Patents Assigned to Mitsui
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Patent number: 5254617Abstract: A resin composition for producing a film is provided. The composition comprises (A) a high-density polyethylene having predetermined melt flow rate, density and melt tension, (B) a propylene-based polymer having predetermined melt flow rate, (C) talc, (D) CaO and/or MgO, and (E) a surface active agent. The resin compositions is readily formable into a film having excellent strength and water resistance as well as paper-like texture and rigidity. A method for producing a film by blown-film extrusion from such a resin composition is also provided. In this method, both ratio of diameter of the resulting bubble to minimum diameter of the bubble and ratio of length in machine direction of the bubble with predetermined diameter to the die diameter are adjusted to fall within predetermined ranges.Type: GrantFiled: June 17, 1991Date of Patent: October 19, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Hiroshi Inoue, Toshihiro Nishimura, Takashi Matsunaga
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Patent number: 5254612Abstract: Compositions provided in accordance with the present invention contain 85-20% by weight of a propylene/1-butene random copolymer (A) having a melt index (ASTM D 1238-65T, 230.degree. C.) of 0.1-100 g/10 min, propylene content of 60-85 mol %, and a heat of fusion, as measured by thermal analysis with a differential scanning calorimeter, of 20-80 joule/g,15-80% by weight of an ethylene/.alpha.-olefin copolymer (B) having a melt index (ASTM D 1238-65T, 190.degree. C.) of 0.1-100 g/10 min, ethylene content of 75-95 mol %, crystallinity index of 0-30%, and .alpha.-olefin having 3-10 carbon atoms, and 0-10% by weight of a tackifier (C), with the proviso that (A)+(B)+(C) is 100% by weight.The strippable protective film according to the invention is a single-layer or multi-layer film, with the proviso that at least one of the outermost surface layers of the film is composed of the composition.Type: GrantFiled: March 1, 1991Date of Patent: October 19, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Masahiro Sugi, Mutsuhiro Tanaka
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Patent number: 5254323Abstract: A gaseous mixture containing chlorine, carbon dioxide and non-condensable gas is compressed and cooled to separate it into a residual gas formed principally of a major portion of the non-condensable gas and a condensate formed primarily of chlorine. The condensate is fed to a stripping column to desorb carbon dioxide and a minor portion of the non-condensable gas dissolved in the condensate. The stripped gas formed primarily of chlorine and carbon dioxide may be treated further. Namely, the stripped gas is mixed with the residual gas. At least a portion of the mixed gas is fed into an absorption column, whereby a major portion of remaining chlorine is absorbed to lower the chlorine content Removal of chlorine from such a gaseous mixture or an off-gas from the above process can be achieved by washing it with an aqueous solution or suspension containing an alkali metal sulfite and/or an alkaline earth metal sulfite while controlling the pH of the solution or suspension within a range of 1.9-6.3.Type: GrantFiled: August 3, 1992Date of Patent: October 19, 1993Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Hiroyuki Itoh, Yoshitsugu Kono, Isao Kikuchi, Shinji Takenaka, Masanobu Ajioka, Mitsuo Kudoh
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Patent number: 5252529Abstract: A solid catalyst for olefin polymerization comprising [A] a particulate carrier composed of (i) an oxide of at least one element selected from among those belonging to the groups of II, III and IV of the periodic table, and containing (ii) at least 1.0% by weight of water, [B] an organoaluminum oxy compound, and [C] a transition metal compound of a metal belonging to the group IV B of the periodic table containing a ligand having a cyclopentadienyl skeleton,wherein the organoaluminum oxy compound [B] and the transition metal compound [C] are supported on the particulate carrier [A].Type: GrantFiled: May 20, 1992Date of Patent: October 12, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Ueda, Kazunori Okawa
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Patent number: 5252707Abstract: There are disclosed a novel inositol-1,4,5-triphosphoric acid derivative, inositol-1,3,4-triphosphoric acid derivative, inositol-1,3,4,5-tetraphosphoric acid derivative, and a bonded substance of the same and a protein. They control the metabolic process of an organism concerned with calcium ions to thereby exert a medicinal virtue.Type: GrantFiled: May 15, 1991Date of Patent: October 12, 1993Assignee: Mitsui Toatsu Chemicals IncorporatedInventors: Shoichiro Ozaki, Yutaka Watanabe, Masato Hirata, Akira Awaya
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Patent number: 5252769Abstract: Anthraquinonic colorant represented by the formula (I): ##STR1## wherein Q.sup.1 and Q.sup.2 are each independently substituted or unsubstituted anthraquinonyl groups, Z.sup.1 and Z.sup.2 are bridge groups, A is an aromatic divalent group, and n is 0 or 1. The polarizing film which contains at least one colorant of the present invention in a hydrophobic resin, has excellent durability and moisture resistance.Type: GrantFiled: June 26, 1992Date of Patent: October 12, 1993Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Tsutami Misawa, Hisato Itoh, Tsutomu Nishizawa, Masami Nakano, Hiroyuki Katayama
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Patent number: 5252700Abstract: The heat resistant adhesive of the invention comprises polyamic acid and/or polyimide which are prepared by using 1,3-bis(3-aminophenoxy)benzene as an aromatic diamine component and 3,3', 4,4'-biphenyltetracarboxylic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic dianhydride and/or 3,3',4,4'-diphenylethertetracarboxylic dianhydride as tetracarboxylic acid dianhydrides, and further by blocking the polymer chain end with dicarboxylic anhydride or a monoamine compound; or comprises a polyimide solution containing the polyimide in a good solvent.The adhesive of the invention is a heat-resistant adhesive capable of adhering under mild temperature/mild pressure conditions. The adhesive of polyimide solution can provide desired adhesion by simple procedures such as applying to the adherend and heating under pressure and exhibits excellent adhesive strength.Type: GrantFiled: April 21, 1992Date of Patent: October 12, 1993Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Hideaki Okikawa, Shoji Tamai, Katsuaki Iiyama, Saburo Kawashima, Akihiro Yamaguchi, Tadashi Asanuma
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Patent number: 5252394Abstract: In accordance with the present invention, there are provided high molecular weight polyethylene molecular orientation molded articles formed from high molecular weight polyethylenes having a weight average molecular weight of 300,000-600,000, said molecular orientation molded articles having a fineness of not more than 15 deniers, a tensile strength of more than at least 1.7 GPa and satisfying the tensile strength S (GPa)-weight average molecular weight M. (g/mol)-fineness D (denier) relationship represented by the formula [I] ##EQU1## and processes for preparing the same. Further in accordance with the present invention, there are also provided high molecular weight polyethylene molecular orientation molded articles formed from high molecular weight polyethylene having a weight average molecular weight of exceeding 600,000 and satisfying the relationship represented by the formula [II].Type: GrantFiled: September 21, 1990Date of Patent: October 12, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yasuo Kouno, Yuichi Itoh, Kazuo Yagi
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Patent number: 5250349Abstract: An adhesive resin composition comprising an ethylene/vinyl acetate copolymer, a styrene polymer resin, graft-modified polyethylene, a polystyrene elastomer and an ethylene/.alpha.-olefin copolymer in combination is disclosed. This adhesive resin composition shows an excellent adhesiveness between a metal and a thermoplastic resin. When this adhesive resin composition is used for bonding a polyester resin and a gas-barrier resin, a good bonding which is not degraded even by high-temperature heating can be attained.Type: GrantFiled: July 6, 1992Date of Patent: October 5, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Mikio Nakagawa, Masaharu Mito
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Patent number: 5251226Abstract: A discharge exciting excimer laser device comprises a pair of main discharge electrodes, a dielectric and an auxiliary electrode. The dielectric is in a cylindrical form and has a side opposed to one of the main discharge electrodes, which side is formed into a flat plate-like portion. The auxiliary electrode is embraced within the dielectric leaving a space and is opposed to one of the main discharge electrodes with the flat plate-like portion of the dielectric sandwiched therebetween. Such a construction increases laser output and improves insulating performance.Type: GrantFiled: November 4, 1991Date of Patent: October 5, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Shuntaro Watanabe, Yasuo Oeda, Ken Ohmata, Michito Uehara, Mitsugu Terada, Hideaki Shibata, Yuichiro Terashi
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Patent number: 5250723Abstract: A novel polymerizable monomer represented by the formula (I) useful as a raw material for the high surface hardness transparent resin. ##STR1## wherein R is an aliphatic residue having or not having an oxygen atom, an alicyclic ring, a heterocyclic ring or an aromatic ring, or an alicyclic residue, l is 0 or 1, each of i and j is an integer of 1 or more, and when l=0, i=j=1, when l=1, (i+j) is 4 or less, when j=1, X is oxygen or sulfur, when j.gtoreq.2, all X's are oxygen or sulfur, or one X is oxygen and the other X's are sulfur, or one X is sulfur and the other X's are oxygen.The high surface hardness transparent resin comprises a crosslinked polymer prepared by copolymerizing a monomer (A) represented by the formula (I) as above and a monomer (B) containing one or more functional groups of at least one kind selected from the group consisting of CH.sub.2 .dbd.CH--C(O)--O--, CH.sub.2 .dbd.C(CH.sub.Type: GrantFiled: August 10, 1992Date of Patent: October 5, 1993Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Toshiyuki Suzuki, Katsuyoshi Sasagawa, Masao Imai, Yoshinobu Kanemura
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Patent number: 5250602Abstract: Disclosed are a polymer emulsion prepared by neutralizing a seed polymer with an acid or a salt or by quaternizing it with a quaternizing agent and a method of preparing the polymer emulsion. The surfaces of the emulsion grains are very densely cationated. The seed polymer is formed by polymerizing a monomer of formula (I) or a mixture of the monomer (I) and copolymerizable ethylenic unsaturated monomer(s) (II) and a seed latex of a carboxyl-modified synthetic rubber latex or synthetic resin emulsion. ##STR1## R.sub.1 is H or CH.sub.3 ; R.sub.2 is a 2-5C alkylene; R.sub.3 and R.sub.4 each are H or a 1-5C alkyl; A is--COO--or--CONH--; and R.sub.1, R.sub.3 and R.sub.4 are so selected that the monomer is hardly soluble or insoluble in water. As a consequence of being very densely cationated by post-modification, the cationic polymer emulsion is useful in various fields as binders, fixers or other additives.Type: GrantFiled: January 31, 1990Date of Patent: October 5, 1993Assignee: Mitsui-Cyanamid, Ltd.Inventors: Hiroshi Itoda, Naotaka Watanabe, Yoshio Hosoya
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Patent number: 5250661Abstract: B cell differentiation factor which acts on B cells and participates in their differentiation into antibody-producing cells is produced by an established cell line.Type: GrantFiled: May 5, 1992Date of Patent: October 5, 1993Assignee: Mitsui Toatsu Chemicals IncorporatedInventors: Yoshiyuki Kanai, Akira Awaya
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Patent number: 5248451Abstract: The present invention provides a conductive copper composition comprising metal powder, a binder, a dispersant, and a solvent, characterized by containing 100 parts by weight of copper powder in the form of spherical or granule particles coated with silver as the metal powder, 6 to 18 parts by weight of resol resin satisfying the following conditions (a) to (c) as the binder, 0.05 to 1 part by weight of the dispersant, and 2 to 15 parts of the solvent:(a) Dimethylene-ether bonds in the skeletal structure or alkyl-ether bonds are contained 5% more of the bonded formaldehyde;(b) The molar ratio of preparation between formaldehyde and phenol (formaldehyde/phenol) is within the range of 1.0 to 3.Type: GrantFiled: July 9, 1991Date of Patent: September 28, 1993Assignees: Mitsui Mining & Smelting Co., Ltd., Gunei Chemical Industry Co., Ltd.Inventors: Masayuki Tsunaga, Takao Suzuki, Kazuaki Yuba, Yoshiaki Kurimoto, Kyoichi Gokan, Masaki Hirosawa
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Patent number: 5248348Abstract: A method for preparing an amorphous silicon solar cell is disclosed which comprises forming on a substrate, in the following order, a first electrode, a first conductive film, a thin first substantially intrinsic film, a thicker second substantially intrinsic film, a second conductive film and a second electrode.the method being characterized in that at least the thicker second substantially intrinsic film is formed by the sequential steps of:(a) depositing a semiconductor film containing 20 atom % or less of bound hydrogen and/or bound deuterium to a thickness of from 5 to 1000 .ANG., and then (b) modifying the deposited film, the sequence of steps being repeated multiple times.The solar cell formed by the above-mentioned method is particularly excellent in long-term stability.Type: GrantFiled: September 5, 1991Date of Patent: September 28, 1993Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Kenji Miyachi, Masato Koyama, Yoshinori Ashida, Nobuhiro Fukuda
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Patent number: 5248784Abstract: A novel 4-carbonyl-substituted coumarin compound which is substituted with a carbonyl group in the position-4 of a 7-alkylaminocoumarin derivative and has photosensitivity in the visible region.Type: GrantFiled: April 16, 1992Date of Patent: September 28, 1993Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tsukasa Ohyama, Kazuhiko Murayama, Yoriaki Matsuzaki, Susumu Kasamatsu, Keisuke Takuma, Kimitoshi Kato
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Patent number: 5248839Abstract: A preparation process of high purity bisphenol A from phenol and acetone with a continuous or batch type reactor by on-line estimating with a computer the composition of the reaction mixture and saturated dissolving temperature of bisphenol A under the reaction conditions and by automatically controlling the reaction conditions and liquid transfer conditions of the reaction mixture to the next step. The process does not form crystals of bisphenol A-phenol adduct in the reactor and cooler. A maximum rate of reaction can be obtained. Consequently, fluctuation of reaction temperature can be prevented and the amount of impurities formed is small. The discharge operation of the reaction mixture from the reactor can be carried out steadily and with ease, and does not disturb the operation of successive steps.Type: GrantFiled: April 7, 1992Date of Patent: September 28, 1993Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Shigeru Iimuro, Akira Yamada, Kenichi Ohmura, Toshio Houri, Tsuguo Kawamura
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Patent number: 5247031Abstract: A catalyst component (X") obtained by treating an olefin polymerization catalyst (X) formed from (A) a solid titanium catalyst component comprising magnesium, titanium, halogen and an electron donor as essential ingredients, (B) an organoaluminum compound catalyst component, and as required, (C) an electron donor with an alpha-olefin by preliminarily polymerizing the alpha-olefin in an amount of 0.1 to 500 g per gram of the solid titanium catalyst component (A) in the presence of said catalyst (X), and contacting the treated catalyst (X') with at least 0.1 mole, per gram-atom of titanium in the treated catalyst (X'), of oxygen. A process for producing the olefin polymerization catalyst component. A catalyst (Y) for olefin polymerization formed from [I] the above catalyst component (X"), [II] an organoaluminum compound catalyst component and as required [III] an electron donor. Also provided is a process for polymerizing olefins in the presence of the olefin polymerization catalyst (Y).Type: GrantFiled: October 31, 1990Date of Patent: September 21, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Mamoru Kioka, Masao Nakano, Akinori Toyota
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Patent number: 5246657Abstract: A polyolefin fiber having improved initial elongation and two characteristic melting point peaks, average creep rate, modulus and tensile strength is obtained by milk-kneading a composition containing two different ultra-high-molecular-weight polyolefins each having an intrinsic viscosity of at least 5 dl/g. The first polyolefin is polyethylene. The second polyolefin is an ethylene/.alpha.-olefin copolymer, e.g., ethylene/propylene, wherein the content of the .alpha.-olefin is such that the number of side chains of the .alpha.-olefin per 1000 carbon atoms in the copolymer is from 0.5 to 10, on average. The weight ratio of the ethylene polymer to the ethylene copolymer is from 10/90 to 90/10. The mixture of the two ultra-high-molecular-weight polyolefins is melt-kneaded in the presence of a diluent, such as wax, and the kneaded mixture is spun and drawn to a draw ratio of at least 10.Type: GrantFiled: April 13, 1992Date of Patent: September 21, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuo Yagi, Hiroyuki Takeda
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Patent number: 5246978Abstract: The present invention relates to a polyol, polyurethane resin, rigid polyurethane foam, preparation process thereof and a preparation process of a rigid polyurethane foam composite. The polyol comprises an epoxy resin based polyol, which may be combined with a phenol resin based polyol component and/or an aromatic amine based polyol component. The polyurethane resin, foam and composite using the polyol as a raw material has resistance to dissolution in a hydrochlorofluorocarbon and a hydrofluorocarbon which are foaming agents having very low public environmental hazards and can be used as a thermal insulation material or a thermal insulation structure for refrigerators, freezers, insulation panels, ships and vehicles.Type: GrantFiled: November 8, 1990Date of Patent: September 21, 1993Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Satoshi Ozaki, Tsukuru Izukawa, Haruhiko Kawakami, Takayoshi Masuda, Toshio Nozawa