Patents Assigned to Mitsui
  • Patent number: 5286418
    Abstract: Disclosed is a polarizing film comprising a hydrophobic polymer containing a dichroic organic colorant in an oriented state which is characterized in that the dichroic organic colorant is substantially insoluble in water, organic solvents and liquid crystals and the dichroic ratio of the colorant is not less than 7 when it is measured with the film obtained by blending the colorant intimately with polyethylene terephthalate, melting the resulting blend and forming it into a film. This polarizing film has exceptionally excellent moisture resistance and thermal resistance.
    Type: Grant
    Filed: July 3, 1991
    Date of Patent: February 15, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Katsuji Nakamura, Junichi Fujio, Shin Hosonuma, Masakatsu Nakatsuka, Tsutomu Nishizawa
  • Patent number: 5286840
    Abstract: A thermally stable polyimide which is blocked at the polymer terminal with a dicarboxylic acid anhydride represented by the formula (III): ##STR1## wherein Z is a divalent radical selected from the group consisting of a monoaromatic radical which is substantially unsubstituted or substituted with a radical having no reactivity with amine or dicarboxylic acid anhydride and has from 6 to 15 carbon atoms, a condensed polyaromatic radical or a noncondensed aromatic radical connected each other with a direct bond or a bridge member, and has a fundamental skeleton represented by recurring structural units of the formula (IV): ##STR2## and a process of preparing the polyimide.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: February 15, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hideaki Oikawa, Nobuhito Koga, Akihiro Yamaguchi, Shoji Tamai
  • Patent number: 5283222
    Abstract: Disclosed are novel crystal of the fluoran compound represented by the formula (I) ##STR1## , characterized by a specific X-ray diffraction diagram; preparation process thereof; and recording materials comprising the crystal.
    Type: Grant
    Filed: September 24, 1992
    Date of Patent: February 1, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Akihiro Yamaguchi
  • Patent number: 5283312
    Abstract: A mercapto compound represented by the following formula (1): ##STR1## is obtained by reacting, in the presence of a mineral acid, thiourea with a compound represented by the following formula (2): wherein X means a hydroxyl group or a chlorine or bromine atom, and then adding a base to alkalinize the reaction mixture so that the reaction product is hydrolyzed.The mercapto compound represented by the formula (1) can be reacted with at least one cyanate compound selected from the group consisting of polyisocyanate compounds, polyisothiocyanate compounds and isocyanate-group-containing isothiocyanate compounds to form a sulfur-containing urethane resin lens made of the resin is colorless and transparent, has high refractive index and low dispersion characteristics, and is excellent especially in heat resistance.
    Type: Grant
    Filed: August 4, 1992
    Date of Patent: February 1, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoshinobu Kanemura, Katsuyoshi Sasagawa, Seiichi Kobayashi
  • Patent number: 5283365
    Abstract: A process for the continuous preparation of aniline by hydrogenating nitrobenzene is disclosed which comprises the steps of suspending, in an aniline solvent, a catalyst of palladium or palladium-platinum which is deposited on a lipophilic carbon having an oil absorbency of at least 100, adding a zinc compound and an alkali metal carbonate or a zinc compound and an alkali metal bicarbonate as promotors to the reaction system, and carrying out reaction at a temperature of from 150 to 250.degree. C. substantially in the absence of water while aniline and water formed in said reaction are continuously distilled off as vapor from the reaction product, and the concentration of nitrobenzene in the reaction solution is maintained at 0.01% by weight or less.
    Type: Grant
    Filed: June 10, 1992
    Date of Patent: February 1, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Teruyuki Nagata, Katsuji Watanabe, Yoshitsugu Kono, Akihiro Tamaki, Takashi Kobayashi
  • Patent number: 5283094
    Abstract: An optical recording medium of a single plate type comprises a substrate, a recording layer overlying the substrate, a reflective layer overlying the recording layer, and a protective layer overlying the reflective layer, the recording layer being produced by coating a nonpolar solvent-soluble substituted phthalocyanine dye in a nonpolar solvent and the nonpolar solvent content of in the recording layer being 5% by weight or less.
    Type: Grant
    Filed: April 27, 1992
    Date of Patent: February 1, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tomoyoshi Sasakawa, Nobuhisa Kitagawa, Tadashi Koike, Hiroyuki Hyakutake
  • Patent number: 5283357
    Abstract: A method for separating .alpha.-L-aspartyl-L-phenylalanine methyl ester (.alpha.-APM) from a solution containing .alpha.-APM and impurities associated with the production thereof which comprises adding a mineral acid or an organic sulfonic acid to the solution in an organic carboxylic acid or in a solvent containing an organic carboxylic acid, and isolating the pure salt of .alpha.-APM which precipitates therefrom.
    Type: Grant
    Filed: April 23, 1991
    Date of Patent: February 1, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Toshio Katoh, Chojiro Higuchi, Takeshi Oura, Masanobu Ajioka, Akihiro Yamaguchi
  • Patent number: 5283313
    Abstract: A readily processable polyimide being blocked at the terminal of a polymer molecule with a divalent radical derived from dicarboxylic acid anhydride represented by the formula (IV): ##STR1## wherein Z is a divalent radical selected from the group consisting of a monoaromatic radical which is substantially unsubstituted or substituted with a radical having no reactivity with amine or carboxylic acid anhydride and has from 5 to 15 carbons atoms, condensed polyaromatic radical or noncondensed aromatic radical connected each other with a direct bond or a bridge member, and having a fundamental skeleton represented by recurring structural units of the formula (III): wherein X and Y are --O-- or --CO-- and differ each other; preparation process of the polyimide; and resin composition containing the polyimide and fibrous reinforcement.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: February 1, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Wataru Yamashita, Shoji Tamai, Akihiro Yamaguchi
  • Patent number: 5283100
    Abstract: Disclosed is a molding a molding for mounting a window glass on the window opening of an automotive body, said molding for automobile windows comprising a flexible leg portion, an upper flange portion which extends toward both sides at an upper part of the leg portion and supports the edge portion of the glass, upper lip portions that form both tips of said upper flange portion, and lower lip portion which are adhered to the window opening of the automotive body, wherein at least the upper lip portions and the lower lip portions of said molding are formed by using a thermoplastic olefinic elastomer or a composition of said elastomer and an olefin-ethylene type unsaturated carboxylic acid copolymer or a salt thereof having a hardness in compliance with JIS A of from 50 to 80, said leg portion and said flange portion are formed by using a blend of the thermoplastic olefinic elastomer and the olefin-ethylene type unsaturated carboxylic acid copolymer or a salt thereof, said blend having a hardness in compliance
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: February 1, 1994
    Assignees: Dupont-Mitsui Polychemicals Co., Ltd., Tokiwa Chemical Industry Co., Ltd.
    Inventors: Toshio Yui, Yoshimasa Yamamoto, Naohisa Miyakawa
  • Patent number: 5281570
    Abstract: A reversible thermochromic material, preferably in the form of a microcapsule, comprising:(a) an electron donative color former;(b) a sulfide, sulfoxide or sulfone containing a hydroxy phenyl radical; and(c) a chemical compound selected from alcohols, esters, ethers, ketones, carboxylic acids or acid amides,chromatizes very brightly and in a dense color, generates a change of chromic hue (colored - colorless) within a narrow temperature range and provides a stable thermochromatism on a long term basis.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: January 25, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Kiyoharu Hasegawa, Yoshimitsu Tanabe, Kazuyoshi Kikkawa, Masakatsu Nakatsuka, Akihiro Yamaguchi
  • Patent number: 5281641
    Abstract: A dental or surgical adhesive filler containing (a) a polymerizable acrylic acid or methacrylic acid derivative, (b) a vinyl polymer powder, (c) an organic boron compound as a curing agent, and optionally, a polar organic compound and an inert diluent. The advantage of the above dental or surgical adhesive filler is that it is easy to handle due to stability in curing time and freedom of ignition.
    Type: Grant
    Filed: March 11, 1993
    Date of Patent: January 25, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hiroshi Nishimura, Shousuke Ito, Masao Nakano, Sunao Kaneda, Kayoko Adachi
  • Patent number: 5279915
    Abstract: Disclosed is a toner composition for electrophotography which comprises, as a principal component, a urethane-modified polyester resin whose loss tangent (tan .delta.) has a maximum and a minimum both falling within the range of from 0.7 to 2.5, the loss tangent being determined at 150.degree. C. and a frequency ranging from 10.sup.-2 to 10 Hz. The toner composition has excellent low temperature fixing ability and offset resistance as well as a wide range of permitted fixing temperature.
    Type: Grant
    Filed: December 19, 1989
    Date of Patent: January 18, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kazuo Hagiwara, Akira Misawa, Kazuo Hisamatsu, Keiichi Ishikawa, Masaaki Shin
  • Patent number: 5280114
    Abstract: Halogenated alkoxyphthalocyanine having a controlled grade of halogenation can be prepared by reacting a single compound or a mixture of phthalocyanine represented by the formula (1): ##STR1## wherein R.sup.1 is a substituted or unsubstituted alkyl group and may be the same or different, and Met is two hydrogen atoms, a divalent metal atom or a trivalent or tetravalent metal derivative, with 1 to 6 mole ratio of a halogenating agent at 0.degree. to 260.degree. C. in a solvent of from 1 to 1000 times by weight.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: January 18, 1994
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Takahisa Oguchi, Shin Aihara
  • Patent number: 5278204
    Abstract: Disclosed is a heat-resistant rubber composition comprising (A) 100 parts by weight of an ethylene/.alpha.-olefin copolymer or a modified ethylene/.alpha.-olefin copolymer formed by graft-copolymerization with at least one compound selected from the group consisting of unsaturated carboxylic acids and anhydrides and esters thereof, and (B) (i) 10 to 100 parts by weight of a silica type filler which has been treated with a silane compound represented by the following formula: ##STR1## wherein R.sup.1 stands for an alkenyl group, a chloroalkenyl group or a chloroalkyl group, and R.sup.2 stands for a lower alkyl group, or (ii) a combination of 10 to 100 parts by weight of said silane-treated silica type filler or an untreated silica type filler and 0.5 to 30 parts by weight of a polyorganosiloxane having an average composition represented by the following formula:(R.sup.3).sub.a (R.sup.4).sub.b SiO.sub.(4-a-b)/2 (II)wherein R.sup.3 stands for a monovalent saturated or unsaturated hydrocarbon group, R.sup.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: January 11, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Tetsuo Tojo, Katsuo Okamoto, Akira Matsuda, Eckhart Louis
  • Patent number: 5277988
    Abstract: A heat seal material having a plurality of resin surfaces which are positioned face to face and can be heat-fused together, at least one of the resin surfaces being formed of a resin composition comprising(A) 30 to 85% by weight of low-density polyethylene having a density of 0.91 to 0.94 g/cm.sup.3 and a crystallinity of more than 40%,(B) 5 to 40% by weight of polypropylene, and(C) 10 to 40% by weight of a low-crystalline or substantially amorphous ethylene/alpha-olefin copolymer.
    Type: Grant
    Filed: January 29, 1992
    Date of Patent: January 11, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Masahiro Sugi, Takasi Nakagawa
  • Patent number: 5278276
    Abstract: Polyimide having repeating units of the following formula (I) and its polyamic acid precursor having repeating units of the following formula (II) are disclosed; ##STR1## (where Y is a radical selected from the group consisting of a bond, divalent hydrocarbon having 1 to 10 carbons, hexafluorinated isopropylidene, carbonyl, thio, sulfinyl, sulfonyl and oxide, and R is a tetra-valent radical selected from the group consisting of aliphatic radical having 2 and more carbons, cyclo-aliphatic radical, monoaromatic radical, condensed polyaromatic radical, and non-condensed polyaromatic radical wherein aromatic radicals are mutually connected with a bond or a crosslinking function).Typical examples of polyimide and polyamic acid include where Y is thio radical and R is ##STR2## Y is a bond and R is III or IV, and Y is isopropylidene radical and R is IV.The polymers can be prepared from corresponding diamine and tetracarboxylic acid dianhydride.
    Type: Grant
    Filed: January 26, 1993
    Date of Patent: January 11, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masahiro Ohta, Saburo Kawashima, Yoshiho Sonobe, Shoji Tamai, Hideaki Oikawa, Kouji Ohkoshi, Akihiro Yamaguchi
  • Patent number: 5278216
    Abstract: A syndiotactic polypropylene resin composition comprising a polypropylene having a substantially syndiotactic structure and a nucleating agent. The syndiotactic polypropylene may be a homopolymer of the propylene, a copolymer of the propylene and a smaller amount of another olefin or a mixture of the above-mentioned (co)polymer and an isotactic polypropylene. The resin composition preferably has a higher crystallization temperature than a polypropylene containing no nucleating agent by 5.degree. C. or more, as measurement is made by a differential scanning thermal analysis.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: January 11, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tadashi Asanuma, Tetsunosuke Shiomura, Nobutaka Uchikawa, Tateyo Sasaki, Takeo Inoue
  • Patent number: 5278214
    Abstract: The present invention discloses a polyolefin resin composition comprising a specific cycloolefin-based polymer (a), a graft-modified elastomer (b) and a compound (c) having one amino group in the molecule, and containing, based on the total amount of the components (a), (b) and (c), 50 to 95% by weight of the component (a), 1 to 50% by weight of the component (b) and 0.01 to 45% by weight of the component (c). This polyolefin resin composition is improved particularly in mechanical properties such as impact strength, etc., while retaining excellent properties of the cycloolefin-based polymer (a).
    Type: Grant
    Filed: January 29, 1992
    Date of Patent: January 11, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Satoru Moriya, Akio Ishimoto, Mamoru Takahashi
  • Patent number: 5275884
    Abstract: Bulky split fibers having bond strength are produced by preparing a composite synthetic resin film of three layer structure having a polypropylene layer formed of a polypropylene/polyethylene blend and a polyethylene layer on either surface of the polypropylene layer, slitting and stretching the composite film to thereby form stretched tapes, and causing splitting of the stretched tapes for fibrillation. An integral article is prepared from the resultant split fibers by mixing them alone or with plant fibers and then heating at a temperature between the melting points of polyethylene and polypropylene, thereby integrating together the split fibers with each other or with the plant fibers.
    Type: Grant
    Filed: September 3, 1992
    Date of Patent: January 4, 1994
    Assignees: Mitsui Petrochemical Industries, Ltd., Uni Charm Corporation
    Inventors: Kazunari Nishino, Shuzo Sasagawa, Hirofumi Katsurayama, Takamitsu Igaue, Tsutomu Kido
  • Patent number: 5276081
    Abstract: A rubber composition containing (A) 100 parts by weight of an amorphous or low-crystalline ethylene-.alpha.-olefin copolymer rubber having an ethylene content of 70 to 90 mole %, a molecular weight distribution (Mw/Mn) of 3.0 or more and a Mooney viscosity ML.sub.1+4 (100.degree. C.) of 5 to 80; and (B) 1 to 120 parts by weight of a liquid ethylene-.alpha.-olefin random copolymer having an ethylene content of 40 to 90 mole % and an intrinsic viscosity [.eta.] of 0.01 to 0.4 dl/g as measured in decalin at 135.degree. C.
    Type: Grant
    Filed: May 13, 1993
    Date of Patent: January 4, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hidenari Nakahama, Tosiaki Kimura, Takasi Misima