Patents Assigned to Nippon Shokubai Kagaku Kogyo Co., Ltd.
  • Patent number: 4939260
    Abstract: A process for producing aromatic or heterocyclic nitriles, which comprises reacting an alkyl-substituted aromatic hydrocarbon or an alkyl-substituted heterocyclic compound with ammonia and oxygen in the presence of a catalyst composition comprising (a) at least one composite oxide selected from the group consisting of a binary composite oxide comprising titanium and silicon, a binary composite oxide comprising titanium and zirconium and a ternary composite oxide comprising titanium, silicon and zirconium, and (b) an oxide of at least one metal selected from the group consisting of vanadium, molybdenum, tungsten, chromium, antimony, bismuth, phosphorus, niobium, iron, nickel, cobalt, manganese and copper.
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: July 3, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Akira Inoue, Mitsuaki Ikeda, Kunio Sano, Sadao Terui, Toshihide Kanzaki
  • Patent number: 4931521
    Abstract: A process for producing a resin having a high refractivve index which comprises radically polymerizing a material monomer, characterized in that said material monomer comprises [I] at least one polymerizable monomer selected from the group consisting of a polyfunctional thioacrylate and a polyfnctional thiomethacrylate (as an indispensable component), and optionally [II] at least one other polymerizable monomer which is radically polymerizable with said polymerizable monomer [I], a resin having a high refractive index produced by said process and optical materials, especially lenses and disk substrates prepared from said resin.
    Type: Grant
    Filed: October 3, 1988
    Date of Patent: June 5, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tatsuhito Matsuda, Yasuaki Funae, Masahiro Yoshida, Tsuguo Takaya
  • Patent number: 4927560
    Abstract: A method for the production of inorganic minute globular particles, which comprises forming a W/O type sol emulsion by mixing at least one metal oxide-containing sol selected from the group consisting of (a) metal oxide sols and (b) mixed sols containing said metal oxide sols and an inorganic compound, an alkoxide, or a sol of at least one other element with an organic solvent insoluble or sparingly soluble in water in the presence of a surfactant; mixing said emulsion with a basic substance or an electrolyte thereby converting the sol forming the water layer in said emulsion into gel thereby obtaining globular gel particles; and subsequently heating the globular gel particles thereby expelling from the system the water in the globular gel particles in the form of a mixture thereof with the organic solvent.
    Type: Grant
    Filed: February 24, 1988
    Date of Patent: May 22, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Shigemi Osaka, Kazuo Hata, Tsukasa Takahashi
  • Patent number: 4925981
    Abstract: A method of isolating and recovering methacrylic acid from a methacrylic acid-containing reaction product gas resulting from the vapor-phase catalytic oxidation of isobutylene, tertiary butanol or isobutyraldehyde, which comprises introducing the reaction product gas comprising methacrylic acid and various by-products including high boiling substances at a high temperature of 250.degree. to 300.degree. C. into a cooling zone, rapidly cooling the gas therein to a temperature of not more than 100.degree. C. to condense methacrylic acid and thus isolate methacrylic acid, while also converting the high boiling substances to fumes, thereafter introducing the cooled gas containing said fumes into a venturi scrubber, contacting it therein with an aqueous medium to remove said fumes, finally introducing the treated gas into a methacrylic acid-absorbing zone and absorbing methacrylic acid by absorption into an aqueous medium.
    Type: Grant
    Filed: January 16, 1987
    Date of Patent: May 15, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Noboru Shimizu, Hiroshi Yoshida, Hiromiki Daigo, Shoichi Matsumoto
  • Patent number: 4920202
    Abstract: A method for the production of a hydrophilic polymer having a small residual monomer content from a hydrated gel polymer, which method comprises drying said hydrated gel polymer by contact thereof with a gas containing at least steam and having a dew point in the range of 50.degree. to 100.degree. C. at a temperature in the range of 80.degree. C. to 250.degree. C., and a hydrophilic polymer obtained therefrom.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: April 24, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshio Irie, Kaoru Iwasaki, Takumi Hatsuda, Kazumasa Kimura, Nobuyuki Harada, Kunihiko Ishizaki, Tadao Shimomura, Teruaki Fujiwara
  • Patent number: 4916233
    Abstract: 4-Methyl-5-[(2-aminoethyl)-thiomethyl]-imidazole can be effectively produced by causing 4-methylimidazole or a salt thereof to react with at least one member selected from the group consisting of (a) a formaldehyde adduct of cysteamine, (b) 2-aminoethanethiol sulfuric acid and formaldehyde or a formaldehyde oligomer, and (c) thiazolidine or a salt thereof, in the presence of a mineral acid, removing a portion of reaction liquid out of the reaction system while maintaining molar concentration of 4-methyl-5-[(2-aminoethyl)-thiomethyl]-imidazole in the reaction system not exceeding 70 mol % based on total mol numbers of 4-methylimidazole and 4-methyl-5-[(2-aminoethyl)-thiomethyl]-imidazole, then separating a liquid containing 4-methyl-5-[(2-aminoethyl)-thiomethyl]-imidazole from the removed portion of reaction liquid, and recycling the remainder into the reaction system.
    Type: Grant
    Filed: April 25, 1989
    Date of Patent: April 10, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tsunemasa Ueno, Koichi Yamamoto, Masao Kitano, Yutaka Morimoto
  • Patent number: 4904633
    Abstract: A catalyst for purifying exhaust gas comprises a honeycomb carrier of monolithic structure and a coating layer deposited on the honeycomb carrier and formed with a catalyst composition containing a refractory inorganic oxide in the form of particles possessing and average particle diameter in the range of 0.5 to 20 microns, which refractory inorganic oxide has platinum and/or palladium and rhodium deposited thereon in high concentrations. This catalyst is produced by coating the honeycomb carrier with an aqueous slurry containing the catalyst composition and calcining the coated carrier.
    Type: Grant
    Filed: December 17, 1987
    Date of Patent: February 27, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tomohisa Ohata, Kazuo Tsuchitani, Eiichi Shiraishi, Shinya Kitaguchi
  • Patent number: 4898788
    Abstract: A thermosetting resin decorative laminated sheet faced with a resin-impregnated sheet layer obtained by impregnating a sheetlike material with a resin composition containing an amino resin (I) produced by the reaction of formaldehyde with an amino compound (A) having as an essential component thereof at least one carboguanamine (a) selected from the group consisting of cyclohexanecarboguanamine and norbornanecarboguanamine and curing the resultant impregnated sheetlike material excels in flexibility, crack resistance, light resistance, and chemical resistance. A decorative overlaid plywood enjoying similarly desirable properties is obtained by integrating the aforementioned sheet layer with a substrate.
    Type: Grant
    Filed: July 19, 1988
    Date of Patent: February 6, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Kenji Minami, Hidetaka Yatagai, Yoshinori Sano
  • Patent number: 4892856
    Abstract: A catalyst for use in the production of acrylic acid by catalytic gas phase oxidation of acrolein, comprising active substances represented by general formulaMo.sub.(a) V.sub.(b) A.sub.(c) B.sub.(d) C.sub.(e) D.sub.(f) O.sub.
    Type: Grant
    Filed: June 1, 1988
    Date of Patent: January 9, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tatsuya Kawajiri, Shinichi Uchida, Masahiro Wada
  • Patent number: 4880857
    Abstract: A carbon black-graft polymer, produced by causing a polymer possessing within the molecular unit thereof at least one reactive group selected from the class consisting of aziridine group, oxazoline group. N-hydroxyalkylamide group, epoxy group, and thioepoxy group to react with carbon black. The polymer can be used as a toner for electrostatically charged image, resin composition, coating composition, ink for thermographic transer, coating gent for magnetic recording medium, rubber composition, and carbon black dispersion and the like.
    Type: Grant
    Filed: December 16, 1987
    Date of Patent: November 14, 1989
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yoshikuni Mori, Mitsuo Kushino, Hayato Ikeda, Nobuaki Urashima, Masuji Izubayashi, Shigeru Tanimori, Yoshihiro Arita, Kiyoshi Kawamura, Kenji Minami, Yoshinori Sano
  • Patent number: 4873217
    Abstract: A catalyst used for producing, by catalytic gas phase oxidation of a C.sub.3 -C.sub.5 oelfin or tertiary alcohol, the corresponding unsaturated aldehyde and unsaturated carboxylic acid, said catalyst characterized by comprising molybdenum, iron and bismuth and having a specific surface area in the range from 1 to 20 m.sup.2 /gr, a pore volume in the range from 0.1 to 1.0 cc/gr and a pore diameter distribution in which the pore diameters are collectively distributed in the range of each of from 1 to 10 microns and from 0.1 to less than 1 micron; and a process for preparing said catalyst by charging an unfired material power into a centrifugal flow coating device to form particles having the average particle diameter of 2 to 10 mm and then firing the particles.
    Type: Grant
    Filed: February 17, 1988
    Date of Patent: October 10, 1989
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Tatsuya Kawajiri, Hideo Onodera, Shinichi Uchida, Yukio Aoki, Masahiro Wada
  • Patent number: 4871700
    Abstract: A method of reactivating a catalyst having reduced activity as a result of having been used in producing an unsaturated aldehyde as a main product by catalytic vapor-phase oxidation reaction of propylene, isobutylene or tertiary butanol, said catalyst being a catalytic oxide comprising molybdenum, bismuth and iron with a Mo:Fe atomic ratio of 12:at least 0.1. The method comprises heat-treating the used catalyst at a temperature of 300.degree. to 500.degree. C. in the presence of a flowing oxidizing gas containing at least 5% by volume of molecular oxygen and at least 0.1% by volume of steam.
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: October 3, 1989
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Shin-ichi Uchida, Kozi Deguchi, Masamitsu Sasaki
  • Patent number: 4866134
    Abstract: An electric metal foil-plated laminate sheet which is obtained by laminating a cured layer of a thermosetting resin composition with electroconductive foils, said thermosetting resin composition comprising 30-85% by weight of (A) a rubber-modified vinyl ester obtained by reacting,(a) an epoxy resin,(b) a carboxyl group containing rubbery polymer derived from a conjugated diene, and(c) at least one unsaturated monocarboxylic acid selected from the group consisting of acrylic acid and methacrylic acid to react one another in amounts such that, based on 100 parts by weight of (a) the epoxy resin, (b) the carboxyl group containing rubbery polymer accounts for a proportion in the range of 5 to 80 parts by weight and that the total number of carboxylic group contained in (b) the rubbery polymer and (c) the unsaturated monocarboxylic acid falls in the range of 1.3 to 1.5 per each of the epoxy groups contained in (a) the epoxy resin at a temperature of 90.degree. to 120.degree. C.
    Type: Grant
    Filed: April 21, 1988
    Date of Patent: September 12, 1989
    Assignees: Matsushita Electric Works, Ltd., Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Hidekazu Takano, Tetsuo Kunitomi, Shigehiro Okada, Toshio Awaji, Katsuaki Shindo, Daisuke Atobe
  • Patent number: 4854123
    Abstract: A method for the removal of nitrogen oxides from the exhaust gas of a diesel engine through catalytic reduction by the use of honeycomb catalyst in the presence of ammonia, which method comprises feeding ammonia into said exhaust gas proportionately to the product of the revolution number of said diesel engine multiplied by the torque of said diesel engine.
    Type: Grant
    Filed: January 27, 1988
    Date of Patent: August 8, 1989
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Motonobu Kobayashi, Futoru Kinoshita, Kiichiro Mitsui, Akira Inoue
  • Patent number: 4853486
    Abstract: In a method for the production of a dithiodialdehyde represented by the formula II: ##STR1## wherein R.sup.1 and R.sup.2 are independently alkyl group of 1 to 8 carbon atoms, by condensation of an active hydrogen-containing aldehyde represented by the formula I: ##STR2## wherein R.sup.1 and R.sup.2 have the same meanings as defined above, with sulfur monochloride, the improvement which comprises simultaneously supplying said active hydrogen-containing aldehyde and sulfur monochloride to an inactive solvent, or adding said active hydrogen-containing aldehyde to a mixture of said inactive solvent with the sulfur monochloride.
    Type: Grant
    Filed: June 7, 1988
    Date of Patent: August 1, 1989
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Masao Kitano, Tsunemasa Ueno, Kouichi Kojima, Yutaka Morimoto
  • Patent number: 4851547
    Abstract: A method for the production of a maleimide by dehydration and ring-closure of maleinamic acid obtained by the reaction of maleic anhydride with an amine, which method is characterized by effecting ring-closure imidation of said maleinamic acid by heating said maleinamic acid in a water-insoluble or water-immiscible inert organic non-polar solvent in the presence of a catalyst of an amine salt produced from the amine and an acid, a mixture of the amine salt and the acid, or a supported catalyst on a solid carrier the catalyst or the acid.
    Type: Grant
    Filed: December 23, 1988
    Date of Patent: July 25, 1989
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yuichi Kita, Koichi Nakagawa, Kentaro Sakamoto, Akio Fukui, Masao Baba, Yoichi Nakagawa
  • Patent number: 4841061
    Abstract: A process for producing a cyclic amine represented by the general formula ##STR1## wherein each of R and R' is selected from hydrogen, a methyl group and an ethyl group, and n is an integer of 2 to 5, which comprises vapor-phase intramolecular dehydration reaction of an alkanolamine represented by the general formula ##STR2## wherein R, R' and n are as defined above, said reaction being carried out in the presence of, as a catalyst, an oxide composition represented by the following formulaX.sub.a P.sub.b Y.sub.c O.sub.dwherein X is at least one element selected from transition metal elements of Groups I through VIII, lanthanide elements, actinide elements and elements of Group IIIA in the periodic table, Si, Ge, Sn, Pb, Sb and Bi, P is phosphorus, Y is at least one element selected from alkali metal elements and alkaline earth metal elements, O is oxygen, the suffixes a, b, c and d are the atomic ratios of the elements X, P, Y and O respectively, and when a=1, b=0.01-6, preferably 0.
    Type: Grant
    Filed: November 30, 1987
    Date of Patent: June 20, 1989
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Yuuji Shimasaki, Michio Ueshima, Hideaki Tuneki, Kimio Ariyoshi
  • Patent number: 4840749
    Abstract: A process for producing 1-aminoanthraquinone, which comprises(a) a step of oxidizing 1-nitronaphthalene in the liquid phase with an acidic aqueous solution containing a ceric ion as an oxidizing agent and separating crystals containing 5-nitro-1,4-naphthoquinone and the acidic aqueous solution containing a cerium ion from the resulting reaction mixture,(b) a step of subjecting the 5-nitro-1,4-naphthoquinone obtained in step (a) to Diels-Alder reaction with 1,3-butadiene in a solvent, precipitating crystals containing the resulting 5-nitro-1,4,4a,9a-tetrahydroanthraquinone, separating them by filtration, separating and recovering the unreacted 1-nitronaphthalene and the solvent in the filtrate in a separation tower, and recycling 1-nitronaphthalene to step (a) for use as the starting material and re-using the recovered solvent for the Diels-Alder reaction,(c) a step of reducing 5-nitro-1,4,4a,9a-tetrahydroanthraquinone obtained in step (b), separating crystals containing 1-aminoanthraquinone and purifying them
    Type: Grant
    Filed: June 16, 1987
    Date of Patent: June 20, 1989
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Noriaki Ikeda, Noboru Sugishima, Yasushi Fujii, Shinji Ikuta, Yoshiyuki Nakanishi, Akira Inoue
  • Patent number: 4841060
    Abstract: Catalytic vapor phase intramolecular dehydration reaction of an alkanolamine represented by the general formula ##STR1## wherein each of R and R' is selected from hydrogen, a methyl group and an ethyl group, and n is an integer of 2 to 5, to convert it into a cyclic amine represented by the general formula ##STR2## wherein R, R' and n are as defined above. The catalyst is an oxide composition represented by the following formulaSi.sub.a X.sub.x Y.sub.y O.sub.bwherein Si is silicon, X is at least one element selected from alkali metals and alkaline earth metals, Y is at least one element selected from B, Al, Ti, Zr, Sn, Zn and Ce, and O is oxygen; and the suffixes a, x, y and b represent the atomic ratios of the elements Si, X, Y and O respectively, and when a=1, x=0.0005-1 and y=0-1, and b is a value determined by a, x and y.
    Type: Grant
    Filed: April 15, 1988
    Date of Patent: June 20, 1989
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Youichi Hino, Yuuji Shimasaki, Michio Ueshima
  • Patent number: 4837280
    Abstract: A thermosetting resin composition of highly satisfactory storage stability comprises 100 parts by weight of a thermosetting resin composition, 0.0001 to 2.0 parts by weight of a thiuram compound possessing at least one atomic group represented by the following formula: ##STR1## wherein p stands for an integer in the range of 1 to 8, and 0.00001 to 0.1 part by weight (as copper metal) of a copper-containing compound.
    Type: Grant
    Filed: September 23, 1987
    Date of Patent: June 6, 1989
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Toshio Awaji, Kenichi Ueda, Daisuke Atobe