Patents Assigned to Mitsui
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Patent number: 5861528Abstract: In a process for preparing a Diels-Alder addition product of a conjugated diolefin and acrylonitrile by reacting the conjugated diolefin with acrylonitrile, a vessel type reactor is used. The pressure of the gaseous phase in the reactor is increased by using an inert gas in the reaction. A premixed solution of the conjugated diolefin or a compound which produces the conjugated diolefin in the reactor and acrylonitrile is released through an upper portion of the reactor into the gaseous phase and then dropped into a liquid phase to react. A reaction product is taken out through a lower portion of the reactor. The process can be carried out continuously in a safe manner over an extended period of time without any adhesion of an insoluble polymer to the reactor or to the inlet or outlet pipes, and without sudden pressure fluctuations.Type: GrantFiled: January 15, 1997Date of Patent: January 19, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Masamitsu Inomata, Masahiro Takeno, Akio Numa, Hiroki Mizutani, Masanobu Ebina, Isao Fukada
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Patent number: 5861108Abstract: Provided is a naphthalene compound represented by the following Formula (1): ##STR1## wherein R.sub.1 and R.sub.2 each represent a linear or branched alkyl group having 1 to 20 carbon atoms, an alkoxyalkyl group having 2 to 20 carbon atoms or an alkenyl group having 2 to 20 carbon atoms which may be substituted with halogen atoms and have no asymmetric carbon atoms; A represents any of the groups represented by the following formulas: ##STR2## (wherein X.sub.1, X.sub.2, X.sub.3 and X.sub.4 each represent a hydrogen atom or a halogen atom); and z represents 0 or 1. The addition of this naphthalene compound to a liquid crystal composition makes it possible to improve various characteristics such as the high speed response property of the liquid crystal composition and the temperature dependency of the response time. The above naphthalene compound is useful as a liquid crystal material for liquid crystal compositions, particularly ferroelectric liquid crystal compositions.Type: GrantFiled: July 1, 1996Date of Patent: January 19, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Tsutomu Ishida, Atsuo Otsuji, Yoshiyuki Totani, Motokazu Hirao, Hiroe Kayashima, Masakatsu Nakatsuka
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Patent number: 5860684Abstract: An apparatus for opening and closing a vehicle door comprises an outer open handle assembly and a latch assembly. The handle assembly has an handle base which is brought into contact with an outer surface of an outer door panel and a handle lever which is rotatably mounted on the handle base. The latch assembly has a bracket which is brought into contact with an inner surface of the outer panel, a latch mechanism which is engaged with a striker and mounted on the bracket, and an opening mechanism which is operative to release the latch mechanism and mounted on the bracket. The handle base and the bracket are fixed to each other with screws or bolts across the outer door panel. The latch assembly is covered with a decorative case.Type: GrantFiled: October 30, 1996Date of Patent: January 19, 1999Assignee: Mitsui Kinzoku Kogyo Kabushiki KaishaInventor: Tetsuro Mizuki
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Patent number: 5859155Abstract: There is provided an adhesive composition for use in a flexible printed circuit board, comprising:(a) an epoxy resin having substantially at least two epoxy groups per molecule;(b) at least one selected from carboxyl group-containing nitrile rubber and carboxyl group-containing hydrogenated nitrile rubber; and(c) a curing agent which comprises aromatic amine having substantially at least two primary amino groups per molecule (c1) and dicyandiamide (c2), the molar ratio of the aromatic amine (c1) to the dicyandiamide (c2) being 35/65.ltoreq.(c1)/(c2).ltoreq.99/1.Type: GrantFiled: May 19, 1997Date of Patent: January 12, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Toshikazu Furihata, Akio Ikeda, Wataru Soejima
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Patent number: 5857397Abstract: A sheet machining apparatus has a die for positioning a sheet to be machined. The die is mounted on a lower die base for movement and has a machining pattern for the sheet, a plurality of punches are mounted on an upper punch base for machining the sheet in coaction with the die in a predetermined number of machining cycles according to the individual machining pattern, and a feed mechanism horizontally moves the die to align a machining position on the sheet with the punches each time the sheet is machined by the die and the punches.Type: GrantFiled: December 20, 1996Date of Patent: January 12, 1999Assignees: NGK Insulators, Ltd., Mitsui High-Tec, Inc.Inventors: Satoshi Matsubayashi, Hiroyuki Tsuji, Kazumasa Kitamura, Motoo Noritake
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Patent number: 5859158Abstract: Disclosed in an olefin polymerization catalyst comprising a transition metal compound having at least two transition metals in which at least one of said metals is bonded to a ligand having a cyclopentadienyl skeleton, at least one of said metals is selected from Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W and lanthanoid metals and at least on of the others is selected from the specific transition metals; and an organoaluminum oxy-compound or an organoboron compound. Corresponding to the kind of the metal combined with said metal selected from Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W and lanthanoid metals, the olefin polymerization catalyst exhibit a property to give polymers having a wide molecular weight distribution in spite of the catalyst system using one kind of a transition metal compound, or to give polymers having high molecular weight and be excellent in the polymerization activity at low polymerization temperature.Type: GrantFiled: November 14, 1996Date of Patent: January 12, 1999Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Teruaki Mukaiyama, Makoto Mitani, Kunihiro Oouchi
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Patent number: 5859272Abstract: Disclosed is a novel transition metal compound represented by the following formula: ##STR1## wherein M is a transition metal, X is halogen or the like, R.sup.1 is a hydrocarbon group or the like, R.sup.2 is an aryl group substituted with a halogenated hydrocarbon group, and Y is a divalent silicon-containing group or the like.Also disclosed are an olefin polymerization catalyst component comprising the transition metal compound, an olefin polymerization catalyst comprising the olefin polymerization catalyst component, and a process for olefin polymerization using the olefin polymerization catalyst.An olefin polymerization catalyst component having high polymerization activity can be formed from the transition metal compound. By the use of the olefin polymerization catalyst or the process for olefin polymerization, polyolefins having a high melting point and a high molecular weight can be prepared with high polymerization activity.Type: GrantFiled: January 24, 1997Date of Patent: January 12, 1999Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Junichi Imuta, Daisuke Fukuoka, Masayasu Yoshida, Junji Saito, Terunori Fujita, Takashi Tashiro, Koji Kawaai, Takashi Ueda, Yoshihisa Kiso
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Patent number: 5858517Abstract: An electrodeposited copper foil for use in the manufacture of a printed wiring board in which the original profile of the matte surface has been completely removed, preferably by buffing, leaving a surface having linear streaks and a roughness 1.5 .mu.m or less. The new surface is then given a nodule forming treatment which produces a surface roughness of 1.5 to 2.0 .mu.m, which may be followed by a corrosion resisting treatment. This invention further provides a method of manufacturing such an electrodeposited copper foil. Such copper foils are especially useful in making fine circuit patterns.Type: GrantFiled: January 15, 1997Date of Patent: January 12, 1999Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Hideyasu Tagusari, Yutaka Hirasawa, Kazuhide Oshima
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Patent number: 5856386Abstract: A crystalline thermoplastic resin composition comprises a rosin acid metallic salt and a crystalline thermoplastic resin. Optionally, a compatibilizing agent may also be included. The rosin acid metallic salt, which acts as a crystal nucleating agent, increases the crystallization rate of the crystalline thermoplastic resin and enables the formation of fine crystals of the resin. Thus, the crystalline thermoplastic resin composition can crystallize at a high rate, and provide molded articles having excellent mechanical properties and/or optical properties.Type: GrantFiled: January 22, 1997Date of Patent: January 5, 1999Assignees: Mitsui Petrochemicals Industries, Ltd., Arakawa Chemical Industries, Ltd.Inventors: Hideki Sakai, Mikio Nakagawa, Tetsuji Kasai, Kimio Ueda, Masao Maeda, Yukiharu Yamada, Hiroyuki Hori, Junji Tan, Kan Matsumoto
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Patent number: 5856399Abstract: The thermoplastic elastomer composition of the invention comprises a crystalline polyolefin resin (A), an olefin rubber (B), a hydrogenated styrene block copolymer (C), a softener (D), and optionally, a peroxide non-crosslinked type hydrocarbon rubber (E) in a specific amount of each, and has a gel content of not less than 97%. This composition may be mixed with a crystalline polyolefin resin. The thermoplastic elastomer composition has excellent moldability and is able to provide a molded product having excellent elastomeric properties, high resistance to permanent compression set and good appearance. In particular, a composition obtained by mixing this thermoplastic elastomer composition and a crystalline polyolefin resin shows excellent moldability.Type: GrantFiled: April 19, 1996Date of Patent: January 5, 1999Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yuichi Itoh, Kyoko Kobayashi, Akira Uchiyama
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Patent number: 5855979Abstract: An optical recording medium comprising a recording layer, a light interference layer, a reflective layer and a protective layer that are laminated on a substrate, characterized in that said recording layer and said light interference layer comprise at least one organic dye, and that a light absorbent and/or a thermal decomposition promoter are/is added to said light interference layer, wherein the optical recording medium has compatibility that allows good recording and/or reproduction by using lasers of different two wavelength ranges and has good recording properties.Type: GrantFiled: August 4, 1997Date of Patent: January 5, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Hideki Umehara, Jun Tokuhiro, Yuji Inatomi, Tomoyoshi Sasakawa, Tsutami Misawa, Kenichi Sugimoto, Taizo Nishimoto, Takeshi Tsuda
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Patent number: 5854354Abstract: A process for preparing a propylene polymer composition comprising conducting multistage polymerization including a step (a) for preparing a propylene (co)polymer (a) and a step (b) for preparing an ethylene copolymer (b) in the presence of (A) a transition metal compound and (B) a compound activating the transition metal compound (A), in which the steps (a) and (b) may be carried out in any order, and the resulting propylene polymer composition contains the propylene (co)polymer (a) in an amount of 20 to 90% by weight and the ethylene copolymer (b) in an amount of 10 to 80% by weight and has MFR, as measured at 230.degree. C. under a load of 2.16 kg, of 0.01 to 500 g/10 min; and a propylene polymer composition prepared by this process. The process according to the invention can prepare a propylene polymer composition having excellent rigidity, heat resistance and impact resistance.Type: GrantFiled: June 7, 1995Date of Patent: December 29, 1998Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Ueda, Mikio Hashimoto, Masaaki Kawasaki, Daisuke Fukuoka, Junichi Imuta
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Patent number: 5854349Abstract: Disclosed is a cycloolefin copolymer composition (C) obtained by copolymerizing an .alpha.-olefin of two or more carbon atoms (a) and a specific cycloolefin (b) in the presence of an aromatic ring-containing vinyl hydrocarbon/conjugated diene copolymer or a product of hydrogenation thereof (A) which has an intrinsic viscosity (.eta.) of 0.5 to 5.0 dl/g; at least one glass transition temperature (measured by DSC) of lower than 15.degree. C.; polymerizable carbon-to-carbon double bonds in an amount of 2 to 150 in terms of iodine value; and a refractive index n.sub.D (A) of 1.50 to 1.65. In the composition (C), the component (A) is contained in an amount of 1 to 40% by weight, and a difference .DELTA.n.sub.D between the refractive index n.sub.D (A) of the component (A) and a refractive index n.sub.D (B) of a cycloolefin copolymer component (B) obtained by copolymerizing the .alpha.-olefin (a) and the cycloolefin (b) in the absence of the component (A) is not more than 0.015.Type: GrantFiled: April 14, 1997Date of Patent: December 29, 1998Assignees: Mitsui Petrochemical Industries, Ltd., Hoechst AktiengesellschaftInventors: Yoshiharu Abe, Toshihiro Sagane
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Patent number: 5853920Abstract: The present invention provides a method of manufacturing a zinc-titanium mother alloy and a manganese dry battery having an anode zinc can prepared from the zinc-titanium alloy. The method comprises: adding spongy titanium to molten zinc; and melting the spongy titanium to alloy with the zinc at 500.degree. to 750.degree. C. for 0.5 to 6 hours, thereby to obtain a zinc-titanium alloy which contains 0.001 to 5% by weight of titanium. The anode zinc can prepared from the zinc-titanium mother alloy is substantially free from metallic titanium and intermetallic compounds having the Zn--Ti atomic ratio of not less than 1/2.Type: GrantFiled: March 5, 1997Date of Patent: December 29, 1998Assignees: Mitsui Mining & Smelting Co., Ltd., Matsushita Electric Industrial Co., Ltd.Inventors: Hajime Murakami, Ryohei Ashihara, Kohei Kubota, Koichi Sato
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Patent number: 5851619Abstract: A hollow and cylindrical laminated molded product which is constituted by mutually overlapped joining of edge sides in a longitudinal direction of at least one or more elongated laminated articles formed by layered lamination of fiber-reinforced thermoplastic resin plates containing reinforcing fibers of not less than 30% and not more than 85% in volume content, and a method of producing the above-mentioned laminated molded product using a simple molding tool.Type: GrantFiled: May 31, 1994Date of Patent: December 22, 1998Assignee: Mitsui Chemicals, Inc.Inventors: Hideo Sakai, Kojiro Motai, Satoru Kishi, Katsuyuki Morita, Nobuyuki Hosoyama, Hiroshi Tanabe
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Patent number: 5852011Abstract: Disclosed are compounds represented by the following chemical formula (I) and pharmacologically acceptable salts thereof which are novel compounds useful as anticancer agents, antiviral agents or antimicrobial agents.Type: GrantFiled: January 19, 1996Date of Patent: December 22, 1998Assignee: Mitsui Chemicals, Inc.Inventors: Akio Matsunaga, Yuki Nakajima, Hiroshi Kohno, Hironori Komatsu, Hajime Edatsugi, Daiji Iwata, Kimiko Takezawa
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Patent number: 5849257Abstract: A process for preparation of nitrous oxide, wherein ammonia is reacted with oxygen in the presence of steam using a copper-manganese oxide catalyst having diffraction angles measured by X-ray diffraction analysis of about 36.degree., about 58.degree. and about 64.degree.; a copper-manganese oxide catalyst suitable for the process. The catalyst is highly active and selective, has a long catalyst-lifetime, gives a non-condensable gas comprising nitrogen, oxygen and nitrous oxide which contains nitrous oxide in a high concentration, and is less deteriorative. The catalyst can be used in a process for preparation of nitrous oxide in which formation of NOx as by-products is reduced; and a process for stably recovering nitrous oxide.Type: GrantFiled: March 31, 1997Date of Patent: December 15, 1998Assignee: Mitsui Chemicals, Inc.Inventors: Kenji Fujiwara, Hideaki Nakamura, Hiroshi Kato, Susumu Yoshinaga, Kazuo Wakimura
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Patent number: 5849826Abstract: The semiaromatic polyamide of the invention comprises 40 to 90% by mol of (A) recurring units derived from terephthalic acid and an aliphatic diamine of 4 to 12 carbon atoms, 0 to 50% by mol of (B) recurring units derived from isophthalic acid and an aliphatic diamine of 4 to 12 carbon atoms, 0 to 60% by mol of (C) recurring units derived from an aliphatic dicarboxylic acid of 4 to 18 carbon atoms and an aliphatic diamine of 4 to 12 carbon atoms and 0 to 50% by mol of (D) recurring units derived from a lactam or an aminocarboxylic acid of 6 to 20 carbon atoms, and has a content of boiling water-soluble components (MO components) of not more than 0.25% by weight. The semiaromatic polyamide has a low content of the MO components, so that mold contamination hardly brought about in the molding process, and also molded articles of good heat resistance can be produced.Type: GrantFiled: June 25, 1997Date of Patent: December 15, 1998Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yoshimasa Ogo, Hidetatsu Murakami, Kunihiro Oouchi, Masaru Sudou, Yoshikatsu Amimoto, Satoshi Omori, Kenji Wakatsuru, Ryuichi Hayashi, Masahiro Nozaki
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Patent number: 5850414Abstract: A spread spectrum communication receiver includes an inverse spread demodulation circuit and a primary demodulation circuit. The inverse spread demodulation circuit has an image PN code generation circuit for generating an image PN code having an image relationship with a PN code which was used in spread modulation of a spread spectrum signal to be received and demodulated, an SS reference signal generation circuit for generating a spread spectrum reference signal having an image relationship with the spread spectrum signal to be demodulated using the image PN code, and a surface acoustic wave device for taking a correlation between the received spread spectrum signal and the spread spectrum reference signal. The primary demodulation circuit has a detection circuit for generating a convolution output by detecting the correlation output from said inverse spread demodulation circuit, and a waveform shaping circuit for shaping the convolution output.Type: GrantFiled: September 12, 1995Date of Patent: December 15, 1998Assignee: Mitsui Mining & Smelting Co., Ltd.Inventor: Hiromitsu Miyajima
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Patent number: 5846904Abstract: Described are a stick-shaped soil fumigant preparation and an application method therefor. The fumigant preparation comprises a water-soluble and/or biodegradable film and a soil sterilizer and/or nematocide hermetically packed in the form of a stick with the film. The soil sterilizer and nematocide are each in a liquid form at room temperature.The soil fumigant preparation according to the present invention remains suppressed in toxicity, volatility and irritation before application to the soil, but its active ingredient(s) are promptly released after application. In addition, the present invention makes it possible to provide a fumigant in such a form as permitting a substantial improvement in the efficiency of work by a fumigating worker and also to provide an effective application method therefor, without the need for any machine designed exclusively for fumigation.Type: GrantFiled: February 5, 1996Date of Patent: December 8, 1998Assignee: Mitsui Chemicals, Inc.Inventors: Masao Imai, Kanemitsu Miyama, Masaru Arai, Hitoshi Shimotori, Tamotsu Asano, Satoru Iwamori, Shohei Nozaki, Nobuhiro Fukuda