Filed: September 24, 1998
    Date of Patent: September 26, 2000
    Assignees: Toyo Engineering Corporation, Mitsui Chemicals, Inc.
    Inventors: Ryuichi Sugimoto, Koji Kawano, Hiroya Honda, Mune Iwamoto, Shiro Otsuzuki, Kenichiro Matsuba, Tetsuo Maeda, Yozo Maeda
  • Patent number: 6123911
    Abstract: A process for producing a lithium manganate for lithium secondary batteries comprising mixing a manganese compound and a lithium compound, firing the mixture at 1000 to 1500.degree. C., mixing the resulting complex oxide with a lithium compound, and firing the mixture at 600 to 800.degree. C.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: September 26, 2000
    Assignee: Mitsui Mining & Smelting Company, Ltd.
    Inventors: Munetoshi Yamaguchi, Koichi Numata
  • Patent number: 6124384
    Abstract: The invention provides a composite resin composition comprising aliphatic polyester resin (component A) having aliphatic hydroxycarboxylic acid units, one or more biomass material (component B) selected from the group consisting of cellulose, lignocellulose and starch and unsaturated carboxylic acid or a derivative thereof (component C), wherein the composite resin composition comprises a component obtained by covalently bonding a portion or the whole of component A and component B through component C. On processing into various formed items, the composite resin composition of the invention exhibits excellent tensile strength and other physical properties and processability and simultaneously has good biodegradability, and enable biomass materials of low added value to apply to high added value uses in a large amount.
    Type: Grant
    Filed: August 14, 1998
    Date of Patent: September 26, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Nobuo Shiraishi, Masanobu Ajioka
  • Patent number: 6124410
    Abstract: The invention provides a method for purification of an .alpha.-olefin selected from ethylene and propylene for polymerization use which comprises contacting the .alpha.-olefin with an alkali metal carried on a support material. The invention further provides a method for production of a poly-.alpha.-olefin which comprises polymerizing the thus purified .alpha.-olefin in the presence of a polymerization catalyst comprising a transition metal catalyst component and an organometallic catalyst component.
    Type: Grant
    Filed: June 17, 1997
    Date of Patent: September 26, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yoshinao Ito, Kazuo Yasuda, Shougo Shimonishi
  • Patent number: 6124466
    Abstract: A novel nitroisourea derivative and a process for producing the same, which is an important intermediate for the production of a nitroguanidine derivative having an insecticidal activity, and a process for producing a nitroguanidine derivative having an insecticidal activity using the nitroisourea derivative. The process for producing a nitroguanidine derivative represented by formula (1), effective as an insecticide is shown by reaction scheme (2): ##STR1## wherein R.sub.1 represents an alkyl group having from 1 to 4 carbon atoms or a benzyl group; R.sub.2 represents an alkyl group having from 1 to 4 carbon atoms; R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each independently represents a hydrogen atom or an alkyl group having from 1 to 4 carbon atoms; and Q represents a 5-membered or 6-membered heterocyclic ring having at least one of the following: a nitrogen atom, an oxygen atom or a sulfur atom, one of the hydrogen atoms being substitutable with a halogen atom.
    Type: Grant
    Filed: July 19, 1999
    Date of Patent: September 26, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hirozumi Matsuno, Kiyoshi Arai, Takeshi Oura, Kenji Kodaka
  • Patent number: 6124424
    Abstract: A transparent optical material containing at least one selenium atom, a plastic lens comprising the transparent optical material, and methods for preparing them. In addition, there are also disclosed novel selenium-containing compounds represented by the following formulae (1), (2) and (4) which are useful for the transparent optical material and the plastic lens: ##STR1## wherein symbols are as defined in the specification.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: September 26, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Koju Okazaki, Mamoru Tanaka, Shiro Honma, Hiroyuki Morijiri, Yoshinobu Kanemura, Masahiko Kusumoto
  • Patent number: 6121394
    Abstract: The present invention is directed to a method for polymerizing an .alpha.-olefin characterized by using a catalyst system which is obtained by reacting a halogenated metallocene compound with an organometallic compound, and then bringing the resultant reaction product into contact with a compound which will be a stable anion by reaction with the reaction product of the halogenated metallocene compound and the organometallic compound.When the method of the present invention is carried out, a polyolefin can be obtained by the use of the inexpensive catalyst in a high activity per unit amount of the catalyst.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: September 19, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Ryuichi Sugimoto, Tadashi Asanuma, Tutomu Iwatani, Katsumi Takeuchi, Osamu Uchida
  • Patent number: 6120576
    Abstract: A method for preparing nickel fine powder is herein disclosed, which comprises the steps of mixing an aqueous sodium hydroxide solution comprising, on the basis of the total weight of the sodium hydroxide present in the aqueous solution, 75 to 85% by weight of liquid caustic soda as specified in JIS K 1203 and 25 to 15% by weight, in total, of at least one of sodium hydroxide as specified in JIS K 8576 and solid caustic soda as specified in JIS K 1202, with an aqueous solution of nickel sulfate to form nickel hydroxide, then reducing the resulting nickel hydroxide with hydrazine and recovering nickel fine powder produced. The nickel fine powder prepared by the method has an average particle size of the primary particles ranging from 0.1 to 0.9 .mu.m, a D.sub.90 value of not more than 2.1 .mu.m and a tap density of not less than 3.5 g/cc.
    Type: Grant
    Filed: July 9, 1998
    Date of Patent: September 19, 2000
    Assignee: Mitsui Mining and Smelting Co., Ltd.
    Inventors: Yoshiharu Toshima, Takayuki Araki, Takao Hayashi, Hiroyuki Shimamura
  • Patent number: 6121378
    Abstract: A thermosetting powder paint composition for top coating excellent in weather resistance and storage stability, which comprising 100 parts by weight of an acrylic copolymer (A) having an epoxy group, and 0.01 to 2.0 parts by weight of an organic modified polysiloxane (B) containing at least one functional group, at least two silicon atoms and no radical-polymerizable unsaturated bond wherein the component (B) is contained in the condition that a part or all thereof has reacted and bonded with the component (A) or the component (C), or all thereof has not reacted with them.
    Type: Grant
    Filed: August 19, 1998
    Date of Patent: September 19, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takahisa Miyawaki, Yoshio Kikuta, Mitsuyuki Mizoguchi, Hiroyuki Sakayama, Tsuyoshi Matsumoto
  • Patent number: 6121393
    Abstract: A process for polymerizing an alpha-olefin using either a catalyst formed by contacting a highly active solid titanium catalyst component, an organo-metallic compound of a metal of Group 1 to 3 of the periodic table, an organic halogen compound or a transition metal compound, and an organosilicon compound or a sterically hindered amine in an inert medium in the absence of an alpha olefin, or a catalyst prepared by preliminarily polymerizing an alpha olefin in the presence of a catalyst comprising the above four catalyst components, provided that the last one is an optional component. This process achieves the industrially advantage that the catalysts are highly active, and give a polymer having excellent stereoregularity.
    Type: Grant
    Filed: April 7, 1995
    Date of Patent: September 19, 2000
    Assignee: Mitsui Chemicals
    Inventors: Mamoru Kioka, Norio Kashiwa, Tomohiko Kimura, Mitsuo Tomura, Toshiki Sotoyama