Abstract: The present invention relates to a composite of a cobalt-based perovskite material with a negative thermal expansion material, and a preparation method of the same, and a solid oxide fuel cell (SOFC) comprising the same, and belongs to the technical field of fuel cells. In the present invention, a negative thermal expansion material is introduced into a cobalt-based perovskite oxide to successfully prepare an SOFC cathode material with excellent electrochemical performance and low thermal expansivity. The composite electrode achieves prominent mechanical tolerance in SOFC, which can moderate a volume change during the whole calcination process and enable a smooth transition to a high-temperature stage. The composite electrode has a thermal expansion coefficient (TEC) only of 12.9×10?6 K?1, which is perfectly matched with that of an SDC electrolyte. In addition, the composite shows excellent oxygen reduction reaction (ORR) activity, high TEC, and extremely-excellent anti-CO2 poisoning performance.

Abstract: A device for preparing a sulfite includes: a mother liquid tank and alkaline bin connected to a concentrated alkaline tank, connected to a tower reactor first reactor, one first reactor bottom output end is connected to a first gas-and-liquid mixer and another to a bubbling reaction kettle upper end, a bubbling reaction kettle gas output end is connected to the first mixer being connected to a first reactor upper portion; first reactor upper portion gas and second reactor bottom output ends are connected to a second mixer being connected to the second reactor top; and the bubbling reaction kettle is connected to a centrifugal machine or the alkaline tank, the machine being connected to a wet material bin and the liquid tank. A method includes preparing main and auxiliary absorption liquids, generating a middle slurry, reabsorbing residual gas SO2, generating a target product, separating the target product, drying and packaging.

Abstract: A heat pipe-enhanced heat accumulation type indirect thermal desorption-based soil remediation device and method. On the one hand, by using thermal desorption gas generated by soil through heating and volatilizing as a heat transfer medium and by a circular heating manner, hot air efficiently transfers heat to the soil by contact, the treatment capacity of equipment is high. Moreover, high-temperature flue gas is kept from direct contact with the soil, so the high-temperature flue gas is prevented from being mixed with gaseous organic contaminants. Therefore, only a small amount of excess gas needs to be purified, so the equipment scale is small. On the other hand, by equipping a reactor with heat pipes and a ceramic heat accumulator, a second soil heating manner is provided, so that the heat transfer capacity per unit volume of the reactor is increased, and the treatment efficiency is significantly improved under the same scale.

Abstract: A hot air circulation type indirect thermal desorption-based soil remediation system and method, belonging to the technical field of soil remediation. The system includes a thermal desorption reactor, a dust remover, a hot air circulating fan, a hot air heater, an air preheater, a combustion fan and a combustion device. By using thermal desorption gas generated by soil being heated and volatilized as a heat transfer medium and by a circular heating manner, hot air efficiently transfers heat to the soil by contact, and the high-temperature fume is kept from direct contact with the soil, so the system has the advantages of high treatment capacity, small equipment scale and the like.

Abstract: A medium internal circulation enhanced thermal desorption soil remediation reactor and a method thereof, and belongs to the technical field of soil remediation. Internal circulation of a thermal medium is realized through a specially designed rotary drum structure, and a way for heating soil by utilizing oxidative decomposition of organic contaminants is provided, so that the treatment efficiency of an apparatus and the contaminant removal effect are improved significantly on the premise of not increasing the scale of the apparatus, and at the same time, the energy consumption of a system is reduced.

Abstract: The present invention discloses a testing method and a testing system for a safe operating window of a lithium-ion battery in a squeezed state. The testing system includes a mechanical loading device, a heating device, a lithium-ion battery tester and a measuring device. By comparing the influence of a combined use of two or more of mechanical abuse with two different fixed variables, thermal abuse, and electrical abuse on critical conditions of thermal runaway of the lithium-ion battery, the influence of the different forms of abuse on the critical conditions of thermal runaway of the lithium-ion battery can be compared qualitatively and quantitatively, and these data can also be used to determine the safe operating windows of the lithium-ion battery under different abuse conditions.

Abstract: It discloses a perovskite optoelectronic device which includes a substrate, electrode layers and functional layers. The electrode layer is deposited on the substrate, the functional layer is deposited between the electrode layers, and the functional layer at least includes a perovskite layer, wherein the perovskite layer is a perovskite material possessing a self-organized multiple quantum well structure. By adjusting material components, controllable adjustment of the structure of the multiple quantum wells and effective energy transfer between the multiple quantum wells can be implemented, and light emitting color may be near-ultraviolet light, visible light and near-infrared light; moreover, the problems of low coverage and poor stability of the existing perovskite films can be effectively solved.

Abstract: It discloses a polyether polyols for preparing flexible polyurethane foam, and a preparation method and application thereof. The method comprises the following steps: (1) carrying out a reaction on phosphorus oxychloride, epichlorohydrin, a first acidic catalyst and an inert solvent in a first microchannel reactor to obtain a chloroalkoxy phosphorus compound; (2) carrying out a reaction on the chloroalkoxy phosphorus compound, glycidol, a second acidic catalyst and an inert solvent in a second microchannel reactor to obtain a hydroxy compound; (3) carrying out a ring-opening reaction on the hydroxy compound, epoxy vegetable oil, a basic catalyst and an inert solvent in a third microchannel reactor to obtain a vegetable oil polyol; and (4) carrying out an addition polymerization reaction on the vegetable oil polyol, propylene oxide and an inert solvent in a fourth microchannel reactor to obtain the polyether polyols for preparing flexible polyurethane foam.

Abstract: Disclosed is a method for preparing polylactone by ring opening, belonging to the technical fields of organic catalysis and polymer materials. The invention proposes a new catalytic mechanism, wherein an organic alcohol is used as an initiator to initiate ring opening polymerization of a cyclic monomer under the catalysis of an organic catalyst to obtain a polylactone; and the catalyst is a pyridinium salt. The present invention has the advantages of non-toxic reaction, simple conditions and controllable process; further, the invention can obtain a narrow molecular weight distribution in the absence of solution polymerization, and can effectively inhibit the occurrence of the transesterification compared with the catalysis of 4-(N,N-dimethylamino)pyridine.

Abstract: The present invention discloses a testing method and a testing system for a safe operating window of a lithium-ion battery in a squeezed state. The testing system includes a mechanical loading device, a heating device, a lithium-ion battery tester and a measuring device. By comparing the influence of a combined use of two or more of mechanical abuse with two different fixed variables, thermal abuse, and electrical abuse on critical conditions of thermal runaway of the lithium-ion battery, the influence of the different forms of abuse on the critical conditions of thermal runaway of the lithium-ion battery can be compared qualitatively and quantitatively, and these data can also be used to determine the safe operating windows of the lithium-ion battery under different abuse conditions.

Abstract: A dual-layer membrane and a method for preparing thereof. By adding a modifying monomer containing an active group and a characteristic group to a dope solution or spinning solution during the preparation of the dual-layer membrane, the grafting reaction occurs between the active group of the monomer and the polymer in the dope solution or spinning solution, and the intermolecular interaction with other polymers is enhanced by the characteristic group of the monomer, to improve the miscibility between the polymers. The method is suitable for preparing both a dual-layer flat sheet membrane and a dual-layer hollow fiber membrane, and can realize the preparation of a dual-layer membrane with an interpenetrated structure at the interface under mild preparation conditions.

Abstract: The present invention discloses a bullet with a negative Poisson's ratio effect and a method of designing thereof. The bullet includes a cylindrical section of the bullet having a negative Poisson's ratio design, and a conical tail of the bullet and a tip of the bullet each with a matching design; the cylindrical section of the bullet is a tubular structure having periodically alternating transverse and vertical holes; the tubular structure includes a plurality of holes, with a center axis of one hole being axially perpendicular to a center axis of another adjacent hole, that is, the axis of each hole being structurally orthogonal to an adjacent hole; and the holes in rows and columns are periodically arranged into the tubular structure, which is a tubular structure having the negative Poisson's ratio effect.

Abstract: A multilayer thin film evaporator for steam heating includes a housing. A three-layer evaporation cylindrical core arranged in a nested manner with one layer placed inside the other is configured inside the housing. A limiting plate is configured to fix the three-layer evaporation cylindrical core. A feeding tube, a heating medium inlet tube, and a heating medium outlet tube are sequentially fixed under the limiting plate in a crosswise manner. A rotary rack spindle passing through a center of the three-layer evaporation cylindrical core, a rotary rack fixed on the rotary rack spindle and capable of rotating with the rotary rack spindle, and a motor component connected to a top end of the rotary rack spindle and capable of driving the rotary rack spindle to rotate are further provided.

Abstract: A method and a system of a high-temperature calcium looping thermochemical energy storage are provided. A thermochemical energy storage system is based on CaCO3/CaO, and an energy storage is performed by a mutual transformation between a thermal energy and a chemical energy. When solar irradiation is sufficient, CaCO3 solid particulates are indirectly heated by hot air generated from solar energy to perform an endothermic decomposition reaction, and received heat is stored in decomposition products of CaO and CO2 in a form of the chemical energy. When heat is required, a reversible thermochemical reaction occurs between the CaO and CO2 under an atmospheric pressure, and the chemical energy stored in the CaO and CO2 is transformed into the heat for release.

Abstract: Disclosed in the present invention is a preparation method for a polyester, relating to the technical field of organic catalysis and polymeric materials. The preparation method in the present invention comprises: (1) using pyridine and saccharin in a ratio of 1:1 to prepare pyridine saccharin salt in tetrahydrofuran at 60° C. and separating the pyridine saccharin salt out in methanol and hexane. (2) Freeing out a small amount of pyridine from the pyridine saccharin salt in a heating state, catalyzing by the pyridine saccharin salt and pyridine a cyclic lactone or a carbonate to be ring-opened and polymerized to form the polyester; and the system has no other compound residues. (3) In the presence of an alcohol initiator, catalyzing by the pyridine saccharin salt the cyclic lactone to be ring-opened and polymerized to obtain the polyester. The catalytic system can efficiently synthesize a specific polylactone.

Abstract: The present invention relates to a method for preparing nanoporous polysulfone-based polymers, including: a copolymer of a polysulfone polymer and a polar polymer is immersed into a compound swelling agent, and maintained for at least 1 minute above room temperature; the compound swelling agent is a “solvent pair” composed of the mixture of solvent A and solvent B; the solvent A has high affinity with the polysulfone polymer; and the solvent B has high affinity with the polar polymer; the treated copolymer is taken out from the compound swelling agent and then dried to remove the solvent to obtain the nanoporous polysulfone-based polymers.

Abstract: The Invention discloses a preparation method for a triptyl polymer separation membrane, wherein, it comprises the following steps: take triptycene compound containing active group, dichloride compound and diamino compound containing ether bond as monomers, and conduct polymerization in aprotic organic solvent in the presence of acid-binding agent; pour the obtained polymer solution into deionized water for precipitation after the reaction, filter out precipitates and wash with methanol and dry to get triptyl polymer; dissolve the triptyl polymer in aprotic organic solvent to produce a membrane-casting solution, apply the solution on support and dry to get a triptyl polymer separation membrane. The Invention solves the problem that the reticular polymer material is insoluble, and breaks the restriction for application of such material in separation membrane due to its insoluble and aging features.

Abstract: A multi-stage evaporation system enhanced by a gravity-reduced field consists of evaporation structures of multiple stages. There are three different operation modes, namely, a serial-connected air and parallel-connected solution mode, a serial-connected air and serial-connected solution mode, and a parallel-connected air and serial-connected solution mode. In the evaporation chambers, the solution directly contacts the air to transfer the heat and mass. The solution is sprayed on the rotating filling material, and is uniformly distributed under the action of the gravity-reduced field, which enhances the heat and mass transfer. The solution is gasified by absorbing the heat energy thereof. Meanwhile, the air can carry more water vapor after being heated by the solution and thus having an increased temperature, and take away the gasified solution, thereby achieving the purpose of evaporation.

Abstract: It discloses a texturing method for a diamond wire cut polycrystalline silicon slice, including the following steps: firstly, immersing the diamond wire cut polycrystalline silicon slice into a mixed aqueous solution of an alkali solution and an alkali reaction control agent, removing a damaged layer on a surface of the silicon slice, and then immersing the silicon slice into a hydrofluoric acid solution containing inorganic ions and organic molecules for reaction; secondly, pretreating the polycrystalline silicon surface by a mixed solution of hydrofluoric acid and hydrogen peroxide, adding a pore-forming regulator at the same time, and finally texturing the surface of the silicon slice by a mixed acid solution of hydrofluoric acid and nitric acid.

Abstract: Determining a white plume control line of smoke after wet desulphurization includes: drawing a saturated air enthalpy humidity curve or equivalent; obtaining annual temperature and humidity change data of located cities or regions along with the time at the frequency of at least one datum every day; drawing the data obtained in the saturated air enthalpy humidity curve; and drawing a tangent line on the saturation curve by using each meteorological point in a chart, the right lower side of the tangent line is a de-pluming control region, the de-pluming effect superior to that at the feature meteorological point can be realized when the smoke enters the region after regulation, a region defined by the de-pluming control line and the saturation curve at a low-temperature side forms a de-pluming day number control region, and the point number falling within the region is the white plume generating day number.