Patents Assigned to National Starch & Chemical Corporation
  • Patent number: 4627847
    Abstract: Leakage resistant waste barriers for use on absorbent articles are prepared by coating a portion of a nonwoven sheet with a water insoluble or water impermeable hot melt adhesive composition.
    Type: Grant
    Filed: April 3, 1985
    Date of Patent: December 9, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Paul P. Puletti, Stanley J. Decowski, Jr.
  • Patent number: 4626363
    Abstract: Cationic emulsion polymers useful as thickening agents in aqueous dense brine solutions are disclosed. The cationic polymers are water-in-oil emulsion polymers of acrylamide or methacrylamide and a cationic monomer. The polymers have an intrinsic viscosity in 1.0 N KCl of at least 1 dl/g and preferably have an acrylamide or methacrylamide to cationic monomer molar ratio of about 60:40 to 95:5.
    Type: Grant
    Filed: August 29, 1984
    Date of Patent: December 2, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Patricia A. Gleason, Marie A. Piccoline
  • Patent number: 4626288
    Abstract: Starch derivatives capable of forming reversible gels are provided. Aqueous dispersions or solutions of the derivatives form thermally reversible hot gels at temperatures above 70.degree. C. and a pH of 3-8, in addition to exhibiting substantial increases in viscosity upon cooling from 95.degree. to 70.degree. C. The starch derivative may be alkali gelatinized at a pH 13 or above and the gel formed at a pH of from 1-10. The gelling agents are starch ethers or starch esters having an amylose content of at least 17% by weight with the ether or ester substituent comprising a linear saturated or unsaturated hydrocarbon chain of at least 12 carbon atoms.
    Type: Grant
    Filed: December 12, 1985
    Date of Patent: December 2, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Peter T. Trzasko, Martin M. Tessler, Teresa A. Dirscherl
  • Patent number: 4623688
    Abstract: Remoistenable hot melt adhesives are prepared from a poly(alkyloxazoline), a diluent and, optionally, a tackifier, plasticizer, stabilizer and non-block additive.
    Type: Grant
    Filed: December 12, 1985
    Date of Patent: November 18, 1986
    Assignee: National Starch and Chemical Corporation
    Inventor: Thomas P. Flanagan
  • Patent number: 4622374
    Abstract: Novel polymerizable imidazolidinone monomers, useful in the preparation of self-crosslinking polymers, have the general structure ##STR1## wherein R.sup.1 is H or a C.sub.1 -C.sub.6 linear or branched alkyl or hydroxyalkyl group; X is a divalent radical selected from the group consisting of --(CH.sub.2).sub.m --, ##STR2## with R being H or CH.sub.3, m being 0-5, and n being 1-5; R.sup.2 is H or CH.sub.3 ; R.sup.3 is H or ##STR3## with R' as defined above; and R.sup.4 and R.sup.5 are independently H or linear or branched C.sub.1 -C.sub.4 alkyl groups. In a preferred embodiment, aqueous emulsions of the imidazolidinone-containing polymers (e.g. 45-60% vinyl acetate, 34-52% butyl acrylate, and 3-6% imidazolidinone) and an acid-curing catalyst (e.g. ZnCl.sub.2) are used as formaldehyde-free binders for nonwoven textiles.
    Type: Grant
    Filed: October 15, 1985
    Date of Patent: November 11, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Carmine P. Iovine, Joseph G. Palmer, James L. Walker
  • Patent number: 4617343
    Abstract: Laminating adhesives are prepared from alcohol and an emulsion polymer, the polymer having been prepared in the presence of a polymerizable surfactant.
    Type: Grant
    Filed: April 23, 1984
    Date of Patent: October 14, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: James L. Walker, Mourad T. Mitry
  • Patent number: 4615888
    Abstract: Chemically and yeast leavened bakery products which have improved shelf lives are provided by the inclusion of an effective amount of a starch or flour selected from a plant of a wxsu.sub.2 genotype in the bakery product dough. Breads which contain the starch or flour, preferably obtained from maize, are provided with a softer, moister crumb after baking as well as a fresher texture and appearance after a storage period.
    Type: Grant
    Filed: March 8, 1984
    Date of Patent: October 7, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: James Zallie, Robert Trimble, Harvey Bell
  • Patent number: 4610920
    Abstract: Nonwoven fabrics characterized by a superior balance of strength and softness are formed utilizing an aqueous emulsion prepared by the emulsion polymerization of: 30 to 50% by weight of vinyl ester of an alkanoic acid; 10 to 30% by weight ethylene; 30 to 50% by weight of C.sub.4 -C.sub.8 alkyl acrylate; and 1 to 5% by weight of copolymerizable N-methylol containing monomer; wherein the polymerization is performed using batch or semi-batch techniques.
    Type: Grant
    Filed: June 27, 1985
    Date of Patent: September 9, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Paul R. Mudge, Howard G. Katz
  • Patent number: 4608265
    Abstract: An imitation cheese product which is functionally equivalent to a caseinate-based imitation cheese product, contains pregelatinized modified high amylose starches, preferably converted and/or derivatized, as partial or total replacement for the caseinate present in the cheese. Suitable converted starches include fluidity starches prepared by acid- or enzyme-conversion, oxidized starch prepared by treatment with less than 5% active chlorine, and dextrins having a calcium chloride water fluidity of less than about 50. Suitable derivatives are prepared by treatment with up to 25% propylene oxide, 5% succinic anhydride, and 10% octenylsuccinic anhydride or with a sufficient amount of acetic anhydride or sodium or potassium ortho or tripolyphosphate to provide a maximum of 6% bound acetyl or 0.8% bound phosphate. Mixtures of modified or unmodified high amylose starches with up to 80% by weight of other starches (0-40% amylose) are also suitable.
    Type: Grant
    Filed: March 8, 1985
    Date of Patent: August 26, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Gary A. Zwiercan, Norman L. Lacourse, Julianne M. Lenchin
  • Patent number: 4602073
    Abstract: Fast curing, two part adhesives and articles bonded therewith are disclosed. The adhesives comprise a first part of free radical polymerizable acrylic monomers and a diazonium salt sufficient to initiate polymerization of said monomers. A second part comprises an activator to induce the free radical decomposition of the diazonium salt, said activator being an aldehyde-amine condensation product. The described curable adhesives are formed just prior to use where the second part containing the activator is placed in contact with the first part. Both the first part and second part component exhibit a high degree of stability when stored separately.
    Type: Grant
    Filed: June 7, 1985
    Date of Patent: July 22, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Martin M. Skoultchi, Alfred G. Battaglia
  • Patent number: 4600515
    Abstract: Low and high solids drilling fluids containing high levels (i.e., at least 10,000 ppm) of divalent cations are provided with improved fluid loss control by employing high molecular weight water-in-oil emulsion copolymers of acrylamide and a water soluble salt of acrylic acid. The copolymers, produced by the copolymerization in water-in-oil emulsions form of acrylamide and acrylic acid or the salt thereof in molar ratios of 70:30 to 95:5 are particularly effective in drilling fluids containing high levels of calcium ions.
    Type: Grant
    Filed: September 12, 1984
    Date of Patent: July 15, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Patricia A. Gleason, Chester D. Szymanski
  • Patent number: 4596850
    Abstract: Novel polymerizable imidazolidinone monomers, useful in the preparation of self-crosslinking polymers, have the general structure ##STR1## wherein R.sup.1 is H or a C.sub.1 -C.sub.6 linear or branched alkyl or hydroxyalkyl group; X is a divalent radical selected from the group consisting of ##STR2## with R being H or CH.sub.3, m being 0-5, and n being 1-5; R.sup.2 is H or CH.sub.3 ; R.sup.3 is H or ##STR3## with R' as defined above; and R.sup.4 and R.sup.5 are independently H or linear or branched C.sub.1 -C.sub.4 alkyl groups. In a preferred embodiment, aqueous emulsions of the imidazolidinone-containing polymers (e.g. 45-60% vinyl acetate, 34-52% butyl acrylate, and 3-6% imidazolidinone) and an acid-curing catalyst (e.g. ZnCl.sub.2) are used as formaldehyde-free binders for nonwoven textiles.
    Type: Grant
    Filed: December 17, 1984
    Date of Patent: June 24, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Carmine P. Iovine, Joseph G. Palmer, James L. Walker
  • Patent number: 4595597
    Abstract: Batter mix for coating pre-fried microwaveable-foodstuff containing 50 to 80% flour containing at least 50% amylose.
    Type: Grant
    Filed: February 25, 1985
    Date of Patent: June 17, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Julianne M. Lenchin, Harvey Bell
  • Patent number: 4590084
    Abstract: Improved retortable farinaceous-based paste products are provided by the inclusion of an effective amount of a high amylose starch with an amylose content of at least 50% in the paste composition. Paste products including pasta and tortillas which contain the high amylose starch, typically in amounts of about 10 to 40%, are provided with improved cooking tolerance and firmness after retorting.
    Type: Grant
    Filed: February 8, 1984
    Date of Patent: May 20, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Birgit J. Miller, Harvey Bell, Eugene Wojcak
  • Patent number: 4588767
    Abstract: A hot-melt adhesive especially useful in the construction of disposable diapers contains a vinyl polymer of 40-90% by weight of a C.sub.1 -C.sub.12 alkyl acrylate and 10-60% by weight of an alpha-olefin of C.sub.20 -C.sub.40, wherein the alkyl acrylate may be partially replaced with vinyl acetate or with a C.sub.6 -C.sub.12 olefin or with mixtures thereof, provided that the polymer contain at least 10% by weight of the alkyl acrylate. The adhesive may also contain a tackifying resin, a wax, an oil or a stabilizer depending on the specific end-use desired. In a preferred embodiment the polymer contains 20-45% by weight of the alpha-olefin.
    Type: Grant
    Filed: May 24, 1985
    Date of Patent: May 13, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Jules E. Schoenberg, Thomas P. Flanagan, Dilip K. Ray-Chaudhuri
  • Patent number: 4582922
    Abstract: A mixture of methyl anthranilate, dissolved in a water-miscible solvent, with a solution of formaldehyde is reduced in a hydrogen atmosphere in the presence of a hyrogenation catalyst at moderate temperatures and pressures to yield methyl N-methylanthranilate. The invention provides a process which is feasible towards producing the compound in commercial quantities in high purity and good yield.
    Type: Grant
    Filed: February 1, 1985
    Date of Patent: April 15, 1986
    Assignee: National Starch and Chemical Corporation
    Inventor: Eric A. Meier
  • Patent number: 4581461
    Abstract: Maleated aminophenoxysiloxanes are prepared by reacting diaminodiphenoxysiloxanes with maleic anhydride. In addition, the resultant maleamic acid derivatives may be cyclized yielding isomaleimide or maleimide siloxane derivatives.
    Type: Grant
    Filed: April 7, 1983
    Date of Patent: April 8, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Robert D. Rossi, Dilip K. Ray-Chaudhuri
  • Patent number: 4578302
    Abstract: Fiber reinforced tape laminates characterized by superior strength properties are prepared utilizing a hot melt pressure sensitive adhesive comprising a styrene-butadiene block or multi-block copolymer, a tackifying resin and an oil.
    Type: Grant
    Filed: June 27, 1985
    Date of Patent: March 25, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Robert C. Schmidt, Jr., Paul P. Puletti
  • Patent number: 4578444
    Abstract: Novel anaerobic curing compositions prepared containing polymerizable (meth)acrylate monomers, free radical initiators and, as a polymerizable activators therefor, monomeric disulfonimides.
    Type: Grant
    Filed: October 1, 1984
    Date of Patent: March 25, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Robert D. Rossi, Dilip K. Ray-Chaudhuri
  • Patent number: 4577031
    Abstract: Novel polymerizable imidazolidinone monomers, useful in the preparation of self-crosslinking polymers, have the general structure ##STR1## wherein R.sup.1 is H or a C.sub.1 -C.sub.6 linear or branched alkyl or hydroxyalkyl group; X is a divalent radical selected from the group consisting of ##STR2## with R being H or CH.sub.3, m being 0-5, and n being 1-5; R.sup.2 is H or CH.sub.3 ; R.sup.3 is H or ##STR3## with R' as defined above; and R.sup.4 and R.sup.5 are independently H or linear or branched C.sub.1 -C.sub.4 alkyl groups. In a preferred embodiment, aqueous emulsions of the imidazolidinone-containing polymers (e.g. 45-60% vinyl acetate, 34-52% butyl acrylate, and 3-6% imidazolidinone) and an acid-curing catalyst (e.g. ZnCl.sub.2) are used as formaldehyde-free binders for nonwoven textiles.
    Type: Grant
    Filed: March 22, 1985
    Date of Patent: March 18, 1986
    Assignee: National Starch and Chemical Corporation
    Inventors: Carmine P. Iovine, Joseph G. Palmer, James L. Walker