Patents Assigned to Mitsui
  • Patent number: 5276133
    Abstract: A favorably processable polyimide which has recurring structural units represented by the formula (I): ##STR1## wherein R is a tetravalent radical having from 2 to 27 carbon atoms and is selected from the group consisting of an aliphatic radical, alicyclic radical, monoaromatic radical, condensed polyaromatic radical and noncondensed aromatic radical connected to each other with a direct bond or a bridge member, and is blocked at the polymer chain end with aromatic dicarboxylic anhydride represented by the formula (II): ##STR2## wherein X is a divalent radical selected from the group consisting of a monoaromatic radical having from 6 to 27 carbon atoms, condensed polyaromatic radical and noncondensed aromatic radical connected to each other with a direct bond or a bridge member.
    Type: Grant
    Filed: June 4, 1992
    Date of Patent: January 4, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yuichi Okawa, Shoji Tamai, Akihiro Yamaguchi
  • Patent number: 5276185
    Abstract: Amides are produced by reacting nitriles with water in a liquid phase in the presence of a manganese oxide containing an element selected from Groups IIIA, IVA, VA, IIIB, IVB, VB , VIB and VIII of the Periodic Table.
    Type: Grant
    Filed: December 24, 1992
    Date of Patent: January 4, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Minato Karasawa, Masamitsu Inomata, Hiroharu Kageyama, Masahiro Tokumitsu, Sinji Tokunoh, Kanemitsu Miyama
  • Patent number: 5276600
    Abstract: A planar reflector is composed of a base and a flexible substrate having a high reflection layer formed thereon and overlayed on the base with an adhesive layer interposed between the high reflection layer and the base. The adhesion strength between the base and the substrate is at least 100 g/cm, and the thickness of the adhesive layer is not smaller than 0.5 .mu.m but not greater than 50 .mu.m. A curved reflector can be obtained by bending the planar reflector so that a curved surface having a radius of curvature not greater than 5 mm is formed presenting a concave surface on a side of the flexible substrate.
    Type: Grant
    Filed: May 27, 1992
    Date of Patent: January 4, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Mitsuo Takase, Nobuhiro Fukuda
  • Patent number: 5275848
    Abstract: A process for preparing a laminate by coating the surfaces of a metal substrate that has been treated with an anchor coating agent, with a modified olefin type resin and heat-adhering the olefin resin onto the surfaces of the metal substrate. The process of this invention is characterized by applying heat-treatment to the laminate at the time of adhesion or after the adhesion in the presence of a treating agent which consists of a compound prescribed in the general formulae (1) and (2). ##STR1## The laminate prepared by this process withstands deterioration of adhesion caused by aging, particularly in an atmosphere where water is present.
    Type: Grant
    Filed: October 2, 1991
    Date of Patent: January 4, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Kazunori Mito, Tatsuo Saito, Naoshi Ishimaru
  • Patent number: 5273824
    Abstract: A cored multi-shell emulsion particle consisting of a core particle, a void layer existing in the exterior of the core particle and a shell layer, each of which has a diameter of .phi., d and D, respectively, and the ratio of .phi., d and D is in the following range..phi./D=0.1-0.6d/D=0.2-0.8 (d>.phi.)The particle exhibits excellent hiding power, brightness, gloss and thermal insulation property as an organic pigment without impairing drying ability and strength of coated layer.
    Type: Grant
    Filed: February 1, 1991
    Date of Patent: December 28, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Futoshi Hoshino, Makoto Nakano, Kousuke Someya, Junko Morita, Takeshi Yanagihara, Akihiro Yamazaki
  • Patent number: 5274150
    Abstract: A color-developing sheet using, as a color developer, polyvalent-metal-modified products of salicylic acid compounds composed mainly of a 3,5-di(.alpha.-methylbenzyl)salicylic acid derivative obtained by reacting a salicylic acid ester with an .alpha.-methylbenzyl halide in the presence of an acid catalyst and hydrolyzing the reaction product.Said color-developing sheet has excellent color developability at low temperatures and gives a color of excellent water resistance.
    Type: Grant
    Filed: August 5, 1991
    Date of Patent: December 28, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yoshimitsu Tanabe, Keizaburo Yamaguchi, Akihiro Yamaguchi
  • Patent number: 5273822
    Abstract: A fibrous electrically-conductive filler comprises fibrous aluminum borate as a core material and a layer of a electrically-conductive substance which covers the core material or comprises fibrous aluminum borate as a core material, a layer of titanium oxide which covers the fibrous aluminum borate and a layer of a electrically-conductive substance which covers the titanium oxide layer. The fibrous electrically-conductive filler can be prepared by a process comprising the step of directly forming a layer of a electrically-conductive substance doped with antimony or fluorine on the surface of fibrous aluminum borate, or the steps of forming, on the surface of the fibrous aluminum borate, an intermediate layer of titanium oxide in an amount ranging from 2 to 50% by weight on the basis of the weight of the fibrous aluminum borate and then forming a layer of a electrically-conductive substance doped with antimony or fluorine on the surface of fibrous aluminum borate.
    Type: Grant
    Filed: November 26, 1991
    Date of Patent: December 28, 1993
    Assignees: Mitsui Mining & Smelting Co., Ltd., Metallgesellschaft Aktiengesellschaft
    Inventors: Takao Hayashi, Norihiro Sato, Chikara Omotani, Manabu Hosoi, Nobuyoshi Kasahara, Wolf-Dieter Griebler, Jorg Hocken, Gunther Rudolph
  • Patent number: 5272221
    Abstract: The present invention provides a nylon composition having increased hydrolyzability which is obtained by physically mixing 100 parts by weight of a nylon with 1 to 50 parts by weight of at least one polymer selected from the group consisting of polylactic acid, polyglycolic acid and a copolymer containing 50 mol % or more of a lactic acid unit or a glycolic acid unit as a repeating unit in its chain; and a method for increasing the hydrolyzability of a nylon by preparing such a composition. High hydrolyzability can be imparted to the nylon inherently having extremely low hydrolyzability without impairing its original mechanical strength. Therefore, various molded articles made from the nylon can be hydrolyzed under natural circumstances, and thus the wastes are not stored.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: December 21, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Toshio Kitao, Yoshiharu Kimura, Hideki Yamane, Hiroki Nakata, Hosei Shinoda
  • Patent number: 5272235
    Abstract: In accordance with the present invention, there are provided cycloolefin random copolymers composed of ethylene and cycloolefin and containing substantially no polyethylene, and processes for preparing the same. Optical disc substrates prepared from the above-mentioned copolymers are excellent in transparency and also capable of minimizing the occurence of errors in reading of the discs due to quality of the substrates used therefor.
    Type: Grant
    Filed: March 6, 1991
    Date of Patent: December 21, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Kenji Wakatsuru, Takehiko Kawate, Shigemi Shiraki, Toshihiro Sagane, Shuji Minami, Masayuki Okabe, Ryosuke Tomita, Hideaki Yamaguchi
  • Patent number: 5270393
    Abstract: Cycloolefin random copolymer compositions which contain a blend of at least two or three cycloolefin random copolymers are disclosed. The random copolymers are obtained by copolymerization of ethylene and at least one of two cycloolefins. The resin compositions exhibit excellent moldability and transparency, heat resistance, thermal aging resistance, chemical resistance, solvent resistance, dielectric and mechanical characteristics and transferability of the pit.
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: December 14, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshihiro Sagane, Masayuki Okabe
  • Patent number: 5270391
    Abstract: A composition for thermosetting powder coating, which comprises(a) an acrylic copolymer of high softening point having an epoxy equivalent of 250-1,000 g/eq and a softening point of 90.degree.-160.degree. C.,(b) an acrylic copolymer of low softening point having an epoxy equivalent of 200-600 g/eq and a softening point of 30.degree.-70.degree. C.,(c) a polycarboxylic acid, and(d) optionally, a phosphoric acid ester compound and/or a phosphorous acid ester compound,and wherein the difference in softening point between (a) and (b) is 60.degree.-120.degree. C., the weight ratio of (a)/(b) is 95/5 to 60/40, and the equivalent ratio of [the total epoxy groups of (a) and (b)] : [the acid group of (c)] is 0.5:1 to 1:0.5.Said composition has excellent storage stability and, when used as a coating for automobiles, gives a film superior in appearance, solvent resistance and acid resistance.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: December 14, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Eiichiro Miyazaki, Makoto Nishimori, Taisaku Kano, Takayoshi Sekido, Masashi Seki
  • Patent number: 5270377
    Abstract: In the case where a polyamide is blended with a specific partially crosslinked graft-modified polyolefin elastomer obtained by dynamically heat-treating a blend of a peroxide-crosslinking olefin copolymer rubber and an olefinic plastic with an unsaturated carboxylic acid or derivative thereof, an unsaturated epoxy monomer or an unsaturated hydroxy monomer in the presence of an organic peroxide, if the graft-modified polyolefin plastomer occupies a major portion, a composition excellent in the oil resistance, the mechanical strength and the resistance against heat aging is obtained and if the polyamide occupies a major portion, a composition excellent in the impact resistance, the rigidity and the tensile strength is obtained.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: December 14, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yasuhiko Otawa, Noboru Sakamaki, Tetsuo Tojo, Katsuo Okamoto, Toshiyuki Maeda
  • Patent number: 5270281
    Abstract: Heat-sensitive recording materials contain an electron-donating chromogenic compound and an electron-attracting compound. The recording materials also contain at least one compound represented by the following formula: ##STR1## wherein R.sub.1 and R.sub.3 mean a hydrogen atom or an alkyl, aralkyl or aryl group, R.sub.2 and R.sub.4 denote an alkyl, alkenyl, aralkyl or aryl group, X.sub.1, X.sub.2, Y.sub.1 and Y.sub.2 stand for an oxygen or a sulfur atom, and --Z.sub.1 -- and --Z.sub.2 -- are a specific aromatic group. Also provided are phenol compounds represented by the following formula: ##STR2## wherein R.sub.1, R.sub.2, X.sub.1 and Y.sub.1 have the same meanings as defined above; R.sub.5 and R.sub.6 are a hydrogen or halogen atom or an alkyl, alkoxy, aralkyl, aryl or hydroxyl group; p and q stand for an integer of 1-4; R.sub.5 and R.sub.6 may be either the same or different when p and q represent an integer of 2 or greater; and --Z.sub.3 -- means a specific divalent group.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: December 14, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Atsuo Otsuji, Toshihiro Motoshima, Yoshimitsu Tanabe, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Masakatsu Nakatsuka, Akihiro Yamaguchi
  • Patent number: 5270444
    Abstract: According to the present invention, a process which comprises bringing polyethylene terephthalate having an intrinsic viscosity of at least 0.50 dl/g and a density of 1.38 g/cm.sup.3 or more into contact with water is provided.In the water-treated polyethylene terephthalate obtained in the present invention, amounts of oligomers and acetaldehyde formed at the time of molding said polyethylene terephthalate into molded articles are small, and the contamination of the mold therewith is difficult to occur and further the contents of said molded articles does not change in flavor and fragrance.
    Type: Grant
    Filed: March 12, 1993
    Date of Patent: December 14, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Shigemi Shiraki, Yasuhiro Tanaka, Masayuki Sakai
  • Patent number: 5270279
    Abstract: This invention relates to a production process of formed activated coke for SOx and NOx removal which is employed in treatment systems for various flue gases and the like.The formed activated coke for SOx and NOx removal obtained in accordance with the process of this invention has excellent pressure resistance, abrasion resistance and impact strength and also superb SOx- and NOx-removing ability, so that the coke is suitable for use in moving-bed, SOx and NOx- removing systems.The formed activated coke for SOx and NOx removal can of course show excellent SOx- and NOx-removing effects when employed in conventional SOx- and NOx-removing processes and, moreover, owing to its characteristic high NOx-removing ability, is suited for the removal of NOx from low-SOx flue gas of a fluidized-bed combustion boiler or cogeneration power plant.According to the process of this invention, dried, formed activated coke prepared from coal as a raw material is reacted with SO.sub.3 gas at 100.degree.-300.degree. C.
    Type: Grant
    Filed: July 28, 1992
    Date of Patent: December 14, 1993
    Assignee: Mitsui Mining Co., Ltd.
    Inventors: Ikuo Shiraishi, Yasuhiko Ninagawa, Kazuhiko Tsuji, Yoshihiro Matsufuji
  • Patent number: 5270463
    Abstract: A method for preparing a halogenated alkoxyphthalocyanine represented by the formula (7) ##STR1## wherein R.sup.3 to R.sup.6 may be different and each of them is a secondary alkyl group, X is a halogen atom, n is the number of X and in the range of from 1 to 4, and Met is two hydrogen atoms, a divalent metal atom, or a trivalent or a tetravalent metallic derivative, which comprises the step of reacting a metal or a metallic compound with one to four kinds of raw materials selected from the group consisting of phthalonitriles represented by the following formula (1) and diiminoisoindolines represented by the following formula (2) ##STR2## wherein R.sup.1 is a secondary alkyl group, X is a halogen atom, and each of p and q is 0 or 1, but in at least one raw material, p or q is 1, and halogenated alkoxyphthalocyanine prepared by said method.
    Type: Grant
    Filed: July 1, 1991
    Date of Patent: December 14, 1993
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Katashi Enomoto, Takahisa Oguchi, Tutomu Nishizawa
  • Patent number: 5268435
    Abstract: A polyol resin substantially free of epoxy groups is useful as a coating material and is prepared by(i) reacting a bisphenol epoxy resin with a compound having one active hydrogen per molecule and optionally a bisphenol to form a polyol resin having secondary hydroxyl groups, and(ii) esterifying part of the secondary hydroxyl groups with a lactone or a monocarboxylic acid (ester) to form a polyol resin with graft-polymerized polyester moieties.
    Type: Grant
    Filed: June 12, 1991
    Date of Patent: December 7, 1993
    Assignees: Mitsui Petrochemical Industries, Ltd., Ricoh Company, Ltd.
    Inventors: Hideo Nakamura, Masaru Wakizaka, Yohzoh Yamamoto
  • Patent number: 5268446
    Abstract: A readily melt-processable polyimide obtained by reacting diamino-diphenyl ether with 3,3',4,4'-biphenyltetracarboxylic dianhydride in the presence of phthalic anhydride and thermally or chemically imidizing the resultant polyamic acid.
    Type: Grant
    Filed: August 9, 1991
    Date of Patent: December 7, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Shoji Tamai, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5268503
    Abstract: .alpha.,.beta.-Unsaturated carboxylic acid esters are produced by a catalytic reaction of .alpha.,.beta.-unsaturated carboxylic acids and/or .alpha.,.beta.-unsaturated carboxylic acid amides with aliphatic alcohols in the presence of a solid acid catalyst comprising zirconium oxide, titanium oxide or a composite oxide thereof containing phosphorus.
    Type: Grant
    Filed: March 9, 1993
    Date of Patent: December 7, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Minato Karasawa, Sinji Tokunoh, Masamitsu Inomata, Takeshi Hiraiwa, Hiroharu Kageyama, Kanemitsu Miyama
  • Patent number: 5268492
    Abstract: An optically active diphosphine having a bicyclo[2.2.1]heptane of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are difined in the specification and a metal complex comprising said optically active diphosphine are disclosed. A process for producing or purifying said optically active diphosphine is disclosed.
    Type: Grant
    Filed: August 27, 1992
    Date of Patent: December 7, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Keiji Yamamoto, Masahiro Miyazawa, Satoru Momose