Abstract: A method for preparing a two-dimensional sheet-shaped Cu-MOF material, includes mixing Cu-BTC with an alkaline solution at a certain solid-liquid ratio by stirring, reacting at a temperature of 25 to 120° C., filtering, washing with ionized water and drying under vacuum, to obtain a two-dimensional sheet-shaped Cu-MOF material, wherein the alkaline solution is at least one of urea, sodium carbonate, sodium bicarbonate, aqueous ammonia, sodium hydroxide or potassium hydroxide. The method has the characteristics of mild operation conditions, controllable transition process, high reaction yield and easy production at large scale, and exhibits excellent oxidation performance in styrene oxidation.

Abstract: A multilayer thin film evaporator for steam heating includes a housing. A three-layer evaporation cylindrical core arranged in a nested manner with one layer placed inside the other is configured inside the housing. A limiting plate is configured to fix the three-layer evaporation cylindrical core. A feeding tube, a heating medium inlet tube, and a heating medium outlet tube are sequentially fixed under the limiting plate in a crosswise manner. A rotary rack spindle passing through a center of the three-layer evaporation cylindrical core, a rotary rack fixed on the rotary rack spindle and capable of rotating with the rotary rack spindle, and a motor component connected to a top end of the rotary rack spindle and capable of driving the rotary rack spindle to rotate are further provided.

Abstract: A multi-stage evaporation system enhanced by a gravity-reduced field consists of evaporation structures of multiple stages. There are three different operation modes, namely, a serial-connected air and parallel-connected solution mode, a serial-connected air and serial-connected solution mode, and a parallel-connected air and serial-connected solution mode. In the evaporation chambers, the solution directly contacts the air to transfer the heat and mass. The solution is sprayed on the rotating filling material, and is uniformly distributed under the action of the gravity-reduced field, which enhances the heat and mass transfer. The solution is gasified by absorbing the heat energy thereof. Meanwhile, the air can carry more water vapor after being heated by the solution and thus having an increased temperature, and take away the gasified solution, thereby achieving the purpose of evaporation.

Abstract: A method and a system of a high-temperature calcium looping thermochemical energy storage are provided. A thermochemical energy storage system is based on CaCO3/CaO, and an energy storage is performed by a mutual transformation between a thermal energy and a chemical energy. When solar irradiation is sufficient, CaCO3 solid particulates are indirectly heated by hot air generated from solar energy to perform an endothermic decomposition reaction, and received heat is stored in decomposition products of CaO and CO2 in a form of the chemical energy. When heat is required, a reversible thermochemical reaction occurs between the CaO and CO2 under an atmospheric pressure, and the chemical energy stored in the CaO and CO2 is transformed into the heat for release.

Abstract: The invention relates to a high-strength hollow fiber zeolite membrane and its preparation method, characterized in that the support of the high-strength zeolite membrane has a multi-channel hollow fiber configuration. The preparation method comprises first preparing a crystal seed solution, then immersing the dry support with the multi-channel hollow fiber configuration in the crystal seed solution, and extracting and drying the support to obtain a crystal-seeded support; and finally placing the crystal-seeded support in a zeolite membrane synthetic fluid, performing hydrothermal synthesis, and taking out, washing and drying the product to obtain the high-strength hollow fiber zeolite membrane. The multi-channel hollow fiber support can provide high mechanical property, which greatly reduces the depreciation rate of the hollow fiber zeolite membrane equipment during use.

Abstract: It discloses a lignin enhanced wood-plastic composite, belonging to the field of polymer based composites. The wood-plastic composite is composed of one or more of plant fiber, lignin, a recycled thermoplastic plastic, mineral powder and a processing aid, and is processed by a screw granulating extrusion process. Compared with the prior art, the mechanical properties, heat stability and aging resistance of a wood-plastic material are improved by adding lignin into the wood-plastic material according to the present invention.

Abstract: A counter-flow fin plate heat exchanger for gas-to-gas heat exchange includes several outer channel fins, an outer channel bending plate, an inner channel fin and an inner channel bending plate. The outer channel bending plate is a flat plate with two sides bending upward vertically. The inner channel bending plate is a cuboid box without a cap on the top, and the top of the inner channel bending plate is hermetically fixed with the bottom of the outer channel bending plate. The several outer channel fins are arranged in parallel inside the outer channel bending plate. The inner channel fins are arranged inside the inner channel bending plate. Ends of a side surface corresponding to two long sides of the inner channel bending plate are respectively provided with an opening, and the two openings are respectively disposed at different ends of the two side surfaces.

Abstract: The present invention relates to a method for preparing nanoporous polysulfone-based polymers, including: a copolymer of a polysulfone polymer and a polar polymer is immersed into a compound swelling agent, and maintained for at least 1 minute above room temperature; the compound swelling agent is a “solvent pair” composed of the mixture of solvent A and solvent B; the solvent A has high affinity with the polysulfone polymer; and the solvent B has high affinity with the polar polymer; the treated copolymer is taken out from the compound swelling agent and then dried to remove the solvent to obtain the nanoporous polysulfone-based polymers.

Abstract: A preparation method of a SiC porous ceramic material and porous ceramic material manufactured by using the method, comprising: mixing a SiC aggregate, a sintering aid (zirconium oxide), a pore-forming agent (activated carbon) and a polymer binder with a reinforcing agent (SiC whiskers) according to a certain proportion, and obtaining a porous ceramic material via forming, drying and high-temperature sintering. The porous ceramic material has a high strength, a high porosity, a good thermal shock resistance and a low sintering temperature, and can server as a filter material of high-temperature flue gas and a carrier material in vehicle exhaust purification.

Abstract: A preparation method of vegetable oil polyol, which is obtains by carrying out allylic oxidation treatment of vegetable oil, increasing the content of hydroxyl group in the product and then one step reaction between epoxidation and ring-opening. At the same time, the present invention also discloses novel vegetable oil polyol made by the preparation method and the application of the vegetable oil polyol in preparation of polyurethane foam material. Compared with the prior art, the method has the advantages of simple operation, low energy consumption and low side reaction occurrence rate.

Abstract: A counter-flow fin plate heat exchanger for gas-to-gas heat exchange includes several outer channel fins, an outer channel bending plate, an inner channel fin and an inner channel bending plate. The outer channel bending plate is a flat plate with two sides bending upward vertically. The inner channel bending plate is a cuboid box without a cap on the top, and the top of the inner channel bending plate is hermetically fixed with the bottom of the outer channel bending plate. The several outer channel fins are arranged in parallel inside the outer channel bending plate. The inner channel fins are arranged inside the inner channel bending plate. Ends of a side surface corresponding to two long sides of the inner channel bending plate are respectively provided with an opening, and the two openings are respectively disposed at different ends of the two side surfaces.

Abstract: A method to prepare functional polyester polyols by using micro-reaction device, wherein mixing ?-caprolactone/?-valerolactone monomer with mercapto alcohol evenly with appropriate organic solution under moistureless conditions, and continuously transferring the prepared mixing solution into a micro-reaction device supported with an immobilized enzyme for polymerization to synthetize a poly (?-caprolactone/?-valerolactone). Compared with the prior art, the present invention achieves a continuous production by using immobilized lipase Novozyme435 as a catalyst.

Abstract: The present disclosure provides a blue luminescent material, and the blue luminescent material is a tertradentate platinum complex having a chemical structure of Formula I comprising a pyridoimidazole carbene platinum structure. The blue luminescent material of the present disclosure may be used in OLED devices and apparatus as a dopant material and emits blue light having a wavelength of 450-490 nm. The present disclosure provides a design route for a material by introducing a pyridoimidazole-type carbene into the ligand of a platinum complex. Since the carbene structure has suitable triplet energy and its carbon-platinum bond is more stable than the nitrogen-platinum bond, the entire spectrum can become narrower, which will promote development of blue luminescent material and improve performances of the devices.

Abstract: It discloses cement grinding aids prepared with waste antifreeze which comprises the following components in parts by weight: 20-75 parts of pretreated waste antifreeze, 5-40 parts of alkanolamine, 1-5 parts of acid solution, 3-12 parts of saccharide and 15-50 parts of water. The pretreated waste antifreeze is prepared by adding an alkaline solution into waste antifreeze to regulate the pH value, adding a flocculant, and stirring and standing; separating upper-layer oil, and then filtering to remove flocculent precipitates, thus obtaining a clear mixed solution.

Abstract: The Invention discloses a preparation method for a triptyl polymer separation membrane, wherein, it comprises the following steps: take triptycene compound containing active group, dichloride compound and diamino compound containing ether bond as monomers, and conduct polymerization in aprotic organic solvent in the presence of acid-binding agent; pour the obtained polymer solution into deionized water for precipitation after the reaction, filter out precipitates and wash with methanol and dry to get triptyl polymer; dissolve the triptyl polymer in aprotic organic solvent to produce a membrane-casting solution, apply the solution on support and dry to get a triptyl polymer separation membrane. The Invention solves the problem that the reticular polymer material is insoluble, and breaks the restriction for application of such material in separation membrane due to its insoluble and aging features.

Abstract: It relates to the field of synthetic macromolecular chemistry, and discloses a method for one-step synthesis of thiol-functionalized polyester polyols by organic catalysis. This method uses lactone monomer as reaction raw material, thiol-alcohol as initiator, and diphenyl phosphate as organic catalyst to catalyze and synthesize the thiol-functionalized polyester polyols. The present invention provides a method which is simple, inexpensive, easily controllable and environmentally friendly to prepare thiol-functionalized polyester polyols with the easily available and controllable catalyst. The method can selectively catalyze the ring opening polymerization of lactone to prepare thiol-functionalized polyester polyols using the organic catalyst.

Abstract: It discloses cement grinding aids prepared with waste antifreeze which comprises the following components in parts by weight: 20-75 parts of pretreated waste antifreeze, 5-40 parts of alkanolamine, 1-5 parts of acid solution, 3-12 parts of saccharide and 15-50 parts of water. The pretreated waste antifreeze is prepared by adding an alkaline solution into waste antifreeze to regulate the pH value, adding a flocculant, and stirring and standing; separating upper-layer oil, and then filtering to remove flocculent precipitates, thus obtaining a clear mixed solution.

Abstract: It discloses a chemical regeneration method of oxidized coenzyme NAD(P)+ which is under an oxygen or air atmosphere condition, adding a catalytic amount of bridged flavin, and oxidizing NAD(P)H to obtain NAD(P)+. The catalyst for regeneration of cofactor is cheap and easily available small organic molecule having no noble metal; this regeneration system can regenerate NADH and NADPH; this regeneration system has a wide pH range and temperature range, being applicable to various oxidation reactions catalyzed by nicotinamide-dependent oxidoreductase.

Abstract: A chemical additive for calcium sulphoaluminate-modified Portland cement comprises the following substances: (a) at least one alkanolamine borate; (b) at least one organic alcohol; and (c) at least one saccharide or a derivative thereof; and the substances and water are sequentially mixed and stirred to obtain the chemical additive for calcium sulphoaluminate-modified Portland cement. The chemical additive for calcium sulphoaluminate-modified Portland cement provided by the invention has better effects of regulating the setting time of the calcium sulphoaluminate-modified Portland cement and improving the 3d/28d strength increase rate, and also has a grinding aid effect when being added during grinding.

Abstract: Provided is a method for preparing a bulk C—AlN composite aerogel with high strength and high temperature resistance, which includes: evenly stirring aluminum chloride crystals, water, ethanol and epoxy propane, to obtain a clear aluminum oxide sol solution, then adding formaldehyde and resorcinol to the solution and performing even stirring, to obtain an RF/Al2O3 composite aerogel sol solution, leaving the gel to stand, treating the sample by using a supercritical CO2 drying method, and finally heat-treating the sample at a high temperature under the condition of nitrogen, to obtain the bulk C—AlN composite aerogel with high strength and high temperature resistance. The composite aerogel prepared by using this method has advantages of high integrity, high specific surface area, intact structure, low heat conductivity, low density, and high strength.