Patents Assigned to Mitsui
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Patent number: 5656691Abstract: A reformed polypropylene resin composition having high degree of fluidity and excellent impact strength and rigidity, and further having a melt flow rate of from 50 to 150 g/10 min. and establishing a relationship between the melt flow rate (X) and the Izod impact strength (Y) which satisfies a relation Y.gtoreq.-4.7878 log X+13.8829. The reformed polypropylene resin composition is obtained by blending 0.01 to 0.2 parts by weight of an organic peroxide and 0.05 to 1 part by weight of a crosslinking agent per 100 parts by weight of a total of 50 to 90 parts by weight of a polypropylene having a melt flow rate at 230.degree. C. of 10 to 70 g/10 min, 0 to 25 parts by weight of an olefin copolymer rubber, and 5 to 40 parts by weight of an organic filler, and by melt-kneading the mixture by using a biaxial extruder maintaining a temperature of 120.degree. to 200.degree. in the preceding stage of the screw and a temperature of 180.degree. to 270.degree. C.Type: GrantFiled: March 14, 1995Date of Patent: August 12, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yasuhiro Niki, Toshio Kobayashi, Takashi Arai
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Patent number: 5654386Abstract: A random copolymer characterized in that (A) the copolymer comprises polymerized units from ethylene and polymerized units from at least one cycloolefin, (B) the mole ratio of the polymerized units from the cycloolefin to the polymerized units from ethylene is from 3:97 to 60:40, (C) the cycloolefin is incorporated in the polymer chain without ring opening, (D) the copolymer has an intrinsic viscosity of 0.01 to 20 dl/g, (E) the copolymer has a molecular weight distribution (Mw/Mn) of not more than 4, and (F) the copolymer has a crystallinity of 0 to 10%. The random copolymer may be grafted by (a) alpha, beta-unsaturated carboxylic acids and/or their derivatives, (b) styrenes, (c) organic silicon compounds having an olefinically unsaturated bond and a hydrolyzable group, or (d) unsaturated epoxy monomers.Type: GrantFiled: June 7, 1995Date of Patent: August 5, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Syuji Minami, Hirokazu Kajiura, Hidekuni Oda
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Patent number: 5653839Abstract: A fire-resistant glass comprising:(a) at least two plate-shaped vitreous materials arranged parallel and apart, the sides of the plate-shaped vitreous materials facing each other being treated with a silane coupling agent,(b) a spacer provided between the plate-shaped vitreous materials at their peripheries via an adhesive,(c) a sealing agent adhered to the outer surface of the spacer, and(d) an aqueous gel filled into the space formed by the plate-shaped vitreous materials and the spacer, the aqueous gel comprising a polymer of a particular (meth)acrylamide derivative, a particulate metal oxide, an aqueous medium and an antifreezing agent.This fire-resistant glass has an excellent fire-resistant property; is stable over a long period of time and is unsusceptible to deterioration.Type: GrantFiled: April 4, 1995Date of Patent: August 5, 1997Assignees: Mitsui Toatsu Chemical Incorporated, Central Glass Company, LimitedInventors: Hiroshi Itoh, Takashi Abe, Hitoshi Yamashita, Toshihiro Yoshimura, Takeshi Hisanaga, Takao Takebayashi, Kunio Nakata, Chikara Hashimoto
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Patent number: 5654248Abstract: A prepolymerized solid catalyst for gaseous phase or slurry polymerization of alpha olefins is disclosed. The catalyst comprises a porous carrier having a particle size of 20 to 200 microns onto which has been deposited an aluminoxane and a transition metal compound having at least one cycloalkadienyl group, the transition metal being from group 4 of the Periodic Table. The transition metal is present in an amount of 0.003 to 3 mmol/gm of carrier, and the aluminum to transition metal atomic ratio is from 15 to 1000. This catalyst is then prepolymerized with 0.2 to 30 gm of an alpha olefin per gram of catalyst to form the final prepolymerized solid catalyst having an intrinsic viscosity of 0.2 to 20 dl/gm as measured in decalin at 135 deg C.Type: GrantFiled: May 2, 1995Date of Patent: August 5, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Mamoru Kioka, Akinori Toyota, Norio Kashiwa, Toshiyuki Tsutsui
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Patent number: 5654483Abstract: A process for producing an alkoxy-substituted tri-phenylamine comprising reacting an alkoxy-substituted cyclohexanone with a diphenylamine or an aniline, while forming said cyclohexanone in the same system from an alkoxy-substituted phenol by using said phenol as a hydrogen acceptor, in the presence of a hydrogen transfer catalyst and a catalytic amount of the alkoxy-substituted cyclohexanone corresponding to the alkoxy-substituted phenol used for the reaction, or after converting partially the alkoxy-substituted phenol to a catalytic amount of the alkoxy-substituted cyclohexanone under a hydrogen pressure in the presence of a hydrogen transfer catalyst, wherein a surface-supported catalyst is used as the hydrogen transfer catalyst.Type: GrantFiled: December 19, 1995Date of Patent: August 5, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Chiyuki Kikuchi, Hiroshi Naruse, Masaru Wada, Teruyuki Nagata
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Patent number: 5652321Abstract: A composition for optical materials is herein disclosed which comprises the following two components (a) and (b):(a) a component containing at least one of poly isocyanates represented by the formula (1)A.paren open-st.S--B--NCO).sub.n (1)wherein A is an alkanediyl group or an alkanetetrayl group which may contain a sulfur atom, or a dithianetetrayl group, and the alkanediyl group or the alkanetetrayl group may be substituted by a phenyl group; B is a methylene chain represented by .paren open-st.CH.sub.2 .paren close-st..sub.m (m is an integer of 1 to 4) which may contain a sulfur atom, and B's may be the same or different; and n is an integer of 2 or 4, and(b) a component containing at least one of polythiols having two or more mercapto groups. The composition is useful to provide optical products such as plastic lenses, filters, substrates for recording media and optical fibers which have a very high refractive index and which are excellent in heat resistance.Type: GrantFiled: October 30, 1995Date of Patent: July 29, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Nobuya Kawauchi, Katsuyoshi Sasagawa, Seiichi Kobayashi
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Patent number: 5652315Abstract: A method for preparing an ethylene copolymer which comprises the step of copolymerizing ethylene with an aromatic vinyl compound in the presence of a catalyst comprising (A) a specific transition metal compound represented by the formula I ##STR1## and (B) a cocatalyst such as an aluminoxane.Type: GrantFiled: June 14, 1996Date of Patent: July 29, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Norihide Inoue, Tetsunosuke Shiomura, Masahiro Kouno
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Patent number: 5651889Abstract: A membrane apparatus includes a bubble supplying portion for supplying micro bubbles which is provided at a location in the vicinity of the entrance of a flow passage for raw liquid. Thus, the growth of a gel layer on a membrane surface can be prevented, and a large filtering amount can be maintained while preventing sludge from blocking the membrane. Moreover, since bubbles uniformly pass through the inter-membrane passages, sludge blocking can be evenly prevented over the entire surface of the membrane. When a flat membrane is used as the filtering membrane, there is provided an advantage of reducing the frequency of work for disassembling the frame and cleaning the membranes. A membrane treatment apparatus includes the membrane apparatus, an aeration apparatus, a circulating tank, and a filtrate pump.Type: GrantFiled: March 25, 1996Date of Patent: July 29, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Sakae Wataya, Kimio Yamamoto, Hirokazu Shirage, Kouji Irie, Tadaaki Hashimoto
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Patent number: 5652303Abstract: A catalyst for polymerization of an olefin, said catalyst being formed from[A] a solid titanium catalyst component comprising magnesium, titanium, halogen and an electron donor as essential ingredients,[B] an organoaluminum compound catalyst component, and[C] an electron donor catalyst component comprising at least two electron donors including an electron donor (1) and an electron donor (2), the MFR (a) of homopolypropylene obtained by using the electron donor (1) together with the solid titanium catalyst component [A] and the organoaluminum compound catalyst component [B] has the following relation to the MFR (b) of homopolypropylene obtained by using the electron donor (2) under the same polymerization conditions as in the case of using the electron donor (1)log [MFR (b)/MFR (a)].gtoreq.1.5.This catalyst can give an olefin polymer having a broad molecular weight. Also provided is a process for polymerizing or copolymerizing an olefin in the presence of the above catalyst.Type: GrantFiled: December 6, 1995Date of Patent: July 29, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Naoshi Ishimaru, Mamoru Kioka, Akinori Toyota
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Patent number: 5650204Abstract: The refillable polyester bottle of the invention has a mean crystallinity of 32 to 70% at the bottle body, a methanol adsorption of 1,500 ppm or less at the same portion and a paraxylene adsorption of 300 ppm or less at the same portion. Therefore, the bottle is excellent in non-adsorptivity and heat resistance. According to the method of removing adsorbates on a polyester bottle of the invention, the adsorbates can be rapidly desorbed by holding the bottle in air of 40.degree. to 150.degree. C. or bringing the bottle into contact with water or water vapor heated at 40.degree. to 150.degree. C.Type: GrantFiled: September 6, 1994Date of Patent: July 22, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Hidenori Kaya, Hiroji Niimi, Susumu Hatabu, Kunio Tomita
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Patent number: 5650471Abstract: There is provided a process for the production of a cycloolefin copolymer which comprises copolymerizing an .alpha.-olefin having 2 or more carbon atoms and a specific cycloolefin in the presence of a specific metallocene type catalyst in a solvent mixture of a hydrocarbon solvent having a solubility parameter (value of .delta.) of 7.7 [(cal/cm.sup.3).sup.1/2 ] or more and a hydrocarbon solvent having a solubility parameter (value of .delta.) of 7.5 [(cal/cm.sup.3).sup.1/2 ] or less as a polymerization solvent. A cycloolefin copolymer having a high molecular weight can be produced in a high concentration by this process at a high yield.Type: GrantFiled: December 27, 1995Date of Patent: July 22, 1997Assignees: Mitsui Petrochemical Industries, Ltd., Hoechst AktiengesellschaftInventors: Yoshiharu Abe, Toshihiro Sagane
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Patent number: 5650463Abstract: Moldable polyimide resin composition which has melt-flowability and excellent processability in addition to essential heat-resistant of polyimide and comprises an aromatic bisimide compound and polyimide to resin. A further aspects relates to, a carbon fiber reinforced polyimide resin composition which has excellent mechanical strengths and comprises a carbon fiber coated with aromatic bisimide compound on the surface and the polyimide to resin, A still further aspect relates to and a novel bisimide compound which is very useful as the aromatic bisimide compound in the composition.Type: GrantFiled: June 7, 1995Date of Patent: July 22, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Masahiro Ohta, Akio Matsuyama, Eiji Senoue, Fumiaki Kuwano, Osamu Yasui, Tadashi Kobayashi
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Patent number: 5650451Abstract: Biaxially oriented films from high molecular weight polyethylene are characterized by a gas permeable structure formed from random-arranged microfibrils. The films have coefficients of static friction and kinetic friction of not more than 1.0. The biaxially oriented films are further characterized by service smoothness as well as tensile (tangent) modulus and tensile strength. The films may be used for lamination, filter, or for packaging for moisture absorbers. The biaxially oriented films may be obtained by extracting a hydrocarbon plasticizer from a sheet formed from the high molecular weight polyethylene and a hydrocarbon plasticizer, stretching the resulting sheet to obtain an oriented film having a specific surface area of at least 70 m.sup.2 /g and a fibril structure, and heating the oriented film under a standard length constraint to reduce the oriented film in specific area by at least 20 m.sup.2 /g.Type: GrantFiled: June 10, 1996Date of Patent: July 22, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuo Yagi, Hitoshi Mantoku, Akinao Hashimoto, Isaburo Higashi, Yoshinori Akana
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Patent number: 5647896Abstract: Provided are a color-developing agent comprising a multivalent metal salt of a salicylic acid derivative and a sulfonated phenol and/or a metal salt thereof and having excellent initial and ultimate color-developing capacities and improved waterproofness; and a color-developing sheet making use of the color-developing agent.Type: GrantFiled: October 30, 1995Date of Patent: July 15, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Takeshi Nishimura, Tomoko Kamashita, Masaru Wada, Teruyuki Nagata, Yoshimitsu Tanabe, Kiyoharu Hasegawa, Masakatsu Nakatsuka
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Patent number: 5648446Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.Type: GrantFiled: March 30, 1995Date of Patent: July 15, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
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Patent number: 5648499Abstract: A safe and reliable method of decomposing halogenated aromatic compounds, wherein a heat-resistant alkaline polar solvent containing halogenated aromatic compounds is contacted with a alkali at a temperature ranging from about 100.degree. C. to 300.degree. C. in order to decompose the halogenated aromatic compounds. The used solvent is removed of solid contents of salts, alkalis and the like, whereby it can be recycled.Type: GrantFiled: March 23, 1995Date of Patent: July 15, 1997Assignees: Mitsui & Co., Ltd., Neos Co., Ltd, Research Institute for Production DevelopmentInventors: Fumio Tanimoto, Tsuneo Yano
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Patent number: 5647921Abstract: A process for producing an amorphous alloy ribbon by the single roll method is disclosed, which comprises injecting through a slot disposed at a nozzle tip a molten alloy having the composition represented by the general formula:(Fe.sub.1-a M.sub.a).sub.100-x-y-z-b Cu.sub.x Si.sub.y B.sub.z M'.sub.bwherein M is Co and/or Ni, M' is at least one element selected from the group consisting of Nb, Mo, W and Ta, and a, x, y, z and b satisfy the relationships: 0.ltoreq.a.ltoreq.0.1, 0.5.ltoreq.x.ltoreq.2 (atomic %), 5.ltoreq.y.ltoreq.20 (atomic %), 5.ltoreq.z.ltoreq.11 (atomic %), 14.ltoreq.y+z.ltoreq.25 (atomic %) and 2.ltoreq.b.ltoreq.5 (atomic %), provided that the ratio of y to z (y/z) is in the range of 0.5.ltoreq.y/z.ltoreq.3, onto a cooling wheel comprising a Cu alloy containing Be in an amount of 0.05 to 3.0% by weight. This process is advantageous in that the position of peel of the amorphous alloy ribbon formed on the cooling wheel can be controlled.Type: GrantFiled: April 23, 1996Date of Patent: July 15, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kenji Odagawa, Hiroshi Watanabe
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Patent number: 5648423Abstract: The polyamide resin composition of the present invention comprises 100 parts by weight of a polyamide resin and 5 to 200 parts by weight of a graft-modified ethylene/1-butene random copolymer having a graft quantity of an unsaturated carboxylic acid or its derivative of 0.01 to 10% by weight. The graft-modified ethylene/1-butene random copolymer is a graft-modified product of an ethylene/1-butene random copolymer having a 1-butene content of 15 to 25% by mol, an intrinsic viscosity [.eta.] of 0.5 to 3.5 dl/g, a glass transition temperature (Tg) of not higher than -60.degree. C., a crystallinity of less than 10%, and a parameter (B value) indicating randomness of a copolymerized monomer chain distribution, as measured by a .sup.13 C-NMR method, of 1.0 to 1.4. The polyamide resin composition shows high melt flowability, namely, good moldability, and it can provide a molded article excellent in flexibility, low-temperature impact resistance, resistance to water absorption and resistance to saline solutions.Type: GrantFiled: April 5, 1995Date of Patent: July 15, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Mamoru Kagami, Mutsuhiro Tanaka, Masahiro Sugi
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Patent number: 5646273Abstract: A phthalocyanine represented by the formula (1) ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently an alkyl group substituted by 0 to 5 halogen atoms and having 1 to 20 carbon atoms, an alkenyl group substituted by 0 to 5 halogen atoms and having 2 to 20 carbon atoms or an alkynyl group substituted by 0 to 5 halogen atoms and having 2 to 20 carbon atoms, and at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.Type: GrantFiled: September 20, 1995Date of Patent: July 8, 1997Assignees: Mitsui Toatsu Chemicals, Inc., Yamamoto Chemicals, Inc.Inventors: Takahisa Oguchi, Hideki Umehara, Kenichi Sugimoto, Ryu Oi, Hisato Itoh
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Patent number: 5646240Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.Type: GrantFiled: March 21, 1996Date of Patent: July 8, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono