Patents Assigned to Mitsui
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Patent number: 5624980Abstract: The present invention provides a thermoplastic cement composition, characterized in that the composition can be easily processed thermoplastically during molding and that when the cement component constituting the composition is hardened by the absorption of water, the composition loses its thermoplasticity to give a product having excellent heat resistance and other properties.The thermoplastic cement composition comprises 100 parts by weight of a thermoplastic, 50 to 600 parts by weight of a hydraulic cement and/or an air-hardening cement and 0.1 to 20 parts by weight of a hydrophilic substance.Type: GrantFiled: March 24, 1995Date of Patent: April 29, 1997Assignees: Tobuchemicals, Inc., Mitsui & Co., Ltd.Inventor: Shigeji Kobori
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Process for preparing surface-modified biaxially oriented film of high molecular weight polyethylene
Patent number: 5624627Abstract: The biaxially oriented films of high molecular weight polyethylene is formed and its surface modified to provide a hydrophilic property to the resulting film. The film is prepared by melt-kneading the high molecular weight polyethylene with an ordinarily solid hydrocarbon plasticizer and a raw fabric sheet is formed from the resulting molten mixture. After the hydrocarbon plasticizer is extracted the resulting unstretched sheet is stretched under conditions providing a stretched film having a specific surface area of 70 m.sup.2 /g or more and a fibril structure. This stretched film is then heated under standard length constraint conditions to reduce the specific surface area of the stretched film by at least 20 m.sup.2 /g to obtain a biaxially oriented film of high molecular weight polyethylene.Type: GrantFiled: June 5, 1995Date of Patent: April 29, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuo Yagi, Hitoshi Mantoku, Akinao Hashimoto, Isaburo Higashi, Yoshinori Akana -
Patent number: 5624998Abstract: The present invention provides an aqueous gel comprising a polymer of (meth)acrylamide or particular (meth)acrylamide derivative(s), particulate metal oxide(s) and an aqueous medium, a process for producing said gel, and products utilizing said gel.This aqueous gel can be produced so as to have transparency, has fire resistance and can prevent the spreading of flames, and is highly elastic. The aqueous gel, when produced as a transparent gel, becomes cloudy when heated or cooled and is useful for the shielding of heat rays or cold radiation.Type: GrantFiled: February 12, 1996Date of Patent: April 29, 1997Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Hiroshi Itoh, Takashi Abe, Hideo Kamio, Hitoshi Yamashita, Atsuhiko Nitta
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Patent number: 5623033Abstract: Disclosed is a titanium catalyst component for ethylene polymerization obtained by contacting [A] a solid magnesium aluminum complex containing magnesium, halogen, aluminum and an alkoxy group and/or alcohol having at least 6 carbon atoms, with [B] a tetravalent titanium compound. The solid magnesium aluminum complex [A] is obtained by contacting (a-1) a magnesium solution formed from a halogen-containing magnesium compound, an alcohol having at least 6 carbon atoms and a hydrocarbon solvent, with (a-2) an organoaluminum compound. Also disclosed is a process for ethylene polymerization comprising polymerizing ethylene or copolymerizing ethylene with an .alpha.-olefin having 3 to 20 carbon atoms in the presence of a catalyst for ethylene polymerization comprising [I] the above-mentioned titanium catalyst component for ethylene polymerization and [II] an organoaluminum compound catalyst component.Type: GrantFiled: June 2, 1995Date of Patent: April 22, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Mamoru Kioka, Tsuneo Yashiki
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Patent number: 5620712Abstract: A topsheet for use in body fluid absorptive articles is so improved that collapse and clogging of liquid passages therein may be reliably avoided. The topsheet includes an upper sheet, provided with skin-contacting areas and liquid passages, and a lower sheet provided with skin-non-contacting areas, areas welded to the liquid passages, and exposed areas. The exposed areas are welded to each of the liquid passages around lower openings thereof so as to protect the liquid passage against collapse and clogging. The exposed areas define a skin-contacting surface which rises up into each of the liquid passages without extending above the upper surface of the skin-contacting areas. The upper sheet cooperates with the lower sheet to define cavities extending in the direction of the topsheet thickness.Type: GrantFiled: November 30, 1994Date of Patent: April 15, 1997Assignees: Mitsui Petrochemical Industries, Ltd, Uni-Charm CorporationInventors: Kazunari Nishino, Shigeyuki Motomura, Shizuo Shimizu, Takamitsu Igaue, Tsutomu Kido, Hisashi Takai
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Patent number: 5620934Abstract: Disclosed herein is a process for the preparation of alkylsilanes and alkenyl silanes by hydrosilylation of their corresponding silanes and unsaturated hydrocarbons in the presence or absence of a catalyst, a process for the preparation of polyalkenylsilanes (some of which are high molecular compounds) by the anionic coordination polymerization, radical polymerization or ionic polymerization of the alkenylsilanes, and a process for the production of silicon carbide by using these polyalkenylsilanes as prepolymers.Type: GrantFiled: March 29, 1995Date of Patent: April 15, 1997Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Masayoshi Itoh, Ryo Takeuchi, Kenji Iwata, Mineo Kobayashi
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Patent number: 5618980Abstract: Disclosed are (1) a method for preparing an aromatic secondary amino compound which comprises reacting an N-cyclohexylideneamino compound in the presence of a hydrogen moving catalyst and a hydrogen acceptor by the use of a sulfur-free polar solvent and/or a cocatalyst, and(2) a method for preparing an aromatic secondary amino compound which comprises reacting cyclohexanone or a nucleus-substituted cyclohexanone, an amine and a nitro compound corresponding to the amine in a sulfur-free polar solvent in the presence of a hydrogen moving catalyst, a cocatalyst being added or not added. In a further aspect, a method is provided for the preparation of aminodiphenylamine by reacting phenylenediamine and cyclohexanone in the presence of a hydrogen transfer catalyst in a sulfur-free polar solvent while using nitroaniline as a hydrogen acceptor.Type: GrantFiled: April 30, 1996Date of Patent: April 8, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Teruyuki Nagata, Chiyuki Kusuda, Masaru Wada, Kenichi Satou, Masae Uchida
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Patent number: 5618068Abstract: A door lock apparatus with automatic door closing mechanism comprises a latch engaging with a striker secured to a vehicle body, an automatic door closing motor for over-rotating the latch at its half-latched position beyond its full-latched position while the motor rightly rotates, a switch adapated to turn to continuously ON when the latch is between the half-latched and full-latched positions and turn to OFF when the latch is at other position than between the half-latched and full-latched positions, and a controller for rightly rotating the motor when door closing operation turns the switch from its OFF condition to ON condition and reversely rotating motor when the switch turns from ON to OFF.Type: GrantFiled: April 6, 1994Date of Patent: April 8, 1997Assignee: Mitsui Kinzoku Kogyo Kabushiki KaishaInventors: Jiro Mitsui, Hirofumi Watanabe, Yoshihiko Fujihara
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Patent number: 5618868Abstract: The present invention is concerned with a novel azo compound represented by formula (1), (2) or (3), a water-soluble dye comprising this azo compound, and a polarizing film containing this azo compound. The obtained polarizing film has high hydrothermoresistance and a high polarization degree and is excellent in optical characteristics: ##STR1## wherein each of R.sub.1, R.sub.3 and R.sub.12 is independently a hydrogen atom, halogen atom, hydroxyl group, alkyl group having 1 or 2 carbon atoms, or alkoxy group having 1 or 2 carbon atoms; each of R.sub.2, R.sub.4, R.sub.8 and R.sub.9 is independently a hydrogen atom, hydroxyl group, alkyl group having 1 or 2 carbon atoms, alkoxy group having 1 or 2 carbon atoms, or acetylamino group; R.sub.5 is a hydroxyl group or amino group at the o-position or p-position to the azo group; each of R.sub.6 and R.sub.10 is a hydrogen atom, carboxyl group, or alkoxy group having 1 or 2 carbon atoms; each of R.sub.7 and R.sub.Type: GrantFiled: April 6, 1994Date of Patent: April 8, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tsutami Misawa, Akira Ogiso, Rihoko Imai, Hisato Itoh
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Patent number: 5618886Abstract: The present invention provides olefin polymerization catalysts and processes for preparing a polypropylene and a propylene block copolymer using said olefin polymerization catalysts.The olefin polymerization catalyst (1) of the invention is formed from:[I-1] a contact product obtained by contacting:(A) a solid titanium catalyst component,(B) an organometallic compound catalyst component, and(C) a specific organosilicon compound;[II-1] (D) a specific polyether compound; and optionally,[III] an organometallic compound catalyst component.The olefin polymerization catalyst (2) of the invention is formed from:[I-2] a contact product obtained by contacting:(A) a solid titanium catalyst component,(B) an organometallic compound catalyst component, and(D) a specific polyether compound;[11-2] (C) a specific organosilicon compound.Type: GrantFiled: July 31, 1996Date of Patent: April 8, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Tetsunori Shinozaki, Mamoru Kioka
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Patent number: 5618984Abstract: An allyletherificated phenol aralkyl resin is obtained through the reaction of a phenol aralkyl resin with an allyl halide in the presence of a base in an organic solvent at room temperature to 100.degree. C. and changed into an allylated phenol aralkyl resin at 160.degree.-250.degree. C. through Claisen rearrangement. The two resins are low in melt viscosity. Epoxy resin compositions containing the allylated phenol aralkyl resin as the curing agent give cured products being excellent in heat and moisture resistances.Type: GrantFiled: June 14, 1995Date of Patent: April 8, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tomoyuki Kawabata, Teruo Yuasa, Shigeru Iimuro
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Patent number: 5616783Abstract: A purification process for polyhydroxycarboxylic acids which comprises dissolving polyhydroxycarboxylic acid in an water-immiscible phenol or an organic solvent containing said water-immiscible phenol, successively bringing the resulting solution into contact with water which contains an acidic material, separating the organic layer from an aqueous layer, and isolating polyhydroxycarboxylic acid from the organic layer. The process can efficiently remove a catalyst contained in the polyhydroxycarboxylic acid prepared in the presence of the catalyst, does not require polyhydroxycarboxylic acid to be in the form of a solid, and can treat polyhydroxycarboxylic acid in a higher concentration as compared with using chlorinated hydrocarbon as a solvent.Type: GrantFiled: September 28, 1995Date of Patent: April 1, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Yasunori Yoshida, Katsuji Watanabe, Shoji Obuchi, Masahiro Ohta
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Patent number: 5615564Abstract: A door locking device with an antitheft mechanism comprises a main lock lever linked to a key cylinder and changed over from an unlock position to an antitheft position through a lock position, a sub lock lever linked to an inside lock button of the door and changed over to an unlock position and a lock position, and a linkage member having sufficient elasticity to connect the lock levers with each other between the lock position and unlock position. As the main lock lever is displaced from the lock position to the antitheft position the linkage member is elastically deformed and permits the sub lock lever to be left at the lock position, and as the main lock lever is displaced to the antitheft position the sub lock lever is composed so that it can not change over the main lock lever.Type: GrantFiled: June 21, 1994Date of Patent: April 1, 1997Assignee: Mitsui Kinzoku Kogyo Kabushiki KaishaInventor: Jiro Inoue
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Patent number: 5616663Abstract: Disclosed is a novel transition metal compound represented by the following formula: ##STR1## wherein M is a transition metal, X is halogen or the like, R.sup.1 is a hydrocarbon group or the like, R.sup.2 is an aryl group substituted with a halogenated hydrocarbon group, and Y is a divalent silicon-containing group or the like.Also disclosed are an olefin polymerization catalyst component comprising the transition metal compound, an olefin polymerization catalyst comprising the olefin polymerization catalyst component, and a process for olefin polymerization using the olefin polymerization catalyst.An olefin polymerization catalyst component having high polymerization activity can be formed from the transition metal compound. By the use of the olefin polymerization catalyst or the process for olefin polymerization, polyolefins having a high melting point and a high molecular weight can be prepared with high polymerization activity.Type: GrantFiled: November 10, 1994Date of Patent: April 1, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Junichi Imuta, Daisuke Fukuoka, Masayasu Yoshida, Junji Saito, Terunori Fujita, Takashi Tashiro, Koji Kawaai, Takashi Ueda, Yoshihisa Kiso
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Patent number: 5616806Abstract: A process for the continuous preparation of aniline by hydrogenating nitrobenzene with hydrogen is disclosed which comprises the steps of suspending, in an aniline solvent, a catalyst of palladium or palladium-platinum which is deposited on a lipophilic carbon having an oil absorbency of at least 100, and carrying out reaction at a temperature of from 150.degree. to 250.degree. C. substantially in the absence of water while aniline and water formed in said reaction are continuously distilled off as vapor from the reaction product, and the concentration of nitrobenzene in the reaction solution is maintained at 0.01% by weight or less, wherein a zinc compound is added to the reaction system as a promotor and carbon monoxide is added to the hydrogen at a concentration of 1-500 ppm.Type: GrantFiled: September 17, 1991Date of Patent: April 1, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Teruyuki Nagata, Katsuji Watanabe, Yoshitsugu Kono, Akihiro Tamaki, Takashi Kobayashi
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Patent number: 5614527Abstract: A tetrahydrofuran-compound is disclosed herein which is represented by the formula (1) ##STR1## wherein each of X.sub.1 and X.sub.2 is a hydrogen atom or a methyl group, Y is a hydrogen atom or a carbonyl group substituted by a lower alkyl group (Y') having 1 to 4 carbon atoms, i.e., an acyl group (--COY'), andn is 2 or 3,and an insecticide containing the tetrahydrofuran-compound as an effective component.Type: GrantFiled: May 23, 1995Date of Patent: March 25, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Katsutoshi Kinoshita, Takeo Wakita, Kenji Kodaka, Hirozumi Matsuno, Kenichi Satoh, Shirou Shiraishi, Kazutomi Ohnuma, Eiichi Yamada, Naoko Yasui, Nobuyuki Kawahara, Koichi Ebihara, Michihiko Nakaya
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Patent number: 5614044Abstract: Laminated ceramic devices useful as an actuator or other device responsive to electrostrictive effects or photoelectric effects are manufactured by a method which includes the steps of forming an internal electrode on each of a plurality of unbaked ceramic sheets. Each of the internal electrodes is provided with a notched area for defining a so-called future space. A plurality of the unbaked ceramic sheets is assembled to form a laminate whereby the notched areas defining the future spaces are alternately located on two different sides of the laminate with the alternate notched areas being vertically aligned. The assembled plurality of ceramic sheets is then fired and the internal electrodes baked to thereby definitively form spaces defined by the notched areas which define the so-called future or void spaces. The resulting formed spaces are thereby alternatively located on different sides of the laminate.Type: GrantFiled: April 3, 1995Date of Patent: March 25, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Hiroyuki Nagayama, Yoshihisa Ushida
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Patent number: 5614443Abstract: Method of producing a frame made of connected semiconductor die mounting substrates comprises i) a first step for producing a metal substrate sheet wherein an original material for metal substrate sheet of a desired size is cut out from a metal material and an erosion preventing layer is provided on the entire surface thereof, ii) a second step for producing a circuit substrate sheet wherein the circuit substrate sheet is made of a resin substrate coated with a copper leaf layer and is provided with a lead pattern on the surface thereof in place, iii) a third step for producing a connected semiconductor die mounting substrate sheet by adhering the metal substrate sheet to the circuit substrate sheet, iv) a fourth step for forming a plurality of pilot apertures and slits on the connected semiconductor die mounting substrate sheet by press working and v) a fifth step for producing a plurality of connected semiconductor die mounting substrate frames by separating the connected semiconductor die mounting substratType: GrantFiled: March 27, 1996Date of Patent: March 25, 1997Assignee: Mitsui High-tec, Inc.Inventors: Takashi Nakashima, Keiji Takai, Kouji Tateishi
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Patent number: 5614769Abstract: A vehicle door locking system comprises a control portion for performing control operations of changing positions of lock levers into locking positions and of changing positions of anti-theft mechanisms into anti-theft positions. The control portion causes sending means to send out a warning signal for a predetermined time period, when a faulty change in position of the lock levers or the anti-theft mechanisms occurs. If a key cylinder or a transmitter is operated during the signal is sent out, the warning signal is stopped even before the predetermined time period has elapsed.Type: GrantFiled: August 1, 1995Date of Patent: March 25, 1997Assignee: Mitsui Kinzoku Kogyo Kabushiki KaishaInventor: Katsuya Kuroda
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Patent number: 5612087Abstract: A fibrous electrically-conductive filler herein provided comprises fibrous aluminum borate as a core material provided thereon with, in order, an optional titanium oxide intermediate layer and an antimony-free tin oxide layer. The fibrous electrically-conductive filler can be prepared by a method which comprises the steps of optionally forming an intermediate layer of titanium oxide by depositing titanium oxide hydrate on the surface of the core material and then calcining the titanium oxide hydrate layer; then forming a coating layer of tin oxide hydrate on the surface of the titanium oxide-coated fibrous aluminum borate or the fibrous aluminum borate as a core material and then calcining the coating layer at a temperature ranging from 150.degree. to 600.degree. C. in an inert gas atmosphere or a reducing atmosphere to form an antimony-free tin oxide layer.Type: GrantFiled: November 30, 1995Date of Patent: March 18, 1997Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Takao Hayashi, Nobuyoshi Kasahara, Norihiro Sato, Kouichi Kawaratani