Patents Assigned to Mitsui
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Patent number: 4247652Abstract: Dynamically partially cured composition comprising a peroxide-curable olefin copolymer rubber (such as EDPM) and a peroxide-decomposing olefin plastic (such as PE and PP) is improved by effecting the dynamic heat-treatment with addition of a peroxide-non-curable hydrocarbon rubber (such as PIB) and/or a mineral oil softener (process oil). The dynamic heat-treatment is preferably carried out not only in the presence of an organic peroxide but also in the presence of divinyl benzene. The elastomeric composition is thermoplastic and, with or without further blending with an olefin plastic, is processable by techniques conventionally used for thermoplastic resins. This elastomer composition and blends of the elastomer composition and olefin plastic can be used for producing foamed product in combination with decomposition type foaming agent (such as azodicarbonamide).Type: GrantFiled: July 17, 1979Date of Patent: January 27, 1981Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Akira Matsuda, Shizuo Shimizu, Shunji Abe
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Patent number: 4246000Abstract: The invention provides: a fuel composition comprising 100 parts by weight of a coal-liquid fuel mixture and 0.02 to 1.0 part by weight of at least one additive selected from the group consisting of dibenzylidene sorbitol, ditoluylidene sorbitol, tribenzylidene sorbitol, tritoluylidene sorbitol and hydrogenated castor oil; and a fuel composition comprising 100 parts by weight of a coal-liquid fuel mixture, 0.02 to 1.0 part by weight of at least one additive selected from the group consisting of dibenzylidene sorbitol, ditoluylidene sorbitol, tribenzylidene sorbitol, tritoluylidene sorbitol and hydrogenated castor oil, and 1 to 10 parts by weight of water. The composition shows high stability over a prolonged period of time, preventing the separation into layers of the components.Type: GrantFiled: September 25, 1979Date of Patent: January 20, 1981Assignees: New Japan Chemical Co., Ltd., Mitsui Coke Co., Ltd., Mitsui Miike Machinery Co., Ltd., Toko Kasei Ltd.Inventors: Toshiaki Kobayashi, Tomio Nobe, Hiroshi Niimi, Tetsuo Wada
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Patent number: 4245061Abstract: An epoxy-modified polyolefin wax, which consists of a low-molecular-weight polyolefin grafted, copolymerized and modified with an epoxy group-containing, ethylenically unsaturated compound and has a number average molecular weight of from 600 to 10,000 and an epoxy equivalent of from 200 to 100,000, is disclosed.This epoxy-modified polyolefin wax is very valuable as a modifier for improving brittleness or adhesion (adhesiveness) in various resins, especially thermosetting resins.Type: GrantFiled: December 11, 1978Date of Patent: January 13, 1981Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Akihiro Tachi, Toru Tomoshige, Harumi Furuta, Norio Matsuzawa
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Patent number: 4245128Abstract: A novel process for producing alkenyl phenols, which comprises continuously feeding a dihydroxydiphenyl alkane such as 2,2-(4,4'-dihydroxydiphenyl)propane, 2,2-(4,4'-dihydroxy-3,3'-dimethyldiphenyl)propane, 2,2-(4,4'-dihydroxydiphenyl)butane, 2,2-(4,4'-dihydroxydiphenyl)-4-methylpentane, 1,1,1-(4,4'-dihydroxytriphenyl)ethane and 1,1-(4,4'-dihydroxydiphenyl)cyclohexane into a high-boiling inert organic reaction medium such as an alkylnaphthalene containing a basic catalyst and heated at 150.degree. to 250.degree. C. under 10 to 100 mmHg while maintaining the concentration of the dihydroxydiphenyl alkane in the reaction medium at not more than 30% by weight, thereby cleaving it in the reaction medium; and continuously distilling off the cleavage product out of the reaction system and recovering it. This process can afford the corresponding highly pure alkenyl phenol as a monomer and/or its polymer almost quantitatively.Type: GrantFiled: August 1, 1979Date of Patent: January 13, 1981Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Nobukatu Kato, Tsutomu Takase, Yoshio Morimoto, Teruo Yuasa, Minoru Hattori
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Patent number: 4243636Abstract: In an apparatus for oxidizing an alkyl-substituted aromatic compound in the liquid phase with a molecular oxygen-containing gas in a lower aliphatic carboxylic acid solvent in the presence of an oxidation catalyst, said apparatus comprising a reaction vessel, a gas exhaust port at the top of the vessel, an inlet at the bottom of the vessel for feeding said molecular oxygen-containing gas, an inlet for feeding said solvent, an inlet for feeding said catalyst, an inlet for feeding said alkyl-substituted aromatic compound, an outlet for withdrawing the oxidation reaction product, and an agitator within the vessel, said agitator consisting of a rotating shaft provided along the axial direction of the vessel and a plurality of stages of agitating blades secured to said rotating shaft at spaced intervals; the improvement wherein at least one stage of agitating blades consists of comb-like flat blades each of which is composed of a plurality of comb tooth-like pieces aligned at spaced intervals.Type: GrantFiled: February 9, 1979Date of Patent: January 6, 1981Assignee: Mitsui Petrochemical Industries Ltd.Inventors: Shigemi Shiraki, Ryoichi Yamamoto
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Patent number: 4243488Abstract: Metallurgical coke is made from coking a blend of coal which is comprised of reformed coal and another suitable coking coal. Reformed coal hereof is preferably made by the method which comprises dissolving at least one component selected from the group consisting of bituminous coal, subbituminous coal, brown coal and lignite in a hydrocarbon solvent, and recovering a reformed coal from said solution.Type: GrantFiled: July 17, 1978Date of Patent: January 6, 1981Assignee: Mitsui Coke Co., Ltd.Inventors: Hidehiko Sugimura, Keichiro Koba
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Patent number: 4242525Abstract: A salt of pyruvic acid is formed by oxidizing a salt of lactic acid with an oxygen-containing gas in a water-containing solvent in the presence of a catalyst. The catalyst used herein comprises (a) at least one component selected from platinum and palladium and (b) at least one component selected from lead, tin, tellurium, indium, bismuth, and compounds of these elements. The resulting pyruvate is isolated in the form of a solid by concentrating the catalyst-free reaction mixture and then mixing isopropyl alcohol therewith.Type: GrantFiled: April 10, 1979Date of Patent: December 30, 1980Assignee: Mitsui Toatsu Chemicals, IncorporatedInventor: Tadamitsu Kiyoura
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Patent number: 4242528Abstract: A novel process for producing isopropenyl phenol such as p-isopropenyl phenol which comprises continuously feeding oligomers of isopropenyl phenol having a degree of polymerization of 2 to 5 into a high-boiling inert organic reaction medium such as an alkylnaphthalene heated at 150.degree. to 250.degree. C. under a pressure of 10 to 100 mmHg while maintaining the concentration of the oligomers in the reaction medium at not more than 30% by weight, thereby thermally decomposing the oligomers in the reaction medium; and continuously distilling off the resulting isopropenyl phenol out of the reaction system and recovering it. The process almost quantitatively gives isopropenyl phenol having reduced contents of impurities.Type: GrantFiled: August 1, 1979Date of Patent: December 30, 1980Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Nobukatu Kato, Tsutomu Takase, Yoshio Morimoto, Teruo Yuasa, Minoru Hattori
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Patent number: 4241220Abstract: Improved process for producing terephthalic acid by liquid-phase catalytic oxidation of p-xylene with oxygen at a temperature of at least about 160.degree. C. and a pressure of at least about 5 kg/cm.sup.2 G under specific recycling condition of the mother liquor, which comprises(A) performing said liquid-phase catalytic oxidation at a temperature (T) within the range of about 170.degree. C. to about 230.degree. C. to form an oxidation reaction mixture containing crude terephthalic acid having a 4-carboxybenzaldehyde content of 500 to 3,000 ppm and an optical density, measured at 340 m.mu., of not more than 0.3,(B) separating about 60 to about 98% by weight of the total mother liquor from the resulting oxidation reaction mixture at a temperaure of from (T-30).degree. C. to (T+10).degree. C.Type: GrantFiled: December 28, 1978Date of Patent: December 23, 1980Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Shikiho Itaya, Takenori Nagaoka, Teruo Itoh, Yukimasa Shigemura, Shigemi Shiraki
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Patent number: 4239644Abstract: A liquid peroxide composition comprising dicumyl peroxide and a dicumyl peroxide derivative having one nucleus substituted by an alkyl group having 1 to 3 carbon atoms is disclosed. This peroxide composition can easily be handled because it is liquid, and it is very valuable as a cross-linking agent for an olefin polymer or a synthetic rubber.Type: GrantFiled: March 21, 1979Date of Patent: December 16, 1980Assignee: Mitsui Petrochemical Industries Ltd.Inventors: Hirohiko Nambu, Kenichi Mizuno, Tetuhiro Matumoto
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Patent number: 4239871Abstract: A process for the polymerization of butene-1 in a liquid aliphatic hydrocarbon medium in the presence of a catalyst composed of a titanium trihalide and an organoaluminum compound which comprises initially polymerizing a minor part of the butene-1 at a temperature within a range sufficiently low that a slurry of polymer in said medium is produced and then increasing the temperature of polymerization so that the greater part of the butene-1 is polymerized within a high temperature range higher than that of the initial polymerization but not at a temperature so high that the polymer formed dissolves in said medium, characterized in that (1) the initial polymerization is carried out at a temperature of not more than 20.degree. C. in the presence of said titanium trihalide in an amount of not less than 50 millimoles and up to 1,000 millimoles per liter of said medium, and then (2) the polymerization is carried out in the presence or absence of said medium at a temperature of 25.degree. C. to less than 48.degree.Type: GrantFiled: November 21, 1979Date of Patent: December 16, 1980Assignee: Mitsui Petrochemical Industries Ltd.Inventor: Kunisuke Fukui
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Patent number: 4238250Abstract: A multi-colored decorative zinc or zinc alloy having locally organic dyestuff-dyed portions in multi-color is prepared by (1) dyeing with a dyestuff zinc or zinc alloy having a dyeable chromate film bonded thereonto, (2) polishing locally the dyed surface of zinc or zinc alloy, (3) making the chromate film on the exposed surface, (4) dyeing with another dyestuff having a different color the chromate film on the exposed surface, and then the steps (2), (3) and (4) may successively be repeated.Type: GrantFiled: March 7, 1979Date of Patent: December 9, 1980Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Nobuyoshi Kasahara, Koutarou Nonomura
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Patent number: 4237037Abstract: A powder coating composition comprising(A) 70 to 97% by weight of an ethylene resin mixture composed of(A-1) an ethylene copolymer having a melt index of 1 to 50 and containing at least one comonomer selected from the group consisting of alpha-olefins other than ethylene, dienes, vinyl acetate, vinyl alcohol, acrylic acid, functional derivatives of acrylic acid, methacrylic acid and functional derivatives of methacrylic acid, and(A-2) a graft copolymer of polyethylene having grafted thereto an unsaturated carboxylic component, the amount of said unsaturated carboxylic component being 0.001 to 2% based on the weight of the ethylene resin mixture (A), and(B) 3 to 30% by weight of a hydrocarbon wax having a number average molecular weight of about 400 to about 3,000 and a density of not less than 0.9 g/cm.sup.3, said wax having an acid value of up to about 5 when it is a modified wax.Type: GrantFiled: April 3, 1979Date of Patent: December 2, 1980Assignee: Mitsui Petrochemical Industries Ltd.Inventor: Takao Takahashi
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Patent number: 4237319Abstract: A process for producing m-diisopropylbenzene dihydroperoxide which comprises oxidizing m-diisopropylbenzene in the liquid phase with molecular oxygen under alkaline conditions; wherein the oxidation is carried out under conditions (A), (B) and (C) below,(A) under conditions which meet (i), (ii), (iii) and (iv) below,(i) 0.ltoreq.x.ltoreq.140(ii) y.gtoreq.80(iii) -0.05x+110.gtoreq.y.gtoreq.-0.15x+95wherein 0.ltoreq.x.ltoreq.100(iv) y.ltoreq.-0.25x+130wherein 100<x.ltoreq.140in which x represents the absolute value of the concentration of hydroperoxides in the oxidation product in % by weight calculated as m-diisopropylbenzene monohydroperoxide, and y represents the absolute value of the reaction temperature in degrees centigrade,(B) until x reaches at least 120, and(C) so that the reaction temperature at 100<x.ltoreq.140 is lower than the reaction temperature at the start of the reaction (x=0).Type: GrantFiled: October 24, 1978Date of Patent: December 2, 1980Assignee: Mitsui Petrochemical Industries Ltd.Inventors: Hirohiko Nambu, Isao Hashimoto, Ichiro Imai
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Patent number: 4235769Abstract: Disclosed is a color-developing composition for pressure-sensitive recording sheet material of the self-contained type comprising (A) 100 parts by weight of a copolymer obtained by reacting a p-alkylphenol having an alkyl moiety of from 1 to 12 carbon atoms and phenol with formaldehyde and (B) from 1 to 20 parts by weight of a hindered phenolic compound selected from phenols having an alkyl, alkylene or hydroxyl substituent radical in at least the 2- or 6-position, or both, of the benzene ring and derivatives thereof, the copolymer and the hindered phenolic compound being homogeneously dissolved in mutual solution. The hindered phenolic compound is either added to the starting materials for the preparation of the copolymer or, at the end of the copolymerization reaction, added to the resulting copolymer and dissolved homogeneously in mutual solution.Type: GrantFiled: January 19, 1979Date of Patent: November 25, 1980Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Makoto Asano, Saburo Kawashima, Kenichi Sugimoto, Tadashi Kobayashi
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Patent number: 4232139Abstract: A process for producing a polymer or copolymer of an olefin containing at least 3 carbon atoms which comprises polymerizing or copolymerizing at least one olefin containing at least 3 carbon atoms, or copolymerizing the olefin with up to 10% mole of ethylene and/or a diolefin, in the presence of a catalyst composed of (A) a magnesium-containing solid titanium composition and (B) an organometallic compound of a metal of Groups I to III of the periodic table; characterized in that the solid titanium composition (A) is a composition formed by contacting (i) a halogen-containing magnesium organo-aromatic compound of the formula Mg(OR).sub.n X.sub.2-n wherein R represents an aryl or aralkyl group and n is a positive number of 0<n<2, (ii) an organic acid ester, and (iii) a titanium compound in the absence of mechanical pulverization.Type: GrantFiled: May 27, 1977Date of Patent: November 4, 1980Assignee: Mitsui Petrochemical Industries Ltd.Inventors: Syuji Minami, Norio Kashiwa
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Patent number: 4231934Abstract: N-(hydroxyphenyl) maleimides of the general formula ##STR1## where R' stands for H, CH.sub.3, C.sub.2 H.sub.5, F, Cl, Br or I and n is an integer of 1-5 are produced by treating the corresponding maleamic acid or by treating the ester of said N-(hydroxyphenyl) maleimide at a temperature of 0-150.degree. C. in the presence of at least one dehydrating agent selected from the group consisting of oxides and oxyacids of sulfur or phosphorus and alkali metal and alkaline earth metal salts of the said oxyacids. The corresponding maleamic acid can be obtained by reacting an aminophenol having one or more hydroxyl groups on its phenyl nucleus with maleic anhydride. The esters of the N-(hydroxyphenyl maleimide) can be obtained by reacting said aminophenol and said maleic anhydride in the presence of a conventional acid anhydride dehydrating agent and a conventional imide-forming cyclization catalyst.Type: GrantFiled: November 2, 1978Date of Patent: November 4, 1980Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Masayuki Oba, Motoo Kawamata, Hikotada Tsuboi, Nobuhito Koga
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Patent number: 4231961Abstract: In a urea synthesis process, the reaction product from the reaction vessel is flowed in series through high pressure, medium pressure and low pressure decomposing and stripping devices to decompose ammonium carbamate to NH.sub.3 gas, CO.sub.2 gas and water vapor, and to remove those gases and unreacted starting materials from the aqueous urea solution. CO.sub.2 gas is used as the stripping gas in the decomposing and stripping devices.Type: GrantFiled: November 5, 1979Date of Patent: November 4, 1980Assignees: Toyo Engineering Corporation, Mitsui Toatsu Chemicals, IncorporatedInventors: Keizo Konoki, Michio Nobue, Akito Fukui, Shigeru Inoue
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Patent number: 4230762Abstract: An asphalt water-proofing material comprising a core impregnated with petroleum asphalt. The core is made of composite material including a non-woven fabric layer formed of long filaments of synthetic resin arranged in random fashion and a woven or knitted fabric layer. The non-woven fabric and woven or knitted fabric layers are connected together by needle-punching whereby the long filaments of the non-woven fabric layer are forced into the woven or knitted fabric layer to integrally connect these layers to form said core.Type: GrantFiled: July 20, 1979Date of Patent: October 28, 1980Assignees: Mitsui Petrochemical Industries Ltd., Mitsuboshi Sangyo Co., Ltd.Inventors: Hajime Iwasaki, Kuninori Mizuta, Yoshinori Kobayashi, Tadayoshi Yoshikawa, Kyouzi Muraoka
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Patent number: 4230840Abstract: A process for producing a hydrocarbon resin having improved color and thermal stability, which comprises treating a petroleum cracking or reforming fraction containing cationically polymerizable hydrocarbons and not more than 0.7% by weight, based on the fraction, of cyclopentadienes and having a boiling range of from 140.degree. C. to 280.degree. C., with 0.8 to 3.0 moles, per mole of the cyclopentadienes, of a dienophile compound having a carbon-to-carbon double bond and a carbonyl or cyano group adjacent to the double bond; and then polymerizing the treated petroleum fraction in the presence of a polymerization catalyst.Type: GrantFiled: December 26, 1978Date of Patent: October 28, 1980Assignee: Mitsui Petrochemical Industries Ltd.Inventors: Shigeru Katayama, Mutsuhiro Aoki