Abstract: The disclosure provides a method for preparing a hollow fiber membrane by melt spinning-stretching and selective swelling, including: preparing a nascent hollow fiber by melt spinning in an inert gas protective atmosphere by using an amphiphilic block copolymer as a film forming material, and stretching the nascent hollow fiber in the cooling process, a stretch rate being controlled at 200-540 mm/min, and a stretch ratio being controlled at 150-600%; immersing the obtained hollow fiber in a swelling solvent, and treating the hollow fiber in a water bath at 65° C. for 1 h; and then transferring the hollow fiber into a long-chain alkane solvent, treating the hollow fiber at the same temperature for 1-12 h, and after the completion of the treatment, immediately taking out the hollow fiber and drying the hollow fiber to obtain the hollow fiber membrane with a bicontinuous porous structure.

Abstract: The present disclosure relates to a mixed matrix carbon molecular sieve (CMS) membrane, a preparation method of the mixed matrix CMS membrane, and use of the mixed matrix CMS membrane in C2H4/C2H6 separation, and belongs to the technical field of membrane separation. The present disclosure solves the problem that the CMS materials in the prior art exhibit low selectivity and low flux during an ethylene/ethane separation process. In this patent, C3N4 is used as a filling particle to prepare a mixed matrix membrane (MMM), and the MMM is pyrolyzed to prepare a CMS membrane. The C3N4/6FDA-DAM MMM has prominent C2 separation performance.

Abstract: The present disclosure relates to a mixed matrix carbon molecular sieve (CMS) membrane, a preparation method of the mixed matrix CMS membrane, and use of the mixed matrix CMS membrane in C2H4/C2H6 separation, and belongs to the technical field of membrane separation. The present disclosure solves the problem that the CMS materials in the prior art exhibit low selectivity and low flux during an ethylene/ethane separation process. In this patent, C3N4 is used as a filling particle to prepare a mixed matrix membrane (MMM), and the MMM is pyrolyzed to prepare a CMS membrane. The C3N4/6FDA-DAM MMM has prominent C2 separation performance.

Abstract: M(SiF6)(pyz)3 (M=Cu, Zn, Co, or Ni) has a pore size between a size of H2 and a size of CO2, and thus exhibits prominent screening performance for H2/CO2. A strong interaction between Cu(SiF6)(bpy)2 and a CO2 molecule can hinder the transport of the CO2 molecule. The above two MOFs both can achieve the H2/CO2 separation. By preparing a dense MSiF6/polymer layer, MSiF6 is uniformly dispersed in the polymer and is fixed, and subsequently, MSiF6 is converted into M(SiF6)(pyz)3 or Cu(SiF6)(bpy)2 by interacting with an organic ligand. Through vapor-induced in-situ conversion, MOF particles can be well dispersed without interface defects between the MOF particles and the polymer. Even at a doping amount of 80%, the mechanical flexibility and stability of the MMM can still be retained.

Abstract: A system for resource recycling of sulfur dioxide includes a charcoal reduction furnace, a high temperature dust remover, a cooling separator A, a liquid sulfur tank, a cooling separator, a tail gas absorption tower, a gas stripping tower, a hypo reactor, a centrifuge, a mother liquor tank and a thickener. And a method for resource recycling of sulfur dioxide includes the following steps: (1) preparing elemental sulfur, (2) removing dust from a process gas containing gaseous sulfur, (3) separating elemental sulfur, (4) reabsorbing residual SO2 gas, (5) purifying sulfur powder, (6) preparing a slurry of cured hypo, (7) performing liquid-solid separation, and (8) preparing an absorption slurry. According to the method, SO2 gas is reduced into liquid sulfur and sulfur powder, and sodium thiosulfate is coproduced.

Abstract: A medium internal circulation enhanced thermal desorption soil remediation reactor and a method thereof, and belongs to the technical field of soil remediation. Internal circulation of a thermal medium is realized through a specially designed rotary drum structure, and a way for heating soil by utilizing oxidative decomposition of organic contaminants is provided, so that the treatment efficiency of an apparatus and the contaminant removal effect are improved significantly on the premise of not increasing the scale of the apparatus, and at the same time, the energy consumption of a system is reduced.

Abstract: A hot air circulation type indirect thermal desorption-based soil remediation system and method, belonging to the technical field of soil remediation. The system includes a thermal desorption reactor, a dust remover, a hot air circulating fan, a hot air heater, an air preheater, a combustion fan and a combustion device. By using thermal desorption gas generated by soil being heated and volatilized as a heat transfer medium and by a circular heating manner, hot air efficiently transfers heat to the soil by contact, and the high-temperature fume is kept from direct contact with the soil, so the system has the advantages of high treatment capacity, small equipment scale and the like.

Abstract: The present disclosure relates to a phenyl-modified polydimethylsiloxane (PDMS) separation membrane, a fabrication method thereof, and a use thereof in the separation of an aromatic compound, and belongs to the technical field of separation membrane materials. A phenyl-modified PDMS separation membrane comprising a substrate layer and a selective layer is provided.

Abstract: A membrane modification method for improving liquid membrane separation of carbon dioxide (CO2) includes grafting an organic substance containing an amine group on a porous membrane material, and loading water into pore channels of the porous membrane material to prepare a supported liquid membrane for a gas mixture separation experiment of CO2. In the method, the amine group is introduced through chemical grafting to make the water being alkaline when used as membrane liquid. Compared with an alkaline solution as the membrane liquid, the method can avoid the loss of active alkaline substances and increase the permeation flux of CO2.

Abstract: A system for resource recycling of sulfur dioxide includes a charcoal reduction furnace, a high temperature dust remover, a cooling separator A, a liquid sulfur tank, a cooling separator, a tail gas absorption tower, a gas stripping tower, a hypo reactor, a centrifuge, a mother liquor tank and a thickener. And a method for resource recycling of sulfur dioxide includes the following steps: (1) preparing elemental sulfur, (2) removing dust from a process gas containing gaseous sulfur, (3) separating elemental sulfur, (4) reabsorbing residual SO2 gas, (5) purifying sulfur powder, (6) preparing a slurry of cured hypo, (7) performing liquid-solid separation, and (8) preparing an absorption slurry. According to the method, SO2 gas is reduced into liquid sulfur and sulfur powder, and sodium thiosulfate is coproduced.

Abstract: The present invention discloses a bullet with a negative Poisson's ratio effect and a method of designing thereof. The bullet includes a cylindrical section of the bullet having a negative Poisson's ratio design, and a conical tail of the bullet and a tip of the bullet each with a matching design; the cylindrical section of the bullet is a tubular structure having periodically alternating transverse and vertical holes; the tubular structure includes a plurality of holes, with a center axis of one hole being axially perpendicular to a center axis of another adjacent hole, that is, the axis of each hole being structurally orthogonal to an adjacent hole; and the holes in rows and columns are periodically arranged into the tubular structure, which is a tubular structure having the negative Poisson's ratio effect.

Abstract: The present invention provides a catalyst for catalytic reduction of an industrial flue gas SO2 with CO to prepare sulfur, a method for preparing the same and use thereof. A CeO2 nanocarrier is prepared by using a hydrothermal method, La and Y are loaded as active components, pre-sulfurization is conducted with 6% of SO2 and 3% of CO, and finally, the catalyst is prepared. The catalyst has high reactivity and sulfur selectivity and strong stability. The by-product sulfur generated by the reaction is recovered with a solvent CS2, and the solvent CS2 is recovered by using a distillation process. The preparation method is low in cost, causes no secondary pollution and is high in sulfur recovery rate. The problem of low sulfur production in China at present is solved.

Abstract: A catalyst for inducing thermal desorption of organic matter-contaminated soil and a preparation method thereof, which uses a colloidal mixture of ferroferric oxide and ferric chloride as a catalytic active component of thermal desorption, and carbon tetrachloride as a solvent. Based on the mass of solvent, a mass percentage of catalytic active component is 0.1%-15%. Ammonia water is added dropwise to ferric chloride aqueous solution to react in oil bath to generate a ferroferric oxide colloidal solution, then ferric chloride and obtained ferroferric oxide colloidal solution are added to carbon tetrachloride, and mixed solution is continuously stirred in an oil bath to evaporate solvent water to prepare a catalyst with carbon tetrachloride as solvent. Catalyst is environmentally friendly and can induce thermal desorption of organic matters in soil. 100% desorption of chlorobenzene, o-xylene and benzo[A]anthracene can be achieved at 130° C., and energy consumption of thermal desorption is greatly reduced.

Abstract: A method for preparing a polyol comprises the following steps of: (1) dissolving 2,3 -epoxybutane and an acid catalyst in an inert solvent to obtain a solution A; dissolving triethylene glycol in an inert solvent to obtain a solution B; and dissolving epoxy vegetable oil in an inert solvent to obtain a solution C; (2) respectively and simultaneously pumping the solutions A and B into a first micromixer for mixing; (3) pumping the solution C and an effluent of the first microreactor into a second micromixer for mixing while carrying out step (2); and (4) dissolving the vegetable oil polyol in an inert solvent to obtain a solution D; dissolving epoxypropane and an alkaline catalyst in an inert solvent to obtain a solution E; and pumping the solution D and the solution E into a tank reactor for reaction, thereby obtaining the polyol.

Abstract: Determining a white plume control line of smoke after wet desulphurization includes: drawing a saturated air enthalpy humidity curve or equivalent; obtaining annual temperature and humidity change data of located cities or regions along with the time at the frequency of at least one datum every day; drawing the data obtained in the saturated air enthalpy humidity curve; and drawing a tangent line on the saturation curve by using each meteorological point in a chart, the right lower side of the tangent line is a de-pluming control region, the de-pluming effect superior to that at the feature meteorological point can be realized when the smoke enters the region after regulation, a region defined by the de-pluming control line and the saturation curve at a low-temperature side forms a de-pluming day number control region, and the point number falling within the region is the white plume generating day number.

Abstract: The present invention provides a room-temperature selective swelling method of pore-forming used for preparing separation membranes, comprising: treating a dense membrane of an amphiphilic block copolymer by a composite swelling agent at 15-30° C. for 1 min-24 h, removing the residual solvent, then leaving the membrane at room temperature to dry, so as to obtain an amphiphilic block copolymer separation membrane with a bi-continuous porous structure, wherein the composite swelling agent is composed of 60-96% of a first swelling agent and 4-40% of a second swelling agent, the first swelling agent is an alcohol solvent, the second swelling agent is selected from any one or a mixture of two or more of toluene, styrene, tetrahydrofuran, 1,4-dioxane and so on. In the method of the invention, selective swelling can be achieved at room temperature, abating the energy consumption in membrane-forming process.

Abstract: An integrated filter material, a preparation method and an application. The filter material is composed of a commercial dust removal filter material and a catalyst that is grown on the filter material and that has a function of simultaneously decomposing nitrogen oxides and dioxins. In the preparation method, a precursor solution of manganese and cerium oxides is impregnated on the filter material, and manganese and cerium oxides are grown on the filter material by means of a chemical reaction; and vanadium oxychloride is used as a precursor of vanadium oxide and is impregnated on the filter material, reacts in water, and prepared by drying, hydrothermal and other processes. The composite filter material may remove three kinds of pollutants in flue gas at the same time, and the catalyst is firmly loaded and does not easily fall off.

Abstract: A membrane modification method for improving liquid membrane separation of carbon dioxide (CO2) includes grafting an organic substance containing an amine group on a porous membrane material, and loading water into pore channels of the porous membrane material to prepare a supported liquid membrane for a gas mixture separation experiment of CO2. In the method, the amine group is introduced through chemical grafting to make the water being alkaline when used as membrane liquid. Compared with an alkaline solution as the membrane liquid, the method can avoid the loss of active alkaline substances and increase the permeation flux of CO2.

Abstract: An infrared selective radiation cooling nano-functional composition and a preparation method thereof, wherein the composition is prepared from silica, a rare earth silicate compound and a molybdate compound according to a mass ratio of 1:(0.5-2):(0.5-2) by ball milling and uniform mixing, and the silica, the rare earth silicate compound and the molybdate compound have high infrared selective radiation performance at 8-10 ?m, 9-12 ?m and 10-14 ?m. The rare earth silicate and molybdate compound are prepared by a sol-gel and a high-temperature solid phase process according to stoichiometric ratios SiO2-(0.5-2)Re2O3-(0.1-1.0)Na2O (Re?La, Sm, Eu, Gd, Tb, Dy, Er, Tm, Yb, Y or Sc) and RMoO4 (R?Mg, Ca, Sr or Ba).

Abstract: Disclosed is a method for predicting corrosion and spontaneous combustion of sulfur-related petrochemical equipment. The method solves the issues in the existing techniques that includes narrow predicting range, high workload in installation and maintenance, and time lag in predicting corrosion and spontaneous combustion inside equipment. The method comprises a step of a dual index system prediction, which includes a step of monitoring a temperature and a step of detecting SO2 gas generated by spontaneous combustion. The time when spontaneous combustion occurs can be accurately calculated by using a fitted quantitative relationship formula generated by the spontaneous combustion of corrosion products. The method has a low Labor cost. The method has a low labor cost and, does not require on-site gas detection to be carried out by means of manual detection, which both reduces the cost and ensures the detection accuracy.