Abstract: A method of converting one or more alkanes to one or more alkenes that includes a) providing a first stream containing one or more alkanes and oxygen to an oxidative dehydrogenation reactor; b) converting at least a portion of the one or more alkanes to one or more alkenes in the oxidative dehydrogenation reactor to provide a second stream exiting the oxidative dehydrogenation reactor containing one or more alkanes, one or more alkenes, oxygen, carbon monoxide and optionally acetylene; and c) providing the second stream to a second reactor containing a catalyst that includes a group 11 metal to convert a least a portion of the carbon monoxide to carbon dioxide and reacting the acetylene.

Abstract: Multilayer Films have a first skin layer that is prepared from a high density polyethylene and a second skin layer (also referred to as the sealant layer) that is prepared from a linear low density polyethylene (LLDPE) having a density of from 0.90 to 0.92 g/cc and a Dilution Index, Yd, of greater than 0°. Seals can be prepared by placing two pieces of this film against each other such that the sealant layers are in contact with each other, then applying heat to at least one high density skin layer such that heat is transmitted/conducted through the multilayer film in a sufficient amount to melt the sealant layer and form a seal. The use of LLDPE having a Dilution Index of greater than 0° has been found to improve the sealing performance of multilayer films in comparison to multilayer films where the sealant layer is a conventional LLDPE having a Dilution Index of less than 0°.

Abstract: Disclosed are methods and conditions for manufacturing a polyethylene polymer or copolymer in a liquid/liquid biphasic non-adiabatic reaction, and the compositions and articles made therefrom.

Abstract: A heat exchanger that is fabricated with high nickel metal alloys provides enhanced corrosion resistance when in contact with fluids that are reducing and contain metal chlorides. In an embodiment, this type of heat exchanger is used in the recovery section of a solution polymerization process.

Abstract: A method for altering the melt flow ratio (MFR) of ethylene copolymers made in a gas phase reactor using a supported Ziegler-Natta catalyst treated with a catalyst modifier. The method involves changing the amount of the catalyst modifier added to the supported Ziegler-Natta polymerization catalyst to effect changes in the MFR of the resulting polymer.

Abstract: The present invention provides a transfer line exchanger which is optimized for one or more objective functions of interest such as pressure drop, erosion rate, fouling, coke deposition and operating costs. The transfer line exchanger is designed by computer modeling a transfer line exchanger in which the cross section of flow path is substantially circular and modeling the operation of the transfer line under industrial conditions to validate the model design and its operation. Then iteratively the model design is deformed and the operation of the deformed part is modeled and compared to values obtained with other deformed models until the value of the objective function is optimized (e.g. at an extreme) or the change in the objective function is approaching zero.

Abstract: A substantially linear ceramic or metallic radiant of ellipsoidal or polygonal cross section is placed proximate furnace tubes or coils in the radiant section of a fired heater to increase the radiant heat directed to the surface of the tubes or coils.

Abstract: This disclosure relates to an improved continuous solution polymerization process wherein production rate is increased. Process solvent, ethylene, optional comonomers, optional hydrogen and a bridged metallocene catalyst formulation are injected into a first reactor to form a first ethylene interpolymer. Optionally, process solvent, ethylene, optional comonomers, optional hydrogen and a bridged metallocene catalyst formulation are injected into a second reactor forming a second ethylene interpolymer. The first and second reactors may be configured in series or parallel modes of operation. Optionally, a third ethylene interpolymer is formed in a third reactor, wherein a homogeneous catalyst formulation or a heterogeneous catalyst formulation is employed. In solution, the first, optional second and optional third ethylene interpolymers are combined, the catalyst is deactivated, the solution is optionally passivated and following a phase separation process an ethylene interpolymer product is recovered.

Abstract: A multilayer film having Machine Direction Orientation (MDO) is prepared by first co-extruding a multilayer film, then stretching the multilayer film in the machine direction at a temperature lower than the melting point of the polyethylene resin that is used to prepare the film. At least one layer of the film is a first polyethylene composition having a density of from about 0.94 to about 0.97 g/cc and at least one second layer is prepared from a polyethylene composition having a lower density than the first polyethylene composition. This disclosure enables the manufacture of films having outstanding barrier properties (low Water Vapor Transmission Rate, WVTR, and low Oxygen Transmission Rate, OTR) and good physical properties.

Abstract: A continuous solution polymerization process is disclosed wherein at least two catalyst formulations are employed. A first homogeneous catalyst formulation is employed in a first reactor to produce a first ethylene interpolymer and a first heterogeneous catalyst formulation is employed in a second reactor to produce a second ethylene interpolymer. Optionally a third ethylene interpolymer is formed in a third reactor. The resulting ethylene interpolymer products possess desirable properties in a variety of end use applications, for example in film applications. A means for increasing the molecular weight of the first ethylene interpolymer is disclosed and/or a means for increasing the temperature of the first reactor, relative to a third homogeneous catalyst formulation. A means for reducing the (?-olefin/ethylene) weight ratio in the first reactor is disclosed and/or reducing the density of the first ethylene interpolymer, relative to a third homogeneous catalyst formulation.

Abstract: This disclosure relates to ethylene interpolymer compositions. Specifically, ethylene interpolymer products having: a Dilution Index (Yd) greater than 0; total catalytic metal ?3.0 ppm; ?0.03 terminal vinyl unsaturations per 100 carbon atoms, and; optionally a Dimensionless Modulus (Xd) greater than 0. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.869 to about 0.975 g/cm3, a polydispersity (Mw/Mn) from about 2 to about 25 and a CDBI50 from about 20% to about 97%. Further, the ethylene interpolymer products are a blend of at least two ethylene interpolymers; where one ethylene interpolymer is produced with a single-site catalyst formulation and at least one ethylene interpolymer is produced with a heterogeneous catalyst formulation.

Abstract: Oxidative dehydrogenation catalysts comprising MoVNbTeO having improved consistency of composition and a 25% conversion of ethylene at less than 420° C. and a selectivity to ethylene above 95% are prepared by treating the catalyst precursor with H2O2 in an amount equivalent to 0.30-2.8 mL H2O2 of a 30% solution per gram of catalyst precursor prior to calcining.

Abstract: Rotomolded polyethylene containers that are used to store sulfuric acid can become discolored on the interior surface which is in contact with the acid. This problem may be mitigated by the use of an additive package that contains two primary antioxidants.

Abstract: Provided in this disclosure are organometallic complexes that contain i) a metal atom selected from Hf and Zr; 2) a phosphinimine ligand; 3) an amido-ether ligand and at least one other ancillary ligand. The use of such a complex, in combination with an activator, as an olefin polymerization catalyst is demonstrated. The catalysts are effective for the copolymerization of ethylene with an alpha olefin (such as 1-butene, 1-hexene, or 1-octene) and enable the production of high molecular weight copolymers (Mw greater than 25,000) with good comonomer incorporation at high productivity.

Abstract: Incorporating into a fixed bed reactor for an exothermal reaction having a catalyst supported on a support having a thermal conductivity typically less than 30 W/mk within the reaction temperature control limits heat dissipative particles having a thermal conductivity of at least 50 W/mk less than 30 W/mk within the reaction temperature control limits helps control the temperature of the reactor bed.

Abstract: The disclosure provides an ethylene copolymer having a density of from 0.912 g/cm3 to 0.925 g/cm3, a melt flow ratio (I21/I2) of from 20 to 30, and a normal comonomer distribution profile in a GPC-FTIR analysis, wherein the normal comonomer distribution profile has a slope of from ?3.5 to ?7.5, where the slope is defined as the number of short chain branches per 1000 carbons at a molecular weight of 300,000 minus the number of short chain branches per 1000 carbons at a molecular weight of 30,000. The ethylene copolymers have improved bulk density and when made into film, provide good physical properties.

Abstract: Provided herein is a unidirectional blow down system for a high-pressure tubular reactor with a hyper that minimizes the tube wall metal temperature during a decomposition event wherein the system prevents the reactor walls from reaching a temperature capable of causing the tube metal to austenize. Also provided are methods of designing and methods of operating a unidirectional blowdown system.

Abstract: A continuous solution polymerization process is disclosed wherein at least two catalyst formulations are employed. A first homogeneous catalyst formulation is employed in a first reactor to produce a first ethylene interpolymer and a first heterogeneous catalyst formulation is employed in a second reactor to produce a second ethylene interpolymer. Optionally a third ethylene interpolymer is formed in a third reactor. The resulting ethylene interpolymer products possess desirable properties in a variety of end use applications, for example in film applications. A means for increasing the molecular weight of the first ethylene interpolymer is disclosed and/or a means for increasing the temperature of the first reactor, relative to a third homogeneous catalyst formulation. A means for reducing the (?-olefin/ethylene) weight ratio in the first reactor is disclosed and/or reducing the density of the first ethylene interpolymer, relative to a third homogeneous catalyst formulation.

Abstract: The preparation of an oxidative dehydrogenation catalyst comprising Mo, V, Nb and Te using a hydrothermal step. In some embodiments, the activity and reproducibility of the catalyst is improved by conducting the hydrothermal step while permitting gaseous products to leave the reactor. In some instances a condenser may be upstream of the outlet of the reactor.

Abstract: A multilayer film having Machine Direction Orientation (MDO) is prepared by first co-extruding a multilayer film, then stretching the multilayer film in the machine direction at a temperature lower than the melting point of the polyethylene resin that is used to prepare the film. At least one layer of the film is a first polyethylene composition having a density of from about 0.94 to about 0.97 g/cc and at least one second layer is prepared from a polyethylene composition having a lower density than the first polyethylene composition. This disclosure enables the manufacture of films having outstanding barrier properties (low Water Vapor Transmission Rate, WVTR, and low Oxygen Transmission Rate, OTR) and good physical properties.