Patents Assigned to Mitsui
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Patent number: 5180636Abstract: A rope for traction of a double structure of a core member coated with a sheath member, in which said core member comprises a molecularly oriented shaped article of an ultrahigh molecular weight polyolefin, and said sheath member comprises a braid. The rope proposed herein is light in weight, floatable on water, easy to handle and excellent in safety to human bodies and weatherability.Type: GrantFiled: April 2, 1991Date of Patent: January 19, 1993Assignee: Mitsui Petrochemical Industries Ltd.Inventors: Hirofumi Harazoe, Hiroyoshi Shiromoto, Kazuo Yagi, Masahiro Kouya
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Patent number: 5178909Abstract: Silver-coated copper-based powders are prepared by the steps of dispersing copper powders in a chelating agent solution, adding a silver ion solution to the resulting dispersion to effect a substitution type of deposition reaction and, then, adding a reducing agent to the resulting solution to effect a reduction type of deposition reaction, thereby forming silver coats on the surfaces of the copper powders, wherein the chelating agent solution is prepared in two portions, a first portion thereof being prepared before the addition of the silver ion solution and a second portion thereof being added during the addition of the reducing agent, or in three portions, a first portion thereof being prepared before the addition of the silver ion solution, a second portion thereof being added during the addition of the reducing agent and a third portion thereof being added at the time of the completion of the reaction.Type: GrantFiled: July 17, 1991Date of Patent: January 12, 1993Assignee: Mitsui Kinzoku Kogyo Kabushiki KaishaInventor: Takao Hayashi
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Patent number: 5179168Abstract: Disclosed is an ionomer composition comprising an ethylene/unsaturated carboxylic acid copolymer which is at least partially neutralized with at least one alkali metal selected from the group consisting of potassium, rubidium and cesium, wherein the ethylene/unsaturated carboxylic acid copolymer is a blend comprising (A) an ethylene/unsaturated carboxylic acid copolymer having an unsaturated carboxylic acid content of 6 to 15 mole % and (B) an ethylene/unsaturated carboxylic acid copolymer having an unsaturated carboxylic acid content of 0.5 to 5 mole % at an (A)/(B) weight ratio of from 10/90 to 80/20, and the alkali metal is present in an amount at least 0.4 millimole but smaller than 1.3 millimoles per gram of the ionomer composition.This ionomer composition has an excellent antistatic property and an excellent heat moldability.Type: GrantFiled: September 21, 1990Date of Patent: January 12, 1993Assignee: Dupont-Mitsui Polychemicals Co., Ltd.Inventor: Eisaku Hirasawa
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Patent number: 5179227Abstract: A fractionation process of a methylene bridged polyphenylene polyisocyanate mixture obtained by phosgenating condensation product of aniline and formaldehyde is disclosed.In order to apply the above mixture to a variety of uses, the process separates the mixture into fractions by giving primary attention to the content of 4,4'-and 2,4'-isomer of diphenylmethane diisocyanate and at the same time reduces the content of impurities having acidity and hydrolyzable chlorine.Type: GrantFiled: October 23, 1991Date of Patent: January 12, 1993Assignee: Mitsui Toatsu Chemicals Inc.Inventors: Noritoshi Ishida, Zunzi Tashima, Mitsunori Shimamatsu, Kazunari Nitta, Takashi Nagou
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Patent number: 5179181Abstract: According to the present invention, there is provided an improvement of a process for producing fluorine-containing copolymers comprising copolymerizing(a) a chlorinated fluoroolefin,(b) vinyl ether, and(c) an organosilicon compound having an olefinically unsaturated bond and a hydrolyzable bond,the improvement resides in that a chlorine trapping agent is allowed to exist in the system during the copolymerization reaction and/or the purification of the resulting copolymer, and the fluorine-containing copolymers are free from coloration.Further, according to the present invention, a fluorine-containing copolymer composition containing a specific curing catalyst is also provided and said composition is excellent in adhesion to substrates or base materials.Type: GrantFiled: May 13, 1991Date of Patent: January 12, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Shiro Honma, Takashi Izumi, Hajime Inagaki, Sakae Murakami
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Patent number: 5178662Abstract: Benzaldehyde acetal compounds represented by the following formula: ##STR1## in which each R is a C.sub.3-8 alkyl group and forms an ether bond with the corresponding oxygen atom of the orthoaldehyde moiety have no injury to crops and, moreover, exhibits superb herbicidal effects owing to the limitation of the number of carbon atoms of each alkyl group to 3-8.Type: GrantFiled: December 16, 1991Date of Patent: January 12, 1993Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tsutomu Ishii, Katsutoshi Ishikawa, Sunao Maeda, Masatoshi Gohbara, Yasunaga Iwasaki, Makoto Nishida, Sadafumi Koda
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Patent number: 5179171Abstract: A random copolymer characterized in that (A) the copolymer comprises polymerized units from ethylene and polymerized units from at least one cycloolefin, (B) the mole ratio of the polymerized units from the cycloolefin to the polymerized units from ethylene is from 3:97 to 60:40, (C) the cycloolefin is incorporated in the polymer chain without ring opening, (D) the copolymer has an intrinsic viscosity of 0.01 to 20 dl/g, (E) the copolymer has a molecular weight distribution (Mw/Mn) of not more than 4, and (F) the copolymer has a crystallinity of 0 to 10%. The random copolymer may be grafted by (a) alpha, beta-unsaturated carboxylic acids and/or their derivatives, (b) styrenes, (c) organic silicon compounds having an olefinically unsaturated bond and a hydrolyzable group, or (d) unsaturated epoxy monomers.Type: GrantFiled: February 10, 1992Date of Patent: January 12, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Syuji Minami, Hirokazu Kajiura, Hidekuni Oda, Hideaki Yamaguchi
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Patent number: 5178815Abstract: A method of manufacturing composite moldings by executing the following steps (a) to (f) by using an injection molding machine provided with a fixed die having a gate which is opened to a cavity forming surface and a movable die which can come into contact with and out of contact with the fixed die:(a) step of setting a desired skin material to a predetermined position of the movable die in a state in which the movable die is sufficiently removed from the fixed die;(b) a first die clamping step in which the movable die is moved toward the fixed die and is stopped at a position where an interval between the movable and fixed dies is equal to a predetermined value of 5 mm or more;(c) step of injecting a fused resin into a cavity;(d) a second die clamping step in which the movable die is stopped at a desired last position;(e) step of cooling for a predetermined time after the second die clamping step;(f) step of removing the movable die from the fixed die and opening the dies and taking out a product.Type: GrantFiled: March 12, 1991Date of Patent: January 12, 1993Assignees: Mitsui Toatsu Chemicals, Inc., Shimizu Seiko Kabushiki GaishaInventors: Sachio Yokote, Kenji Yokogi, Masaki Misumi
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Patent number: 5179224Abstract: Disclosed herein is a process for preparing a corresponding cinnamate ester by reacting a styrene compound, carbon monoxide, an alcohol and oxygen by the use of (1) metallic palladium or a compound thereof, (2) a copper compound, (3) a compound of at least one metal selected from Groups 4A, 5A, 7A, 8A (the iron group only) and 2B in the Periodic Table and (4) a halogen compound as a catalyst which comprises treating the catalyst components recovered from the reaction liquid after completion of the reaction with an oxidizing agent in the presence of an organic acid to regenerate their catalytic activity, using the resulting catalyst components again in the reaction as a catalyst and repeating the foregoing procedure.The regenerated catalyst is recovered in catalytic activity to the extent of that of a fresh catalyst and thus gives a high reaction performance in the subsequent reaction. Thus, the catalyst containing expensive metal can be used circulatively.Type: GrantFiled: October 1, 1991Date of Patent: January 12, 1993Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Usaji Takaki, Yoshihiro Yamamoto, Toshio Matsuhisa, Isamu Sudo, Shinobu Aoki
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Patent number: 5176341Abstract: An airship yaw line tractor comprising: a yaw line connector for holding and releasing the yaw line of the airship through remote control; a winch for winding and unwinding a cable connected to the yaw line connector; and a control unit for automatically controlling the tensile force of the cable extending from the winch to the yaw line connector and automatically releasing the yaw line held by the yaw line connector in an emergency.Type: GrantFiled: July 12, 1991Date of Patent: January 5, 1993Assignee: Mitsui Engineering & Shipbuilding Co., Ltd.Inventors: Katsuhisa Ishikawa, Keiji Nakamura, Takao Suzuki, Noriaki Kondo
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Patent number: 5175309Abstract: A process for the preparation of N-substituted maleimides by conducting heat-dehydration and dehydrating imidization of N-substituted maleamic acids under azeotropic distillation of generated water in a solvent mixture containing a solvent capable of forming water azeotrope and an organic aprotic polar solvent, in the presence as catalyst of a zinc salt of a maleamic acid, metallic zinc or a zinc compound which forms a zinc salt of the N-substituted maleamic acid in the reaction system.Type: GrantFiled: December 8, 1989Date of Patent: December 29, 1992Assignee: Mitsui Toatsu Chemicals Inc.Inventors: Ryuichiro Tsumura, Kunimitsu Fukumura, Teruo Muraishi
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Patent number: 5175313Abstract: The present invention provides a process for preparing dihydrofuranone derivative of the formula (I): ##STR1## wherein R.sup.1 and R.sup.3 are individually lower alkyl, and R.sup.2 is hydrogen or lower alkyl, by reacting a dihydrofuranone derivative of the formula(I): ##STR2## wherein R.sup.1 is as defined above, with a malonic acid derivative of the formula (II): ##STR3## wherein R.sup.2 and R.sup.3 are as defined above, in the presence of an alkalimetal alkoxide and/or an alkalimetal hydroxide.Type: GrantFiled: May 3, 1991Date of Patent: December 29, 1992Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Junichi Imuta, Aiichiro Ori, Noriaki Kihara
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Patent number: 5174853Abstract: In a method for manufacturing forsterite single crystals containing tetravalent chromium as luminescent ions, the method which comprises the use of chromium dioxide or comprises the use of a sintered body obtained either by sintering in a non-reducing atmosphere chromium trioxide or a mixture of at least 30 wt. % of chromium trioxide with up to 70 wt. % of dichromium trioxide, together with other oxide materials for forsterite, or by firing in an oxidizing atmosphere a mixture of more than 70 wt. % of dichromium trioxide with less than 30 wt. % of chromium trioxide, together with other oxide materials for forsterite. This invention also relates to forsterite single crystals obtained by each of the above methods.Type: GrantFiled: August 27, 1991Date of Patent: December 29, 1992Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Yasuhide Yamaguchi, Yukio Nobe, Akiko Sugimoto
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Patent number: 5175308Abstract: A process is provided for the preparation of an indole from aniline or a derivative thereof and a polyhydric alcohol. The reaction is carried out in the presence of a catalyst composed of a carrier having a specific surface area of at least 10 m.sup.2 /g and silver supported on the carrier. The catalyst also contains as an additional component a specific amount of at least one element selected from Co, Fe and Ni. Deterioration in catalytic performance of the catalyst during the reaction and its regeneration are therefore minimized.Type: GrantFiled: November 6, 1990Date of Patent: December 29, 1992Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tadatoshi Honda, Makoto Kotani
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Patent number: 5175208Abstract: An improved method for preparing block copolymers of propylene which comprises providing a polymerizer composed of at least two reaction vessels connected to one another, substantially homopolymerizing propylene in a first step and then copolymerizing ethylene and propylene in a second step in the presence of a stereoregular catalyst, characterized by carrying out the homopolymerization of propylene in the polymerizer composed of at least two reaction vessels connected to one another in series, then introducing the resulting polymer slurry into a countercurrent washing column and countercurrently washing the slurry with propylene, introducing the washed slurry withdrawn from the lower part of the washing column into a reaction vessel in the second step connected to the washing column and performing the polymerization of ethylene and propylene, of which ratio ranges from 15/85 to 95/5. According to this method, a block copolymer of propylene exhibiting excellent physical properties can be obtained efficiently.Type: GrantFiled: July 10, 1989Date of Patent: December 29, 1992Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tadashi Asanuma, Mitsuru Ito, Tutomu Iwatani, Kaoru Kawanishi, Nobutaka Uchikawa, Shigeru Kimura, Ryuichi Sugimoto
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Patent number: 5173310Abstract: A device for cooling molten filaments in a spinning apparatus is improved by using a heating wire type heater in which a pitch of the heating wires surrounding the cooling apparatus is made closer in the upstream (top) region of the extruded filament than in the downstream (bottom) region. Through use of the device the temperature of the cooling air blown from the cooling apparatus for a plurality of molten filaments extruded from a die is controlled so that the cooling is made progressively stronger from the upstream side (i.e., top side) to the downstream side (i.e., bottom side).Type: GrantFiled: January 8, 1991Date of Patent: December 22, 1992Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Eiji Katou, Akifumi Katou, Yoshihiro Yoshimura
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Patent number: 5173524Abstract: A conductive polysulfone resin composition which has excellent processability and is prepared by mixing (A) 100 parts by weight of a composition essentially consisting of from 5 to 95% by weight of an aromatic polysulfone resin and from 95 to 5% by weight of a polyphenylene sulfide resin with (B) from 3 to 40 parts by weight of conductive carbon, is provided by the present invention; and molded articles having excellent electrical conductivity, heat resistance and mechanical strength, for example, a high-heat-resistant, conductive semi-conductor-chip-carrier can be prepared from the composition by injection molding and other processing methods.Type: GrantFiled: April 5, 1991Date of Patent: December 22, 1992Assignee: Mitsui Toatsu Chemicals, IncorporatedInventor: Takashi Satoh
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Patent number: 5173369Abstract: A tape carrier having a connection function prepared by etching a metal foil to form an conductive pattern comprising outer leads and inner leads on a starting tape carrier and then providing, by plating, the connection portion of at least one group of said outer and inner lead groups with nodules for connecting said at least one group of the leads to a mating conductive pattern via the nodules.Type: GrantFiled: October 19, 1990Date of Patent: December 22, 1992Assignee: Mitsui Mining & Smelting Co., Ltd.Inventor: Tatsuo Kataoka
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Patent number: 5172946Abstract: A frame assembly of a trunk lid locking device comprises a lower frame of vessel-shaped formed by bending four sides of a base plate about at a right angle, a latch placed in an interior of the lower frame and engaged with a striker to be rotated, a ratchet for preventing the latch from reversely rotating, an upper frame of approximately flat plate-like for closing an upper opening of the lower frame. An engagement hole extending in a left-and-right direction is formed on one of a front side of the upper frame and a top end of the lower frame, and a L-shaped engagement portion is formed on the other of the top end of the lower frame and the front side of the upper frame so as to engage with the engagement hole.Type: GrantFiled: March 25, 1992Date of Patent: December 22, 1992Assignee: Mitsui Kinzoku Kogyo Kabushiki KaishaInventor: Patrick J. Dowling
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Patent number: 5173162Abstract: A multi-layered electrostrictive effect element comprises films or thin plates of an electrostrictive material and inner electrodes alternatively arranged in layers, the inner electrodes being formed on the entire surface of the films or thin plates of the electrostrictive material, wherein the insulating layer which insulates the inner electrodes exposed on the side end faces of the element comprises a polyimide resin having repeating units represented by the following general formula (I): ##STR1## (wherein X represents a tetravalent group selected from the group consisting of tetravalent phenyl groups; tetravalent biphenyl groups; and tetravalent polyphenyl groups in which at least one of either the phenyl or bipheny groups are bonded through at least one member selected from the group consisting of O, CO, S, CH.sub.2, C(CH.sub.3).sub.2 and C(CF.sub.3).sub.Type: GrantFiled: January 4, 1991Date of Patent: December 22, 1992Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Atsushi Hagimura, Mutsuo Nakajima, Kunio Nishihara, Ikuo Inage